This document specifies a method for calibrating the kinetic energy scales of Auger electron spectrometers with an uncertainty of 3 eV, for general analytical use in identifying elements at surfaces. This document also specifies a method for establishing a calibration schedule. It is applicable to instruments used in either direct or differential mode, where the resolution is less than or equal to 0,5 % and the modulation amplitude for the differential mode, if used, is 2 eV peak-to-peak. It is applicable to those spectrometers equipped with an inert gas ion gun or other method for sample cleaning and with an electron gun capable of operating at 4 keV or higher beam energy.

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This part of ISO 21068 specifies analytical techniques for the determination of volatile components by thermal treatment at specified temperatures, and methods for the determination of the total carbon content, free carbon, silicon carbide, total and free silicon and free and surface silica content of silicon carbide, silicon nitride, silicon oxynitride and sialon containing raw materials and refractory products.

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This part of ISO 21068 specifies analytical techniques for the determination of total nitrogen and nitrogen calculated as silicon nitride, total oxygen, and metallic and oxidic components in silicon carbide raw materials and refractory products.

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This standard describes methods for the determination of mineralogical phases typically apparent in nitride and oxy-nitride bonded silicon carbide refractory products using a Bragg-Brentano diffractometer.
It includes details of sample preparation and general principles for qualitative and quantitative analysis of mineralogical phase composition. Quantitative determination of -Si3N4, -Si3N4, Si2ON2, AlN, and SiAlON are described.
NOTE   For the refinement procedures the total nitrogen content, analysed in accordance with ISO 21068-3 is needed.

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This document specifies a procedure by which the intensity scale of an X-ray photoelectron spectrometer that employs a concentric hemispherical analyser can be calibrated using low-density poly(ethylene). This document is applicable to instruments using quartz-crystal-monochromated Al Kα X-rays and is suitable for all instrument geometries. The intensity calibration is only valid for the specific settings of the instrument (pass energy or retardation ratio, lens mode, slit and aperture settings) used during the calibration procedure. The intensity calibration is applicable at kinetic energies higher than 180 eV. The intensity calibration is suitable for instruments that do not have an ion gun for the purpose of cleaning metal specimens in-situ (i.e. Au, Ag, Cu), or exhibit detector saturation when these specimens are measured using standard instrument parameters. This document is not applicable to XPS instruments which do not have a system of charge compensation, or instruments that have a non-linear intensity response. This document is not applicable to instruments and operating modes which generate significant intensity from electrons scattered internally in the spectrometer (i.e. >1 % contribution of scattering intensity to the total spectral intensity).

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This part of ISO 21068 gives definitions and specifies techniques for the preparation of samples for the chemical analysis of silicon-carbide-containing raw materials and refractory products including:
a)   SiC raw materials;
b)   graphite brick containing silicon carbide;
c)   silicon carbide brick (includes the bricks containing silicon nitride, silicon oxynitride, sialon);
d)   refractories containing carbon and/or silicon carbide mixed with clay;
e)   refractories containing carbon and/or silicon carbide mixed with silica (and fused silica);
f)   refractories containing carbon and/or silicon carbide mixed with high alumina material;
g)   refractories containing carbon and/or silicon carbide mixed with magnesia (and dolomite);
h)   refractories containing carbon and/or silicon carbide mixed with chrome mineral or magnesia-chrome materials;
i)   refractories containing carbon and/or silicon carbide except those described in a) to g) above.
The items of chemical analysis described in ISO 21068, Parts 1 to 4 are as follows:
1)   loss on drying (LOD);
2)   loss on ignition (LOI);
3)   total carbon, Ctotal;
4)   free carbon, Cfree;
5)   silicon carbide, SiC;
6)   free silicon (Sifree);
7)   free aluminium (Alfree);
8)   free magnesium (Mgfree);
9)   free iron (Fefree);
10)   silicon(IV) dioxide (SiO2);
11)   aluminium oxide (Al2O3);
12)   iron(III) oxide (total iron oxide calculated as Fe2O3);
13)   titanium(IV) oxide (TiO2);
14)   calcium oxide (CaO);
15)   magnesium oxide (MgO);
16)   sodium oxide (Na2O);
17)   potassium oxide (K2O);
18)   chromium(III) oxide (Cr2O3);
19)   zirconium oxide (ZrO2);
20)   boron oxide (total boron calculated as B2O3);
21)   nitrogen;
22)   oxygen;
23)   nitrides (undifferentiated: Si3N4, AlN, BN, sialon, oxy-nitrides, etc.);
24)   XRD-methods.

