71.060.50 - Salts
ICS 71.060.50 Details
Salts
Salze
Sels
Soli
General Information
Frequently Asked Questions
ICS 71.060.50 is a classification code in the International Classification for Standards (ICS) system. It covers "Salts". The ICS is a hierarchical classification system used to organize international, regional, and national standards, facilitating the search and identification of standards across different fields.
There are 244 standards classified under ICS 71.060.50 (Salts). These standards are published by international and regional standardization bodies including ISO, IEC, CEN, CENELEC, and ETSI.
The International Classification for Standards (ICS) is a hierarchical classification system maintained by ISO to organize standards and related documents. It uses a three-level structure with field (2 digits), group (3 digits), and sub-group (2 digits) codes. The ICS helps users find standards by subject area and enables statistical analysis of standards development activities.
ABSTRACT
This specification covers the requirements for sulfur hexafluoride intended for use as an electrical insulating gas. However, this specification applies only to gas as purchased. Tests for water content, acidity (hydrolyzable fluorides), noncondensable gas and carbon tetrafluoride content, and assay shall be performed and shall conform to the requirements specified.
SCOPE
1.1 This specification applies to sulfur hexafluoride for use as an electrical insulating gas.
Note 1: This specification is intended to apply only to gas as purchased. However, the test methods referred to in this standard may be useful in the evaluation of in-service or used gas. Test Method D2284 may be particularly helpful since many sulfur hexafluoride decomposition products are acidic. Test Method D2284 should not be used to evaluate the total amount of sulfur hexafluoride decomposition nor to identify contaminant species. This can only be done by gas chromatography and similar instrumental techniques.
1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
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ABSTRACT
This specification covers technical grade calcium chloride typically used for, but not limited to, dust control, stabilization, ice/snow removal, other road-conditioning purposes, acceleration of the set of concrete, and as a desiccant. Two types of calcium chloride are covered, as follows: Type S (solid), flake, pellet, or granular calcium chloride in varying concentrations; and Type L (liquid), water solutions of calcium chloride in varying concentrations. Concentrations shall be expressed as a percentage of the total. Impurities such as alkali chlorides, magnesium, and calcium hydroxide should be within specified composition limits.
SCOPE
1.1 This specification covers calcium chloride, technical grade, typically used for, but not limited to, dust control, stabilization, ice/snow removal, other road-conditioning purposes, acceleration of the set of concrete, and as a desiccant.
1.2 The values stated in SI units are to be regarded as the standard.
1.3 For purposes of determining conformance to this specification, values for chemical analysis shall be rounded to the nearest 0.1 %, and values for grading shall be rounded to the nearest 1 %, in accordance with the rounding method in Practice E29.
1.4 The text of this standard references notes and footnotes, which provide explanatory material. These notes and footnotes (excluding those in tables and figures) shall not be considered as requirements of the standard.
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
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ABSTRACT
This specification covers technical-grade calcium hypochlorite in granular form. Sampled specimens shall be tested and conform accordingly to chemical and physical requirements such as available chlorides, moisture content, and particle sizes through a U.S. 14 and U.S. 100 mesh.
SCOPE
1.1 This specification covers technical-grade calcium hypochlorite in granular form.
1.2 The following applies to all specified limits in this specification: for purposes of determining conformance with this specification, an observed value or a calculated value shall be rounded off “to the nearest unit” in the last right-hand digit used in expressing the specification limit, in accordance with the rounding-off method of Practice E29.
1.3 Units—The values stated in SI units are to be regarded as standard. The values given in parentheses are for information only.
1.4 Review the current Safety Data Sheets (SDS) for detailed information concerning toxicity, first aid procedures, handling and safety precautions.
1.5 The following safety hazards caveat pertains only to the test methods listed in Sections 3 – 5. This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
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SIGNIFICANCE AND USE
A1.2 Significance and Use
A1.2.1 The procedure for chemical analysis in this annex determines the total amount of chlorides present in the sample and expresses that value as sodium chloride.
