ISO 687:2024
(Main)Coke - Determination of moisture in the general analysis test sample
Coke - Determination of moisture in the general analysis test sample
This document specifies a method for determining the moisture in the general analysis test sample of coke. It can be used for the determination of moisture in blast-furnace coke, foundry-coke and other high-temperature carbonization products.
Coke — Détermination de l'humidité de l'échantillon pour analyse
General Information
- Status
- Published
- Publication Date
- 14-Mar-2024
- Technical Committee
- ISO/TC 27/SC 5 - Methods of analysis
- Drafting Committee
- ISO/TC 27/SC 5 - Methods of analysis
- Current Stage
- 6060 - International Standard published
- Start Date
- 15-Mar-2024
- Due Date
- 06-Feb-2025
- Completion Date
- 15-Mar-2024
Relations
- Effective Date
- 11-Feb-2023
Overview
ISO 687:2024 - "Coke - Determination of moisture in the general analysis test sample" specifies a standardized gravimetric method for measuring moisture in coke test samples. Applicable to blast-furnace coke, foundry coke and other high‑temperature carbonization products, the method determines moisture by heating a known mass of the general analysis sample until constant mass and calculating the moisture mass fraction from the mass loss. The 2024 fourth edition adds the optional use of nitrogen atmospheres and a minimum free space oven.
Key topics and technical requirements
- Scope: Moisture determination for general analysis test samples of coke and related products.
- Principle: Gravimetric loss-on-drying - heat a weighed sample in air or nitrogen at a controlled temperature until constant mass is achieved.
- Temperatures:
- Typical range: 120 °C to 200 °C (optionally 105 °C for lower-temperature drying).
- Faster procedure: 320 °C in nitrogen (1 h usually sufficient) using a minimum free space oven.
- Atmosphere:
- Dry air or nitrogen (optional); nitrogen must have oxygen < 30 µl/l. Commercial nitrogen with moisture < 5 µl/l is acceptable.
- For nitrogen operation, recommended flow ≈ 15 × oven volume per hour in minimum free space ovens.
- Apparatus and sample:
- Analytical balance with 0.1 mg readability.
- Shallow glass or corrosion‑resistant metal dish with cover; sample layer ≤ 0.20 g/cm²; nominal sample mass 1 ± 0.1 g.
- Cooling vessel (desiccator) without desiccant; option to cool under air or nitrogen flow.
- Procedure highlights:
- Weigh empty dish + cover, add sample, heat until constant mass (reheat 30 min intervals if needed until mass change ≤ 1 mg).
- Report mean of duplicate determinations to nearest 0.1 %.
- Calculation:
- Moisture mass fraction (%) = (mass loss on drying / sample mass before drying) × 100.
- Precision:
- Repeatability limit: 0.2 % absolute for duplicate determinations in the same lab. Reproducibility across labs not specified due to varying humidity conditions.
Applications and users
- Quality control and routine testing in metallurgical plants, coke producers, foundries, and independent analytical laboratories.
- Laboratories correcting other analyses (e.g., volatile matter, hydrogen) to a dry basis when moisture in the general analysis sample must be known.
- Users who require standardized, traceable moisture results for product specification, process control, compliance and inter‑laboratory comparison.
Related standards
- ISO 1213-2 (vocabulary for sampling, testing and analysis) - referenced for terms and definitions.
- ISO 687:2024 complements other coke and coal test methods used in laboratory quality systems.
Keywords: ISO 687:2024, coke moisture determination, moisture in coke, general analysis test sample, minimum free space oven, nitrogen drying, blast-furnace coke, foundry coke.
Frequently Asked Questions
ISO 687:2024 is a standard published by the International Organization for Standardization (ISO). Its full title is "Coke - Determination of moisture in the general analysis test sample". This standard covers: This document specifies a method for determining the moisture in the general analysis test sample of coke. It can be used for the determination of moisture in blast-furnace coke, foundry-coke and other high-temperature carbonization products.
This document specifies a method for determining the moisture in the general analysis test sample of coke. It can be used for the determination of moisture in blast-furnace coke, foundry-coke and other high-temperature carbonization products.
ISO 687:2024 is classified under the following ICS (International Classification for Standards) categories: 75.160.10 - Solid fuels. The ICS classification helps identify the subject area and facilitates finding related standards.
ISO 687:2024 has the following relationships with other standards: It is inter standard links to ISO 687:2010. Understanding these relationships helps ensure you are using the most current and applicable version of the standard.
ISO 687:2024 is available in PDF format for immediate download after purchase. The document can be added to your cart and obtained through the secure checkout process. Digital delivery ensures instant access to the complete standard document.
Standards Content (Sample)
International
Standard
ISO 687
Fourth edition
Coke — Determination of moisture
2024-03
in the general analysis test sample
Coke — Détermination de l'humidité de l'échantillon pour
analyse
Reference number
© ISO 2024
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ii
Contents Page
Foreword .iv
Introduction .v
1 Scope . 1
2 Normative references . 1
3 Terms and definitions . 1
4 Principle . 1
5 Reagents . 1
6 Apparatus . 1
7 Preparation of the test sample. 2
8 Procedure . 2
9 Expression of results . 3
10 Precision . 3
10.1 Repeatability limit .3
10.2 Reproducibility limit .3
11 Test report . 3
Annex A (informative) Example of a suitable oven for drying in nitrogen . 4
iii
Foreword
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This document was prepared by Technical Committee ISO/TC 27, Coal and coke, Subcommittee SC 5, Methods
of analysis.
This fourth edition cancels and replaces the third edition (ISO 687:2010), which has been technically revised.
The main change is as follows:
— adding the optional use of nitrogen and a minimum free space oven.
Any feedback or questions on this document should be directed to the user’s national standards body. A
complete listing of these bodies can be found at www.iso.org/members.html.
iv
Introduction
The determination of moisture in the general analysis test sample is required to correct the results of certain
analytical determinations, e.g. volatile matter and hydrogen, for the effect of water in the determination and
to allow all determinations to be corrected to a dry basis.
Since coke is hygroscopic, its moisture will vary with a change in humidity of the atmosphere, and the
moisture in the genera
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