Bio-based products - Bio-based carbon content - Determination of the bio-based carbon content using the radiocarbon method

This European Standard specifies a method for the determination of the bio-based carbon content in products, based on the 14C content measurement.
This European Standard also specifies three test methods to be used for the determination of the 14C content from which the bio-based carbon content is calculated:
-   Method A: Liquid scintillation-counter method (LSC) (normative);
-   Method B: Beta-ionization (BI) (informative);
-   Method C: Accelerator mass spectrometry (AMS) (normative).
The bio-based carbon content is expressed by a fraction of sample mass or as a fraction of the total carbon content. This calculation method is applicable to any product containing carbon, including bio composites.
NOTE   This European standard does not provide the methodology for the calculation of the biomass content of a sample see prEN 16785-1 [5] and prEN 16785-2 [6].

Biobasierte Produkte - Gehalt an biobasiertem Kohlenstoff - Bestimmung des Gehalts an biobasiertem Kohlenstoff mittels Radiokarbonmethode

Diese Europäische Norm legt ein Verfahren zur Bestimmung des Gehalts an biobasiertem Kohlenstoff in Produkten auf der Grundlage der Messung des 14C Gehalts fest.
Es werden auch drei Prüfverfahren festgelegt, die zur Bestimmung des 14C Gehalts anzuwenden sind, aus dem der biobasierte Kohlenstoffgehalt berechnet wird:
-   Verfahren A: Flüssigszintillationszählverfahren (LSC) (normativ);
-   Verfahren B: Beta Ionisation (BI) (informativ);
-   Verfahren C: Beschleuniger Massenspektrometrie (AMS) (normativ).
Der biobasierte Kohlenstoffgehalt wird als Anteil der Masse der Probe angegeben oder als Anteil des gesamten Kohlenstoffgehalts. Dieses Berechnungsverfahren ist auf alle kohlenstoffhaltigen Produkte anwendbar, einschließlich Bioverbundwerkstoffen.
ANMERKUNG   Diese Europäische Norm bietet kein Verfahren für die Berechnung des Biomassegehalts einer Probe; diesbezüglich siehe prEN 16785 1 [5] und prEN 16785 2 [6].

Produits biosourcés - Teneur en carbone biosourcé - Détermination de la teneur en carbone biosourcé par la méthode au radiocarbone

La présente Norme européenne spécifie une méthode permettant de déterminer la teneur en carbone biosourcé dans des produits à partir du mesurage de la teneur en 14C.
Elle spécifie également trois méthodes d'essai à utiliser pour déterminer la teneur en 14C, à partir de laquelle la teneur en carbone biosourcé est calculée :
-   Méthode A : compteur à scintillation liquide (CSL) (normative) ;
-   Méthode B : ionisation bêta (IB) (informative) ;
-   Méthode C : spectrométrie de masse par accélérateur (SMA) (normative).
La teneur en carbone biosourcé est exprimée en fraction de masse d'échantillon ou en fraction de la teneur en carbone total. Cette méthode de calcul est applicable à tout produit contenant du carbone, y compris les biocomposites.
NOTE   La présente Norme européenne ne fournit pas la méthodologie permettant de calculer la teneur en biomasse d'un échantillon ; voir le prEN 16785-1 [5] et le prEN 16785-2 [6].

Bioizdelki - Delež bioogljika - Ugotavljanje deleža bioogljika z radioogljično metodo

Ta evropski standard določa metodo za ugotavljanje deleža bioogljika v izdelkih na podlagi meritve deleža 14C.
Poleg tega ta evropski standard določa tri preskusne metode za ugotavljanje deleža 14C, na podlagi katerih se izračuna delež bioogljika:
– Metoda A: metoda števca s tekočinskim scintilatorjem (LSC) (normativni);
– Metoda B: beta ionizacija (BI) (informativni);
– Metoda C: pospeševalna masna spektrometrija (AMS) (normativni).
Delež bioogljika se izrazi z deležem mase vzorca ali kot delež skupnega deleža ogljika. Ta metoda izračuna se uporablja za vse izdelke, ki vsebujejo ogljik, vključno z biokompoziti.
OPOMBA: ta evropski standard ne zagotavlja metodologije za izračun deleža biomase vzorca. Glej standard prEN 16785-1 [5] in prEN 16785-2 [6].

