This document specifies requirements for the installation of permanently installed liquefied petroleum gas (LPG) systems and LPG-burning appliances on small craft.
This document is applicable to portable cooking appliances with internal LPG cartridges, with a capacity of 225 g or less (see Annex D).
This document is applicable to the storage of all LPG cylinders.
NOTE 1        National regulations can apply to the technical requirements of LPG cylinders.
This document does not contain procedures for commissioning new LPG installations or system maintenance or upgrades.
This document does not apply to LPG-fuelled propulsion engines or LPG-driven generators.
NOTE 2        National codes and procedures appropriate to the country concerned can be available.

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This document specifies how to design and operate allocation systems for gas production facilities. It describes the most common types, principles and methods used for the allocation of gas and associated liquids. The objective is to provide an approach to current best practice in the oil and gas industry. It applies to gas and liquid allocations to be performed in production, processing, transportation, storage and terminal installations dealing with natural gas and associated liquids as well as end products like sales gas, liquefied petroleum gas (LPG), liquefied natural gas (LNG), condensate and to some extend non-hydrocarbon gases like CO2, H2. This document provides the minimum information needed to develop and implement allocation procedures and systems both for internal purposes (well allocation) and fiscal or commercial applications with different owners and stakeholders. This document can be used to develop gas and liquid processing and transportation agreements and regulatory documents as well as to conduct audit of measurement and allocation systems. It also introduces the areas of competence needed and the terminology used in the industry.

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This document specifies requirements and guidance for manufacturers of ammonia-fired boilers regarding functional tests performed at the time of design and on-site acceptance tests, in order to meet the required environmental performance. This document stipulates the test methods, the measurement items, the evaluation methods and the test reports for each test. This document is applicable to: a) land boilers used for power generation with an electrical output of 100 MWe or more; b) equipment that uses NH3 of any mixing ratio as fuel; c) boilers with burners for combustion of fuel. This document does not apply to heat recovery steam generators for gas turbines, fluidized bed boiler, stokers, black liquor recovery boiler and process heat transfer equipment (used in petroleum refining).

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Ta nacionalni standard določa zahtevane lastnosti utekočinjenega naftnega plina – komercialne mešanice propan-butan in dodatne podatke, ki jih mora zagotoviti proizvajalec. Zahtevane lastnosti se nanašajo na uporabo proizvoda v gospodinjstvu in splošni uporabi. Ta standard se ne uporablja za utekočinjeni naftni plin, ki se uporablja kot gorivo za motorna vozila.

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SIGNIFICANCE AND USE
5.1 Samples of liquefied petroleum gases are examined by various test methods to determine physical and chemical characteristics and conformance with specifications.  
5.2 Equipment described by this practice may be suitable for transportation of LPG samples, subject to applicable transportation regulations.
SCOPE
1.1 This practice covers equipment and procedures for obtaining a representative sample of specification Liquefied Petroleum Gas (LPG), such as specified in Specification D1835, GPA 2140, and comparable international standards. This standard is applicable to flow-through cylinders with two valves and is not applicable to single valve cylinders or larger LPG sample containers such as those utilized for barbecue grills and/or forklift cylinders.  
1.2 This practice is suitable for obtaining representative samples for all routine tests for LP gases required by Specification D1835. In the event of a dispute involving sample integrity when sampling for testing against Specification D1835 requirements, Practice D3700 shall be used as the referee sampling procedure.  
1.3 This practice may also be used for other Natural Gas Liquid (NGL) products that are normally highly volatile, single phase materials (NGL mix, natural gasoline, field butane, etc.), defined in other industry specifications or contractual agreements, where use of open sample containers would risk the loss of volatile components. It is not intended for non-specification products that contain significant quantities of undissolved gases (N2, CO2), free water or other separated phases, such as raw or unprocessed gas/liquids mixtures and related materials. The same equipment can be used for these purposes, but additional precautions are generally needed to obtain representative samples of multiphase products (see Appendix X1 on Sampling Guidelines in Practice D3700).
Note 1: Practice D3700 describes a recommended practice for obtaining a representative sample of a light hydrocarbon fluid and the subsequent preparation of that sample for laboratory analysis when dissolved gases are present. Use of Practice D1265 will result in a small but predictable low bias for dissolved gases due to the liquid venting procedure to establish the 20 % minimum ullage.  
1.4 This practice includes recommendations for the location of a sample point in a line or vessel. It is the responsibility of the user to ensure that the sampling point is located so as to obtain a representative sample.  
1.5 The values stated in SI units are to be regarded as standard.  
1.5.1 Exception—Non-SI units are shown in parentheses for information only.  
1.6  This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.7 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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ABSTRACT
This specification presents the thermophysical property tables for methane, which are used in the calculation of the pressure-volume-temperature (PVT), thermodynamic, and transport properties of methane for process design and operations. Tables are provided for gaseous and liquid methane at specified temperature and pressure ranges. One table provides properties at the conditions of liquid-vapor equilibrium (saturation properties). The other table provides properties at selected T, p points for the equilibrium phase at those conditions. These tables apply directly only to pure gaseous methane, but are expected to be substantially useful in mathematical models and tables for the thermophysical properties of mixtures containing methane.
SCOPE
1.1 The thermophysical property tables for methane are for use in the calculation of the pressure-volume-temperature (PVT), thermodynamic, and transport properties of methane for process design and operations. Three tables are provided for gaseous and liquid methane at temperatures between 90 K and 600 K at pressures to 30 MPa. Two tables provide properties for the liquid and vapor phases at liquid-vapor equilibrium (saturation properties). The third table provides properties at selected T, p points for the equilibrium phase at those conditions. The tables were developed by the National Institute of Standards and Technology from a Standard Reference Database product REFPROP, version 10.02.  
1.2 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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SCOPE
1.1 This terminology standard covers the compilation of terminology developed by Committee D03 on Gaseous Fuels. It does not include terms, definitions, abbreviations, acronyms, and symbols specific to only a single D03 standard in which they appear. These terms, definitions, abbreviations, acronyms, and symbols are used in:  
1.1.1 The sampling of gaseous fuels,  
1.1.2 The analysis of gaseous fuels for composition and various other physical properties, and  
1.1.3 Other practices related to the processing, transmission, and distribution of gaseous fuels.  
1.2 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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SCOPE
1.1 This specification defines the minimum fuel quality requirements for gaseous fuels consisting primarily of methane blended with volume fraction of up to 10 % hydrogen (H2) when used as an internal combustion engine fuel.  
