ISO/TR 27929:2024

Technical
Report
ISO/TR 27929
First edition
Transportation of CO by ship
2024-10
Transport de CO par bateau
Reference number
© ISO 2024
All rights reserved. Unless otherwise specified, or required in the context of its implementation, no part of this publication may
be reproduced or utilized otherwise in any form or by any means, electronic or mechanical, including photocopying, or posting on
the internet or an intranet, without prior written permission. Permission can be requested from either ISO at the address below
or ISO’s member body in the country of the requester.
ISO copyright office
CP 401 • Ch. de Blandonnet 8
CH-1214 Vernier, Geneva
Phone: +41 22 749 01 11
Email: copyright@iso.org
Website: www.iso.org
Published in Switzerland
ii
Contents Page
Foreword .v
Introduction .vi
1 Scope . 1
2 Normative references . 1
3 Terms and definitions . 1
4 Abbreviations . 3
5 Re gulatory regime for maritime and inland waterways for CO transportation . 3
5.1 General .3
5.2 Maritime governance .4
5.3 Technical safety regime for maritime transportation of liquid CO .5
5.4 Greenhouse gas emissions .6
5.5 Trading and cross-border transportation .6
6 Ship transport of CO . . 7
6.1 General .7
6.2 CO cargo transport conditions .7
6.2.1 General .7
6.2.2 Low pressure .8
6.2.3 Medium pressure .8
6.2.4 Elevated pressure .8
6.2.5 Density effects .9
6.2.6 Solid state CO (dry ice) .9
6.3 Cargo tank design .9
6.3.1 Cargo tank design considerations.9
6.3.2 Tank material .10
6.3.3 Novel materials .10
6.3.4 Design pressure .11
6.3.5 Insulation .11
6.4 CCS ship transport concepts.11
6.4.1 General .11
6.4.2 Ship terminal to terminal . 12
6.4.3 Barge terminal to terminal (inland waterways) . 12
6.4.4 Offshore floating storage and injection unit (FSIU) . 12
6.4.5 Offshore injection unit . 12
6.4.6 Offshore direct injection . 13
6.5 Multi Gas and dedicated carriers . 13
6.5.1 General . 13
6.5.2 Existing ship conversion . 13
6.6 Ship design . 13
7 Properties of CO , CO streams and mixing of CO streams influencing the ship
2 2 2
transportation .13
7.1 Thermodynamic properties of CO and CO composition . 13
2 2
7.2 CO impurities and trace components . 15
7.2.1 Common impurities . 15
7.3 Flexibility and mixing of CO streams from different sources .16
8 Ship operation . 17
8.1 Ship and terminal modes of operation .17
8.2 Compatibility and interface .17
8.3 Cargo operations . .18
8.3.1 Responsibilities .18
8.3.2 Manifold operations .18
8.3.3 Loading operations .18
8.3.4 Offloading operations .19

iii
8.4 Cargo management .19
8.4.1 General .19
8.4.2 Cargo tank preparation .19
8.4.3 Cargo voyage management .19
8.4.4 Cargo losses . 20
9 Technical gaps and development.20
9.1 Applicability and precision of existing requirements . 20
9.2 Identification of additional relevant requirements such as practices onshore . 20
9.3 Qualification and process for new technology .21
9.4 Gaps and need for development .21
10 Safety and risks .21
10.1 Health, safety and environment (HSE) .21
10.1.1 Toxicity and asphyxiation .21
10.1.2 Hazards of liquid CO . 22
10.2 Measures to mitigate risks . 22
10.2.1 Gas detection . 22
10.2.2 Emergency shut down . 22
10.2.3 Emergency release system . 22
10.3 Special risks with liquid CO as ship cargo . 22
10.3.1 Solid formation . 22
10.3.2 Material integrity . 22
10.3.3 Electrostatic charge . 23
11 Quantification and verification of CO cargo .23
11.1 General . 23
11.2 Quantification and measurement . 23
11.2.1 General . 23
11.2.2 Cargo measurement . 23
11.2.3 CO quality .24
11.2.4 Co-mingling .24
11.2.5 Onboard carbon capture .24
11.3 Verification . .24
12 Summary status and development needs for CO ship transportation for CCS value
chains .24
Bibliography .26

iv
Foreword
ISO (the International Organization for Standardization) is a worldwide federation of national standards
bodies (ISO member bodies). The work of preparing International Standards is normally carried out through
ISO technical committees. Each member body interested in a subject for which a technical committee
has been established has the right to be represented on that committee. International organizations,
governmental and non-governmental, in liaison with ISO, also take part in the work. ISO collaborates closely
with the International Electrotechnical Commission (IEC) on all matters of electrotechnical standardization.