A1.2.2 This rapid method of analysis does not distinguish between sodium chloride and other evaporite chloride compounds with ice-melting capabilities. Typical rock salt and solar salt sometimes contains small amounts of CaCl2, MgCl2, and KCl, depending on the source of the material. When this rapid method is used on continuing shipments from a known source, it will provide a fast, essentially accurate determination of the sodium chloride content of the material furnished. Thus, the need for testing by the referee method, Test Method E534, is reduced.
SCOPE
1.1 This specification covers sodium chloride intended for use as a deicer and for road construction or maintenance purposes.
1.2 The values stated as SI units are to be regarded as the standard.
1.3 For purposes of determining conformance to this specification, values for chemical analysis shall be rounded to the nearest 0.1 %, and values for grading shall be rounded to the nearest 1 %, in accordance with the rounding method in Practice E29.
1.4 The text of this specification references notes and footnotes that provide explanatory material. These notes and footnotes shall not be considered as requirements of the specification.
1.5 The following precautionary caveat pertains only to the test method in Annex A1 of this specification: This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
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SIGNIFICANCE AND USE
3.1 These test methods compile in one place, recommended procedures for analysis of the pigment known commercially as calcium borosilicate. This pigment is used extensively in paints and the composition is important to the user and producer.
SCOPE
1.1 These test methods cover the analysis of the pigment commercially known as calcium borosilicate.
1.2 The test methods appear in the following order:
Test Methods
Sections
Silicon Dioxide (SiO2)
6 – 9
Iron Oxide (Fe2O3)
10 – 13
Boron Trioxide (B2O3)
17 – 20
Calcium Oxide (CaO)
21 – 23
Moisture and Volatile Matter
24
Water of Hydration
25 to 26
Coarse Particles
27
Oil Absorption
28
1.3 Individual specimens may be used for the direct determinations of SiO2, B2O3, and CaO. SiO2 and Fe2O3 should be removed before the determination of the B2O3 and CaO.
1.4 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
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SCOPE
1.1 This specification applies to boron carbide pellets for use as a control material in nuclear reactors.
1.2 The values stated in SI units are to be regarded as standard. The values given in parentheses after SI units are provided for information only and are not considered standard.
1.3 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
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ABSTRACT
This specification applies to composite pellets composed of mixtures of nuclear-grade aluminum oxide and boron carbide that may be ultimately used in a reactor core, for example, in neutron absorber rods. Specimens shall be sampled and tested as appropriate, and shall adhere accordingly to required chemical compositions, physical dimensions, density, boron carbide homogeneity, mechanical properties, visual appearance, end and circumferential chips, cracks, and fissures and other defects.
SCOPE
1.1 This specification applies to pellets composed of mixtures of aluminum oxide and boron carbide that may be ultimately used in a reactor core, for example, in neutron absorber rods.
1.2 The values stated in SI units are to be regarded as standard. The values given in parentheses after SI units are provided for information only and are not considered standard.
1.3 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
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SIGNIFICANCE AND USE
4.1 Acidic fluorides are undesirable in SF6 used as an electrical insulating gas in that they may contribute to corrosion or constitute dielectric hazard.
4.2 This test method is valid for both new and used SF6. In used SF6, it will only measure those active species which are hydrolyzable.
SCOPE
1.1 This test method covers the determination of the acidic fluorides of sulfur hexafluoride (SF6).
1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
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SIGNIFICANCE AND USE
4.1 Air and carbon tetrafluoride (CF4) are two contaminants of interest in sulfur hexafluoride (SF6). Both of these contaminants adversely affect the performance of SF6 when used as an electrical insulating gas. Specification for maximum levels of these contaminants are given in Specification D2472.
4.2 Gas chromatography is used to separate these contaminants from a sample of SF6 and to determine their concentration.
SCOPE
1.1 This test method covers the determination of air (Note 1) and carbon tetrafluoride as impurities in sulfur hexafluoride.
Note 1: Nitrogen, oxygen, or any of their mixtures is considered to be air. Commercial grade air or nitrogen is used for standardization.
