2016-01-2488 - Pravilnik o izdelavi ocene odpadka pred odlaganjem in ocene nevarnega odpadka pred sežiganjem ter o izvedbi kontrolne kemične analize odpadkov

This document specifies a method for the determination of the elements aluminium, antimony, arsenic,
barium, beryllium, bismuth, boron, cadmium, caesium, calcium, cerium, chromium, cobalt, copper,
dysprosium, erbium, gadolinium, gallium, germanium, gold, hafnium, holmium, indium, iridium, iron,
lanthanum, lead, lithium, lutetium, magnesium, manganese, mercury, molybdenum, neodymium, nickel,
palladium, phosphorus, platinum, potassium, praseodymium, rubidium, rhenium, rhodium, ruthenium,
samarium, scandium, selenium, silver, sodium, strontium, terbium, tellurium, thorium, thallium,
thulium, tin, titanium, tungsten, uranium and its isotopes, vanadium, yttrium, ytterbium, zinc and
zirconium in water (e.g. drinking water, surface water, ground water, waste water and eluates).
Taking into account the specific and additionally occurring interferences, these elements can be
determined in water and digests of water and sludge (e.g. digests of water as described in ISO 15587-1
or ISO 15587-2).
The working range depends on the matrix and the interferences encountered. In drinking water and
relatively unpolluted waters, the limit of quantification (LOQ) lies between 0,002 μg/l and 1,0 μg/l for
most elements (see Table 1). The working range typically covers concentrations between several ng/l
and mg/l depending on the element and specified requirements.
The quantification limits of most elements are affected by blank contamination and depend
predominantly on the laboratory air-handling facilities available on the purity of reagents and the
cleanliness of glassware.
The lower limit of quantification is higher in cases where the determination suffers from interferences
(see Clause 5) or memory effects (see ISO 17294-1).
Elements other than those mentioned in the scope can also be determined according to this document
provided that the user of the document is able to validate the method appropriately (e.g. interferences,
sensitivity, repeatability, recovery).

This document specifies Procedure A, using manual glass viscometers, and Procedure B, using glass capillary viscometers in an automated assembly, for the determination of the kinematic viscosity, ν, of liquid petroleum products, both transparent and opaque, by measuring the time for a volume of liquid to flow under gravity through a calibrated glass capillary viscometer. The dynamic viscosity, η, is obtained by multiplying the measured kinematic viscosity by the density, ρ, of the liquid. The range of kinematic viscosities covered in this test method is from 0,2 mm2/s to 300 000 mm2/s over the temperature range –20 °C to +150 °C. The products it is applicable to contain kerosene, diesel fuels, biodiesel fuels, and biodiesel fuel blends.

This document is applicable to single and double leaf, hinged and pivoted doorsets with timber-based leaves or timber framed glazed door leaves, covered by EN 15269-3 and / or EN 15269-20.
This document prescribes the methodology for extending the application of test results obtained from durability of self-closing test(s) conducted in accordance with EN 1191 and or EN 12605:2000, as appropriate.
Subject to the completion of the appropriate self-closing test(s), the extended application can cover all or some of the following examples:
-   door leaf; pass doors;
-   glazed doorsets including vision panels and framed glazed doorsets;
-   side, transom and/or overpanels;
-   ventilation grilles and/or louvres;
-   wall or ceiling fixed elements (door frame/suspension system);
-   glazing for door leaf, side, transom and flush over panels;
-   items of building hardware;
-   decorative finishes;
-   intumescent, strips, smoke, draught or acoustic seals;
-   alternative supporting construction(s).

This document covers steel rolling shutters as covered by EN 15269 10 or EN 15269 20.
This document prescribes the methodology for extending the application of test results obtained from durability self-closing test(s) conducted in accordance with EN 16034.
Subject to the completion of the appropriate self-closing test or tests, the extended application could cover all or some of the following non-exhaustive list:
—   shutter curtain;
—   wall/ceiling fixed elements (frame/suspension system);
—   decorative finishes;
—   intumescent, smoke, draught or acoustic seals;
—   alternative supporting construction(s).