The procedures used to develop this document and those intended for its further maintenance are described
in the ISO/IEC Directives, Part 1. In particular, the different approval criteria needed for the different types
of ISO document should be noted. This document was drafted in accordance with the editorial rules of the
ISO/IEC Directives, Part 2 (see www.iso.org/directives).
ISO draws attention to the possibility that the implementation of this document may involve the use of (a)
patent(s). ISO takes no position concerning the evidence, validity or applicability of any claimed patent
rights in respect thereof. As of the date of publication of this document, ISO had not received notice of (a)
patent(s) which may be required to implement this document. However, implementers are cautioned that
this may not represent the latest information, which may be obtained from the patent database available at
www.iso.org/patents. ISO shall not be held responsible for identifying any or all such patent rights.
Any trade name used in this document is information given for the convenience of users and does not
constitute an endorsement.
For an explanation of the voluntary nature of standards, the meaning of ISO specific terms and expressions
related to conformity assessment, as well as information about ISO's adherence to the World Trade
Organization (WTO) principles in the Technical Barriers to Trade (TBT), see www.iso.org/iso/foreword.html.
This document was prepared by Technical Committee ISO/TC 265, Carbon dioxide capture, transportation,
and geological storage.
Any feedback or questions on this document should be directed to the user’s national standards body. A
complete listing of these bodies can be found at www.iso.org/members.html.

v
Introduction
In a carbon dioxide capture and storage (CCS) value chain, the main means for transportation of CO from an
emitter to storage are by ships or by pipelines. Transportation of gas in liquid state is well established in the
shipping industry and has been done for decades. However, liquid CO is different from other gases carried
by ships and poses new challenges for both ship design and ship operation. Compatibility along the value
chain is an essential element in the development of CCS. It is important to have a common understanding
of how different aspects, such as cargo temperature and pressure, can influence the ship design and ship
operation.
The purpose of this document is to support consistency and compatibility in the design of CCS value chains
and address important areas where future development and standardization can add value. This document
will discuss CO ship types, ship logistics and interface-specific aspects related to the safe and reliable
design and operation of CO ships.
Transportation of liquified gas on ships is governed by the regulations, codes and conventions drawn up
under the International Maritime Organization (IMO) which is referred to under United Nations Convention
on the Laws of the Sea (UNCLOS). Ships carrying CO are regulated by the IMO International Code for the
Construction and Equipment of Ships Carrying Liquefied Gases in Bulk (IGC Code), which serves as the main
technical regulation for CO carriers under the International Convention for the Safety of Life at Sea (SOLAS).
Ship transportation of CO is currently limited to commercial trade for small-scale use in industries such
as the food or beverage industries and is served by a handful of small ships. However, the evolving industry
around CCS will demand transportation volumes of a different magnitude and involve development of new
ship designs and ship logistics concepts. These are introducing a need for knowledge-sharing related to
type of transportation concepts, CCS value chain compatibility, technical and operational reliability and the
safety of CO carriers.
Quantification, verification and reporting along the different elements in the CCS value chain will become
important. This document describes limitations and challenges to them and how they can be done onboard
the ship.