1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
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ABSTRACT
This specification defines the chemical and physical requirements for boron carbide powder intended for a variety of nuclear applications. The powder shall be classified as: Type 1; Type 2; and Type 3. The material shall conform to the chemical composition requirements prescribed. Quality control tests, acceptance tests, referee tests, and retention of archive samples by the seller shall be performed to conform to the specified requirements.
SCOPE
1.1 This specification defines the chemical and physical requirements for boron carbide powder intended for a variety of nuclear applications. Because each application has a different need for impurity and boron requirements, three different chemical compositions of powder are specified. In using this specification, it is necessary to dictate which type of powder is intended to be used. In general, the intended applications for the various powder types are as follows:
1.1.1 Type 1—For use as particulate material in nuclear reactor core applications.
1.1.2 Type 2—Powder that will be further processed into a fabricated shape for use in a nuclear reactor core or used in non-core applications when the powder directly or indirectly may cause adverse effects on structural components, such as halide stress corrosion of stainless steel.
1.1.3 Type 3—Powder that will be used for non-core applications or special in-core applications.
1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.3 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
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SIGNIFICANCE AND USE
3.1 Sodium chloride occurs in nature. It is a necessary article of diet as well as the source for production of many sodium compounds and chlorine. The methods listed in 1.2 provide procedures for analyzing sodium chloride to determine if it is suitable for its intended use.
SCOPE
1.1 These test methods cover the chemical analyses usually required for sodium chloride.
1.2 The analytical procedures appear in the following sections:
Section
Sample Preparation
5 to 9
Moisture
10 to 17
Water Insolubles
18 to 26
Calcium and Magnesium
27 to 34
Sulfate
35 to 42
Reporting of Analyses
43 to 45
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.
1.5 Review the current safety data sheets (SDS) for detailed information concerning toxicity, first-aid procedures, handling, and safety precautions.
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
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SIGNIFICANCE AND USE
3.1 Calcium chloride is available in various forms and purities. A major use is the de-icing and dust control of roads. It is also used in the coal industry for dustproofing and freezeproofing, in foods, in electrolytic cells, and in refrigeration brines. The test methods listed in 1.2 provide procedures for analyzing calcium chloride to determine if it is suitable for its intended use.
SCOPE
1.1 These test methods cover the analysis of calcium chloride and solutions.
1.2 Procedures are given for the determination of calcium chloride, magnesium chloride, potassium chloride, sodium chloride, and calcium hydroxide. The test methods appear in the following order:
Sections
Calcium Chloride
8 to 17
Magnesium Chloride, Potassium Chloride,
and Sodium Chloride
18 to 28
Calcium Hydroxide
29 to 36
1.3 The values stated in SI units are to be regarded as standard. The values given in parentheses are for information only.
1.4 Review the current Safety Data Sheet (SDS) for detailed information concerning toxicity, first aid procedures, handling, and safety precautions.
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. Specific hazard statements are given in Section 5.
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
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SIGNIFICANCE AND USE
5.1 DOSS is an anionic detergent that is approved by the United States Food and Drug Administration (U.S. FDA) and is used widely as a laxative, emulsifying, solubilizing, and dispersing agent, and is used in the cosmetic industry.4 DOSS may also be used as a dispersing agent to treat oil. DOSS may be released into the environment at levels that may be harmful to aquatic life. The U.S. EPA aquatic life benchmark for DOSS is 40 ppb.5
5.2 This test method has been investigated for use with reagent and sea water.
SCOPE
1.1 This test method covers the determination of dioctyl sulfosuccinate (DOSS) in sea water by direct injection using liquid chromatography (LC) and detection with tandem mass spectrometry (MS/MS). This analyte is qualitatively and quantitatively determined by this test method. This test method adheres to selected reaction monitoring (SRM) mass spectrometry.
1.2 The detection verification level (DVL) and reporting range for DOSS are listed in Table 1.
1.2.1 The DVL is required to be at a concentration at least 3 times below the reporting limit (RL) and have a signal/noise ratio greater than 3:1. Fig. 1 and Fig. 2 display the signal/noise ratio of the selected reaction monitoring (SRM) transition.
