Determination of certain substances in electrotechnical products - Part 4: Mercury in polymers, metals and electronics by CV-AAS, CV-AFS, ICP-OES and ICP-MS

Verfahren zur Bestimmung von bestimmten Substanzen in Produkten der Elektrotechnik - Teil 4: Quecksilber in Polymeren, Metallen und Elektronik mit CV-AAS, CV-AFS, ICP-OES und ICP-MS

Détermination de certaines substances dans les produits électrotechniques - Partie 4: Mercure dans les polymères, métaux et produits électroniques par CV-AAS, CV-AFS, ICP-OES et ICP-MS

Določevanje posameznih snovi v elektrotehničnih izdelkih - 4. del: Določevanje živega srebra v polimerih, kovinah in elektroniki s CV-AAS, CV-AFS, ICP-OES in ICP-MS - Dopolnilo A1

General Information

Status
Published
Publication Date
11-Dec-2017
Current Stage
6060 - National Implementation/Publication (Adopted Project)
Start Date
28-Nov-2017
Due Date
02-Feb-2018
Completion Date
12-Dec-2017

Relations

Effective Date
08-Mar-2016

Overview

EN 62321-4:2014/A1:2017 (IEC 62321-4:2013/A1:2017) specifies analytical procedures for the determination of mercury in electrotechnical products - including polymers, metals and electronic assemblies - using instrumental techniques: CV‑AAS, CV‑AFS, ICP‑OES and ICP‑MS. The A1 amendment updates sampling and calculation guidance, adds warnings on matrix effects (e.g., phosphors), and identifies preferred methods for specific product types.

Key topics and technical requirements

  • Scope: Measurement of mercury content in materials and finished electrotechnical products (polymers, metals, electronics).
  • Analytical methods covered: Cold‑Vapor Atomic Absorption Spectrometry (CV‑AAS), Cold‑Vapor Atomic Fluorescence Spectrometry (CV‑AFS), Inductively Coupled Plasma Optical Emission Spectrometry (ICP‑OES) and ICP‑MS.
  • Sampling: For fluorescent lamps, sample preparation must follow IEC 62554 (as required by the amendment).
  • Method preference: CV‑AAS is noted as the preferred method for fluorescent lamps because of sensitivity and ease of use.
  • Matrix/interference caution: Laboratories are warned to assess matrix effects or phosphor interferences when testing lamp materials and to choose appropriate conditions.
  • Calculation and reporting: The standard provides calculation procedures converting measured mercury concentration in solution to total mercury amount and to concentration in the original sample. Calculations explicitly include: blank correction, total solution volume, dilution factor, and sample mass to produce results in mg (total) or µg/g (concentration).

Applications

  • Regulatory compliance testing (e.g., RoHS and other chemical restrictions where mercury limits apply).
  • Product safety and environmental assessment for manufacturers of lamps, connectors, printed circuit boards and polymer parts.
  • Quality control and incoming/outgoing inspection in electronics manufacturing.
  • Third‑party testing and certification laboratories performing mercury quantification in complex matrices.

Who should use this standard

  • Analytical and environmental testing laboratories performing mercury determinations in electrotechnical products.
  • Product compliance engineers and materials specialists in electronics and lighting industries.
  • Regulatory bodies and conformity assessment bodies verifying material content declarations.

Related standards

  • IEC 62321 series (general methods for determination of restricted substances in electronic products).
  • IEC 62554 (sample preparation and guidance for fluorescent lamps) - explicitly referenced for lamp sampling in the amendment.

Keywords: EN 62321-4, IEC 62321-4, mercury determination, CV‑AAS, CV‑AFS, ICP‑OES, ICP‑MS, fluorescent lamps, polymers, metals, electronics, RoHS compliance.

Amendment

SIST EN 62321-4:2014/A1:2018

English language
5 pages
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Frequently Asked Questions

SIST EN 62321-4:2014/A1:2018 is a amendment published by the Slovenian Institute for Standardization (SIST). Its full title is "Determination of certain substances in electrotechnical products - Part 4: Mercury in polymers, metals and electronics by CV-AAS, CV-AFS, ICP-OES and ICP-MS". This standard covers: Determination of certain substances in electrotechnical products - Part 4: Mercury in polymers, metals and electronics by CV-AAS, CV-AFS, ICP-OES and ICP-MS

Determination of certain substances in electrotechnical products - Part 4: Mercury in polymers, metals and electronics by CV-AAS, CV-AFS, ICP-OES and ICP-MS

SIST EN 62321-4:2014/A1:2018 is classified under the following ICS (International Classification for Standards) categories: 29.020 - Electrical engineering in general; 31.020 - Electronic components in general. The ICS classification helps identify the subject area and facilitates finding related standards.