In this document, CO means a captured CO stream, including potential impurities following the capture
2 2
process, if not otherwise explicitly referred to as pure CO .
vi
Technical Report ISO/TR 27929:2024(en)
Transportation of CO by ship
1 Scope
This document provides insights into the essential aspects of CO shipping and provides basic descriptions
of how the CO carrier and technology therein is technically integrated with the CCS value chain. It also
includes a description of specific challenges of transporting CO as cargo, how this differs from other gases
transported by ships today, and how this influences the ship design and operation. Finally, this document
introduces how CO ships are regulated within the existing international maritime regulatory framework.
This document's main focus is on the technical aspects of CO shipping. Commercial, liability and financial
aspects are intentionally kept out of this document. However, general reference to commercial impact is
made where relevant.
This document focuses on the ship transportation of CO between loading and offloading facilities where the
system boundaries are at the ship manifold equipment that connects the ship to the other components in the
value chain. In the document, the basis for the description of ship operation is transportation between two
shore-based terminals. A high-level description of other relevant interfaces is given on a conceptual level
as this has impact on the ship design. However, any further description of potential solutions upstream and
downstream from the CO carrier is outside the scope. This document also gives a high-level description of
the physical properties of CO streams at the conditions relevant for shipping and how relevant impurities
can impact the ship and ship operation.
2 Normative references
There are no normative references in this document.
3 Terms and definitions
For the purposes of this document, the following terms and definitions apply.
ISO and IEC maintain terminology databases for use in standardization at the following addresses:
— ISO Online browsing platform: available at https:// www .iso .org/ obp
— IEC Electropedia: available at https:// www .electropedia .org/
3.1
barge
floating unit carrying freight on canals, rivers and in ports, either under its own power or towed by another
3.2
cargo containment system
arrangement for containment of the cargo including, where fitted, a primary and secondary barrier,
associated insulation and any intervening spaces, and adjacent structure, if necessary, for the support of
these elements
Note 1 to entry: See Reference [9].
3.3
convention
written agreement between countries
Note 1 to entry: Conventions form a major part of maritime affairs governed by the International Maritime
Organization (IMO).
3.4
CO carrier
cargo ship or barge constructed or adapted and used for the carriage of CO as cargo
3.5
CO stream
stream consisting overwhelmingly of carbon dioxide
[SOURCE: ISO 27917: 2017, 3.2.10]
3.6
dynamic positioning system
equipment and system that is used for keeping a vessel at a given position using the thruster and propulsion
of the vessel to compensate for the environmental loads, including waves, wind, current, etc.
3.7
export location
location where the ship loads the CO for transport to the import location
3.8
flag state
jurisdiction under whose laws the ship is registered
3.9
heat ingress
transfer of heat from the surroundings into the cargo
3.10
heel
liquid cargo maintained at the bottom of the tank on the return voyage to maintain cargo tank temperature
3.11
import location
location where the ship offloads the CO that is transported from the export location
3.12
inland waterway
natural or artificial navigable inland body of water, or system of interconnected bodies of water, used for
transport, such as lakes, rivers or canals
3.13
intermediate storage
storage of CO volumes before being loaded to a ship and storage after being offloaded from the ship
3.14
multi-lobe
bi-lobe
tri-lobe
cargo tanks which consist of two (bi-lobe) or three (tri-lobe) lobes where lobes represent cylinder segments
partly merged and connected by a common bulkhead
3.15
muster area
location where the crew assemble in the event of an emergency
3.16
riser
flexible pipe that connects an offshore well to a ship or floating offshore unit
3.17
ship master
person in charge of the ship, its crew and any passengers or cargo it is carrying, on the water and in port

3.18
territorial seas
areas which extend up to 12 nautical miles from the baseline of a country’s coastal line
3.19
triple point
temperature and pressure at which three phases (gas, liquid and solid) of a substance coexist in
thermodynamic equilibrium
3.20
two-phase flow
simultaneous flow of gas and liquid
3.21
vapour return
connection between ship and terminal for vapour exchange to ensure pressure equilibrium between the
shore storage tanks and the ship cargo tanks
3.22
vapour-liquid equilibrium
state where a substance's liquid and vapour phases are in equilibrium
4 Abbreviations
CO carbon dioxide
CCS carbon dioxide capture and storage
ESD emergency shut down
FSIU floating storage and injection unit
IGC Code International Code of the Construction and Equipment of Ships Carrying Liquefied Gases in Bulk
IMO International Maritime Organization
LNG liquified natural gas
LPG liquefied petroleum gas
NIST National Institute of Standards and Technology
OCIMF Oil Companies International Maritime Forum
SIGTTO Society of International Gas Tanker and Terminal Operators
SOLAS International Convention for the Safety of Life at Sea
UNCLOS United Nations Convention on the Law of the Sea
IACS International Association of Classification Societies
ES-TRIN European Standard — Technical Requirements for Inland Navigation vessels
5 R egulatory regime for maritime and inland waterways for CO transportation
5.1 General
International and national shipping are subject to an extensive and stringent set of laws and regulations
which are enforced by international, regional and national regulatory bodies. Considering the large number

of stakeholders and the significant environmental and economic impact the maritime industry has on the
society, regulations are developed to enable cooperation between stakeholders and to promote and improve
safety, security, efficiency and to prevent marine and atmospheric pollution by ships.