FIG. 1 Detection Verification Level Signal/Noise Ratio
FIG. 2 Reporting Level Signal/Noise Ratio
1.2.2 The reporting limit is the concentration of the Level 1 calibration standard as shown in Table 5 for DOSS, taking into account the 50 % sample preparation dilution factor.
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
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SIGNIFICANCE AND USE
5.1 Hexavalent chromium salts are used extensively in the metal finishing and plating industries, in the leather industry as a tanning agent, and in the manufacture of paints, dyes, explosives, and ceramics. Trivalent chromium salts are used as mordants in textile dying, in the ceramic and glass industry, and in photography. Chromium, in either oxidation state, may be present in wastewater from these industries and may also be discharged from chromate-treated cooling waters.
5.2 Hexavalent chromium is toxic to humans, animals, and aquatic life. It can produce lung tumors when inhaled and readily induces skin sensitization. It is not known whether cancer will result from ingestion of chromium in any of its valence states.
5.3 Ion chromatography provides a means of separating the hexavalent chromium from other species present in the sample, many of which interfere with other detection methods. The combination of this separation with a sensitive colorimetric detection method provides a selective and sensitive analytical method for hexavalent chromium with minimal sample preparation.
SCOPE
1.1 This test method covers procedures for the determination of dissolved hexavalent chromium in wastewater, surface water, and drinking water.
1.2 The precision and bias of this test method has been tested in reagent water and industrial wastewater and has been found suitable over the range of approximately 1 to 1000 μg/L. Higher levels can be determined by appropriate dilution.
1.3 Samples containing very high levels of anionic species (that is, chloride, sulfate, etc.) may cause column overload. Samples containing high levels of reducing species (that is, sulfides, sulfites, etc.) may cause reduction of Cr(VI) to Cr(III). This can be minimized by buffering the sample to a pH of 9 to 9.5, filtering it, storing it at
1.4 The values stated in SI units are to be regarded as standard. The values given in parentheses are mathematical conversions to inch-pound units that are provided for information only and are not considered standard.
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
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SIGNIFICANCE AND USE
3.1 Soda ash is used in a number of manufacturing processes. The procedures listed in 1.2 are suitable for specification acceptance and manufacturing control of commercial soda ash.
SCOPE
1.1 These test methods cover the analyses usually required on commercial soda ash (sodium carbonate).
1.2 The analytical procedures appear in the following sections:
Sections
Total Alkalinity, Titrimetric
8 – 15
Sodium Bicarbonate, Titrimetric
17 – 24
Loss on Heating, Gravimetric
26 – 32
Moisture, Calculation
34 – 38
Sodium Chloride, Titrimetric
40 – 46
Sodium Sulfate, Gravimetric
48 – 54
Iron, Photometric
56 – 64
Sieve Analysis
66 – 72
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.4 In determining the conformance of the test results using this method to applicable specifications, results shall be rounded off in accordance with the rounding-off method of Practice E29.
1.5 Review the current Safety Data Sheets (SDS) for detailed information concerning toxicity, first aid procedures, handling and safety precautions.
1.6 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. Specific hazards statements are given in Section 6.
1.7 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
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ABSTRACT
This specification covers sodium bicarbonate for use in various washing, cleaning, and scouring processes. As received sodium bicarbonate shall conform to the chemical requirements according to this specification. Sodium bicarbonate shall be a white, uniform powder, and caking shall be readily disintegrated. Sampling and chemical analysis shall be in accordance with the ASTM standard test methods of alkaline detergents.
SCOPE
1.1 This specification covers material suitable for use in various washing, cleaning, and scouring processes, with or without soap as conditions demand, and where a mildly alkaline material is desired. (Warning—This material may be hazardous if not properly managed. Precautionary information for the safe use, storage, and disposal of this material should be preliminarily obtained from suppliers and others. In case of personal accident with this material, apply appropriate first aid; telephone nearest Poison Control Center for assistance, and get medical attention immediately.)