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This European Standard specifies a method for the direct determination total fluorine, chlorine, bromine and sulfur content in environmental solid matrices. The method is applicable for the determination of concentrations ≥ 10 mg/kg of each element based on dry matter. The upper limit and exact concentration range covered depends on system blank levels of instrumentation and capacity of the chromatographic separation column used for determination.

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This document describes a method for measuring the spatial resolutions, lateral and axial, of the Raman microscope.

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This document gives guidance on the measurement and use of experimentally-determined relative sensitivity factors for the quantitative analysis of homogeneous materials by Auger electron spectroscopy and X-ray photoelectron spectroscopy. The methods described only apply to polycrystalline and amorphous materials, as effects inherent to single-crystal samples are not addressed.

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This document describes the static gravimetric preparation of Class II calibration gas mixtures and describes a method for calculating the measurement uncertainty associated with the amount fraction of each component. In addition to all of the contributions to the measurement uncertainty mentioned in ISO 6142-1, this document also considers the uncertainty resulting from the validation process for Class II mixtures that are not individually verified, as is the case for Class I mixtures. This document extends the uncertainty evaluation described in ISO 6142-1 to include the effects of batch production and the verification process. It provides guidance on how to derive an uncertainty budget that is representative of a particular category of mixtures. Methods for the batch production of more than one mixture in a single process are included in this document. This document is only applicable to mixtures of gaseous or totally vaporized components, which can be introduced into the cylinder in the gaseous or liquid state. Both binary and multi-component gas mixtures are covered by this document. This document is limited to non-reactive molecules/components that are greater than or equal to an amount fraction of 100 μmol/mol. This document excludes components that react with each other, or with common mixture contaminants such as water vapour or oxygen or react with the inner surface of the cylinder and valve in the form of absorption or adsorption.

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The document specifies test methods for industrial thiourea properties, such as thiourea content, water insoluble substance, ignition residue, initial melting point, turbidity, thiocyanate content, calcium element and heavy metals.

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This document specifies requirements for three classes, marking, package, transport and storage of thiourea for industrial purpose. The different types of thiourea specified are defined according to their content, application, and requirements (see Table 1).

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ISO 1833-4:2017 specifies a method, using hypochlorite, to determine the mass percentage of protein fibre, after removal of non-fibrous matter, in textiles made of mixtures of certain non-protein fibres and certain protein fibres, as follows:
- wool, other animal-hair (such as cashmere, mohair), silk, protein,
with
- cotton, cupro, viscose, modal, acrylic, chlorofibres, polyamide, polyester, polypropylene, glass, elastane, elastomultiester, elastolefin, melamine and polypropylene/polyamide bicomponent.

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This document specifies an empirical method for the simultaneous direct determination of the fluorine, chlorine, bromine, and sulfur content in environmental solid matrices by oxidative pyrohydrolytic combustion at (1 050 ± 50) °C, followed by ion chromatography. The method is applicable for the determination of concentrations ≥ 10 mg/kg of each element based on dry matter. The upper limit and exact concentration range covered depends on the blank levels of the instrumentation and the capacity of the chromatographic separation column used for determination.
NOTE 1   Simultaneous determination of iodine content is possible but currently not validated.
NOTE 2   Other detection methods can be applied if validated.