Marine transportation of liquefied gases, including CO in bulk by dedicated gas carriers, is well
regulated with proven and high safety standards developed by IMO and other governmental and industry
organizations. Considering the increased focus on CCS, it is however expected that laws and regulations for
maritime transportation of CO will be further developed.
General description of the maritime governance scheme is explained in 5.2. It is followed by a description of
the main regulatory regime for CO carriers.
5.2 Maritime governance
International shipping involves vessels which operate across the oceans as well as territorial seas and
exclusive economic zones. Other vessels are limited to coastal and inland waterways transport within
territorial waters covered by the jurisdictions of a single state or multiple states. Maritime shipping is a
mature industry with well-established international governance institutions; however, the regulatory
scheme can be different depending on the area and type of operation. A generic overview of the maritime
governance scheme and stakeholders involved in maritime shipping is shown in Figure 1.
Figure 1 — Governance and stakeholders in maritime shipping
The governance of the ocean emerges from the United Nations. UNCLOS lays down a comprehensive regime
of law and order in the world’s oceans and seas by, inter alia, defining the maritime geographical jurisdiction,
including the coastal states’ sovereignty over their respective maritime zones.
IMO is a specialized agency under the United Nations that develops conventions containing detailed
regulations to safety, security and environment, with the intention of establishing a global minimum
standard for the shipping industry. Under IMO, more than 60 conventions, codes and regulations have been
developed which serve the basis for the implementation in the legislations of the individual member states.

Regional governmental organizations can develop additional regulations which apply for specific
geographical areas or member states. The European Union (EU) is an example of a regional governmental
organization which through its regulations and directives aim at ensuring common standards among the EU
member states.
The regulations developed by IMO or any other governmental organization are upon ratification implemented
into the national laws of the ratifying states. The flag states enforce the regulations for ships registered
under their flag. Port states exercise port state control on ships visiting their ports based on domestic
laws, to ensure the ship’s condition and equipment are in compliance with the provisions of international
conventions and that the ship is safely manned and operated pursuant to applicable international law.
Flag and port states can introduce additional regional or domestic regulations which apply within their
jurisdiction.
Within the convention framework set by IMO and the regulations set by flag states, the classification
societies play an important role as independent governance actors. The major classification societies form
the International Association of Classification Societies (IACS), which works together with the industry
and maritime regulators to ensure that the legislative framework is supported and enhanced by the
practical implementation of classification rules. IACS has an observer role in IMO which allows them to
provide support and advise to the IMO process. The classification societies develop and maintain technical
rules and standards for the construction and operation of ships, and carry out classification, certification
and verification services, as well as surveys to ensure compliance with the standards. The classification
is the basis for the registration with the flag state and is required by IMO for international voyages. The
classification standards are generally internationally recognized and in compliance with international
maritime regulations.
The classification societies can, on behalf of a flag state administration, undertake statutory certification
to the extent the society has been authorized to do so by the individual flag state administration. Statutory
certification includes among others approval, surveys, and the issuance of statutory certificates.