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ISO/TR 4277:2009 describes a conventional test for the evaluation of the free fluorides content of natural, artificial and recovered cryolite. This method is applicable to products having free fluorides content greater than 0,15 % (mass fraction) of AIF3 or 0,4 % (mass fraction) of NaF.
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ISO 20292:2009 covers materials for the production of primary aluminium. ISO 20292:2009 specifies a method for the determination of the resistance of dense refractory bricks to cryolite melt with excess sodium fluoride.
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Specifies a method based on the fusion of a test portion with sodium carbonate and boric acid and dissolution in perchloric acid solution, followed by formation of the ammonium molybdophosphate complex and extraction of the complex with isobutyl acetate. The solution is absorbed into an acetylene/dinitrogen monoxide flame and the molybdenum, and hence the phosphorus, is determined by measuring the absorbance of the 379,8 nm line emitted by a molybdenum hollow-cathode lamp.
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Covers a method, the orinciple of which consists in preparing tablets from a mixture of the test portion and a binder and measuring the intensity of the K line emitted by the sulphur. The measured intensity is then compared with the intensity of emission of standard tablets of known sulphur content. The method is applicable to products having sulphur contents between 0,01 and 2 % (m/m).
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Applicable to the determination of losses equal to or more than 0.008 % (m/m). The principle consists in drying of a test portion at (105 1) °C for 6 h. The dried test portion is retained for the other determinations given in the annex. Has also been approved by the IUPAC.
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Applicable to products having contents, expressed as phosphorus pentoxide, of 0.005 % (m/m) to 0.05 % (m/m). The residue from the determination of the loss of mass according to ISO 5444 is used to prepare the test sample. Dissolution in dilute hydrochloric acid and nitric acid solutions. Formation of the yellow molybdovanadate and spectrophotometric measurement at a wavelength of about 420 nm. Calculation of the content from the measured absorbance.
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Applicable to products having a content, expressed as sulphur trioxide, equal to or more than 0.1 % (m/m). Bases on alkaline fusion of a test portion with a mixture of sodium carbonate and boric acid. Extraction of the fused mass with perchloric acid solution and precipitation of the sulphate ions with barium chloride in an acidified medium. Filtration on a fine-texture, ashless filter paper (pore diameter approximately 0.4 to 1.0 m). Calcination after drying in an electric oven at (850 20) °C. Weighing of the residue.
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With respect to the free acidity, applicable to products having contents, expressed as H2 SiF6 , equal to or more than 0,1 % (m/m). First, determination of the free acid contents by titration of an ice-cooled test portion with a standard volumetric sodium hydroxide solution in the presence of potassium nitrate and using bromothymol blue as indicator, then, followed by titration at near boiling temperature with standard volumetric sodium hydroxide solution to the appearance of a permanent blue colour.
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Specifies the determination for natural and synthetic materials having a molar ratio sodium fluoride/aluminium trifluoride between 3 and 1,7 approximately. The principle consists in fusion of a test portion with sodium carbonate, separation of fluorine by distillation with sulphuric acid or perchloric acid. Titration with thorium nitrate solution in presence of sodium alizarinsulphonate/methylene blue as indicator. Alternatively, the thorium nitrate titration may be made using only sodium alizarinsulphonate, the end-point being*spectrophotometrically determined at 525 nm.
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Specifies methods of test for natural and synthetic materials having a molar ratio sodium fluoride/aluminium trifluoride between 3 and 1,7 approximately. The method is applicable to products the phosphorus pentoxide content of which does not exceed 0,02 % (m/m). The procedure consists in alkaline fusion of a test portion by means of a mixture of sodium carbonate and boric acid. Dissolution of the fused mass in excess nitric acid so that the pH value is between 0,7 and 0,9. Formation of the (Yellow) oxidized molybdosilicate under clearly defined conditions of acidity, temperature, time and concentration of reagents. Selective reduction in the presence of tartaric acid and measurement at a wvelength of about 815 nm.
