KAZ - Air quality

The method described in this document quantifies the absolute exposure to mineral oil vapours and droplets, within a concentration range from 0,5 mg/m3 to 125 mg/m3, in the inhalable fraction of the workplace air.
This document contains comprehensive information and instructions on the equipment and chemicals to be used.
This method is applicable for water soluble oils and metal working fluids.

This document describes a method for the sampling and determining mercury species in flue gas passing through ducts or chimney stacks. Mercury generally exists in gaseous elemental form, gaseous oxidized form and particulate-bound form. This method applies to the sampling and determination of gaseous elemental mercury (Hg0), gaseous oxidized mercury (Hg2+), particulate-bound mercury (HgP) and total mercury (HgT) in the flue gas from stationary sources.
This method is suitable at locations with high dust content, including locations upstream of the dust removal device with high particulate loadings in flue gas up to 120 g/m3.
This method is applicable to locations with sulfur dioxide (SO2) concentration up to 0,25 % when the sampling volume is 0,5 m3 (on a dry basis as corrected to standard conditions).
The limit of detection and the limit of determination depend on the instrumental limit of detection, reagent blank, field blank, measurement technique and volume of sampled gas. When the sampling volume is 1,5 m3 (on a dry basis as corrected to standard conditions), the expected limits of detection for Hg0, HgP, Hg2+ and HgT are 0,103 μg/m3, 0,011 μg/m3, 0,035 μg/m3 and 0,127 μg/m3, respectively. The expected limits of determination for Hg0, HgP, Hg2+ and HgT are 0,229 μg/m3, 0,025 μg/m3, 0,082 μg/m3 and 0,263 μg/m3, respectively.

This document provides a methodology for calculating greenhouse gas (GHG) emissions from the semiconductor and display industry. This document includes the manufacture of semiconductor devices, microelectromechanical systems (MEMS), photovoltaic (PV) devices and displays. This document allows to report GHG emissions for various purposes and on different bases, such as a per-plant basis, per-company basis (by country or by region) or an international group basis. This document addresses all of the following direct and indirect sources of GHG:
— direct GHG emissions [as defined in ISO 14064-1:2018, 5.2.4 a)] from sources that are owned or controlled by the company, such as emissions resulting from the following sources:
— process: fluorinated compound (FC) gases and nitrous oxide (N2O) used in etching and wafer cleaning (EWC), remote plasma cleaning (RPC), in situ plasma cleansing (IPC), in situ thermal cleaning (ITC), N2O thin film deposition (TFD), and other N2O using process;
— fuel combustion related to equipment and on-site vehicles, room heating/cooling;
— fuel combustion of fuels for on-site power generation;
— indirect GHG emissions [as defined in ISO 14064-1:2018, 5.2.4 b)] from the generation of imported electricity, heat or steam consumed by the organization.
Other indirect GHG emissions [as defined in ISO 14064-1:2018, 5.2.4 c) to f)], which are the consequence of an organization’s activities, but arise from GHG sources that are owned or controlled by other organizations, are excluded from this document.

This document specifies a method for the sampling of NO2 in ambient air using diffusive sampling followed by extraction and analysis by colourimetry or ion chromatography (IC). It can be used for the NO2 measurement in a concentration range of approximately 3 µg/m3 to 130 µg/m3 [12]. A sample is typically collected for a period of 1 to 4 weeks [14], with exposure periods depending on the design of the samplers and the concentration levels of NO2.
Several sorbents can be used for trapping NO2 in ambient air using a diffusive sampler [15]. This document specifies the application of triethanolamine as the reagent.
This document describes the application of a tube-type sampler (with either a cylindrical or a slightly conical tube), a badge-type sampler and a radial-type sampler.
The relative expanded uncertainty of NO2 measurements performed using these tube-type diffusive samplers can potentially be lower than 25 % for individual measurements. When aggregating results to form annual average values, the relative expanded uncertainty can be further reduced to levels below 15 % due to the reduction of random effects on uncertainty [9].
NOTE   NO2 passive samplers are also employed to measure NOx with the addition of an oxidant to convert ambient NO into NO2. A second NO2 sampler is also deployed without the oxidant and the concentration of NO is determined from the difference of the two samplers [16].

This document provides rules for workplace sampling and the sample analysis for the determination and characterization of airborne NOAA for electron microscopy and includes:
-   the choice of appropriate samplers and their use for the determination and characterization (e.g. classification of structures and morphology) of airborne NOAA using electron microscopic methods (SEM and (S)TEM);
-   counting rules and criteria for the determination and characterization (e.g. classification of structures, chemical composition and morphology) of airborne NOAA using electron microscopic methods (SEM and (S)TEM), especially for nanofibres and platelets.
This document is based on extensive laboratory tests for airborne NOAA, in particular those released during the handling of engineered nanomaterials.

This document specifies a manual reference method for the determination of the mass concentration of specific elements in stationary source emissions. The method is applicable to each of the specific elements in the concentration range of 0,005 mg/m3 to 5 mg/m3.
This document has been validated for the determination of the mass concentration of metals in incineration exhaust gases - applying the performance criteria stated in Clause 9 - for the following elements:
-   arsenic (As), cadmium (Cd), chromium (Cr), cobalt (Co), copper (Cu), manganese (Mn), nickel (Ni), lead (Pb), antimony (Sb), thallium (Tl), and vanadium (V) and their compounds.
The document can be used to determine metals other than those listed above (for example, selenium (Se) (ISO 17211), tellurium (Te), beryllium (Be), tin (Sn) and zinc (Zn)).
NOTE 1   These other metals mentioned above are commonly required by National Regulations, but this document currently has not yet been validated for these metals.
The document was validated for waste incinerators, but it is also applicable to other industrial processes, the practical experience shows that it can be applied over wide concentration ranges and various emission sources.
If mercury is intended to be determined as well, this can be sampled in a side stream arrangement of the sampling train (EN 13211) [5].
NOTE 2   This document has been validated with the described materials, equipment, sampling, and digestion performances etc., followed by analyses with atomic absorption spectroscopy (AAS) and inductively coupled plasma optical emission spectroscopy (ICP-OES,) or inductively coupled mass spectrometry (ICP-MS). This does not exclude the use of other types of equipment or analyses that meet the requirements and have been proven to be equivalent to the described European Standard.