Other non-governmental organizations such as International Chamber of Shipping (ICS), International
Association of Independent Tanker Owners (INTERTANKO), Oil Companies International Maritime Forum
(OCIMF), Society of International Gas Tanker and Terminal Operators (SIGTTO), are also important
stakeholders in maritime shipping. These are industry organizations with the aim of sharing experiences,
addressing common problems and establishing a framework of standards, guidelines, and best practices for
the industry. Publications from these organizations often become industry standards and are important
for ensuring standardization particularly regarding operational compatibility and safety. Several of these
organizations have consultative status in IMO.
Considering the sovereignty of the territorial seas and internal waters as laid down in UNCLOS, the coastal
states are not bound by the framework issued by IMO and other organizations when forming the legislative
framework for ships operating within the territory of the state, unless the instruments are ratified by the
individual states. Hence, the regulatory framework which is basis for the national legislations can differ
from that of international shipping. Many states do however use the international legislative framework
as a basis for their national frameworks, potentially with modifications and adjustments as found relevant
depending on the type of ship and trade, the operational area, etc. regional (e.g. bi-lateral or multi-lateral)
requirements and agreements can apply to specific operational areas within the territories of two or more
states. One example is the regulations applicable for the inland waterways system in Europe, which is
described in more detail in 5.3.
5.3 Technical safety regime for maritime transportation of liquid CO
The carriage of liquid CO onboard ships for international trade is governed pursuant to the IMO framework
and by the provisions in the SOLAS, and is further detailed in mandatory codes, depending on the mode
of transport. The regulations distinguish between the carriage of the product in packaged form, e.g. as
modular tank containers on cargo ships, and the carriage of the product in bulk on dedicated gas carriers
as explained in more detail in the following. Carriage of product in package form is regulated by the
International Maritime Dangerous Goods Code (IMDG) while the carriage of product in bulk on dedicated
gas carriers is regulated by the IGC Code.

The IGC Code is the governing international technical standard prescribing the design and construction
requirements of ships carrying liquid gases, including CO in bulk. The IGC Code requirements are targeted
to address the particular hazards related to different liquefied gases, including flammability, toxicity,
asphyxiation, etc., including a set of specific requirements for the carriage of CO .
Classification societies normally have specific class notations which cover design and construction
requirements for gas carriers. These requirements are normally based on the IGC Code, but are often more
detailed on the specific requirements to ensure practical implementation of the requirements given in the
Code and that the overall safety targets are met. Industry organizations such as SIGTTO have developed a
series of best practices, guidelines and standards targeting liquified gas carriers and terminals. Although
these are focusing on commonly transported products such as LNG and LPG, many of these can also be
applicable for CO transportation.
As explained in 5.2, an individual state is not bound to the international standards and codes described
above for trades within the territory of the state, e.g. for inland waterways. Russia, Brazil, China, India,
EU members, and many other countries have well developed inland waterway systems which can be an
attractive alternative for CO transportation. It is expected that a regulatory framework will be developed
for the individual areas when and where this mode of transport becomes relevant, including cross border
agreements. Some countries have existing regulations for transport of dangerous goods on inland waterways
which can be relevant. It is, however, expected that IGC Code and other international standards will be used
as supplementary references for establishing the regulatory framework for domestic and cross-border CO
trades on inland waterways.
Vessels used for goods transport on inland waterways within the European Union are regulated by the
EU Directive 2016/1629 Technical Requirements for Inland Waterway Vessels, which is the mechanism
for incorporating technical standards (e.g. ES-TRIN) into EU law. Within this framework the European
Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways contains
the provisions for the carriage of dangerous goods in packages and in bulk. Other countries, regions and
territories can have other applicable regulations.
5.4 Greenhouse gas emissions
Ships today use fossil fuels for propulsion, with few exceptions, and in that sense ship transportation of
CO will have a CO footprint depending mainly on the type of fuel and the ship size. IMO has an ambition
2 2
to reduce the total emissions from the world fleet and in carbon intensity (CO emitted per cargo-carrying
capacity and nautical mile) by 2050. To meet the defined targets regulations are gradually being enforced.