1.2 This specification defines the criteria for blending hydrogen with natural gas, biogas, or renewable natural gas (RNG) and then compressed into compressed natural gas (CNG) for use as a fuel for internal combustion engines in motor vehicles.  
1.3 The total volume fraction of hydrogen within the fuel shall consist of hydrogen contained in the natural gas, biogas, or renewable gas and any additional hydrogen blended into the fuel mixture.  
1.4 This specification covers the needs of internal combustion engines designed for use in motor vehicles.  
1.5 This specification applies to the fuel as delivered into the on-board fuel tanks of a motor vehicle as a compressed gas.  
1.6 This specification is not a natural gas pipeline standard; those requirements are determined by national and regional tariffs.  
1.7 Units—The values stated in SI units are to be regarded as standard. The values given in parentheses after SI units are provided for information only and are not considered standard.  
1.8 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.9 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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ABSTRACT
This test method is for the determination of total sulfur in combustible fuel gases and is applicable to natural gases, manufactured gases, mixed gases, and other miscellaneous gaseous fuels. For the use of barium chloride titration following collection of sulfur dioxide by alternative procedures, ammonia, amines, substances producing water soluble cations, and fluorides will interfere with the titration. The apparatus includes the following: (1) burner, (2) chimneys, absorbers, and spray traps, (3) flow meter, (4) vacuum system, (5) air-purifying system, and (6) monometer. The schematic diagrams of the gas burner, combustion and absorption apparatus, suction system, and purified air system are provided. Reagent grade chemicals shall be used in all tests and include: (1) water, (2) denatured ethyl or isopropyl alcohol, (3) barium chloride, standard solution, (4) hydrochloric acid, (5) hydrogen peroxide, (6) iso-propanol, (7) potassium hydrogen phthalate, (8) phenolphthalein, (9) methyl orange indicator solution, (10) silver nitrate solution, (11) sodium carbonate solution, (12) sodium hydroxide solution, (13) sulfuric acid, (14) tetrahydroxyquinone indicator, and (15) thorin indicator. The procedure for the following are detailed: (1) calibration and standardization of sodium hydroxide, sulfuric acid, and barium chloride solutions, (2) preparation of apparatus, (3) sulfur determination, (4) analysis of absorbent, and (5) quality assurance. The formula of calculating the volume of gas in standard cubic feet burned during the determination and the concentration of sulfur from the results of titration are given.
SCOPE
1.1 This test method is for the determination of total sulfur in combustible fuel gases, when present in sulfur concentrations between approximately 25 and 700 mg/m3 (1 to 30 grains per 100 cubic feet). It is applicable to natural gases, manufactured gases, mixed gases, and other miscellaneous gaseous fuels.  
1.2 The values stated in inch-pound units are to be regarded as standard.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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SIGNIFICANCE AND USE
5.1 This test method is useful in determining the concentration of hydrogen sulfide in gaseous samples and in verifying compliance with operational needs and/or environmental limitations for H2S content. The automated performance operation of this method allows unattended measurement of H2S concentration. The user is referred to Practice D7166 for unattended on-line use of instrumentation based upon the lead acetate reaction rate method.
SCOPE
1.1 This test method covers the determination of hydrogen sulfide (H2S) in gaseous fuels. It is applicable to the measurement of H2S in natural gas, liquefied petroleum gas (LPG), substitute natural gas, landfill gas, sewage treatment off gasses, recycle gas, flare gasses, and mixtures of fuel gases. This method can also be used to measure the hydrogen sulfide concentration in carbon dioxide. Air does not interfere. The applicable range is 0.1 to 16 parts per million by volume (ppm/v) (approximately 0.1 to 22 mg/m3) and may be extended to 100 % H2S by manual or automatic volumetric dilution.  
1.2 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.3 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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SIGNIFICANCE AND USE
5.1 Elemental sulfur impacts the quality of pipeline natural gas and deposits on pipeline flanges, fittings and valves, thereby impacting their performance. Natural gas suppliers and distributers require a standardized test method for measuring elemental sulfur. Some government regulators are also interested in measuring elemental sulfur since it would provide a means for assessing the contribution of elemental sulfur in pipelines to the SOx emission inventory from burning of gaseous fuels. Use of this method in concert with sulfur gas laboratory test methods such as Test Methods D4084, D4468, D5504, and D6228 or on-line methods such as D7165 or D7166 can provide users with a comprehensive sulfur compound profile for natural gas or other gaseous fuels. Other applications may include elemental sulfur in particulate deposits such as diesel exhausts.
SCOPE
1.1 This test method is primarily for the determination of elemental sulfur in natural gas pipelines, but it may be applied to other gaseous fuel pipelines and applications provided the user has validated its suitability for use. The detection range for elemental sulfur, reported as sulfur, is 0.0018 mg/L to 30 mg/L. The results may also be reported in units of mg/kg or ppm.  
1.2 The values stated in either SI units or inch-pound units are to be regarded separately as standard. The values stated in each system are not necessarily exact equivalents; therefore, to ensure conformance with the standard, each system shall be used independently of the other, and values from the two systems shall not be combined.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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SIGNIFICANCE AND USE
5.1 This test method can be used to determine specification, or regulatory compliance to requirements, for total sulfur in gaseous fuels. In gas processing plants, sulfur can be a contaminant and must be removed before gas is introduced into gas pipelines. In petrochemical plants, sulfur is a poison for many catalysts and must be reduced to acceptable levels, usually in the range from 0.01 ppm/v to 1 ppm/v. This test method may also be used as a quality-control tool for sulfur determination in finished products, such as propane, butane, ethane, and ethylene.
SCOPE
1.1 This test method covers the determination of sulfur gaseous fuels in the range from 0.001 to 20 parts per million by volume (ppm/v).  