This document specifies a continuous measurement method for the determination of the concentrations of nitrogen dioxide and nitrogen monoxide present in ambient air based on the chemiluminescence measuring principle. This document describes the performance characteristics and sets the relevant minimum criteria required to select an appropriate chemiluminescence analyser by means of type testing. It also includes the evaluation of the suitability of an analyser for use in a specific fixed site so as to meet the data quality requirements as specified in Annex I of Directive 2008/50/EC [1] and requirements during sampling, calibration and quality assurance for use.
The method is applicable to the determination of the concentration of nitrogen dioxide present in ambient air up to 500 µg/m3. This concentration range represents the certification range for nitrogen dioxide for type testing.
The method is applicable to the determination of the concentration of nitrogen monoxide present in ambient air up to 1 200 µg/m3. This concentration range represents the certification range for nitrogen monoxide for the type testing.
NOTE 1   It is possible to use other ranges depending on the levels present in ambient air.
NOTE 2   When this document is used for purposes other than for measurements required by Directive2008/50/EC, the ranges and uncertainty requirements possibly do not apply.
The method covers the determination of ambient air concentrations of nitrogen dioxide and nitrogen monoxide in zones classified as rural areas, urban-background areas, traffic-orientated locations and locations influenced by industrial sources.
The results are expressed in µg/m3 (at 20 °C and 101,3 kPa).
NOTE 3   500 µg/m3 of nitrogen dioxide corresponds to 261 nmol/mol of nitrogen dioxide at 20 °C and 101,3 kPa. 1 200 µg/m3 of nitrogen monoxide corresponds to 962 nmol/mol of nitrogen monoxide at 20 °C and 101,3 kPa.
This document contains information for different groups of users.
Clause 5 to Clause 7 and Annex B and Annex C contain general information about the principles of NOx measurement by chemiluminescence analyser and sampling equipment.
Clause 8 and Annex E are specifically directed towards test houses and laboratories that perform type testing of NOx analysers. These sections contain information about:
—   type testing conditions, test procedures and test requirements;
—   analyser performance requirements;
—   evaluation of the type testing results;
—   evaluation of the uncertainty of the measurement results of the NOx analyser based on the type testing results.
Clause 9 to Clause 11 and Annex F and Annex G are directed towards monitoring networks performing the practical measurements of NOx in ambient air. These sections contain information about:
—   initial installation of the analyser in the monitoring network and acceptance testing;
—   ongoing quality assurance/quality control;
—   calculation and reporting of measurement results;
—   evaluation of the uncertainty of measurement results under practical monitoring conditions.
This document represents an evolution of earlier editions (EN 14211:2005 and EN 14211:2012). It is advisable that when equipment is procured it complies fully with this document.
NOTE 4   Type testing performed prior to the publication of this document for the purpose of demonstrating equivalence are still valid.
NOTE 5   Analysers type tested prior to the publication of this document remain valid for use for regulated monitoring purposes.

This document specifies a method for the determination of sulfur dioxide (SO2) in flue gases of stationary sources and describes the fundamental structure and the key performance characteristics of automated measuring systems.
The method allows continuous monitoring with permanently installed measuring systems of SO2 emissions.
This document describes extractive systems and in situ (non-extractive) systems in connection with a range of analysers that operate using, for example, the following principles:
— non-dispersive infrared absorption (NDIR);
— Fourier transform infrared (FTIR) spectroscopy;
— laser spectroscopic technique or tunable laser spectroscopy (TLS);
— non-dispersive ultraviolet absorption (NDUV);
— differential optical absorption spectroscopy (DOAS).
Other equivalent instrumental methods can be used provided they meet the minimum performance requirements specified in this document. The measuring system can be validated with reference materials, according to this document, or comparable methods.
Automated measuring system (AMS) based on the principles listed above has been used successfully in this application for the measuring ranges as shown in Annex E.

This document specifies the sampling and analysis of phthalates in indoor air and describes the sampling and analysis of phthalates in house dust and in solvent wipe samples of surfaces by means of gas chromatography-mass spectrometry (GC-MS).
Two alternative sampling, sample preparation and sample introduction methods, whose comparability has been proven in an interlaboratory test, are specified for indoor air[1]:
— sorbent tubes sampling with subsequent thermal desorption GC-MS, and
— sampling by adsorption and subsequent solvent extraction and injection to GC-MS.
Additional adsorbents that can be used are described in Annex B.
Depending on the sampling method, the compounds dimethyl phthalate to diisoundecylphthalate can be analysed in house dust as described in Annex D. The investigation of house dust samples is only appropriate as a screening method. This investigation only results in indicative values and is not acceptable for a final assessment of a potential need for action.
Dimethyl phthalate to diisoundecylphthalate can be analysed in solvent wipe samples as described in Annex C. Solvent wipe samples are suitable for non-quantitative source identification.
NOTE In principle, the method is also suitable for the analysis of other phthalates, adipates and cyclohexane dicarboxylic acid esters, but this is confirmed by determination of the performance characteristics in each case.
General information on phthalates are given in Annex A.