Emissions from a ship’s machinery during operation are reported through schemes defined by both IMO and
EU (for vessels calling at European ports).
5.5 Trading and cross-border transportation
For cross-border transportation of CO where the CO is transported for the purpose of offshore storage,
2 2
the 1972 Convention on the Prevention of Marine Pollution by Dumping of Wastes and Other Matter
(London Convention) and its 1996 London Protocol are important. The London Convention is one of the
first international conventions protecting the marine environment from human activities. Its objective is
to promote the effective control of all sources of marine dumping and take all practicable steps to prevent
pollution of the sea by the dumping of waste and other matter. The contracting parties (countries party to
the London Protocol) eventually recognized the need for a more precautionary and preventative approach
and undertook a full review of the Convention. This review resulted in the 1996 London Protocol.
The London Protocol is a stand-alone agreement that supersedes the London Convention for the states
that are party to both instruments. This means that the London Protocol will prevail if there is a conflict
between the two instruments. The Protocol is more restrictive and adopts a general ban on all dumping
activities, with the exception of the wastes and other matter listed in Annex 1 of the London Protocol. The
dumping of wastes and other matter listed as an exception in the London Protocol Annex 1 requires a prior
permit issued in line with the London Protocol Annex 2 requirements. In 2006, the contracting parties to the
London Protocol adopted an amendment to Annex 1, adding CO to the list of exceptions, thereby creating a
legal basis in international environmental law to regulate CO storage in sub-seabed geological formations.
This was necessary as storage falls within the definition of dumping.
Article 6 of the London Protocol prohibits the export of wastes and other matter across borders for dumping
at sea. This presented a barrier for cross-border CCS operations as it prohibits the export of CO for storage
in other countries where the intended storage site is offshore. In order to overcome this barrier, Article
6 was amended in 2009 to allow for export of CO for offshore storage by adding a second paragraph
exempting CO from the general ban. The new Article 6.2 sets out criteria for the export to occur, including
the need for an agreement or arrangement between the states involved identifying and allocating permitting
responsibilities. The amendment is not yet in force at the time of writing as an amendment requires two-
thirds of the contracting parties to have formally accepted it. After ten years with little progress of reaching
the required number, the contracting parties agreed to an interim solution of provisional application in
2019. This entails that the contracting parties can provisionally apply the 2009 amendment and export CO
across borders provided that the parties have deposited a declaration of provisional application to the IMO
(who acts as the Secretariat for the London Convention and the Protocol).
While the London Protocol has implications for cross-border transportation and offshore storage for its
contracting parties, it can also impact non-contracting parties that wish to engage in such CCS operations.
This is the case where a contracting party seeks to export CO by pipeline or ship for offshore storage in a
non-contracting party. In this scenario, the contracting party has a duty to ensure that the non-contracting
party has a regulatory framework in place that is the same as, or provides better protection of the marine
environment than, the provisions contained in the Protocol. This is to ensure that the contracting parties do
not evade their obligations under the Protocol, and that the CO is always stored according to the Protocol’s
requirements in a safe and long-term manner. The Protocol can therefore indirectly apply to non-contracting
parties in these instances.
6 Ship transport of CO
6.1 General
The main option for transporting CO by ships is in liquid state. CO is different from other liquefied gases
2 2
transported by ships as it cannot be liquid at atmospheric pressure regardless of temperature. CO therefore
needs to be pressurized to above the triple point pressure to exist in liquid form. The combination of
temperature and pressure required to maintain the CO in its liquid phase, as well as the high density, set
high requirements for the tank design, tank supporting structure and tank material terms of the strength
and low temperature properties.
The CO is conditioned to a liquid at the specified pressure and temperature before it can be transported on
a ship. This involves compressing, cooling and condensing the CO as well as removing any impurities to an
acceptable level.
6.2 CO cargo transport conditions
6.2.1 General
For liquid CO cargoes there are three diffe
...