This document specifies a method for determining the bulk density of solid recovered fuels (SRF) by the use of a standard measuring container. This method is applicable to all SRFs with a nominal top size of particle less than 1/3 of the container diameter specified in this document.

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This document specifies a method for determination of the moisture content in a test portion of the laboratory sample by drying the test portion in an oven. This method is applicable for routine production control on site, e.g. if a high precision of the determination of moisture content is not required. It is applicable to all solid recovered fuels.
If the solid recovered fuel contains large amounts of oil-fractions, a lower temperature is advisable (e.g. 50 °C ± 10 °C) and a longer drying time until constant mass is achieved. As an alternative, the Karl-Fischer-Titration-Method (see ISO 760[1]) is advisable.
NOTE 1        The total moisture content of recovered fuels is not an absolute value and therefore standardised conditions for its determination are indispensable to enable comparative determinations.
NOTE 2        The term moisture content when used with recovered materials can be misleading since solid recovered materials, e.g. biomass, frequently contain varying amounts of volatile compounds (extractives) which can evaporate when determining the moisture content of the general analyses sample by oven drying.

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This document specifies a method for determination of the moisture content in a test portion of the laboratory sample by drying the test portion in an oven. This method is applicable for routine production control on site, e.g. if a high precision of the determination of moisture content is not required. It is applicable to all solid recovered fuels.
If the solid recovered fuel contains large amounts of oil-fractions, a lower temperature is advisable (e.g. 50 °C ± 10 °C) and a longer drying time until constant mass is achieved. As an alternative, the Karl-Fischer-Titration-Method (see ISO 760[1]) is advisable.
NOTE 1        The total moisture content of recovered fuels is not an absolute value and therefore standardised conditions for its determination are indispensable to enable comparative determinations.
NOTE 2        The term moisture content when used with recovered materials can be misleading since solid recovered materials, e.g. biomass, frequently contain varying amounts of volatile compounds (extractives) which can evaporate when determining the moisture content of the general analyses sample by oven drying.

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This document specifies a method for determination of the moisture content in a test portion of the laboratory sample by drying the test portion in an oven. This method is applicable for routine production control on site, e.g. if a high precision of the determination of moisture content is not required. It is applicable to all solid recovered fuels. If the solid recovered fuel contains large amounts of oil-fractions, a lower temperature is advisable (e.g. 50 °C ± 10 °C) and a longer drying time until constant mass is achieved. As an alternative, the Karl-Fischer-Titration-Method (see ISO 760[ REF Reference_ref_4 \r \h 1 08D0C9EA79F9BACE118C8200AA004BA90B0200000008000000100000005200650066006500720065006E00630065005F007200650066005F0034000000 ]) is advisable. NOTE 1 The total moisture content of recovered fuels is not an absolute value and therefore standardised conditions for its determination are indispensable to enable comparative determinations. NOTE 2 The term moisture content when used with recovered materials can be misleading since solid recovered materials, e.g. biomass, frequently contain varying amounts of volatile compounds (extractives) which can evaporate when determining the moisture content of the general analyses sample by oven drying.

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This document specifies a method for determining the bulk density of solid recovered fuels (SRF) by the use of a standard measuring container. This method is applicable to all SRFs with a nominal top size of particle less than 1/3 of the container diameter specified in this document.

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This document specifies a method for determining the bulk density of solid recovered fuels (SRF) by the use of a standard measuring container. This method is applicable to all SRFs with a nominal top size of particle less than 1/3 of the container diameter specified in this document.

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This document describes a method for the measurement of the swelling properties of hard coal using a dilatometer.

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This document sets out principles and procedures for testing the bias of test samples of coals or cokes, taken according to the ISO 13909 series.