This document specifies a continuous measurement method for the determination of the concentration of sulfur dioxide present in ambient air based on the ultraviolet fluorescence measuring principle. This document describes the performance characteristics and sets the relevant minimum criteria required to select an appropriate ultraviolet fluorescence analyser by means of type testing. It also includes the evaluation of the suitability of an analyser for use in a specific fixed site so as to meet the data quality requirements as specified in Annex I of Directive 2008/50/EC [1] and requirements during sampling, calibration and quality assurance for use.
The method is applicable to the determination of the mass concentration of sulphur dioxide present in ambient air up to 1000 µg/m3. This concentration range represents the certification range for sulfur dioxide for type testing.
NOTE 1   It is possible to use other ranges depending on the levels present in ambient air.
NOTE 2   When this document is used for purposes other than for measurements required by Directive 2008/50/EC, the ranges and uncertainty requirements possibly do not apply.
The method covers the determination of ambient air concentrations of sulfur dioxide in locations classified as rural areas, urban-background areas, and for sampling influenced by traffic or industrial sources.
The results are expressed in µg/m3 (at 20 °C and 101,3 kPa).
NOTE 3   1 000 µg/m3 of SO2 corresponds to 376 nmol/mol of SO2.
This document contains information for different groups of users.
Clause 5 to Clause 7 and Annex C and Annex D contain general information about the principles of sulfur dioxide measurement by ultraviolet fluorescence analyser and sampling equipment.
Clause 8 and Annex E are specifically directed towards test houses and laboratories that perform type testing of sulfur dioxide analysers. These sections contain information about:
—   type testing conditions, test procedures and test requirements;
—   analyser performance requirements;
—   evaluation of the type testing results;
—   evaluation of the uncertainty of the measurement results of the sulfur dioxide analyser based on the type testing results.
Clause 9 to Clause 11 and Annex F and Annex G are directed towards monitoring networks performing the practical measurements of sulfur dioxide in ambient air. These sections contain information about:
—   initial installation of the analyser in the monitoring network and acceptance testing;
—   ongoing quality assurance/quality control;
—   calculation and reporting of measurement results;
—   evaluation of the uncertainty of the measurement results under practical monitoring conditions.
This document represents an evolution of earlier editions (EN 14212:2005 and EN 14212:2012). It is advisable that when equipment is procured it complies fully with this document.
NOTE 4   Type testing performed prior to the publication of this document for the purpose of demonstrating equivalence are still valid.
NOTE 5   Analysers type tested prior to the publication of this document remain valid for use for regulated monitoring purposes.

This European Standard specifies a continuous measurement method for the determination of the concentrations of ozone present in ambient air based on the ultraviolet photometric measuring principle. This standard describes the performance characteristics and sets the relevant minimum criteria required to select an appropriate ultraviolet photometric analyser by means of type approval tests. It also includes the evaluation of the suitability of an analyser for use in a specific fixed site so as to meet the data quality requirements as specified in Annex I of Directive 2008/50/EC [1] and requirements during sampling, calibration and quality assurance for use.
The method is applicable to the determination of the concentration of ozone present in ambient air up to 500 μg/m3.
This concentration range represents the certification range for ozone for the type approval test.
NOTE 1 Other ranges may be used for measurement systems applied at rural locations monitoring ecosystems.
NOTE 2 When the standard is used for other purposes than Directive 2008/50/EC, the ranges and uncertainty requirements may not apply.
The method covers the determination of ambient air concentrations of ozone in zones classified as rural areas, urban and urban-background areas.
The results are expressed in μg/m3 (at 20 °C and 101,3 kPa).
NOTE 3 500 μg/m3 of O3 corresponds to 250 nmol/mol of O3 at 20 °C and 101,3 kPa.
This standard contains information for different groups of users.
Clauses 5 to 7 and Annexes B and C contain general information about the principles of ozone measurement by ultraviolet photometric analyser and sampling equipment.
Clause 8 and Annex E are specifically directed towards test houses and laboratories that perform type-approval testing of ozone analysers. These sections contain information about:
− type-approval test conditions, test procedures and test requirements;
− analyser performance requirements;
− evaluation of the type-approval test results;
− evaluation of the uncertainty of the measurement results of the ozone analyser based on the type-approval test results.
Clauses 9 to 11 and Annexes F and G are directed towards monitoring networks performing the practical
measurements of ozone in ambient air. These sections contain information about:
− initial installation of the analyser in the monitoring network and acceptance testing;
− ongoing quality assurance/quality control;
− calculation and reporting of measurement results;
− evaluation of the uncertainty of measurement results under practical monitoring conditions.