1.2 This test method may be extended to higher concentration by dilution.  
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.4 This standard may involve hazardous materials, operations, and equipment. This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. Specific precautionary statements are given in 7.7, 7.8, and 8.3.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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SIGNIFICANCE AND USE
5.1 On-line, at-line, in-line and other near-real time monitoring systems that measure fuel gas characteristics such as the total sulfur content are prevalent in the natural gas and fuel gas industries. The installation and operation of particular systems vary on the specific objectives, contractual obligations, process type, regulatory requirements, and internal performance requirements needed by the user. This protocol is intended to provide guidelines for standardized start-up procedures, operating procedures, and quality assurance practices for on-line, at-line, in-line and other near-real time total sulfur monitoring systems.
SCOPE
1.1 This practice is for the determination of total sulfur from gas phase sulfur-containing compounds in high methane or hydrogen content gaseous fuels using on-line/at-line instrumentation.  
1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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SIGNIFICANCE AND USE
5.1 The methane number (MN) is a measure of the resistance of the gaseous fuel to autoignition (knock) when used in an internal combustion engine. The relative merits of gaseous fuels from different sources and having different compositions can be compared readily on the basis of their methane numbers. Therefore, the calculated methane number (MNC) is used as a parameter for determining the suitability of a gaseous fuel for internal combustion engines in both mobile and stationary applications.
SCOPE
1.1 This practice covers the method to determine the calculated methane number (MNC) of a gaseous fuel used in internal combustion engines. The basis for the method is a dynamic link library (DLL) suitable for running on computers with Microsoft Windows operating systems.  
1.2 This practice pertains to commercially available natural gas products that have been processed and are suitable for use in internal combustion engines. These fuels can be from traditional geological or renewable sources and include pipeline gas, compressed natural gas (CNG), liquefied natural gas, liquefied petroleum gas, and renewable natural gas as defined in Section 3.  
1.3 The calculation method within this practice is based on the MWM Method as defined in EN 16726, Annex A.2 The calculation method is an optimization algorithm that uses varying sequences of ternary and binary gas component tables generated from the composition of a gaseous fuel sample.3 Both the source code and a Microsoft Excel-based calculator are available for this method.  
1.4 This calculation method applies to gaseous fuels comprising of hydrocarbons from methane to hexane and greater (C6+); carbon monoxide; hydrogen; hydrogen sulfide; nitrogen; and carbon dioxide. The calculation method addresses pentanes (C5) and higher hydrocarbons and limits the individual volume fraction of C5 and C6+ to 3 % each and a combined total of 5 %. (See EN 16726, Annex A.) The calculation method is performed on a dry, oxygen-free basis.  
1.5 Units—The values stated in SI units are to be regarded as standard. Other units of measurement included in this standard are provided for information only and are not considered standard.  
1.6 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.7 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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SIGNIFICANCE AND USE
5.1 The hydrocarbon component distribution of liquefied petroleum gases and propene mixtures is often required for end-use sale of this material. Applications such as chemical feed stocks or fuel require precise compositional data to ensure uniform quality. Trace amounts of some hydrocarbon impurities in these materials can have adverse effects on their use and processing.  
5.2 The component distribution data of liquefied petroleum gases and propene mixtures can be used to calculate physical properties such as relative density, vapor pressure, and motor octane (see Practice D2598). Precision and accuracy of compositional data are extremely important when these data are used to calculate various properties of these petroleum products.
SCOPE
1.1 This test method covers the quantitative determination of individual hydrocarbons in liquefied petroleum (LP) gases and mixtures of propane and propene, excluding high-purity propene in the range of C1 to C5. Component concentrations are determined in the range of 0.01 % to 100 % by volume.  
1.2 This test method does not fully determine hydrocarbons heavier than C5 and non-hydrocarbon materials, and additional tests may be necessary to fully characterize an LPG sample.  
1.3 The values stated in SI units are to be regarded as standard. The values given in parentheses are for information only.  
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4.1 The user is advised to obtain LPG safety training for the safe operation of this test method procedure and related activities.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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SIGNIFICANCE AND USE
4.1 These test methods are used to determine trace amounts of volatile chlorides in butane-butene mixtures. Such information is valuable in cases where chloride is deleterious in the use of this product; also, chloride contributes to corrosion problems in processing units in instances where further processing of this material is involved.
SCOPE
1.1 These test methods cover the determination of the total volatile organic chlorides in concentrations from 10 mg/kg to 100 mg/kg in butane-butene mixtures. The amperometric finish is not directly applicable in the presence of other substances that combine with silver ion or oxidize chloride ion in dilute acid solution. Bromides, sulfides, ammonia, tobacco smoke, and more than 25 μg of hydrogen peroxide in the test solution interfere in the spectrophotometric procedure.  
1.2 Dissolved sodium chloride is not quantitatively determined using these test methods.  
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.   Specific warning statements are given in Sections 5, 8, 11, 14, 19, and Annex A1.  
1.4.1 The user is advised to obtain LPG safety training for the safe operation of this test method procedure and related activities.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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SIGNIFICANCE AND USE
5.1 LP-gas is colorless and odorless, and not detectable by normal human senses. To provide an olfactory warning in the event of a leak, LP-gas intended for domestic or commercial fuel use is intentionally odorized so as to be readily detectable well below flammable or suffocating concentration levels of LP-gas in air. (See Appendix X1 for important explanations.) The most common odorant for LP-gas is ethyl mercaptan. The field use of this test method will rapidly determine the presence and concentration of ethyl mercaptan in LP-gas vapor without the necessity for complex laboratory equipment.
SCOPE
1.1 This test method describes a rapid and simple procedure using length-of-stain tubes for field measurement of ethyl mercaptan in the vapor phase of LP-gas systems. Although length-of-stain tubes are available to detect ethyl mercaptan concentrations in the range of 0.5 to 120 parts per million by volume, this test method is specifically applicable to systems containing 5 ppm by volume or more of ethyl mercaptan in LP-gas vapors.  
Note 1: A chromatographic technique can be used for more precise, quantitative determination of ethyl mercaptan in LP-gas.  
1.2 The values stated in SI units are to be regarded as standard. The values given in parentheses after SI units are provided for information only and are not considered standard.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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SIGNIFICANCE AND USE
5.1 Information on the vapor pressures of liquefied petroleum gas products under temperature conditions from 37.8 °C to 70 °C (100 °F to 158 °F) is pertinent to selection of properly designed storage vessels, shipping containers, and customer utilization equipment to ensure safe handling of these products.  