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This document specifies a method for the determination of the gross calorific value of coal and coke at constant volume and at the reference temperature of 25 °C in a combustion vessel calorimeter calibrated by combustion of certified benzoic acid. The result obtained is the gross calorific value of the analysis sample at constant volume with all the water of the combustion products as liquid water. In practice, fuel is burned at constant (atmospheric) pressure and the water is not condensed but is removed as vapour with the flue gases. Under these conditions, the operative heat of combustion is the net calorific value of the fuel at constant pressure. The net calorific value at constant volume can also be used; formulae are given for calculating both values. General principles and procedures for the calibrations and the fuel tests are specified in the main text, whereas those pertaining to the use of a particular type of calorimetric instrument are described in Annexes A to C. Annex D contains checklists for performing calibration and fuel tests using specified types of calorimeters. Annex E gives examples illustrating some of the calculations. Annex F provides guidance around safe use, maintenance and testing of the calorimeter combustion vessel. NOTE Descriptors: solid fuels, coal, coke, tests, determination, calorific value, rules of calculation, calorimetry.

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This document specifies a method of determining the characteristic fusion temperatures of ash from hard coal. NOTE Descriptors: fossil fuels, ash, ashes, tests, high temperature tests, determination, and fusibility.

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This document specifies a method of determining the total carbon and the total hydrogen in coal and coke, by the Liebig method.

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This document specifies procedures and requirements for the design and establishment of mechanical samplers for the sampling of coal from moving streams and describes the methods of sampling used. It does not cover mechanical sampling from stationary lots, which is dealt with in ISO 13909-3.

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This document defines the basic terms used in the sampling of coal and coke, describes the general principles of sampling and details the information to be provided in the documentation and the sampling report. It also lists the other parts of the ISO 13909 series and gives guidance on the selection of the appropriate part. The ISO 13909 series also includes sampling of brown coals and lignites.

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This document describes the preparation of samples of coke from the combination of primary increments to the preparation of samples for specific tests.

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This document specifies procedures and requirements for the design and establishment of sampling schemes for the mechanical sampling of coke from moving streams and the methods of sampling used. The diversity of types of equipment for sampling and the conditions under which mechanical sampling is performed make it inappropriate to specify standard designs for samplers which will be applicable to all situations.

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This document specifies procedures for the mechanical sampling of coal from stationary lots, for example, from wagons, barges, ships and stockpiles. These procedures are to be used when it is not possible to sample the lots during loading or discharge according to ISO 13909-2. Procedures for sample preparation are given in ISO 13909-4. This document is applicable to mechanical sampling from stationary coal lots, to obtain samples from which test samples for the determination of moisture, and for general analysis including physical and chemical tests, can be prepared in accordance with the requirements and recommendations set out in ISO 13909-4. In this document, the principles and procedures for designing a sampling scheme are given, together with typical examples of applications; in addition, practices for the execution of sampling in different sampling situations are described. The methods described are limited to those on which it is possible to conduct a test for bias.

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This document defines methods for estimating overall precision and for deriving values for primary increment variance which can be used to modify the sampling scheme to change the precision. Methods for checking the variance of sample preparation and testing are also described. In this document, formulae are developed which link the variables that contribute to overall sampling precision.

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This document describes the preparation of samples of coal from the combination of primary increments to the preparation of samples for specific tests.

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This document specifies the method for determining the true relative density of coke, in relation to water. NOTE “True relative density” varies according to the displacement liquid used.

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This document specifies the method for the determination the porosity of the coke.

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This document specifies the method for the determination of the apparent relative density of coke, i.e. the ratio of the mass of a volume of dry coke to the mass of an equal volume of water.

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This document describes the extraction from coal by dilute hydrochloric acid and determination of extractable sodium, potassium, calcium, iron and magnesium.

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This document specifies a procedure for the determination of the total cadmium mass fraction of coal.

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This document specifies a reduced molybdophosphate photometric method for the determination of the total phosphorus mass fraction of hard coal, lignites and coke. Two methods for taking the phosphorus into solution are specified, namely extraction from the coal or coke ash with acid or by repeated oxidation of the coal or coke, by acid, to remove carbonaceous matter.

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This document specifies a method using Eschka's mixture during ashing, extraction of the ash residue with acid, and hydride generation atomic absorption spectrometry or hydride generation atomic fluorescence spectrometry, for the determination of arsenic and selenium in solid mineral fuels. The method is also applicable for the determination of the analytes by hydride generation inductively coupled plasma atomic emission spectrometry.