This European Standard specifies a continuous measurement method for the determination of the concentration of carbon monoxide present in ambient air based on the non-dispersive infrared spectroscopic measuring principle.
This standard describes the performance characteristics and sets the relevant minimum criteria required to select an appropriate non-dispersive infrared spectroscopic analyser by means of type approval tests. It also includes the evaluation of the suitability of an analyser for use in a specific fixed site so as to meet the data quality requirements as specified in Annex I of Directive 2008/50/EC [1] and requirements during sampling, calibration and quality assurance for use.
The method is applicable to the determination of the mass concentration of carbon monoxide present in ambient air up to 100 mg/m3 carbon monoxide. This concentration range represents the certification range for the type approval test.
NOTE 1 Other ranges may be used depending on the levels present in ambient air.
NOTE 2 When the standard is used for other purposes than for measurements required by Directive 2008/50/EC, the ranges and uncertainty requirements may not apply.
The method covers the determination of ambient air concentrations of carbon monoxide in zones classified as rural areas, urban-background areas and traffic-orientated locations and locations influenced by industrial sources.
The results are expressed in mg/m3 (at 20 °C and 101,3 kPa).
NOTE 3 100 mg/m3 of CO corresponds to 86 μmol/mol of CO.
This standard contains information for different groups of users.
Clauses 5 to 7 and Annexes B, C and D contain general information about the principles of carbon monoxide measurement by non-dispersive infrared spectroscopic analyser and sampling equipment.
Clause 8 and Annex E are specifically directed towards test houses and laboratories that perform type-approval testing of carbon monoxide analysers. These sections contain information about:
− type-approval test conditions, test procedures and test requirements;
− analyser performance requirements;
− evaluation of the type-approval test results;
− evaluation of the uncertainty of the measurement results of the carbon monoxide analyser based on the type approval test results.
Clauses 9 to 11 and Annex F are directed towards monitoring networks performing the practical measurements of carbon monoxide in ambient air. These sections contain information about:
− initial installation of the analyser in the monitoring network and acceptance testing;
− ongoing quality assurance/quality control;
− calculation and reporting of measurement results;
− evaluation of the uncertainty of measurement results under practical monitoring conditions.

This document specifies a method for the determination of the mass concentration of particulate cadmium and cadmium compounds in workplace air, using either flame or electrothermal atomic absorption spectrometry.
The sample digestion procedure specified in 10.2.2 has been validated for a selection of cadmium compounds and pigments and glass enamels containing cadmium.
The analytical method has been validated for the determination of masses of 10 ng to 600 ng of cadmium per sample using electrothermal atomic absorption spectrometry, and 0,15 µg to 96 µg of cadmium per sample using flame atomic absorption spectrometry. The concentration range for cadmium in air for which this procedure is applicable is determined in part by the sampling procedure selected by the user.
The method is applicable to personal sampling of the inhalable or respirable fraction of airborne particles, as defined in ISO 7708, and to stationary sampling.

This document specifies the standard reference method (SRM) for the measurement of low dust concentration in ducted gaseous streams in the concentrations below 50 mg/m3 at standard conditions.
This document is primarily developed and validated for gaseous streams emitted by waste incinerators. More generally, it can be applied to gases emitted from other stationary sources, and to higher concentrations.
If the gases contain unstable, reactive or semi-volatile substances, the measurement depends on the sampling and filter treatment conditions.
This method has been validated in field tests with special emphasis to dust concentrations around 5 mg/m3. The results of the field tests are presented in Annex A.

This document gives guidelines on the use, calibration and evaluation of low-cost optical particulate matter sensor modules and systems for workplace exposure assessments.
This document is based on extensive laboratory and workplace tests for airborne NOAA.
This document is particularly aimed at engineered NOAA at workplaces and the sensors’ applicability for process control of NOAA-producing plants via airborne particle concentration measurements in workplace air.
NOTE   This document is also applicable to other airborne particles included in some of the tests during the prenormative research.

This document specifies the general principles, including testing procedures and requirements, for the classification of performance of low-cost sensor systems for the monitoring of particulate matter in ambient air at fixed sites. The classification of sensor systems includes tests that are performed under prescribed conditions. It does not guarantee performance in locations that are different from the tests, variations in meteorological climate from the test programme or account for stability over time, which can only be assessed under ongoing quality control strategies.
The described procedure is applicable to the determination of the mass concentration of particulate matter. The pollutants that are considered in this document are PM10 and PM2,5 in the range of concentrations expected in ambient air.
This document provides a classification that is consistent with the requirements for indicative measurements and objective estimation defined in Directive 2008/50/EC. In addition, it provides a classification for applications (non-regulatory measurements) that require more relaxed performance criteria.
This document applies to sensor systems used as individual systems. It does not apply to sensor systems as part of a sensor network. However, for some applications (e.g. in cities) sensor systems are deployed as part of a sensor network. Annex A provides information on the use of sensor systems as nodes in a sensor network.

This document specifies a process for the electrical diffusion charging of aerosols with subsequent measurement of particle charge. With the aid of this method, it is possible to determine the lung-deposited surface area (LDSA) concentration of particles in ambient air. Depending on the design of the electrical diffusion charger, the LDSA of particles in the size range of approximately 20 nm to approximately 300 nm is measurable.
Furthermore, this document specifies design criteria for LDSA measuring aerosol monitors as well as performance criteria and the associated test procedures. The performance criteria depend on the application and they are more stringent when the instrument is operated in an air quality monitoring station.
In the determination of the LDSA concentration, the share of geometric particle surface area concentration is determined that can be deposited in the alveolar region of the human lung. Typical particle surface area concentrations with alveolar deposition measured in urban areas range from 5 µm2/cm3 to 50 µm2/cm3.
Instruments based on this measurement principle can be designed to be very compact with a low power consumption. This makes them ideally suited for handheld measurements, other forms of mobile application or to measure personal exposure. On the other hand, they can be easily adapted to serve as a stationary instrument in air quality monitoring stations.

This document specifies a general laboratory test method for the determination of the area specific emission rate of volatile organic compounds (VOCs) from samples of newly produced building products or furnishing under defined climate conditions. The method can also, in principle, be applied to samples of aged products. The emission data obtained can be used to calculate concentrations in a model room (see Table B.1).
This document is applicable to various emission test chambers used for the determination of the emission of VOCs from building products or furnishing.
This document is also applicable to samples of wood-based panels and other building products, in order to determine the emission rate of formaldehyde.
NOTE            In principle, this document can be applied to the study of any gas phase emissions from samples of building products and furnishing.