5.2 Determination of the vapor pressure of liquefied petroleum gas is important for safety reasons to ensure that the maximum operating design pressures of storage, handling, and fuel systems will not be exceeded under normal operating temperature conditions.  
5.3 For liquefied petroleum gases, vapor pressure can be considered a semi-quantitative measure of the amount of the most volatile material present in the product, and this can give an indication of low temperature operability.
SCOPE
1.1 This test method covers the determination of the gauge vapor pressures of liquefied petroleum gas products at temperatures of 37.8 °C (100 °F) up to and including a test temperature of 70 °C (158 °F). (Warning—Extremely flammable gas. May be harmful when inhaled.)
Note 1: An alternative method for measurement of vapor pressure of liquefied petroleum gases is Test Method D6897.  
1.2 The values stated in SI units are to be regarded as standard. The values given in parentheses after SI units are provided for information only and are not considered standard.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. For specific warning statements, see 1.1 and Annex A2.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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SIGNIFICANCE AND USE
5.1 Liquefied petroleum gases and their products of combustion must not be unduly corrosive to the materials with which they come in contact. The potential personnel exposure hazards of H2S also make the detection and measurement of hydrogen sulfide important, even in low concentrations. In addition, in some cases the odor of the gases shall not be objectionable. (See Specification D1835 and GPA 2140.)
SCOPE
1.1 This test method2 covers the detection of hydrogen sulfide in liquefied petroleum (LP) gases. The sensitivity of the test is about 4 mg/m3 (0.15 to 0.2 grain of hydrogen sulfide per 100 ft3) of gas.  
1.2 The values stated in SI units are to be regarded as standard. The values given in parentheses after SI units are provided for information only and are not considered standard.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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SIGNIFICANCE AND USE
5.1 Proton exchange membranes (PEM) used in fuel cells are susceptible to contamination from a number of species that can be found in hydrogen. It is critical that these contaminants be measured and verified to be present at or below the amounts stated in SAE J2719 and ISO 14687 to ensure both fuel cell longevity and optimum efficiency. Contaminant concentrations as low as single-figure ppb(v) for some species can seriously compromise the life span and efficiency of PEM fuel cells. The presence of contaminants in fuel-cell-grade hydrogen can, in some cases, have a permanent adverse impact on fuel cell efficiency and usability. It is critical to monitor the concentration of key contaminants in hydrogen during the production phase through to delivery of the fuel to a fuel cell vehicle or other PEM fuel cell application. In ISO 14687, the upper limits for the contaminants are specified. Refer to SAE J2719 (see 2.3) for specific national and regional requirements. For hydrogen fuel that is transported and delivered as a cryogenic liquid, there is additional risk of introducing impurities during transport and delivery operations. For instance, moisture can build up over time in liquid transfer lines, critical control components, and long-term storage facilities, which can lead to ice buildup within the system and subsequent blockages that pose a safety risk or the introduction of contaminants into the gas stream upon evaporation of the liquid. Users are reminded to consult Practice D7265 for critical thermophysical properties such as the ortho/para hydrogen spin isomer inversion that can lead to additional hazards in liquid hydrogen usage.
SCOPE
1.1 This test method describes contaminant determination in fuel cell grade hydrogen as specified in relevant ASTM and ISO standards using cavity ring-down spectroscopy (CRDS). This standard test method is for the measurement of one or multiple contaminants including, but not limited to, water (H2O), oxygen (O2), methane (CH4), carbon dioxide (CO2), carbon monoxide (CO), ammonia (NH3), and formaldehyde (H2CO), henceforth referred to as “analyte.”  
1.2 This test method applies to CRDS analyzers with one or multiple sensor modules (see 6.2 for definition). This test method describes sampling apparatus design, operating procedures, and quality control procedures required to obtain the stated levels of precision and accuracy.  
1.3 The values stated in either SI units or inch-pound units are to be regarded separately as standard. The values stated in each system are not necessarily exact equivalents; therefore, to ensure conformance with the standard, each system shall be used independently of the other, and values from the two systems shall not be combined.  
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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SIGNIFICANCE AND USE
5.1 Gaseous fuels, such as natural gas, petroleum gases and bio-gases, contain sulfur compounds that are naturally occurring or that are added as odorants for safety purposes. These sulfur compounds are odorous, toxic, corrosive to equipment, and can inhibit or destroy catalysts employed in gas processing and other end uses. Their accurate continuous measurement is important to gas processing, operation and use, and is frequently of regulatory interest.  
5.2 Small amounts (typically, total of 4 to 6 ppm(v)) of sulfur odorants are added to natural gas and other fuel gases for safety purposes. Some sulfur odorants are reactive and may be oxidized to form more stable sulfur compounds having higher odor thresholds which adversely impact the potential safety of the gas delivery systems and gas users. Gaseous fuels are analyzed for sulfur compounds and odorant levels to assist in pipeline integrity surveillance and to ensure appropriate odorant levels for public safety.  
5.3 This method offers an on-line method to continuously identify and quantify individual target sulfur species in gaseous fuel with automatic calibration and validation.
SCOPE
1.1 This test method is for on-line measurement of gas phase sulfur-containing compounds in gaseous fuels by gas chromatography (GC) and electrochemical (EC) detection. This test method is applicable to hydrogen sulfide, C1 to C4 mercaptans, sulfides, and tetrahydrothiophene (THT).  
1.1.1 Carbonyl sulfide (COS) is not measured according to this test method.  
1.1.2 The detection range for sulfur compounds is approximately from 0.1 to 100 ppm(v) (mL/m3) or 0.1 to 100 mg/m3 at 25 °C, 101.3 kPa. The detection range will vary depending on the sample injection volume, chromatographic peak separation, and the sensitivity of the specific EC detector.  
1.2 This test method describes a GC-EC method using capillary GC columns and a specific detector for natural gas and other gaseous fuels composed of mainly light (C4 and smaller) hydrocarbons. Alternative GC columns including packed columns, detector designs, and instrument parameters may be used, provided that chromatographic separation, quality control, and measurement objectives needed to comply with user or regulator needs, or both, are achieved.  
1.3 This test method does not intend to identify and measure all individual sulfur species and is mainly employed for monitoring naturally occurring reduced sulfur compounds commonly found in natural gas and fuel gases or employed as an odorant in these gases.  