This document is applicable to the following types of steel based doorsets: horizontally sliding single and double leaf doorsets, horizontally sliding single and double leaf telescopic doorsets, vertically sliding single leaf doorsets and vertically sliding single leaf telescopic doorsets as covered by EN 15269-7 or EN 15269-20.
This document prescribes the methodology for extending the application of test results obtained from durability of self-closing test(s) conducted in accordance with EN 12605:2000 and/or EN 1191.
Subject to the completion of the appropriate durability of self-closing test or tests, the extended application can cover all or some of the following non-exhaustive list:
- door leaf (of the sliding doorset and its pass door);
- integrated pass doors;
- wall or ceiling fixed parts or items of the doorset, e.g. frame or suspension systems;
- ventilation grilles and/or louvres;
- glazing for door leaf;
- items of building hardware;
- decorative finishes;
- intumescent, smoke, draught or acoustic seals;
- alternative supporting construction(s).

This document specifies different methods for quantitative determination of 16 polycyclic aromatic hydrocarbons (PAH) (see Table 2) in soil, sludge, treated biowaste, and waste, using GC-MS or HPLC-UV-DAD/FLD covering a wide range of PAH contamination levels (see Table 2).
NOTE   The method can be applied to sediments provided that validity is demonstrated by the user.
When using fluorescence detection, acenaphthylene cannot be measured.
[Table 2 -Target analytes of this document]
The limit of detection depends on the determinants, the equipment used, the quality of chemicals used for the extraction of the sample and the clean-up of the extract.
Under the conditions specified in this document, the lower limit of application from 10 μg/kg (expressed as dry matter) for soils, sludge and biowaste to 100 μg/kg (expressed as dry matter) for solid waste can be achieved. For some specific samples (e.g. bitumen) the limit of 100 μg/kg cannot be reached.
Sludge, waste and treated biowaste can differ in properties as well as in the expected contamination levels of PAH and presence of interfering substances. These differences make it impossible to describe one general procedure. This document contains decision tables based on the properties of the sample and the extraction and clean-up procedure to be used.
The method can be applied to the analysis of other PAH not specified in the scope, provided suitability is proven by proper in-house validation experiments.
Sampling is not part of this standard. In dependence of the materials, the following standards need to be considered, e.g. EN 14899, ISO 5667-12 and EN ISO 5667-13.

This document covers single and double leaf, hinged and pivoted, steel based doorsets as covered by EN 15269-2 and/or EN 15269-20.
This document prescribes the methodology for extending the application of test results obtained from durability of self-closing test(s) conducted in accordance with EN 1191 and or EN 12605:2000, as appropriate.
Subject to the completion of the appropriate durability of self-closing test(s), the extended application can cover all or some of the following non-exhaustive list:
- door leaf;
- side, transom and/or overpanels;
- ventilation grilles and/or louvres;
- wall or ceiling fixed parts or items of the doorset, e.g. frame or suspensions systems;
- glazing for door leaf, side, transom and flush over panels;
- items of building hardware;
- decorative finishes;
- intumescent strips, smoke, draught or acoustic seals;
- alternative supporting construction(s).

This document specifies two methods for the determination of total organic carbon (TOC) in sludge, treated biowaste, soil and waste samples containing more than 0,1 % carbon in relation to the dry mass (dm).
NOTE   This method can also be applied to other environmental solid matrices, provided the user has verified the applicability.

This document specifies an instrumental method for the routine determination of pH within the range pH 2 to pH 12 using a glass electrode in a 1:5 (volume fraction) suspension of soil, sludge and treated biowaste in either water (pH in H2O), in 1 mol/l potassium chloride solution (pH in KCl) or in 0,01 mol/l calcium chloride solution (pH in CaCl2).
This document is applicable to all types of air-dried soil and treated biowaste samples.
NOTE       For example, pretreated in accordance with ISO 11464 or EN 16179 or EN 15002.

This document specifies a method for the determination of the loss on ignition (LOI) at 550 °C. The dry matter is determined according to EN 15934.
This method applies to the determination of loss on ignition of sediment, sludge, treated biowaste, soil and waste.
NOTE   The loss on ignition is often used as an estimate for the content of organic matter in the sample. Inorganic substances or decomposition products (e.g. H2O, CO2, SO2, O2) are released or absorbed and some inorganic substances are volatile under the reaction conditions.