This document provides definitions of the quantities measured by various candidate methods, their basic principles, and their advantages and disadvantages.
Currently no traceable primary reference materials are available for EC and OC analyses. This document provides guidance to test the equivalence between candidate methods and EN 16909 for EC and/or OC determination(s), based on EN 16450.

This document specifies a measurement method based on an automatic method for determination of the mass concentration of formaldehyde in ducts and stacks emitting to the atmosphere. It specifies the sampling and gas conditioning system. Furthermore, it specifies the characteristics to be determined and the performance criteria to be fulfilled by portable automated measuring systems (P-AMS) using appropriate techniques to measure formaldehyde.
This method is intended for intermittent monitoring of formaldehyde emissions as well as for the calibration and validation of automated formaldehyde measuring systems.
The analyser is calibrated using test gases produced by a test gas generator.

This document specifies a standard method for determining the particle number concentration in ambient air in a range up to about 107 cm–3 for averaging times equal to or larger than 1 min. The standard method is based on a Condensation Particle Counter (CPC) operated in the counting mode and an appropriate dilution system for concentrations exceeding the counting mode range. It also defines the performance characteristics and the minimum requirements of the instruments to be used. The lower and upper sizes considered within this document are 10 nm and a few micrometres, respectively. This document gives guidance on sampling, operation, data processing and QA/QC procedures including calibration parameters.

This document specifies the sampling procedures, transport conditions, storage and substrate used that can affect emissions of volatile organic compounds for three types of building products or furnishing: solid, liquid and combined. For individual products, the preparation of a test specimen for each type is specified.

This document specifies a chromatographic method for the determination of levoglucosan in aqueous or organic extracts of filter samples collected in accordance with EN 12341:2023 [5]. The method has been tested for concentrations of ca. 10 ng/m3 up to ca. 3 000 ng/m3 with a sampling duration of 24 h. The procedure is also suitable for the determination of galactosan and mannosan.
Depending on the analysis instrumentation used, the carbohydrates inositol, glycerol, threitol/erythritol, xylitol, arabitol, sorbitol, mannitol, threalose, mannose, glucose, galactose and fructose can also be determined. However, no performance characteristics are given for these compounds in this document.

This document specifies the performance criteria and test procedures for the performance test of stationary automated measuring systems (AMS) that continuously measure gases and particulate matter in, and flow of, the waste gas from stationary sources.
This document supports the requirements of particular EU Directives. It provides the detailed procedures covering the QAL1 requirements of EN 14181 and, where required, input data used in QAL3.

This document gives general guidance for the sampling and analysis of benzene in air by pumped sampling, thermal desorption and capillary gas chromatography.
This document is in accordance with the generic methodology selected as the basis of the European Union reference method for the determination of benzene in ambient air [1] for the purpose of comparison of measurement results with limit values with a one-year reference period.
This document is valid for the measurement of benzene in a concentration range of approximately 0,5 μg/m3 to 50 μg/m3. Air samples are typically collected over periods ranging from a few hours to 7 days.
The upper limit of the useful range is set by the sorptive capacity (the safe sampling volume) of the sorbent and by the linear dynamic range of the gas chromatograph column and detector or by the sample splitting capacity of the analytical instrumentation used. The lower limit of the useful range depends on the noise level of the detector and on blank levels of benzene and/or interfering artefacts on the sorbent. Artefacts are typically sub ng for graphitised carbon sorbents, but higher levels of aromatic hydrocarbons have been noted in other sorbents - e.g. porous polymers. The detection limit will be approximately 1/10 of the lower concentration range.
This document provides general guidance for the sampling of benzene using either a single sampler, which is changed manually after every exposure period, or a multi-sampler capable of storing and exposing multiple samples without user intervention.

This document specifies the general performance criteria and test procedures for the performance test of portable automated measuring systems (P-AMS) used for periodic measurements of stationary source emissions. It applies to the performance test of P-AMS based on measurement techniques specified by the standard reference method (SRM) or an alternative method (AM).
The performance test is based on the general performance criteria and test procedures specified in this document and on the specific requirements specified for the SRM or AM. This includes testing of the applicability and correct implementation of the QA/QC procedures specified for the SRM or AM.
This document supports the requirements of particular EU Directives.

Ta tehnična specifikacija določa zahteve za prve, občasne in izredne meritve emisije iz malih kurilnih
naprav na trdna goriva v skladu s predpisom, ki ureja emisijo snovi v zrak iz malih kurilnih naprav, ter s
predpisom, ki ureja preglede, čiščenje in meritve pri malih kurilnih napravah. Tehnična specifikacija se
uporablja za ugotavljanje emisije, vključno z meritvami prahu, iz navedenih naprav. Poleg tega so
opisane tudi kontrolne aktivnosti, povezane z napravo in obratovanjem, ki morajo biti predhodno
izvedene, da se zagotovi ustrezen postopek merjenja emisije.
Dodatek A obravnava posebnosti pri kurilnih napravah na trdna goriva za ogrevanje posameznega
prostora, imenovanih enosobne male kurilne naprave.
Dodatek B vsebuje vzorec zapisnika o meritvah emisije na enosobnih malih kurilnih napravah.
Merila za razvrščanje enosobnih malih kurilnih naprav na trdna goriva so navedena v dodatku C.