1.4 This test method is typically employed in repetitive or continuous on-line monitoring of sulfur components in natural gas and fuel gases using a single sulfur calibration standard. Guidance for producing calibration curves specific to particular analytes or enhanced quality control procedures can be found in Test Methods D5504, D5623, D6228, D6968, ISO 19739, or GPA 2199.  
1.5 The test method can be used for measuring sulfur compounds listed in Table 1 in air or other gaseous matrices, provided that compounds that can interfere with the GC separation and electrochemical detection are not present.  
1.6 This test method is written as a companion to Practices D5287, D7165 and D7166.  
1.7 Units—The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.8 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.9 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Tec...

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This document defines a gas chromatographic analysis for the determination of the composition of fuel gases, as used in refinery heating gas. These results are used to calculate the carbon content and the lower calorific value.
With this gas chromatographic analysis, an overall of 23 refinery heating gas components are determined in concentrations as typically found in refineries (see Table 1 for further details).
Water is not analysed. The results represent dry gases.
NOTE 1   Depending on the equipment used, there is a possibility to determine higher hydrocarbons as well.
NOTE 2   For the purposes of this document, the terms “% (V/V)” is used to represent the volume fraction (φ).
IMPORTANT — This document does not purport to address all of the safety problems associated with its use. It is the responsibility of the user of this document to establish appropriate safety and health practices and determine the applicability of regulatory limitations.

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ABSTRACT
This specification covers liquefied petroleum gases consisting of propane, propene (propylene), butane, and mixtures of these materials. The products are intended for use as domestic, commercial and industrial heating, and engine fuels. Care must be taken to in sampling of the liquefied gases for test results to be significant. All four types of liquefied petroleum gases covered by this specification should conform to the specified requirements for vapor pressure, volatile residue, residue matter, relative density, and corrosion.
SCOPE
1.1 This specification covers those products commonly referred to as liquefied petroleum gases, consisting of propane, propene (propylene), butane, and mixtures of these materials. Four basic types of liquefied petroleum gases are provided to cover the common use applications.  
1.2 This specification is applicable to products intended for use as domestic, commercial and industrial heating, and engine fuels.  
1.3 The values stated in SI units are to be regarded as standard. The values given in parentheses after SI units are provided for information only and are not considered standard.  
1.3.1 The non-SI unit ‘psig’ is the standard unit for footnote C of Table 1 because that unit of measurement is widely used in North American industry.  
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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SIGNIFICANCE AND USE
5.1 Combustion of gaseous fuel containing significant siloxane concentrations results in conversion of these siloxanes to silicon dioxide (SiO2). This SiO2 accumulates on downstream equipment such as the interior of reciprocating engine cylinders (used for electricity generation and transportation applications), flame sensors, and condenser coils in residential/commercial furnaces, or post-combustion catalysts used for the removal of NO and NO2. In each of these cases, SiO2 compromises the performance of the equipment and may lead to eventual failure. Continuous measurement of siloxane concentrations enables a fuel producer to ensure their gas quality meets contractual obligations, regulatory requirements, pipeline injection tariff limits, and internal performance requirements. This method is intended to provide procedures for standardized start-up procedures, operating procedures, and quality assurance practices for on-line analysis of siloxanes using a GC-IMS analyzer.
SCOPE
1.1 This test method is for the determination of speciated siloxane concentrations in gaseous fuels using on-line Gas Chromatography Ion-Mobility Spectrometry (GC-IMS).  
1.2 Units—The values stated in SI units are to be regarded as standard. The values given in parentheses after SI units are provided for information only and are not considered standard.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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This document specifies the requirements for the installation of liquefied petroleum gas systems for habitation purposes in leisure accommodation vehicles and for accommodation purposes in other vehicles.
It details health and safety requirements on:
—   the selection of materials;
—   components and appliances;
—   design considerations;
—   tightness testing of installations;
—   the contents of the user's handbook.
This document only covers installations supplied with 3rd family gases (LPG).
It does not cover:
—   water connections or electrical power supplies to the appliance(s);
—   portable appliances, incorporating their own LPG supply;
—   the installation of LPG appliances to be used for commercial purposes;
—   LPG installations on boats;
—   LPG supply equipment and LPG appliances separate from and external to the body of the vehicle.
This document covers LPG tanks fulfilling the requirements of the Pressure Equipment Directive (2014/68/EU).
Attention is drawn to the Pressure Equipment Directive (2014/68/EU) for any parts of the installation operating above 0,5 bar.

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This document defines a gas chromatographic analysis for the determination of the composition of fuel gases, as used in refinery heating gas. These results are used to calculate the carbon content and the lower calorific value.
With this gas chromatographic analysis, an overall of 23 refinery heating gas components are determined in concentrations as typically found in refineries (see Table 1 for further details).
Water is not analysed. The results represent dry gases.
NOTE 1   Depending on the equipment used, there is a possibility to determine higher hydrocarbons as well.
NOTE 2   For the purposes of this document, the terms “% (V/V)” is used to represent the volume fraction (φ).
IMPORTANT — This document does not purport to address all of the safety problems associated with its use. It is the responsibility of the user of this document to establish appropriate safety and health practices and determine the applicability of regulatory limitations.

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SIGNIFICANCE AND USE
5.1 Control over the residue content (required by Specification D1835) is of considerable importance in end-use applications of LPG. In liquid feed systems, residues can lead to troublesome deposits and, in vapor withdrawal systems, residues that are carried over can foul regulating equipment. Residues that remain in vapor-withdrawal systems will accumulate, can be corrosive, and will contaminate subsequent product. Water, particularly if alkaline, can cause failure of regulating equipment and corrosion of metals.  
5.2 See Appendix X2 for information on the effect of temperature on the measurement of residue in LPG.
SCOPE
1.1 This test method covers the determination of extraneous materials weathering above 38 °C that are present in liquefied petroleum gases. The extraneous materials will generally be dissolved in the LPG, but may have phase-separated in some instances.  
1.2 Liquefied petroleum gases that contain certain anti-icing additives can give erroneous results by this test method.  
1.3 Although this test method has been used to verify cleanliness and lack of heavy contaminants in propane for many years, it might not be sensitive enough to protect some equipment from operational problems or increased maintenance. A more sensitive test, able to detect lower levels of dissolved contaminants, could be required for some applications.  