This document is applicable to single and double leaf, hinged and pivoted metal framed, glazed doorsets or openable windows as covered by EN 15269 5 or EN 15269 20.
This document prescribes the methodology for extending the application of test results obtained from durability of self-closing test(s) conducted in accordance with EN 1191.
Subject to the completion of the appropriate self-closing test(s), the extended application can cover all or some of the following non-exhaustive list:
-   doorsets and openable windows;
-   door or window leaves;
-   wall or ceiling fixed elements (frame or suspension system);
-   glazing and non-glazed panels in doorset and openable window, side, transom and/or overpanels;
-   items of building hardware;
-   decorative finishes;
-   intumescent, smoke, draught or acoustic seals;
-   alternative supporting construction(s).

This document specifies the determination of total content of carbon, hydrogen, nitrogen and sulfur in solid recovered fuels by instrumental method. Depending on the amount of test portion, micro or macro instrumental apparatus are used.
This method is applicable for concentrations on dry matter basis of C > 0,1 %, N > 0,1 %, H > 0,1 % and S > 0,05 %.

This document specifies three methods for the digestion of soil, treated biowaste, sludge and waste by the use of an acid mixture composed of hydrochloric (HCl), nitric (HNO3) and tetrafluoroboric (HBF4) or hydrochloric (HCl), nitric (HNO3) and hydrofluoric (HF) acid as the digestion solution.
Digestion with these acids is effectively considered as a total decomposition of the sample. For a broad range of samples the extracted analyte concentrations will reflect the total content in the sample.
This document is applicable for the following elements:
Aluminium (Al), antimony (Sb), arsenic (As), barium (Ba), beryllium (Be), cadmium (Cd), calcium (Ca), chromium (Cr), cobalt (Co), copper (Cu), iron (Fe), lead (Pb), magnesium (Mg), manganese (Mn), mercury (Hg), molybdenum (Mo), nickel (Ni), phosphorus (P), potassium (K), selenium (Se), silver (Ag), sodium (Na), strontium (Sr), sulfur (S), tellurium (Te), thallium (Tl), tin (Sn), titanium (Ti), vanadium (V), and zinc (Zn).
This document can also be applied for the digestion of other elements, provided the user has verified the applicability.

This document summarizes methods for the determination of the parameters pH, ammonium, AOX, As, Ba, Cd, Cl-, easily liberatable cyanide, Co, Cr, Cr(VI), Cu, DOC/TOC, electrical conductivity, F-, Hg, Mo, Ni, NO2-, Pb, phenol index, total S, Sb, Se, SO42-, TDS, V and Zn in aqueous eluates for the characterization of waste.

ISO/IEC 17025:2017 specifies the general requirements for the competence, impartiality and consistent operation of laboratories.
ISO/IEC 17025:2017 is applicable to all organizations performing laboratory activities, regardless of the number of personnel.
Laboratory customers, regulatory authorities, organizations and schemes using peer-assessment, accreditation bodies, and others use ISO/IEC 17025:2017 in confirming or recognizing the competence of laboratories.

This standard specifies a combustion method for the determination of halogen and sulfur contents in materials by combustion in a closed system containing oxygen (calorimetric bomb), and the subsequent analysis of the combustion product using different analytical techniques.
This method is applicable to solid, pasty and liquid samples containing more than 0,025 g/kg of halogen and/or 0,025 g/kg of sulfur content. The limit of detection depends on the element, the matrix and the determination technique used.
Insoluble halides and sulphate present in the sample or produced during the combustion step are not completely determined by these methods.

ISO 22155:2016 specifies a static headspace method for quantitative gas chromatographic determination of volatile aromatic and halogenated hydrocarbons and selected aliphatic ethers in soil.
ISO 22155:2016 is applicable to all types of soil.
The limit of quantification is dependent on the detection system used and the quality of the methanol grade used for the extraction of the soil sample.
Under the conditions specified in this International Standard, the following limits of quantifications apply (expressed on basis of dry matter).
Typical limit of quantification when using GC-FID:
-   volatile aromatic hydrocarbons: 0,2 mg/kg;
-   aliphatic ethers as methyl tert.-butyl ether(MTBE) and tert.-amyl methyl ether (TAME): 0,5 mg/kg.
Typical limit of quantification when using GC-ECD:
-   volatile halogenated hydrocarbons: 0,01 mg/kg to 0,2 mg/kg.
Lower limits of quantification for some compounds can be achieved by using mass spectrometry (MS) with selected ion detection (see Annex D).