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This document specifies test methods and performance requirements for alcohol interlocks having a mouthpiece. It covers alcohol interlocks to be used in all general preventive programmes and those for drink driving offenders and legally regulated programmes monitored or controlled in a comparable way.
This document can also be used for alcohol interlocks intended for other applications.
This document is directed at test laboratories and manufacturers of alcohol interlocks. It defines requirements and test procedures for type testing.
Several parameters (such as alcohol concentration or breath volume) are specified in this document for the purpose of type testing according to this document only. However, it can be necessary due to national regulations or depending on user requests to set the values of the prescribed parameters differently when the alcohol interlocks are in use.
This document also applies to alcohol interlocks integrated into other control systems of the vehicle as well as to accessory devices connected to the alcohol interlock.
This document does not apply to
—   instruments measuring the alcohol concentration in the ambient air in the vehicle,
—   alcohol interlocks not having a mouthpiece,
—   methods of installation and connections to the vehicle.

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This document specifies test methods and performance requirements for alcohol interlocks having a mouthpiece. It covers alcohol interlocks to be used in all general preventive programmes and those for drink driving offenders and legally regulated programmes monitored or controlled in a comparable way. This document can also be used for alcohol interlocks intended for other applications. This document is directed at test laboratories and manufacturers of alcohol interlocks. It defines requirements and test procedures for type testing. Several parameters (such as alcohol concentration or breath volume) are specified in this document for the purpose of type testing according to this document only. NOTE It can be necessary due to national regulations or depending on user requests to set the values of the prescribed parameters differently when the alcohol interlocks are in use. This document also applies to alcohol interlocks integrated into control systems of the vehicle as well as to accessory devices connected to the alcohol interlock. This document does not apply to - instruments measuring the alcohol concentration in the ambient air in the vehicle, - alcohol interlocks not having a mouthpiece, - methods of installation and connections to the vehicle.

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This document defines terms for surface chemical analysis. It covers general terms and those used in spectroscopy, while ISO 18115‑2 covers terms used in scanning-probe microscopy and ISO 18115‑3 covers terms used in optical interface analysis.

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This document describes a method for determining the minimum detectability of surface plasmon resonance device. This document is applicable to surface plasmon resonance devices of the white-light illumination type and the laser illumination type with the angle scanning capability.

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This document gives guidance and requirements on the optimization of sputter-depth profiling parameters using appropriate single-layered and multilayered reference materials, in order to achieve optimum depth resolution as a function of instrument settings in Auger electron spectroscopy, X-ray photoelectron spectroscopy and secondary ion mass spectrometry. This document is not intended to cover the use of special multilayered systems such as delta doped layers.

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This document specifies a glow discharge optical emission spectrometric method for the determination of the thickness and mass per unit area of single and metallic nanolayers on iron-based substrates. This method is applicable to single and metallic nanolayers, 10 nm to 100 nm thick, on iron-based substrates. The metallic elements of the layers are Cr, Ni, Ti, Mn and Al. Other elements that can be determined according to this document are P and S.

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This document specifies a method for determining the maximum count rate for an acceptable limit of divergence from linearity of the intensity scale in single ion counting time-of-flight (TOF) secondary ion mass spectrometers using a test based on isotopic ratios in spectra from poly(tetrafluoroethylene) (PTFE). It also includes a method to correct for intensity nonlinearity arising from intensity lost from a microchannel plate (MCP) or scintillator and photomultiplier followed by a time-to-digital converter (TDC) detection system caused by secondary ions arriving during its dead-time. The correction can increase the intensity range for 95 % linearity by a factor of up to more than 50 so that a higher maximum count rate can be employed for those spectrometers for which the relevant correction formulae have been shown to be valid.

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This document specifies performance requirements and test methods for remote alcohol monitoring devices that use breath alcohol testing technology. It covers remote alcohol monitoring devices having a mouthpiece and which are intended to be used by participants in programmes designed to monitor alcohol consumption. This document is directed at test laboratories and manufacturers of remote alcohol monitoring devices. It defines requirements and test procedures for type testing. Several parameter settings (such as alcohol concentration, breath volume or units of measurement) are specified in this document for the purpose of type testing according to this standard only. However, it may be necessary due to national regulations or depending on user requests to set the values of the prescribed parameter settings differently when the remote alcohol monitoring devices are in use.