1.4 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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SIGNIFICANCE AND USE
3.1 Generally, contracts governing the pipeline transmission of natural gas contain specifications limiting the maximum concentration of water vapor allowed. Excess water vapor can cause corrosive conditions, degrading pipelines and equipment. It can also condense and freeze or form methane hydrates causing blockages. Water–vapor content also affects the heating value of natural gas, thus influencing the quality of the gas. This test method permits the determination of water content of natural gas.
SCOPE
1.1 This test method covers the determination of the water vapor content of gaseous fuels by measurement of the dew-point temperature and the calculation therefrom of the water vapor content.  
Note 1: Some gaseous fuels contain vapors of hydrocarbons or other components that easily condense into liquid and sometimes interfere with or mask the water dew point. When this occurs, it is sometimes very helpful to supplement the apparatus in Fig. 1 with an optical attachment that uniformly illuminates the dew–point mirror and also magnifies the condensate on the mirror. With this attachment it is possible, in some cases, to observe separate condensation points of water vapor, hydrocarbons, and glycolamines as well as ice points. However, if the dew point of the condensable hydrocarbons is higher than the water vapor dew point, when such hydrocarbons are present in large amounts, they may flood the mirror and obscure or wash off the water dew point. Best results in distinguishing multiple component dew points are obtained when they are not too closely spaced.
FIG. 1 Bureau of Mines Dew-Point Apparatus  
Note 2: Condensation of water vapor on the dew-point mirror may appear as liquid water at temperatures as low as 0 to −10°F (−18 to −23°C). At lower temperatures an ice point rather than a water dew point likely will be observed. The minimum dew point of any vapor that can be observed is limited by the mechanical parts of the equipment. Mirror temperatures as low as −150°F (−100°C) have been measured, using liquid nitrogen as the coolant with a thermocouple attached to the mirror, instead of a thermometer well.  
1.2 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.3 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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SIGNIFICANCE AND USE
4.1 This practice provides requirements for the handling, transportation, and storage of 2-BTP encountered in distribution through both commercial and military channels. It is intended to ensure that 2-BTP is handled, transported, and stored in such a way that its physical property virtues are not degraded. Transport may be by various means, such as, but not limited to, highway, rail, water, and air.
SCOPE
1.1 This practice covers guidance and direction to suppliers, reclaimers, purchasers, and users in the handling, transportation, and storage of 2-Bromo-3,3,3-Trifluoro-1-Propene (“2-BTP”).  
1.2 The values stated in inch-pound units are to be regarded as standard. The values given in parentheses are mathematical conversions to SI units that are provided for information only and are not considered standard.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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ABSTRACT
This specification applies to 2-Bromo-3, 3,3-Trifluoro-1-Propene (“2-BTP”) as a fire-fighting medium. It does not address the fire-fighting equipment or hardware that employs 2-BTP or the conditions of employing such equipment (for example, handhelds, fixed installations, etc.). The storage or transportation of 2-BTP is also not covered.
SCOPE
1.1 This specification covers requirements for 2-Bromo-3,3,3-Trifluoro-1-Propene (“2-BTP”) as a fire-fighting medium.  
1.2 This specification does not address the fire-fighting equipment or hardware that employs 2-BTP or the conditions of employing such equipment (for example, handhelds, fixed installations, etc.).  
1.3 This specification does not address the storage or transportation of 2-BTP. Storage, handling, and transportation issues are addressed in Practice D8061.  
1.4 The values stated in inch-pound units are to be regarded as standard. The values given in parentheses are mathematical conversions to SI units that are provided for information only and are not considered standard.  
1.5 The following safety hazards caveat pertains only to the test methods portion, Section 6, of this specification:  
1.5.1 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. Specific hazards statements are given in Section 4.  
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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This document specifies the quality requirements for Liquefied Natural Gas (LNG) used as a fuel for marine applications. It defines the relevant parameters to measure as well as the required values and the test reference methods for all those parameters.
This document applies to LNG from any source, e.g. gas from conventional reservoirs, shale gas, coalbed methane, biomethane, synthetic methane. LNG described in this document can come from synthesis process out of fossil fuels or renewable sources.
This document identifies the required specifications for fuels delivered at the time and place of custody transfer (at the delivery point).

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SIGNIFICANCE AND USE
4.1 The sulfur content of LPG, used for fuel purposes, contributes to SOx emissions and can lead to corrosion in engine and exhaust systems. Some process catalysts used in petroleum and chemical refining can be poisoned by sulfur bearing materials in the feed stocks. This test method can be used to determine sulfur in process feeds, to measure sulfur in finished products, and can also be used for compliance determinations when acceptable to a regulatory authority.
SCOPE
1.1 This test method covers the determination of total volatile sulfur in gaseous hydrocarbons and liquefied petroleum (LP) gases. It is applicable to analysis of natural, processed, and final product materials. Precision has been determined for sulfur in gaseous hydrocarbons in the range of 1 mg/kg to 100 mg/kg and for sulfur in LP gases in the range of 1 mg/kg to 196 mg/kg (Note 1).
Note 1: An estimate of pooled limit of quantification (PLOQ), information regarding sample stability and other general information derived from the interlaboratory studies on precision can be referenced in the ASTM research reports.2,3  
1.2 This test method may not detect sulfur compounds that do not vaporize under the conditions of the test.  
1.3 This test method is applicable for total volatile sulfur determination in LP gases containing less than 0.35 % (mass/mass) halogen(s).  
1.4 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. See 3.1 and Sections 6 and 7 for specific warning statements.  
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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SIGNIFICANCE AND USE
5.1 On-line, at-line, in-line, and other near-real time monitoring systems that measure fuel gas characteristics such as the heating value are prevalent in the natural gas and fuel gas industries. The installation and operation of particular systems vary on the specific objectives, process type, regulatory requirements, and internal performance requirements needed by the user. This protocol is intended to provide guidelines for standardized start-up procedures, operating procedures, and quality assurance practices for on-line, at-line, in-line, and other near-real time heating value monitoring systems.
SCOPE
1.1 This practice is for the determination of heating value in high methane content gaseous fuels such as natural gas using an on-line/at-line gas chromatograph.  