This European Standard is applicable for the preparation of representative test portions from the laboratory sample that has been taken according to the sampling plan (EN 14899), prior to physical and/or chemical analysis (e.g. preparation of eluates, extractions, digestion and/or analytical determinations) of solid (including monolithic material) and liquid samples and sludge. It is also applicable for the preparation of test portions from digests and eluates for the subsequent analyses.
This European Standard is intended to find the correct sequence of operations and treatments to be applied to the laboratory sample in order to obtain suitable test portions in compliance with the specific requirements defined in the corresponding analytical procedures.

This Technical Specification specifies a simplified method for the determination of the gross calorific value of waste at constant volume and at the reference temperature of 25 °C in a bomb calorimeter calibrated by combustion of certified benzoic acid. This Technical Specification does not include thermo-chemical corrections.
This Technical Specification also specifies a simplified calculation of the net calorific value from the gross calorific value.
This Technical Specification is applicable for the evaluation of suitability of waste to be treated by thermal processes and for the energy to be recovered.
This Technical Specification is applicable to all kinds of waste.

ISO 12846:2012 specifies two methods for the determination of mercury in drinking, surface, ground, rain and waste water after appropriate pre-digestion. For the first method, an enrichment step by amalgamation of the Hg on, for example, a gold/platinum adsorber is used. For the second method, the enrichment step is omitted.
The choice of method depends on the equipment available, the matrix and the concentration range of interest. Both methods are suitable for the determination of mercury in water. The method with enrichment commonly has a practical working range from 0,01 µg/l to 1 µg/l. The mean limit of quantification (LOQ) reported by the participants of the validation trial was 0,008 µg/l. This information on the LOQ gives the user of ISO 12846:2012 an orientation and does not replace the estimation of performance data from laboratory specific data. It has to be considered that it is possible to achieve lower LOQs with specific instrumentation (e.g. single mercury analysers).
The method without enrichment commonly has a practical working range starting at 0,05 µg/l. The LOQ reported by the participants of the validation trial was 0,024 µg/l. It is up to the user, based on the specific application, to decide whether higher concentrations are determined by omitting the enrichment step and/or by diluting the sample(s). The sensitivity of both methods is dependent on the selected operating conditions.
Another possibility for the determination of extremely low Hg concentrations down to 0,002 µg/l without pre-concentration is the application of atomic fluorescence spectrometry (see ISO 17852). Specific atomic-absorption mercury analysers allow determinations down to 0,010 µg/l without pre-concentration.
In general, the determination of trace concentrations of Hg by AAS (or AFS) is dependent on clean operating conditions in the laboratory and on the use of high-purity chemicals with negligible low-Hg blanks.
Note that ISO 12846:2012 may be applied to industrial and municipal waste water after an additional digestion step performed under appropriate conditions and after suitable method validation. A potential sample stability issue (mercury loss) for anaerobic reducing industrial effluents has to be considered thoroughly.

ISO 11885:2007 specifies a method for the determination of dissolved elements, elements bound to particles ("particulate") and total content of elements in different types of water (e.g. ground, surface, raw, potable and waste water) for the following elements: aluminium, antimony, arsenic, barium, beryllium, bismuth, boron, cadmium, calcium, chromium, cobalt, copper, gallium, indium, iron, lead, lithium, magnesium, manganese, molybdenum, nickel, phosphorus, potassium, selenium, silicon, silver, sodium, strontium, sulfur, tin, titanium, tungsten, vanadium, zinc and zirconium.
Taking into account the specific and additionally occurring interferences, these elements can also be determined in digests of water, sludges and sediments (for example, digests of water as specified in ISO 15587‑1 or ISO 15587‑2). The method is suitable for mass concentrations of particulate matter in waste water below 2 g/l. The scope of this method may be extended to other matrices or to higher amounts of particulate matter if it can be shown that additionally occurring interferences are considered and corrected for carefully. It is up to the user to demonstrate the fitness for purpose.

This Technical Report describes techniques for sampling liquid and granular waste material, including paste-like materials and sludges, found in a variety of locations. The Technical Report provides information to allow the selection and preparation of equipment and apparatus to be used in the sampling activity.
NOTE 1   This Technical Report provides a shop shelf of example sampling techniques that can be selected to meet a wide range of sampling situations. For a specific situation one of the presented procedures may be appropriate.
NOTE 2    The procedures listed in this Technical Report reflect current best practice, but these are not exhaustive and other procedures may be equally relevant.