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IEC 61207-3:2019 is available as IEC 61207-3:2019 RLV which contains the International Standard and its Redline version, showing all changes of the technical content compared to the previous edition. IEC 61207-3:2019 applies to the three main methods for measuring oxygen by its paramagnetic property, which are outlined in the introduction. It considers essential ancillary units and applies to analyzers installed indoors and outdoors. Safety-critical applications can require additional requirements from system and analyzer specifications not covered in this document. This document is intended: - to specify terminology and definitions related to the functional performance of paramagnetic gas analyzers for the measurement of oxygen in a source gas; - to unify methods used in making and verifying statements on the functional performance of such analyzers; - to specify what tests are performed to determine the functional performance and how such tests are carried out; - to provide basic documents to support the application of internationally recognized quality management standards. This third edition cancels and replaces the second edition published in 2002. This edition constitutes a technical revision. This edition includes the following significant technical changes with respect to the previous edition: a) all references (normative and informative) have been updated, deleted or added to as appropriate; b) all the terms, descriptions and definitions relating to the document have been updated where appropriate; c) all references to “errors” have been replaced by “uncertainties” and appropriate updated definitions applied.

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Applies to gas analyzers using high temperature electrochemical sensors for measurement of oxygen in gas. Applies to both 'in situ' and extractive analyzers installed indoors or outdoors.

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This document specifies the interface between an alcohol interlock for production and aftermarket installation and a vehicle. It details the modes of electrical connections, the assignment of electrical connection lines as well as the information to be exchanged between the vehicle and the alcohol interlock. This document is applicable to alcohol interlocks for drink-driving-offender programmes (as in EN 50436 1) as well as to alcohol interlocks for general preventive use (as in EN 50436 2). This document is mainly directed at manufacturers of alcohol interlocks and at vehicle manufacturers. This document is referenced in EN 50436 7 and provides details of the preferred data bus connection suggested therein. NOTE This document describes the information exchange using a LIN or a CAN (J1939) connection.

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This document describes a procedure for the quantitative characterization of the probe tip of an atomic force microscope (AFM) probe and a restoration of AFM topography images dilated by finite probe size. The three-dimensional shape of the probe apex is extracted by image reconstruction using suitable reference materials. This document is applicable to the reconstruction of AFM topography images of solid material surfaces.

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This document defines terms for surface chemical analysis in the area of optical interface analysis including ellipsometry, Raman spectroscopy and nonlinear optical techniques as well as general optical terms.

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This document specifies a method for the quantitative depth profiling of amorphous heavy metal oxide ultrathin films on Si substrates using medium energy ion scattering (MEIS).

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This document specifies a method for measuring the mass resolution in SIMS, and how to compare the mass resolution between different instruments (e.g. TOF-SIMS, Magnetic SIMS, Quadrupole SIMS, Fourier Transform SIMS, etc.) by considering the peak shapes.

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This document specifies a method for the calibration of the sputtered depth of a material from a measurement of its sputtering rate under set sputtering conditions using a single- or multi-layer reference sample with layers of the same material as that requiring depth calibration. The method has a typical accuracy in the range of 5 % to 10 % for layers 20 nm to 200 nm thick when sputter depth profiled using AES, XPS and SIMS. The sputtering rate is determined from the layer thickness and the sputtering time between relevant interfaces in the reference sample and this is used with the sputtering time to give the thickness of the sample to be measured. The determined ion sputtering rate can be used for the prediction of ion sputtering rates for a wide range of other materials so that depth scales and sputtering times in those materials can be estimated through tabulated values of sputtering yields and atomic densities.

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This part of IEC 60746 is intended: - to specify terminology, definitions and requirements for statements by manufacturers for analyzers, sensor units and electronic units used for the determination of dissolved oxygen partial pressure or concentration; - to establish performance tests for such analyzers, sensor units and electronic units; - to provide basic documents to support the applications of quality assurance standards [1]1. This document applies to analyzers using membrane covered amperometric sensors. It applies to analyzers suitable for use in water containing liquids, ultrapure waters, fresh or potable water, sea water or other aqueous solutions, industrial or municipal waste water from water bodies (e.g. lakes, rivers, estuaries), as well as for industrial process streams and process liquids. Whilst in principle amperometric oxygen-analyzers are applicable in gaseous phases, the expression of performance in the gas phase is outside the scope of this document. This document is applicable to analyzers specified for permanent installation in any location (indoors or outdoors) using membrane-covered amperometric sensors.