1.2 Units—The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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SIGNIFICANCE AND USE
4.1 Vapor pressure is an important specification property of commercial propane, special duty propane, propane/butane mixtures, and commercial butane that assures adequate vaporization, safety, and compatibility with commercial appliances. Relative density, while not a specification criterion, is necessary for determination of filling densities and custody transfer. The motor octane number (MON) is useful in determining the products' suitability as a fuel for internal combustion engines.
SCOPE
1.1 This practice covers, by compositional analysis, the approximate determination of the following physical characteristics of commercial propane, special-duty propane, commercial propane/butane mixtures, and commercial butane (covered by Specification D1835): vapor pressure, relative density, and motor octane number (MON).  
1.1.1 This practice is not applicable to any product exceeding specifications for nonvolatile residues. (See Test Method D2158.)  
1.1.2 For calculating motor octane number, this practice is applicable only to mixtures containing 20 % or less of propene.  
1.1.3 For calculated motor octane number, this practice is based on mixtures containing only components shown in Table 1.  
1.2 The values stated in SI units are to be regarded as standard.  
1.2.1 Exceptions:  
1.2.1.1 Non-SI units in parentheses are given for information only.
1.2.1.2 Motor octane number and relative density are given in MON numbers and dimensionless units, respectively.  
1.3 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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SIGNIFICANCE AND USE
5.1 The measurement of carbon dioxide in natural gas is important, because of gas quality specifications, the corrosive nature of carbon dioxide on pipeline materials, and the affects of carbon dioxide on utilization equipment.  
5.2 This test method provides inexpensive field screening of carbon dioxide. The system design is such that it may be used by nontechnical personnel with a minimum of proper training.
SCOPE
1.1 This test method covers a rapid and simple field determination of carbon dioxide in natural gas pipelines. Available detector tubes provide a total measuring range of 100 ppm (parts per million) up to 60 % by volume, although the majority of applications will be on the lower end of this range (that is, under 5 %). At least one manufacturer provides a special kit for measurements from 10 to 100 % CO2, but the normal 100 cc hand pump is not used. See Note 1.  
Note 1: High-range carbon dioxide detector tubes will have measuring ranges in percent (%) CO2, and low-range tubes will be in parts per million (ppm). To convert percent to ppm, multiply by 10 000 (1 % = 10 000 ppm).  
1.2 Units—The values stated in SI units are regarded as standard. The inch-pound units in parentheses are for information only.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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This document specifies the quality requirements for Liquefied Natural Gas (LNG) used as a fuel for marine applications. It defines the relevant parameters to measure as well as the required values and the test reference methods for all those parameters.
This document applies to LNG from any source, e.g. gas from conventional reservoirs, shale gas, coalbed methane, biomethane, synthetic methane. LNG described in this document can come from synthesis process out of fossil fuels or renewable sources.
This document identifies the required specifications for fuels delivered at the time and place of custody transfer (at the delivery point).

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SIGNIFICANCE AND USE
5.1 Many sources of natural and petroleum gases contain sulfur compounds that are odorous, corrosive, and poisonous to catalysts used in gaseous fuel processing.  
5.2 Low ppm amounts of sulfur odorants are added to natural gas and LP gases for safety purposes. Some odorants are unstable and react to form compounds having lower odor thresholds. Quantitative analysis of these odorized gases ensures that odorant injection equipment is performing to specification.  
5.3 Although not intended for application to gases other than natural gas and related fuels, this test method has been successfully applied to fuel type gases, including refinery, landfill, cogeneration, and sewage digester gas. Refinery, landfill, sewage digester, and other related fuel type gases inherently contain volatile sulfur compounds that are subject to federal, state, or local control. The methane fraction of these fuel type gases is occasionally sold to distributors of natural gas. For these reasons, both regulatory agencies and production and distribution facilities may require the accurate determination of sulfur to satisfy regulatory, production, or distribution requirements. Fuel gases are also used in energy production or are converted to new products using catalysts that are poisoned by excessive sulfur in the feed gas. Industry frequently requires measurement of sulfur in these fuel type gases to protect their catalyst investments.  
5.4 Analytical Methods—Gas chromatography (GC) is commonly used in the determination of fixed gas and organic composition of natural gas (Test Method D1945). Other standard ASTM methods for the analysis of sulfur in fuel gases include Test Methods D1072 and D4468 for total sulfur and Test Methods D4010 and D4884 for hydrogen sulfide.
SCOPE
1.1 This test method is primarily for the determination of speciated volatile sulfur-containing compounds in high methane content gaseous fuels such as natural gas. It has been successfully applied to other types of gaseous samples, including air, digester, landfill, and refinery fuel gas. The detection range for sulfur compounds, reported as picograms sulfur, is 0.01 to 1000. This is equivalent to 0.01 to 1000 mg/m3, based upon the analysis of a 1 cc sample.  
1.2 The range of this test method may be extended to higher concentration by dilution or by selection of a smaller sample loop.
Note 1: Dilution will reduce method precision.  
1.3 This test method does not purport to identify all sulfur species in a sample. Only compounds that are eluted through the selected column under the chromatographic conditions chosen are determined. The detector response to sulfur is equimolar for all sulfur compounds within the scope (1.1) of this test method. Thus, unidentified compounds are determined with equal precision to that of identified substances. Total sulfur content is determined from the total of individually quantified components.  
1.4 Units—The values stated in SI units are to be regarded as standard. The values given in parentheses after SI units are provided for information only and are not considered standard.  
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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This document specifies the quality requirements for Liquefied Natural Gas (LNG) used as a fuel for marine applications. It defines the relevant parameters to measure as well as the required values and the test reference methods for all those parameters. This document applies to LNG from any source, e.g. gas from conventional reservoirs, shale gas, coalbed methane, biomethane, synthetic methane. LNG described in this document can come from synthesis process out of fossil fuels or renewable sources. This document identifies the required specifications for fuels delivered at the time and place of custody transfer (at the delivery point).

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SIGNIFICANCE AND USE
5.1 The hydrocarbon component distribution of gaseous mixtures is often required for end-use sale of this material. Applications such as chemical feedstock or fuel require precise compositional data to ensure uniform quality. Trace amounts of some hydrocarbon impurities in these materials can have adverse effects on their use and processing. Certain regulations may require use of such method.  