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This document specifies methods for the determination of major and minor element concentrations in solid recovered fuels after digestion by the use of different acid mixtures and by addition of a fluxing agent for solid recovered fuel (SRF) ash.
a)       Method A: Microwave assisted digestion with hydrochloric, nitric and hydrofluoric acid mixture (6 ml HCl; 2 ml HNO3; 2 ml HF) followed by boric acid complexation;
b)       Method AT: Microwave assisted digestion with hydrochloric, nitric and tetrafluoroboric acid mixture (6 ml HCl; 2 ml HNO3; 4 ml HBF4);
c)        Method B: Microwave assisted digestion with hydrochloric, nitric and hydrofluoric acid mixture (0,5 ml HCl; 6 ml HNO3; 1 ml HF) followed by boric acid complexation;
d)       Method BT: Microwave assisted digestion with hydrochloric, nitric and tetrafluoroboric acid mixture (0,5 ml HCl; 6 ml HNO3; 2 ml HBF4);
e)       Method C: Microwave assisted digestion with nitric acid, hydrogen peroxide and hydrofluoric acid mixture (2,5 ml H2O2; 5 ml HNO3; 0,4 ml HF) and optional boric acid complexation;
f)         Method CT: Microwave assisted digestion with nitric acid, hydrogen peroxide and tetrafluoroboric acid mixture (2,5 ml H2O2; 5 ml HNO3; 0,8 ml HBF4);
g)       Method D: Digestion of the ashed SRF sample with fluxing agent lithium metaborate in an oven at 1 050 °C.
This document is applicable for the following major and minor/trace elements:
—     Major elements: aluminium (Al), calcium (Ca), iron (Fe), potassium (K), magnesium (Mg), sodium (Na), phosphorus (P), sulfur (S), silicon (Si) and titanium (Ti).
—     Minor/trace elements: arsenic (As), barium (Ba), beryllium (Be), cadmium (Cd), cobalt (Co), chromium (Cr), copper (Cu), mercury (Hg), molybdenum (Mo), manganese (Mn), nickel (Ni), lead (Pb), antimony (Sb), selenium (Se), tin (Sn), thallium (Tl), vanadium (V) and zinc (Zn).
Method A is applicable for general use for SRF and ashed SRFs, but the amount of the test portion can be very low in case of high concentration of organic matter. Method AT can be used if an alternative to HF is necessary.
Method B with a higher volume of nitric acid is applicable for SRFs with high organic matter (e.g. suitable for high plastic content) that can be difficult to digest with less nitric acid or as a substitute for method A if appropriate equipment is not available. Method BT can be used if an alternative to HF is necessary.
Method C with combination of nitric acid and hydrogen peroxide and addition of hydrofluoric acid is applicable for wood based SRFs (e.g. demolition wood) or when there is a need for comparability to solid biofuel standards. Method CT can be used if an alternative to HF is necessary.
Method D is specifically applicable for determination of major elements in ashed SRF samples.
XRF can be used for the analysis of major elements (Al, Ca, Fe, K, Mg, Na, P, S, Si, Ti) after ashing (815 °C) of the samples and several major and minor/trace elements in SRF can be analysed by XRF after suitable calibration provided that the concentration levels are above instrumental detection limits of the XRF instrumentation and after proper preliminary testing and validation.
Digestion methods with HF and subsequent boric acid complexation or application of method D are applicable for determination of Si and Ti (better digestion efficiency).
Alternative digestion methods can be applied, if their performance is proved to be comparable with those of the methods described in this document.

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This document specifies a method of determining the total carbon and the total hydrogen in coal and coke by a high temperature combustion method.

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This document specifies a procedure for the determination of the total mercury mass fraction of coal.

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This document specifies a method for determining the swelling properties of hard coal when heated in a covered crucible. NOTE The "crucible swelling number" (CSN) is also known as the "free swelling index" (FSI).