This document specifies a method for the determination of nitrogen oxides (NOx) in flue gas of stationary sources and describes the fundamental structure and the key performance characteristics of automated measuring systems.
The method allows continuous monitoring with permanently installed measuring systems of NOx emissions.
This document describes extractive systems and in situ (non-extractive) systems in connection with a range of analysers that operate using, for example, the following principles:
— chemiluminescence (CL);
— infrared absorption (NDIR);
— Fourier transform infrared (FTIR) spectroscopy;
— ultraviolet absorption (NDUV);
— differential optical absorption spectroscopy (DOAS);
Other equivalent instrumental methods such as laser spectroscopic techniques can be used provided they meet the minimum performance requirements specified in this document. The measuring system can be validated with reference materials, in accordance with this document, or comparable methods.
Automated measuring system (AMS) based on the principles listed above has been used successfully in this application for the measuring ranges as shown in Annex F.

This document specifies procedures for establishing quality assurance levels (QAL) for automated measuring systems (AMS) installed on industrial plants for the determination of the flue gas components and other flue gas parameters.
This document specifies:
— a procedure (QAL2) to calibrate the AMS and determine the variability of the measured values obtained by it, so as to demonstrate the suitability of the AMS for its application, following its installation;
— a procedure (QAL3) to maintain and demonstrate the required quality of the measurement results during the normal operation of an AMS, by checking that the zero and span characteristics are consistent with those determined during QAL1;
— a procedure for the annual surveillance tests (AST) of the AMS in order to evaluate (i) that it functions correctly and its performance remains valid and (ii) that its calibration function and variability remain as previously determined.
This document is designed to be used after the AMS has been certified in accordance with the series of documents EN 15267.

This document specifies the requirements for the manufacturer’s quality management system (QMS), the initial assessment of the manufacturer’s production control and the continuing surveillance of the effect of subsequent changes on the performance of certified air quality monitoring equipment (AQME).
This document also serves as a reference document for auditing the manufacturer’s QMS.
This document elaborates and supplements the requirements of EN ISO 9001:2015.

This document specifies a determination of formaldehyde (HCHO) and other carbonyl compounds (aldehydes and ketones) in air. The method is specific to formaldehyde but, with modification, at least 12 other aromatic as well as saturated and unsaturated aliphatic carbonyl compounds can be detected and quantified. It is suitable for determination of formaldehyde and other carbonyl compounds in the approximate concentration range 1 µg/m3 to 1 mg/m3. The sampling method gives a time-weighted average (TWA) sample. It can be used for long-term (1 h to 24 h) or short-term (5 min to 60 min) sampling of air for formaldehyde.
This document specifies a sampling and analysis procedure for formaldehyde and other carbonyl compounds that involves collection from air on to adsorbent cartridges coated with 2,4-dinitrophenylhydrazine (DNPH) and subsequent analysis of the hydrazones formed by high performance liquid chromatography (HPLC) with detection by ultraviolet absorption[12],[16]. The method is not suitable for longer chained or unsaturated carbonyl compounds.

This document specifies the general principles of certification, including common procedures and requirements, for the certification of air quality monitoring equipment (AQME).
This document applies to the certification of AQME for ambient air quality and emissions from stationary sources for which performance criteria and test procedures are available in European Standards.
This document provides for the certification of AQME according to the requirements of EN ISO/IEC 17065:2012.
This document elaborates and supplements the requirements of EN ISO/IEC 17065:2012 for bodies certifying AQME. It specifies requirements on testing laboratories as well as the manufacturer’s quality management system (QMS) and the surveillance for the manufacturing process as part of the certification process.

This document specifies flame and electrothermal atomic absorption spectrometric methods for the determination of the time-weighted average mass concentration of particulate lead and lead compounds in workplace air.
These methods are typically applicable to personal sampling of the inhalable fraction of airborne particles, as defined in ISO 7708, and to static (area) sampling. It can be applied to other health-related fractions as required.
The sample dissolution procedure specifies hot plate or microwave assisted digestion, or ultrasonic extraction (see 11.2). The use of an alternative, more vigorous dissolution procedure is necessary when it is desired to extract lead from compounds present in the test atmosphere that are insoluble using the dissolution procedures described herein (see Clause 5).
The flame atomic absorption method is applicable to the determination of masses of approximately 1 µg to 200 µg of lead per sample, without dilution[1]. The electrothermal atomic absorption method is applicable to the determination of masses of approximately 0,01 µg to 0,5 µg of lead per sample, without dilution[1].
The ultrasonic extraction procedure has been validated for the determination of masses of approximately 20 µg to 100 µg of lead per sample, for laboratory-generated lead fume air filter samples[2].
The concentration range for lead in air for which this procedure is applicable is determined in part by the sampling procedure selected by the user (see 10.1).

This European Standard describes a standard method for determining the PM10 or PM2,5 mass concentrations of suspendedparticulate matter in ambient air by sampling the particulate matter on filters and weighing them by means of a balance.
Measurements are performed with samplers with inlet designs as specified in Annex A, operating at a nominal flow rate of 2,3 m3/h,over a nominal sampling period of 24 h. Measurement results are expressed in μg/m3, where the volume of air is the volume atambient conditions near the inlet at the time of sampling.
The range of application of this European Standard is for 24 h measurements from approximately 1 μg/m3 (i.e. the limit of detection ofthe standard measurement method expressed as its uncertainty) up to 150 μg/m3 for PM10 and 120 μg/m3 for PM2,5.
This European Standard describes procedures and gives requirements for the testing and use of so-called sequential samplers,equipped with a filter changer, suitable for extended stand-alone operation. Sequential samplers are commonly used throughout theEuropean Union for the measurement of concentrations in ambient air of PM10 or PM2,5. However, this European Standard does notexclude the use of single-filter samplers.
This European Standard represents an evolution of earlier European Standards (EN 12341:1998 and 2014, EN 14907:2005). Newequipment procured shall comply fully with this European Standard.
Older versions of these samplers, including those described in EN 12341:2014 Annex B, have a special status in terms of their use. These samplers can still be used for monitoring purposes and for ongoing quality control, provided that a well justified additionalallowance is made to their uncertainties
This European Standard also provides guidance for the selection and testing of filters with the aim of reducing the measurementuncertainty of the results obtained when applying this European Standard.