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This document defines terms for surface chemical analysis. ISO 18115-1 covers general terms and those used in spectroscopy while this document covers terms used in scanning probe microscopy.

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The purpose of this new standard is to define a list of functionalities for a standard connector / interface between the vehicle and the alcohol interlock, which can be used for communication between the vehicle and the alcohol interlock in both directions for information exchange. It specifies the interface for an aftermarket installation of alcohol interlocks

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This document specifies a method, using formic acid and zinc chloride, to determine the mass
percentage of viscose or certain types of cupro or modal or lyocell, after removal of non-fibrous matter,
in textiles made of mixtures of
— viscose or certain types of the cupro or modal or lyocell fibres
with
— flax fibres.
This document is not applicable to mixtures in which the flax fibre has suffered extensive chemical
degradation, nor when the viscose, cupro, modal or lyocell fibre is rendered incompletely soluble by the
presence of certain permanent finishes or reactive dyes that cannot be removed completely.

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The stable isotope ratios of carbon, hydrogen, oxygen and nitrogen can be used to obtain information about the origin of bio-based feedstock and characteristics of production processes of bio-based products. However, no or limited attention for the use of the elements nitrogen and sulphur is given in this document due to the fact that these applications are not yet available.
This Technical Report provides an overview of existing applications of isotope ratio analysis of carbon, hydrogen, oxygen and nitrogen that are relevant to the analysis of bio-based feedstocks, products and production processes

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This document specifies the minimum amount of information spectroscopy to be reported with the analytical results to describe the methods of charge control and charge correction in measurements of core-level binding energies for insulating specimens by X‑ray photoelectron. It also provides methods for charge control and for charge correction in the measurement of binding energies.

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This document specifies a method of determining relative sensitivity factors (RSFs) for secondary-ion mass spectrometry (SIMS) from ion-implanted reference materials. The method is applicable to specimens in which the matrix is of uniform chemical composition, and in which the peak concentration of the implanted species does not exceed one atomic percent.

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This document gives guidance on methods of handling, mounting and surface treatment for a biomaterial specimen prior to surface chemical analysis. It is intended for the analyst as an aid in understanding the specialized specimen-handling conditions required for analyses by the following techniques: — X-ray photoelectron spectroscopy (XPS or ESCA); — secondary ion mass spectrometry (SIMS); — Auger electron spectroscopy (AES). The protocols presented are also applicable to other analytical techniques that are sensitive to surface composition, such as: — attenuated total reflectance -Fourier transform infrared spectroscopy (ATR-FTIR); — total reflection X-ray fluorescence (TXRF); — ultraviolet photoelectron spectroscopy (UPS). The influence of vacuum conditions applied and the issue of contamination before and after analysis and implantation, as well as issues related to contamination during analysis, are addressed. Biomaterials covered here are hard and soft specimens such as metals, ceramics, scaffolds and polymers. This document does not cover such viable biological materials as cells, tissues and living organisms. Other related topics not covered in this document include: preparation of specimens for electron or light microscopy.

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This document provides guidelines for measuring the sputtered depth in sputtered depth profiling. The methods of sputtered depth measurement described in this document are applicable to techniques of surface chemical analysis when used in combination with ion bombardment for the removal of a part of a solid sample to a typical sputtered depth of up to several micrometres. The depth typically determined by this approach is between 1 nm to 500 µm.