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This document specifies methods for the determination of major and minor element concentrations in solid recovered fuels after digestion by the use of different acid mixtures and by addition of a fluxing agent for solid recovered fuel (SRF) ash.
a)       Method A: Microwave assisted digestion with hydrochloric, nitric and hydrofluoric acid mixture (6 ml HCl; 2 ml HNO3; 2 ml HF) followed by boric acid complexation;
b)       Method AT: Microwave assisted digestion with hydrochloric, nitric and tetrafluoroboric acid mixture (6 ml HCl; 2 ml HNO3; 4 ml HBF4);
c)        Method B: Microwave assisted digestion with hydrochloric, nitric and hydrofluoric acid mixture (0,5 ml HCl; 6 ml HNO3; 1 ml HF) followed by boric acid complexation;
d)       Method BT: Microwave assisted digestion with hydrochloric, nitric and tetrafluoroboric acid mixture (0,5 ml HCl; 6 ml HNO3; 2 ml HBF4);
e)       Method C: Microwave assisted digestion with nitric acid, hydrogen peroxide and hydrofluoric acid mixture (2,5 ml H2O2; 5 ml HNO3; 0,4 ml HF) and optional boric acid complexation;
f)         Method CT: Microwave assisted digestion with nitric acid, hydrogen peroxide and tetrafluoroboric acid mixture (2,5 ml H2O2; 5 ml HNO3; 0,8 ml HBF4);
g)       Method D: Digestion of the ashed SRF sample with fluxing agent lithium metaborate in an oven at 1 050 °C.
This document is applicable for the following major and minor/trace elements:
—     Major elements: aluminium (Al), calcium (Ca), iron (Fe), potassium (K), magnesium (Mg), sodium (Na), phosphorus (P), sulfur (S), silicon (Si) and titanium (Ti).
—     Minor/trace elements: arsenic (As), barium (Ba), beryllium (Be), cadmium (Cd), cobalt (Co), chromium (Cr), copper (Cu), mercury (Hg), molybdenum (Mo), manganese (Mn), nickel (Ni), lead (Pb), antimony (Sb), selenium (Se), tin (Sn), thallium (Tl), vanadium (V) and zinc (Zn).
Method A is applicable for general use for SRF and ashed SRFs, but the amount of the test portion can be very low in case of high concentration of organic matter. Method AT can be used if an alternative to HF is necessary.
Method B with a higher volume of nitric acid is applicable for SRFs with high organic matter (e.g. suitable for high plastic content) that can be difficult to digest with less nitric acid or as a substitute for method A if appropriate equipment is not available. Method BT can be used if an alternative to HF is necessary.
Method C with combination of nitric acid and hydrogen peroxide and addition of hydrofluoric acid is applicable for wood based SRFs (e.g. demolition wood) or when there is a need for comparability to solid biofuel standards. Method CT can be used if an alternative to HF is necessary.
Method D is specifically applicable for determination of major elements in ashed SRF samples.
XRF can be used for the analysis of major elements (Al, Ca, Fe, K, Mg, Na, P, S, Si, Ti) after ashing (815 °C) of the samples and several major and minor/trace elements in SRF can be analysed by XRF after suitable calibration provided that the concentration levels are above instrumental detection limits of the XRF instrumentation and after proper preliminary testing and validation.
Digestion methods with HF and subsequent boric acid complexation or application of method D are applicable for determination of Si and Ti (better digestion efficiency).
Alternative digestion methods can be applied, if their performance is proved to be comparable with those of the methods described in this document.