This Technical Report describes procedures for reducing the overall size of the waste materials in the field to aid practical transportation of a sample to the laboratory.
NOTE 1   This Technical Report provides a shop shelf of example sampling techniques that can be selected to meet a wide range of sampling situations. For a specific situation one of the presented procedures may be appropriate.
NOTE 2   The procedures listed in this Technical Report reflect current best practice, but these are not exhaustive and other procedures may be equally relevant.

This Technical Report discusses the statistical principles of sampling, and provides a number of statistical tools to assist in the design of testing programmes for application to sampling under various conditions.
NOTE 1   Given the great variety of waste types, sampling situations and objectives, this Technical Report cannot provide definitive instructions that cover all scenarios. Instead, it discusses the basic statistical approach to be followed, and provides statistical tools that can be applied to determine the amount and type of sampling (e.g. number of samples and sample size) in any given situation to achieve results of adequate reliability (i.e. precision and confidence).
NOTE 2   The document provides considerable detail on current best practice, but is not exhaustive.
NOTE 3   To clarify the text, the document provides a number of worked examples.

This Technical Report provides guidance on process of defining of a Sampling Plan based on the objective of the testing programme. It specifically deals with the strategic decisions that are needed, based on the sampling objective.
NOTE 1   Given the great variety of waste types, sampling situations and objectives, this Technical Report cannot provide definitive instructions that cover all scenarios. Instead, it discusses the basic statistical approach to be followed, and provides statistical tools that can be applied to determine the amount and type of sampling (e.g. number of samples and sample size) in any given situation to achieve results of adequate reliability (i.e. precision and confidence).
NOTE 2    The document provides considerable detail on current best practice, but is not exhaustive.
NOTE 3   To clarify the text, the document provides a number of worked examples.

This Technical Report describes procedures for the packaging, preservation, short-term storage and transport of both solid and liquid waste samples, including paste-like substances and sludges. Where available and appropriate for field application, requirements for specific storage conditions and/or preservation methods should be selected from the chosen analytical standard and collaboration with the testing laboratory.
NOTE 1   This Technical Report provides a shop shelf of example sampling techniques that can be selected to meet a wide range of sampling situations. For a specific situation one of the presented procedures may be appropriate.
NOTE 2   The procedures listed in this Technical Report reflect current best practice, but these are not exhaustive and other procedures may be equally relevant.

This Technical Specification is applicable to determine the acid and/or base neutralization capacity of a material. The property is expressed in mol/kg. This Technical Specification is a parameter specific test as specified in EN 12920. The application of this test method alone is not sufficient for the determination of the detailed leaching behaviour of a waste under specified conditions. The property allows assessing the final pH of mixed waste as well as consequences of external influences (carbonation, oxidation) on the pH of a waste.
NOTE   This generally requires the application of several test methods, behavioral modeling and model validation as specified in EN 12920.

This European Standard specifies the procedural steps to be taken in the preparation and application of a Sampling Plan. The Sampling Plan describes the method of collection of the laboratory sample necessary for meeting the objective of the testing programme. The principles or basic rules outlined in this European Standard, provide a framework that can be used by the project manager to:
   produce standardised Sampling Plans for use in regular or routine circumstances (elaboration of daughter/derived standards dedicated to well defined sampling scenarios);
   incorporate the specific sampling requirements of European and national legislation;
   design and develop a Sampling Plan for use on a case by case basis.
This European Standard has been developed for the characterization of waste.
There may be a need for more than one Sampling Plan to meet all the requirements of the testing programme. Ultimately the Sampling Plan provides the sampler with detailed instructions on how sampling should be carried out.
NOTE   Although this European Standard in most cases refers to the taking of one sample or increment or the preparation of one laboratory sample, it should be noted that often this should be more than one. For simplicity reasons this European Standard uses singular terms, while plural terms are also possible or even likely.