5.2 The component distribution data of gaseous mixtures can be used to calculate physical properties such as relative density, vapor pressure, and heating value calculations found in Practice D3588. Precision and accuracy of compositional data is extremely important when this data is used to calculate various properties of petroleum products.
SCOPE
1.1 This test method is intended to quantitatively determine the non-condensed hydrocarbon gases with carbon numbers from C1 to C5+ and non-hydrocarbon gases, such as H2, CO2, O2, N2, and CO, in gaseous samples. This test method is a companion standard test method to Test Method D1945 and Practice D1946, differing in that it incorporates use of capillary columns instead of packed columns and allows other technological differences.  
1.2 Hydrogen sulfide can be detected but may not be accurately determined by this procedure due to loss in sample containers or sample lines and possible reactions unless special precautions are taken.  
1.3 Non-hydrocarbon gases have a lower detection limit in the concentration range of 0.03 to 100 mole percent using a thermal conductivity detector (TCD), and C1 to C6 hydrocarbons have a lower detection limit in the range of 0.005 to 100 mole percent using a flame ionization detector (FID); using a TCD may increase the lower detection limit to approximately 0.03 mole percent.  
1.3.1 Hydrocarbon detection limits can be reduced with the use of pre-concentration techniques or cryogenic trapping, or both.  
1.4 This test method does not fully determine individual hydrocarbons heavier than benzene, which are grouped together as C7+. When detailed analysis is not required, the compounds with carbon number greater than C5 may be grouped as either C6+ or C7+. Accurate analysis of C5+ components depends on proper vaporization of these compounds during sampling at process unit sources as well as in the sample introduction into the analyzer in the laboratory.  
1.5 Water vapor may interfere with the C6+ analysis if a TCD detector is used.  
1.6 Helium and argon may interfere with the determination of hydrogen and oxygen respectively. Depending on the analyzer used, pentenes, if present, may either be separated or grouped with the C6+ components.  
1.7 Units—The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.8 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.9 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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This document provides guidance to support organizations with the implementation of the European standards on CNG and LNG stations for fuelling vehicles (i.e. EN-ISO 16923:2018 and EN-ISO 16924:2018, respectively).
This document cross-references European standards to the international standards listed in EN-ISO 16923:2018 and EN-ISO 16924:2018 and links these standards to relevant European Directives, where applicable.

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This document specifies a wavelength-dispersive X-ray fluorescence (WDXRF) test method for the determination of the sulfur content of liquid, homogeneous automotive fuels from 5 mg/kg to 500 mg/kg, which have a maximum oxygen content of 3,7 % (m/m). This product range covers:
—          diesel fuels containing up to about 30 % (V/V) fatty acid methyl esters (FAME),
—          motor gasolines containing up to about 10 % (V/V) ethanol,
—          synthetic fuels such as hydrotreated vegetable oil (HVO) and gas to liquid (GTL) having sulfur contents in the range of 5 mg/kg to 45 mg/kg.
Products with higher oxygen content show significant matrix effects, e.g. pure FAME used as biodiesel, nevertheless, pure FAME can be analysed when the corresponding procedures are followed (see 5.3 and 8.1).
Other products can be analysed with this test method, though precision data for products other than those mentioned have not been established for this document.
NOTE 1   Sulfur contents higher than 500 mg/kg can be determined after sample dilution, however, the precision was not established for diluted samples.
NOTE 2    For the purposes of this document, "% (m/m)" and "% (V/V)" are used to represent the mass fraction, w, and the volume fraction, φ, of a material respectively.

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This document specifies an ultraviolet (UV) fluorescence test method for the determination of the sulfur content of the following products:
—     having sulfur contents in the range 3 mg/kg to 500 mg/kg,
—     motor gasolines containing up to 3,7 % (m/m) oxygen [including those blended with ethanol up to about 10 % (V/V)],
—     diesel fuels, including those containing up to about 30 % (V/V) fatty acid methyl ester (FAME),
—     having sulfur contents in the range of 3 mg/kg to 45 mg/kg,
—     synthetic fuels, such as hydrotreated vegetable oil (HVO) and gas to liquid (GTL).
Other products can be analysed and other sulfur contents can be determined according to this test method, however, no precision data for products other than automotive fuels and for results outside the specified range have been established for this document. Halogens interfere with this detection technique at concentrations above approximately 3 500 mg/kg.
NOTE 1  Some process catalysts used in petroleum and chemical refining can be poisoned when trace amounts of sulfur-bearing materials are contained in the feedstocks.
NOTE 2  This test method can be used to determine sulfur in process feeds and can also be used to control sulfur in effluents.
NOTE 3  For the purposes of this document, "% (m/m)" and "% (V/V)" are used to represent the mass fraction, w, and the volume fraction, φ, of a material respectively.
NOTE 4  Sulfate species in ethanol do not have the same conversion factor of organic sulfur in ethanol. Nevertheless, sulfates have a conversion factor close to that of organic sulfur.
NOTE 5  Nitrogen interference can occur, see 6.5 for further guidance.

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ABSTRACT
This specification covers the isobutane thermophysical property tables which are used in the calculation of the pressure-volume-temperature (PVT), thermodynamic, and transport properties of isobutane for process design and operations. Tables are provided for gaseous and liquid isobutane at temperatures between 135 and 600K at pressures to 35 MPa. These tables apply directly only to pure gaseous and liquid isobutane. However, it is expected that mathematical models and tables shall be useful for the thermophysical properties of mixtures containing isobutane, such as natural gas. These thermophysical property tables are: Thermophysical Properties of Coexisting Gaseous and Liquid Isobutane, in SI units and Thermophysical Properties of Isobutane, along isobars, in SI units.
SCOPE
1.1 The thermophysical property tables for isobutane are for use in the calculation of the pressure-volume-temperature (PVT), thermodynamic, and transport properties of isobutane for process design and operations. Two tables provide properties at the conditions of liquid-vapor equilibrium (saturation properties), one for liquid and one for vapor, at temperatures between 120 K and the critical point, 407.81 K. A third table provides properties at selected T, p points for the equilibrium phase at temperatures between 120 K and 570 K at pressures to 20 MPa. The tables were developed using the National Institute of Standards and Technology Standard Reference Database product REFPROP, version 9.1.  
1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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