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This document specifies methods for the determination of major and minor element concentrations in solid recovered fuels after digestion by the use of different acid mixtures and by addition of a fluxing agent for solid recovered fuel (SRF) ash. a) Method A: Microwave assisted digestion with hydrochloric, nitric and hydrofluoric acid mixture (6 ml HCl; 2 ml HNO3; 2 ml HF) followed by boric acid complexation; b) Method AT: Microwave assisted digestion with hydrochloric, nitric and tetrafluoroboric acid mixture (6 ml HCl; 2 ml HNO3; 4 ml HBF4); c) Method B: Microwave assisted digestion with hydrochloric, nitric and hydrofluoric acid mixture (0,5 ml HCl; 6 ml HNO3; 1 ml HF) followed by boric acid complexation; d) Method BT: Microwave assisted digestion with hydrochloric, nitric and tetrafluoroboric acid mixture (0,5 ml HCl; 6 ml HNO3; 2 ml HBF4); e) Method C: Microwave assisted digestion with nitric acid, hydrogen peroxide and hydrofluoric acid mixture (2,5 ml H2O2; 5 ml HNO3; 0,4 ml HF) and optional boric acid complexation; f) Method CT: Microwave assisted digestion with nitric acid, hydrogen peroxide and tetrafluoroboric acid mixture (2,5 ml H2O2; 5 ml HNO3; 0,8 ml HBF4); g) Method D: Digestion of the ashed SRF sample with fluxing agent lithium metaborate in an oven at 1 050 °C. This document is applicable for the following major and minor/trace elements: — Major elements: aluminium (Al), calcium (Ca), iron (Fe), potassium (K), magnesium (Mg), sodium (Na), phosphorus (P), sulfur (S), silicon (Si) and titanium (Ti). — Minor/trace elements: arsenic (As), barium (Ba), beryllium (Be), cadmium (Cd), cobalt (Co), chromium (Cr), copper (Cu), mercury (Hg), molybdenum (Mo), manganese (Mn), nickel (Ni), lead (Pb), antimony (Sb), selenium (Se), tin (Sn), thallium (Tl), vanadium (V) and zinc (Zn). Method A is applicable for general use for SRF and ashed SRFs, but the amount of the test portion can be very low in case of high concentration of organic matter. Method AT can be used if an alternative to HF is necessary. Method B with a higher volume of nitric acid is applicable for SRFs with high organic matter (e.g. suitable for high plastic content) that can be difficult to digest with less nitric acid or as a substitute for method A if appropriate equipment is not available. Method BT can be used if an alternative to HF is necessary. Method C with combination of nitric acid and hydrogen peroxide and addition of hydrofluoric acid is applicable for wood based SRFs (e.g. demolition wood) or when there is a need for comparability to solid biofuel standards. Method CT can be used if an alternative to HF is necessary. Method D is specifically applicable for determination of major elements in ashed SRF samples. XRF can be used for the analysis of major elements (Al, Ca, Fe, K, Mg, Na, P, S, Si, Ti) after ashing (815 °C) of the samples and several major and minor/trace elements in SRF can be analysed by XRF after suitable calibration provided that the concentration levels are above instrumental detection limits of the XRF instrumentation and after proper preliminary testing and validation. Digestion methods with HF and subsequent boric acid complexation or application of method D are applicable for determination of Si and Ti (better digestion efficiency). Alternative digestion methods can be applied, if their performance is proved to be comparable with those of the methods described in this document.

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This document specifies an alternative method of determining the total sulfur mass fraction of coal and coke by high-temperature combustion by Coulomb titration.

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This document specifies a method for the determination of total carbon, hydrogen and nitrogen in coal and coke by instrumental methods. NOTE This document has been validated for coal only, in accordance with the principles of ISO 5725-1. The suite of samples used in the interlaboratory study (ILS) to determine the precision data did not include coke and therefore there is insufficient data to state precision limits for coke.

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This document specifies requirements for barbecues that burn solid fuels with regard to materials, construction, design, test methods, markings and instructions relating to them.
This document also applies to barbecues originally burning non-solid fuels that have been converted to burn solid fuels.
This document does not apply to single use barbecues. Single use barbecues are covered by EN 1860-4.

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This document specifies the requirements and the test methods for creosotes for industrial wood preservation.
Different grades of creosote are used depending on the desired properties of the treated wood.
WARNING — The use of this document can involve hazardous materials, operations and equipment. This document cannot address all of the safety implications associated with its use. It is the responsibility of the user of this document to establish appropriate health and safety practices and assess the applicability of regulatory limitations prior to use. The warnings to use are covered in Annex C.

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This document specifies a method of determining the volatile matter of hard coal and of coke. It is not applicable to brown coals and lignites.

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This document defines terms commonly employed in the sampling, testing and analysis of coal (3.39) and coke (3.42). Alternative names are given for several terms. In some cases, the use of the alternative name is deprecated (as indicated).