This document specifies a method for the quantitative determination of the hydrocarbon content (C10 to C40) in solid waste by gas chromatography.
It is applicable to hydrocarbon content between 100 mg/kg and 10 000 mg/kg expressed as dry matter basis.
Using this standard all hydrocarbons with a boiling range of approximately 175 °C to 525 °C, e.g. n-alkanes from C10H22 to C40H82, isoalkanes, cycloalkanes, alkyl benzenes, alkyl naphthalenes and polycyclic aromatic compounds are determined as hydrocarbons, provided they do not adsorb on the Florisil column during clean-up. Volatile hydrocarbons cannot be quantitatively determined using this standard. This will affect the determination of some common hydrocarbon fuels, e.g. petrol.
NOTE 1   On the basis of the peak pattern of the gas chromatogram (see Annex A) and of the boiling points of the individual n alkanes listed in Annex B the approximate boiling range of the hydrocarbons and some qualitative information on the nature of the hydrocarbons can be obtained.
NOTE 2   At the moment there is no sufficient information on how to handle organic liquid wastes for the analysis of hydrocarbons.
NOTE 3   Aqueous liquid waste samples can be analysed in accordance with EN ISO 9377-2 or the procedure specified in Annex E.
NOTE 3   Aqueous liquid waste samples can be analysed according to EN ISO 9377-2 or the procedure specified in annex E.

This part of the European Standard specifies a compliance test providing information on leaching of granular wastes and sludges under the experimental conditions specified hereafter, and particularly a liquid to solid ratio of 10 l/kg dry matter. It applies to waste which has a particle size below 10 mm without or with limited size reduction. Note: In some cases, it could be useful to test the material with coarser particles up to 40 mm in diameter: This requires a larger amount for material and liquid.

This Technical Report specifies a laboratory method of determining the pentachlorophenol content of wood. The method is applicable to all types of PCP- treated wood and wood-based materials as well as for the analysis of waste timber with respect to its PCP content.
The method has a quantification limit corresponding to 100 µg PCP per kilogram of wood material expressed as dry matter. The method described has a measurement range up to PCP contents of 25 mg/kg of dry matter. These figures refer to the given example (where an aliquot of 1 ml of the extract is used for acetylation, see 8.4).
NOTE 1   If lower quantification limits are required, a higher volume of extract aliquot can be used for derivatisation.
NOTE 2    This method could have some modifications with some wood species as hardwoods.

Cancels and replaces the first edition (1976). Gives specifications and operating instructions for glass capillary viscometers widely used for the determination of kinematic viscosity of petroleum products by the procedure described in ISO 3104. Also describes the calibration of these viscometers. These viscometers are modified Ostwald viscometers, suspended-level viscometers and reverse-flow viscometers.

This European Standard specifies methods for the calculation of the dry matter of sludge, treated biowaste, soil and waste for which the results of performed analysis are to be calculated to the dry matter basis. Depending on the nature and origin of the sample, the calculation is based on a determination of the dry residue (Method A) or a determination of the water content (Method B). It applies to samples containing more than 1 % (mass fraction) of dry residue or more than 1 % (mass fraction) of water.
Method A applies to sludge, treated biowaste, soil and solid waste, Method B applies to liquid waste and to samples which are suspected or known to contain volatiles except for water.

This document specifies methods for quantitative determination of seven selected polychlorinated biphenyls (PCB28, PCB52, PCB101, PCB118, PCB138, PCB153 and PCB180) in soil, sludge, sediment, treated biowaste, and waste using GC-MS and GC-ECD (see Table 2).
The limit of detection depends on the determinants, the equipment used, the quality of chemicals used for the extraction of the sample and the clean-up of the extract.
Under the conditions specified in this document, lower limit of application from 1 μg/kg (expressed as dry matter) for soils, sludge and biowaste to 10 μg/kg (expressed as dry matter) for solid waste can be achieved. For some specific samples the limit of 10 μg/kg cannot be reached.
Sludge, waste and treated biowaste may differ in properties, as well as in the expected contamination levels of PCB and presence of interfering substances. These differences make it impossible to describe one general procedure. This document contains decision tables based on the properties of the sample and the extraction and clean-up procedure to be used.
NOTE   The analysis of PCB in insulating liquids, petroleum products, used oils and aqueous samples is referred to in EN 61619, EN 12766-1 and EN ISO 6468 respectively.
The method can be applied to the analysis of other PCB congeners not specified in the scope, provided suitability is proven by proper in-house validation experiments.