This document provides guidelines for the design, manufacture, installation, and maintenance of a WPR. It describes the following:
— Measurement principle (Clause 5). Scatterers that produce echoes and methods of wind velocity measurement are described. The description of the measurement principle mainly aims at providing the information necessary for describing the guidelines in Clauses 6 to 11.
— Guidelines for WPR system (Clause 6). Frequency, hardware, software, and signal processing are described. They are mainly applied in designing and manufacturing the hardware and software of WPR.
— Guidelines for system performance (Clause 7). Measurement resolution, range sampling, radar sensitivity evaluation, and measurement accuracy are described. They can be used for estimating the measurement performance of a WPR’s system design and operation.
— Guidelines for quality control (QC) in digital signal processing (Clause 8).
— Guidelines for measurement products and data format (Clause 9). Measurement products obtained by a WPR and their data levels are defined. Guidelines for data file formats are also described.
— Guidelines for installation (Clause 10) and maintenance (Clause 11).
This document does not aim at providing a thorough description of the measurement principle, WPR systems, and WPR applications. For further details of these items, users are referred to technical books (e.g. References [1],[2],[3]).
WPRs are referred to by various names (e.g. radar wind profiler, wind profiler radar, wind profiling radar, atmospheric radar, or clear-air Doppler radar). Conventional naming for WPRs should be allowed.

This document specifies a method for determination of volatile organic compounds (VOC) in indoor air and in air sampled for the determination of the emission from products or materials used in indoor environments (according to ISO 16000‑1) using test chambers and test cells. The method uses sorbent sampling tubes with subsequent thermal desorption (TD) and gas chromatographic (GC) analysis employing a capillary column and a mass spectrometric (MS) detector with or without an additional flame ionisation detector (FID)[13].
The method is applicable to the measurement of most GC-compatible vapour-phase organic compounds at concentrations ranging from micrograms per cubic metre to several milligrams per cubic metre. Many very volatile organic compounds (VVOC) and semi-volatile organic compounds (SVOC) can be analysed depending on the sorbents used.

This document specifies the whole vehicle test chamber, the vapour sampling assembly and the operating conditions for the determination of volatile organic compounds (VOCs), and carbonyl compounds in vehicle cabin air. There are three measurements performed: one (for VOCs and carbonyl compounds) during the simulation of ambient conditions (ambient mode) at standard conditions of 23 °C - 25 °C with no air exchange; a second only for the measurement of formaldehyde at elevated temperatures (parking mode); and a third for VOCs and carbonyl compounds simulating driving after the vehicle has been parked in the sun starting at elevated temperatures (driving mode). For the simulation of the mean sun irradiation, a fixed irradiation in the whole vehicle test chamber is employed.
The VOC method is valid for measurement of non-polar and slightly polar VOCs in a concentration range of sub-micrograms per cubic metre up to several milligrams per cubic metre. Using the principles specified in this method, some semi-volatile organic compounds (SVOC) can also be analysed. Compatible compounds are those which can be trapped and released from the Tenax TA®[1] sorbent tubes described in ISO 16000‑6, which includes VOCs ranging in volatility from n-C6 to n-C16.
The sampling and analysis procedure for formaldehyde and other carbonyl compounds is performed by collecting air on to cartridges coated with 2,4-dinitrophenylhydrazine (DNPH) and subsequent analysis by high performance liquid chromatography (HPLC) with detection by ultraviolet absorption. Formaldehyde and other carbonyl compounds can be determined in the approximate concentration range 1 µg/m3 to 1 mg/m3.
The method is valid for passenger cars, as defined in ECE-TRANS-WP.29/1045.
This document gives guidelines for:
a) transport and storage of the test vehicles until the start of the test;
b) conditioning for the surroundings of the test vehicle and the test vehicle itself as well as the whole vehicle test chamber;
c) conditioning of the test vehicle prior to measurements;
d) simulation of ambient air conditions (ambient mode);
e) formaldehyde sampling at elevated temperatures (parking mode);
f) simulation of driving after the test vehicle has been parked in the sun (driving mode).
[1] Tenax TA® is the trade name of a product supplied by Buchem. This information is given for the convenience of users of this document and does not constitute an endorsement by ISO of the product named. Equivalent products may be used if they can be shown to lead to the same results.

This document specifies the requirements for the installation and on-going quality assurance and quality control of data acquisition and handling systems (DAHS). This includes requirements on:
-   installation (Clause 5);
-   quality assurance and quality control during QAL2 (Clause 6);
-   quality assurance and quality control during on-going operation (Clause 7);
-   annual functional test (Clause 8);
-   documentation (Clause 9).
This document supports the requirements of EN 14181 and legislation such as the IED [1], MCPD [2] and E-PRTR [3]. It does not preclude the use of additional features and functions provided the minimum requirements of this document are met and that these features do not adversely affect data quality, clarity or access.

This document supports the elaboration of standardized measurement methods for the determination of stationary source emissions by manual or automated measurement methods.
This document describes the basic elements of standardized measurement methods for the determination of stationary source emissions.
This document is supplemented by an electronic template providing a uniform structure and common elements and texts.
NOTE   Detailed information on the electronic template is given in Annex A.
This document is addressed to working groups of CEN/TC 264 dealing with stationary source emissions. It aims at facilitating in the working groups the elaboration and the harmonization of documents produced by CEN/TC 264. Such documents can be European standards (EN), European Technical Specifications (CEN/TS) or European Technical Reports (CEN/TR).