SIST EN 62321-4:2014/A1:2018 has the following relationships with other standards: It is inter standard links to SIST EN 62321-4:2014. Understanding these relationships helps ensure you are using the most current and applicable version of the standard.

SIST EN 62321-4:2014/A1:2018 is associated with the following European legislation: EU Directives/Regulations: 2011/65/EU. When a standard is cited in the Official Journal of the European Union, products manufactured in conformity with it benefit from a presumption of conformity with the essential requirements of the corresponding EU directive or regulation.

You can purchase SIST EN 62321-4:2014/A1:2018 directly from iTeh Standards. The document is available in PDF format and is delivered instantly after payment. Add the standard to your cart and complete the secure checkout process. iTeh Standards is an authorized distributor of SIST standards.

Standards Content (Sample)


SLOVENSKI STANDARD
01-januar-2018
'RORþHYDQMHSRVDPH]QLKVQRYLYHOHNWURWHKQLþQLKL]GHONLKGHO'RORþHYDQMH
åLYHJDVUHEUDYSROLPHULKNRYLQDKLQHOHNWURQLNLV&9$$6&9$)6,&32(6LQ
,&306'RSROQLOR$
Determination of certain substances in electrotechnical products - Part 4: Mercury in
polymers, metals and electronics by CV-AAS, CV-AFS, ICP-OES and ICP-MS
Verfahren zur Bestimmung von bestimmten Substanzen in Produkten der Elektrotechnik
- Teil 4: Quecksilber in Polymeren, Metallen und Elektronik mit CV-AAS, CV-AFS, ICP-
OES und ICP-MS
Détermination de certaines substances dans les produits électrotechniques - Partie 4:
Mercure dans les polymères, métaux et produits électroniques par CV-AAS, CV-AFS,
ICP-OES et ICP-MS
Ta slovenski standard je istoveten z: EN 62321-4:2014/A1:2017
ICS:
29.020 Elektrotehnika na splošno Electrical engineering in
general
31.020 Elektronske komponente na Electronic components in
splošno general
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.

EUROPEAN STANDARD EN 62321-4:2014/A1

NORME EUROPÉENNE
EUROPÄISCHE NORM
November 2017
ICS 13.020; 43.040.10
English Version
Determination of certain substances in electrotechnical products
- Part 4: Mercury in polymers, metals and electronics
by CV-AAS, CV-AFS, ICP-OES and ICP-MS
(IEC 62321-4:2013/A1:2017)
Détermination de certaines substances dans les produits Verfahren zur Bestimmung von bestimmten Substanzen in
électrotechniques - Partie 4: Mercure dans les polymères, Produkten der Elektrotechnik - Teil 4: Quecksilber in
métaux et produits électroniques par CV-AAS, CV-AFS, Polymeren, Metallen und Elektronik mit CV-AAS, CV-AFS,
ICP-OES et ICP-MS ICP-OES und ICP-MS
(IEC 62321-4:2013/A1:2017) (IEC 62321-4:2013/A1:2017)
This amendment A1 modifies the European Standard EN 62321-4:2014; it was approved by CENELEC on 2017-08-17. CENELEC
members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this amendment the
status of a national standard without any alteration.
Up-to-date lists and bibliographical references concerning such national standards may be obtained on application to the CEN-CENELEC
Management Centre or to any CENELEC member.
This amendment exists in three official versions (English, French, German). A version in any other language made by translation under the
responsibility of a CENELEC member into its own language and notified to the CEN-CENELEC Management Centre has the same status as
the official versions.
CENELEC members are the national electrotechnical committees of Austria, Belgium, Bulgaria, Croatia, Cyprus, the Czech Republic,
Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia,
Lithuania, Luxembourg, Malta, the Netherlands, Norway, Poland, Portugal, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden,
Switzerland, Turkey and the United Kingdom.

European Committee for Electrotechnical Standardization
Comité Européen de Normalisation Electrotechnique
Europäisches Komitee für Elektrotechnische Normung
CEN-CENELEC Management Centre: Avenue Marnix 17, B-1000 Brussels
© 2017 CENELEC All rights of exploitation in any form and by any means reserved worldwide for CENELEC Members.
Ref. No. EN 62321-4:2014/A1:2017 E

European foreword
The text of document 111/414/CDV, future IEC 62321-4:2013/A1, prepared by IEC/TC 111
"Environmental standardization for electrical and electronic products and systems" was submitted to
the IEC-CENELEC parallel vote and approved by CENELEC as EN 62321-4:2014/A1:2017.

The following dates are fixed:
(dop) 2018-05-17
• latest date by which the document has to be
implemented at national level by
publication of an identical national
standard or by endorsement
• latest date by which the national (dow) 2020-08-17
standards conflicting with the
document have to be withdrawn
Attention is drawn to the possibility that some of the elements
...

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