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This document specifies the determination of the share of material recovery in the case of energy recovery (i.e. co-processing) of solid recovered fuels (SRFs), for example, in a cement kiln. This share, called the recycling index (R-index), is calculated on the basis of the ash content and the ash composition.

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This document specifies a method for the determination of the ash of coal and coke.

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This document specifies the determination of the share of material recovery in the case of energy recovery (i.e. co-processing) of solid recovered fuels (SRFs), for example, in a cement kiln. This share, called the recycling index (R-index), is calculated on the basis of the ash content and the ash composition.

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This document specifies the determination of the share of material recovery in the case of energy recovery (i.e. co-processing) of solid recovered fuels (SRFs), for example, in a cement kiln. This share, called the recycling index (R-index), is calculated on the basis of the ash content and the ash composition.

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This document specifies a method for determining the moisture in the general analysis test sample of coke. It can be used for the determination of moisture in blast-furnace coke, foundry-coke and other high-temperature carbonization products.

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This document specifies an analytical method for quantification of the spontaneous heat generation from solid recovered fuels using isothermal calorimetry.
This document gives guidance on the applicability and use of the specified analytical method. It further establishes procedures for sampling and sample handling of solid recovered fuels prior to the analysis of spontaneous heat generation.
The test procedure given in this document quantifies the thermal power (heat flow) of the sample during the test. It does not identify the source of self-heating in the test portion analysed.

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This document specifies an analytical method for quantification of the spontaneous heat generation from solid recovered fuels using isothermal calorimetry.
This document gives guidance on the applicability and use of the specified analytical method. It further establishes procedures for sampling and sample handling of solid recovered fuels prior to the analysis of spontaneous heat generation.
The test procedure given in this document quantifies the thermal power (heat flow) of the sample during the test. It does not identify the source of self-heating in the test portion analysed.

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This document specifies the safety, performance, consumer packaging and marking requirements including the test methods for firelighters used to light solid fuels in barbecue and grill appliances.
This document covers firelighters supplied as either solid, liquid, thickened liquid or gel formulations. However, the use of highly flammable liquids (except in stabilized formulations) is specifically excluded from the scope of this document as their use as barbecue firelighters is regarded as highly dangerous.
This document is intended to reduce the risks which may occur during and through barbecuing with solid fuels.

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This document specifies the requirements and test methods for barbecue charcoal and barbecue charcoal briquettes for use in barbecue appliances.
This document is intended to reduce the risks which can occur during and through barbecuing with solid fuels.
Barbecue charcoal in accordance with this document refers to the solid remainder of dry distillation of wood or other vegetable matter.

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This document is applicable to single use barbecues which burn solid fuels.
This document specifies requirements for materials, construction, design and test methods to ensure safe use and satisfactory performance.
This document is intended to reduce the risks which may occur during and through barbecuing with solid fuels.
This document deals with the reasonably foreseeable hazards presented by single use barbecues when used by adults. Very vulnerable people can have needs that go beyond the level of safety addressed in this document.

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This document specifies the safety, performance, consumer packaging and marking requirements including the test methods for firelighters used to light solid fuels in barbecue and grill appliances.
This document covers firelighters supplied as either solid, liquid, thickened liquid or gel formulations. However, the use of highly flammable liquids (except in stabilized formulations) is specifically excluded from the scope of this document as their use as barbecue firelighters is regarded as highly dangerous.
This document is intended to reduce the risks which may occur during and through barbecuing with solid fuels.

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This document is applicable to single use barbecues which burn solid fuels.
This document specifies requirements for materials, construction, design and test methods to ensure safe use and satisfactory performance.
This document is intended to reduce the risks which may occur during and through barbecuing with solid fuels.
This document deals with the reasonably foreseeable hazards presented by single use barbecues when used by adults. Very vulnerable people can have needs that go beyond the level of safety addressed in this document.

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This document specifies the requirements and test methods for barbecue charcoal and barbecue charcoal briquettes for use in barbecue appliances.
This document is intended to reduce the risks which can occur during and through barbecuing with solid fuels.
Barbecue charcoal in accordance with this document refers to the solid remainder of dry distillation of wood or other vegetable matter.

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