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This document is provided to assist in the surface analysis of thin films on materials which are not thought to contain carbon compounds as intended components but for which a C1s peak is observed in the survey spectrum. The films can be those generated on metals and alloys by aerobic or electrochemical oxidation or be those deposited on inert substrates. The procedure described is not suitable for discontinuous deposits of particles on a substrate. With this exception, a simple procedure is provided for identifying the C1s signal from carbon-containing surface contamination. When the C1s peak is identified as arising from an adventitious over-layer the composition derived from the survey spectrum can be corrected for its influence. Recommended procedures are provided in the form of simple Rules structured in the 'If - Then` format with the intention that the information they embody might be utilised by automated procedures in data-systems. The rules provided utilize only information retrieved from the XPS survey scan.

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This document provides guidelines that are applicable to bulk and depth profiling GD-OES analyses. The guidelines discussed herein are limited to the analysis of rigid solids, and do not cover the analysis of powders, gases or solutions. Combined with specific standard methods which are available now and, in the future, these guidelines are intended to enable the regulation of instruments and the control of measuring conditions. Although several types of glow discharge optical emission sources have been developed over the years, the Grimm type with a hollow anode accounts for a very large majority of glow discharge optical emission devices currently in use both for dc and rf sources. However, the cathode contact is often located at the back of the sample, in e.g. the Marcus type source, rather than at the front as in the original Grimm design. The guidelines contained herein are equally applicable to both and other source designs and the Grimm type source is used only as an example.

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This document specifies a method, using acetone, to determine the mass percentage of acetate, after
removal of non-fibrous matter, in textiles made of mixtures of
— acetate
with
— wool, animal hair, silk, protein, cotton (scoured, kiered, or bleached), flax (or linen), hemp, jute, abaca,
alfa, coir, broom, ramie, sisal, cupro, viscose, modal, polyamide, polyester, polypropylene, acrylic,
elastolefin, elastomultiester, melamine, polypropylene/polyamide bicomponent, polyacrylate and
glass fibres.
It is not applicable to mixtures containing modacrylic fibres, certain chlorofibres, nor to mixtures
containing acetate fibres that have been deacetylated on the surface.

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This document specifies the general provisions and gives the basic definitions of terms relating to sampling for gas analysis, including sampling devices, sampling methods, sampling technical considerations, and sampling safety. This document applies to both direct and indirect sampling of gas in pressure receptacles and pipelines, including pure gases and gas mixtures. Compressed and liquefied gases are both considered. This document applies to the sampling of processed gases and does not involve gas treatment processes. The sampling procedures specified are not intended for the sampling of special products which are the subject of other International Standards, such as liquefied petroleum gases (see ISO 4257) and gaseous natural gases (see ISO 10715).

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This document specifies a method using hot formic acid to determine the mass percentage of melamine
fibres after removal of non-fibrous matter, in textiles made of mixtures of:
— melamine fibres
with
— cotton, polypropylene or aramid fibres.

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This document specifies a method, using sulfuric acid, to determine the mass percentage of silk, after
removal of non-fibrous matter, in textiles made of mixtures of
— silk
with
— wool or other animal hair.

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This document specifies a method, using dimethylformamide, to determine the mass percentage of
acrylic, modacrylic, chlorofibre or elastane, after removal of non-fibrous matter, in textiles made of
mixtures of
— acrylic, certain modacrylics, certain chlorofibres, certain elastane fibres
with
— wool, animal hair, silk, cotton, viscose, cupro, modal, lyocell, polyamide, polyester, polypropylene,
elastomultiester, elastolefin, melamine, polypropylene/polyamide bicomponent, polyacrylate or
glass fibres.
It is not applicable to animal hair, wool and silk dyed with chromium based mordant dyes.
NOTE Dyestuff identification is described in ISO 16373-1.

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This document specifies a method for determining the use of certain azo colourants which can release
certain aromatic amines.

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This document specifies methods for the alignment of the ion beam to ensure good depth resolution in sputter depth profiling and optimal cleaning of surfaces when using inert gas ions in Auger electron spectroscopy (AES) and X-ray photoelectron spectroscopy (XPS). These methods are of two types: one involves a Faraday cup to measure the ion current; the other involves imaging methods. The Faraday cup method also specifies the measurements of current density and current distributions in ion beams. The methods are applicable for ion guns with beams with a spot size less than or equal to 1 mm in diameter. The methods do not include depth resolution optimization.

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