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Applies for the determination of natural and synthetic materials having a molar ratio sodium fluoride/aluminium trifluoride between 3 and 1,7 approximately. The method is applicable to products having an iron content equal to or greater than 0,020 % (m/m). The principle consists in dissolution of a test portion by either alkaline or acid fusion. Reduction of iron(III) with hydroxylammonium chloride, formation of the complex iron(II)-1, 10-phenathroline in a buffered medium at pH value between 3,5 and 4,2. Photometric measurement of the coloured complex at a wavelength of about 510 nm. Applies ISO Recommendation R 1694-1970.
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Specifies the procedure for the preparation of crude samples and dried samples and of natural and synthetic materials having a molar ratio sodium fluoride/aluminium trifluoride between 3 and 1,7 approximately. The crude sample is intended for the determination of geometric characteristics, for certain physical and physico-chemical tests and for moisture determination. The dried sample serves especially for chemical tests. The principle of the procedure consists in grinding followed by sieving of the sample until the whole passes through a sieve of mesh aperture 0,125 mm. Thorough mixing and drying at approximately 110 °C.
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Describes the preparation of the calibration graph and the dissolution of a test portion in concentrated sulphuric acid and heating on a hot-plate until the hydrofluoric acid has evaporated. Treatment of the residue with concentrated hydrochloric acid. Aspiration of the solution into an acetylene/dinitrogen monoxide flame and spectrophotometric measurement of the absorption of the 422.7-nm line emitted by a calcium hollow cathode lamp.
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Specifies a gravimetric method for the determination of moisture content of cryolite. Describes the principle, the apparatus, the procedure, gives the expression of results and the test report. An annex lists the ISO Publications of concern.
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Applicable to products the F content of which is equal to or more than 0.5 mg/kg. Specifies the separation of the element from a test portion by steam distillation in a phosphoric acid medium. Formation of a blue-coloured complex with a combined reagent alizarin complexone/lanthanum nitrate in a buffered medium at the pH of 4.6. Addition of acetone to increase the stability of the complex and the sensitivity. Photometric measurement of the complex at a wavelength of about 600 nm.
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Three cases, defined by a preliminary test, are envisaged: silicates containing neither sulphides nor chlorates; silicates containing sulphides; silicates containing chlorates. The method based on boiling of an acidified test portion containing methyl orange and with a lead paper strip in the vapour. The presence of sulphides produces blackening of the paper and the presence of chlorates decolorizes the methyl orange. Volumetric*measurement of carbon dioxide evolved from silicates containing neither sulphides nor chlorates by reaction with a hydrochloric acid solution. The principle for the oxidation of sulphides and the reduction of chlorates are specified.
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The principle of the procedure based on titration of a test portion with a standard volumetric hydrochloric acid solution, in the presence of methyl orange as indikator. The alkalinity is expressed as a percentage by mass of sodium oxide potassium oxide.
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The procedure is based on evaporation to dryness of a test portion previously acidified with hydrochloric acid. Dissolution of the soluble salts, filtration and washing of the insoluble matter. Second evaporation of the filtrate and washings under the same conditions, further dissolution of the soluble salts, filtration and washing. Calcination and weighing of the two lots of insoluble matter simultaneously. Volatilization of silica by heating with hydrofluoric and sulphuric acids and weighing of the residue after calcination. The*difference in mass represents the silica present in the test portion.
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The method specified are applicable directly to soluted mateials or materials soluble in boiling water. In case of solid chemicals not readily soluble in boiling water, a special preliminary treatment is necessary. Precautions shall be taken in order to avoid absorption of moisture and carbon dioxide. All tests and analyses shall be carried out at a temperature of 20 °C. In order to avoid incorrect results use only reagents of analytical grade. Replaces ISO Recommendation R 1686-1970
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The document specifies the formula for the calculation. In this ratio, only sodium oxide and potassium oxide combined in the form of silicates is considered. Replaces ISO Recommendation R 1689-1970.
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Specifies a titrimetric test method for the determination of the basicity of soluted material. The principle of the procedure consists in solution of a test portion in water, filtration of the solution and titration with a standard volumetric solution of hydrochloric acid in presence of methyl orange as indicator. Repaces ISO Recommendation R 740-1968.