This document specifies requirements for the calibration and validation (QAL2), the ongoing quality assurance during operation (QAL3) and the annual surveillance test (AST) of AMS used for monitoring total mercury emissions from stationary sources to demonstrate compliance with an emission limit value (ELV). This document is derived from EN 14181 and is only applicable in conjunction with EN 14181.
This document is applicable by direct correlation with the standard reference method (SRM) described in EN 13211.

This document specifies requirements for the evaluation of measuring procedures using samplers for the determination of a chemical agent present in the workplace atmosphere as a mixture of airborne particles and vapour.
The procedures given in this document provide results only for the sum of airborne particles and vapour. The concentration is calculated in terms of mass per unit volume.
NOTE      The physical behaviour of a mixture of airborne particles and vapour is described in Annex A. Examples of substances which can be present in multiple phases are toluene diisocyanate, diethanolamine, ethyleneglycol and tributylphosphate.
This document can also be applied to complex mixtures, such as metal working fluids or bitumen fumes.
This document is applicable to samplers and measuring procedures using these samplers in which sampling and analysis are carried out in separate stages.

This document specifies performance requirements for battery powered pumps used for personal sampling of chemical and biological agents in workplace air. It also specifies test methods in order to determine the performance characteristics of such pumps under prescribed laboratory conditions.
This document is applicable to battery powered pumps having a nominal volumetric flow rate above 10 ml ⋅ min−1, as used with combinations of sampler and collection substrate for sampling of gases, vapours, dusts, fumes, mists and fibres.
This document is primarily intended for flow-controlled pumps.

This document defines recommendations dealing with the quality of the air on civil aircraft concerning chemical compounds potentially originating from, but not limited, to, the ventilation air supplied to the cabin and flight deck.
A special emphasis is on the engine and APU bleed air contaminants potentially brought into the cabin through the air conditioning, pressurization and ventilation systems.
The document is applicable to civil aircraft in operation from the period that is defined as when the first person enters the aircraft until the last person leaves the aircraft.
The document recommends means to prevent exposure to certain types of chemical compounds, including those that could cause adverse effects, taking into account the Precautionary Principle.

This document supplements the requirements of EN ISO/IEC 17043 by providing clarification and additional information for proficiency testing schemes for emission measurements. It gives specific requirements for:
—   competence of proficiency testing providers;
—   proficiency testing facility characteristics; and
—   design, operation and evaluation of proficiency testing schemes by means of interlaboratory comparisons.
All these aspects are necessary in order to organize and conduct proficiency testing on emission measurements.
Requirements on the competence of proficiency testing providers cover personnel, organisation, equipment and environment.
Requirements on the proficiency testing facility characteristics cover measurement sections, measurements ports and working area for the participants.
Requirements on the proficiency testing schemes cover:
—   design, including planning, preparations, homogeneity and stability of test atmospheres and statistical design;
—   operation, including handling and instruction of participants;
—   calculation and use of assigned values; and
—   testing results evaluation, including statistical data.
This document supports the application of proficiency testing schemes for checking the performance of testing laboratories in the context of qualification, accreditation and related quality checks in relation to the application of standardized measurement methods such as standard reference methods (SRM) or alternative methods (AM).
This document is applicable in combination with EN ISO/IEC 17043 only.

This document specifies performance requirements and test methods under prescribed laboratory conditions for the evaluation of diffusive samplers (see Reference [1]) and of procedures using these samplers for the determination of gases and vapours in workplace atmospheres (see Reference [2]).
This document is applicable to diffusive samplers and measuring procedures using these samplers, such as ISO 16200‑2 and ISO 16017‑2, in which sampling and analysis are carried out in separate stages.
This document is not applicable to
—    diffusive samplers which are used for the direct determination of concentrations, and
—    diffusive samplers which rely on sorption into a liquid.
This document addresses requirements for method developers and/or manufacturers.
NOTE      For the purposes of this document a manufacturer can be any commercial or non-commercial entity.

This document specifies the framework for determining emissions to the atmosphere of Volatile Organic Compounds (VOCs). It specifies a system of methods to detect and/or identify and/or quantify VOC emissions from industrial sources. These methods include Optical Gas Imaging (OGI), Differential Absorption Lidar (DIAL), Solar Occultation Flux (SOF), Tracer Correlation (TC), and Reverse Dispersion Modelling (RDM). It specifies the methodologies for carrying out all the above, and also the performance requirements and capabilities of the direct monitoring methods, the requirements for the results and their measurement uncertainties.
This document specifically addresses, but is not restricted to, the petrochemicals, oil refining, and chemical industries receiving, processing, storing, and/or exporting of VOCs, and includes the emissions of VOCs from the natural gas processing/conditioning industry and the storage of natural gas and similar fuels. The methods specified in this document have been validated at onshore facilities.
This document is applicable to diffuse VOC emissions to atmosphere but not to the emissions of VOCs into water and into solid materials such as soils. It is complementary to EN 15446 [9], the standardized method for the detection, localization of sources (individual leaks from equipment and piping), and quantification of fugitive VOC emissions within the scope of a Leak Detection and Repair Programme (LDAR).
This document has been validated for non-methane VOCs, but the methodology is in principle applicable to methane and other gases.
This document specifies methods to determine (detect, identify and/or quantify) VOC emissions during the periods of monitoring. It does not address the extrapolation of emissions to time periods beyond the monitoring period.