General Information

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Published
Publication Date
21-Feb-2017
Withdrawal Date
30-Aug-2017
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2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.UDGLRRJOMLþQRPHWRGRBiobasierte Produkte - Gehalt an biobasiertem Kohlenstoff - Bestimmung des Gehalts an biobasiertem Kohlenstoff mittels RadiokarbonmethodeProduits biosourcés - Teneur en carbone biosourcé - Détermination de la teneur en carbone biosourcé par la méthode au radiocarboneBio-based products - Bio-based carbon content - Determination of the bio-based carbon content using the radiocarbon method71.040.40Kemijska analizaChemical analysis13.020.55Biološki izdelkiBiobased productsICS:Ta slovenski standard je istoveten z:EN 16640:2017SIST EN 16640:2017en,fr,de01-junij-2017SIST EN 16640:2017SLOVENSKI
STANDARDSIST-TS CEN/TS 16640:20141DGRPHãþD

EUROPEAN STANDARD NORME EUROPÉENNE EUROPÄISCHE NORM
EN 16640
February
t r s y
vEnglish Version
Bioæbased products æ Bioæbased carbon content æ Determination of the bioæbased carbon content using the radiocarbon method Produits biosourcés æ Teneur en carbone biosourcé æ Détermination de la teneur en carbone biosourcé par la méthode au radiocarbone
Biobasierte Produkte æ Gehalt an biobasiertem Kohlenstoff æ Bestimmung des Gehalts an biobasiertem Kohlenstoff mittels Radiokarbonmethode This European Standard was approved by CEN on
v December
t r s xä
egulations which stipulate the conditions for giving this European Standard the status of a national standard without any alterationä Upætoædate lists and bibliographical references concerning such national standards may be obtained on application to the CENæCENELEC Management Centre or to any CEN memberä
translation under the responsibility of a CEN member into its own language and notified to the CENæCENELEC Management Centre has the same status as the official versionsä
CEN members are the national standards bodies of Austriaá Belgiumá Bulgariaá Croatiaá Cyprusá Czech Republicá Denmarká Estoniaá Finlandá Former Yugoslav Republic of Macedoniaá Franceá Germanyá Greeceá Hungaryá Icelandá Irelandá Italyá Latviaá Lithuaniaá Luxembourgá Maltaá Netherlandsá Norwayá Polandá Portugalá Romaniaá Serbiaá Slovakiaá Sloveniaá Spainá Swedená Switzerlandá Turkey and United Kingdomä
EUROPEAN COMMITTEE FOR STANDARDIZATION COMITÉ EUROPÉEN DE NORMALISATION EUROPÄISCHES KOMITEE FÜR NORMUNG
CEN-CENELEC Management Centre:
Avenue Marnix 17,
B-1000 Brussels
t r s y CEN All rights of exploitation in any form and by any means reserved worldwide for CEN national Membersä Refä Noä EN
s x x v rã t r s y ESIST EN 16640:2017

Procedures for sampling of products . 15 A.1 General . 15 Table A.1. — Sampling procedures . 15 Annex B (normative)
Procedure for the conversion of the carbon present in the sample to a suitable sample for 14C determination . 16 B.1 General . 16 B.2 Sample preparation . 16 Table B.1— Sample preparations . 16 B.3 Preparation for 14C measurement . 16 B.3.1 General . 16 B.3.2 Reagents and materials . 17 B.4 Combustion of the sample . 17 SIST EN 16640:2017

Method A - Liquid scintillation-counter method (LSC) . 21 C.1 General . 21 C.2 Principle . 21 C.3 Reagents and materials . 21 C.4 Apparatus . 21 C.5 Procedure . 22 C.5.1 General . 22 C.5.2 Benzene conversion . 22 C.5.3 Direct absorption of the CO2 in a carbamate solution . 22 C.5.4 Measurement . 22 C.5.5 Blank correction . 23 C.6 Calculation of the results . 23 Annex D (informative)
Method C - Beta-ionization (BI) . 24 D.1 General . 24 D.2 Principle . 24 D.3 Reagents and materials . 24 D.4 Apparatus . 25 D.5 Procedure . 25 D.6 Calculation of the results . 26 Annex E (normative)
Method B - Accelerator Mass Spectrometry (AMS) . 27 E.1 General . 27 E.2 Principle . 25 E.3 Reagents and materials . 27 E.4 Apparatus . 27 E.5 Procedure . 27 E.6 Calculation of the results . 28 Annex F (informative)
Performance characteristics . 29 Table F.1 — description of sample types . 29 Table F.2 — Performance data for 14C methods . 30 Bibliography . 31 SIST EN 16640:2017
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