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The principle of the method consists in dissolution of a test portion and filtration of the solution through a tared filter. Washing of the insoluble matter at approximately 50 C until the washings are no longer alkaline. Drying of the residue and weighing. Replaces ISO Recommendation R 746-1968.
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Based on hydrolysis of a test portion by prolonged boiling in the presence of hydrochloric acid. Precipitation of the phosphate ions in the form of quinoline phosphomolybdate in the presence of acetone. Filtration by means of a filter crucible, washing, drying and weighing of the precipitate.
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Based on dissolution of a test sample in water, distillation of the ammonia after displacement by an alkali solution. Absorption in an excess of standard volumetric sulphuric acid solution and back-titration with standard volumetric sodium hydroxide solution in the presence of methyl red/methylene blue mixed indicator. A typical distillation apparatus is shown in a figure.
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Not applicable to the analysis of mixtures for agricultural use such as herbicides or pesticides. Indicates the risk in handling with clorates. Dissolution of the test portion in water and reduction by a known quantity, in access, of an iron(II) salt in a sulphuric acid and orthophosphoric acid medium. Titration of the excess iron(II) salt with a standard volumetric solution of potassium dichromate in the presence of barium diphenylamine-4-sulphonate solution as indicator.
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The methods are applicable as alternatives to products for which the molar ratio NaF/AlF3 is equal to about 3. The principle of the flame emission method consists in atomization of the test solution in a flame of oxygen/hydrogen and determination by measurement of the intensity of the radiation at 589 nm. The principle of the flame atomic absorption method is based on atomization in an air/acetylene flame and measuremnt of the absorption of the 589 nm line emitted by a sodium hollow-cathode lamp. The preparation of the test solution is carried out by dissolution of a test portion in hydrochloric acid and water after attack by concentreted sulphuric acid.
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Applicable to products having a free acidity, expressed as H2 SO4 , equal to or more than 0.01 % (m/m). Dissolution of a test portion in Water and titration with standard volumetric sodium hydroxide solution in the presence of an indicator. The indicator must have a colour change in the pH range between 5.2 and 5.6. Has also been approved by the IUPAC.
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Applicable to Fe contents of equal to or more than 0.0001 % (m/m). The reaction bases on the reduction of iron(III) by hydroxylammonium chloride. Formation of the complex between iron(II) and 2,2'-dipyridyl in a buffered medium (pH value between 4.5 and 6). Photometric measurement of the coloured complex at a wavelength of about 522 nm. Has also been approved by the IUPAC.
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Applicable to products having a normal composition for which the molar ratio NaF/AlF3 is equal to about 3. Dissolution of a test portion in concentrated suphuric acid and elimination of hydrogen fluoride. Treatment with hydrochloric acid and water. Atomization of the solution into an acetylene measurement of the absorption of the 309.3 nm line emitted by an aluminium hollow cathode lamp. Has also been approved by the IUPAC.
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Describes a gravimetric method of analysis. It consists in drying a test portion in an electric oven ventilated by convection at (110 2) 0C. Calculation of the moisture content by the loss of mass. Has also been approved by the IUPAC.
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The principle consists in dissolution of a test portion, separation of all insoluble matter by filtration of the solution by vacuum through a filter crucible, drying and weighing. Has also been approved by the IUPAC.
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The principle consists in separation of the fluorine from a test portion by distillation with sulphuric acid or perchloric acid. Titration with thorium nitrate solution using sodium alizarinsuphonate and methylene blue as indicators. Alternatively the thorium nitrate titration may be carried out using sodium alizarinsuphonate alone as indicator, the end-point being determined spectrophotometrically under carefully defined conditions. The absorbance at a wavelength of 525 nm shall reach the arbitrary value of 0.6. Has also been approved by the IUPAC.
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The method is applicable to products with a content greater than 0,01 % (m/m). It is not applicable to the analysis of mixtures of products such as herbicides and insecticides. The principle consists in titration of the chloride ions with mercury(II) nitrate in the presence of diphenylcarbazone as indicator.
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