CEN/TS 17195:2018

SLOVENSKI STANDARD
01-januar-2019
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Construction products - Assessment of release of dangerous substances - Analysis of
inorganic substances in eluates
Bauprodukte - Bewertung der Freisetzung von gefährlichen Stoffen - Analyse von
anorganischen Stoffen in Eluaten
Produits de construction - Evaluation de l’émission de substances dangereuses -
Analyse des substances inorganiques dans les éluats
Ta slovenski standard je istoveten z: CEN/TS 17195:2018
ICS:
13.020.99 Drugi standardi v zvezi z Other standards related to
varstvom okolja environmental protection
91.100.01 Gradbeni materiali na Construction materials in
splošno general
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.

CEN/TS 17195
TECHNICAL SPECIFICATION
SPÉCIFICATION TECHNIQUE
July 2018
TECHNISCHE SPEZIFIKATION
ICS 91.100.01
English Version
Construction products: Assessment of release of
dangerous substances - Analysis of inorganic substances in
eluates
Produits de construction - Evaluation de l'émission de Bauprodukte - Bewertung der Freisetzung von
substances dangereuses - Analyse des substances gefährlichen Stoffen - Analyse von anorganischen
inorganiques dans les éluats Stoffen in Eluaten
This Technical Specification (CEN/TS) was approved by CEN on 9 March 2018 for provisional application.

The period of validity of this CEN/TS is limited initially to three years. After two years the members of CEN will be requested to
submit their comments, particularly on the question whether the CEN/TS can be converted into a European Standard.

CEN members are required to announce the existence of this CEN/TS in the same way as for an EN and to make the CEN/TS
available promptly at national level in an appropriate form. It is permissible to keep conflicting national standards in force (in
parallel to the CEN/TS) until the final decision about the possible conversion of the CEN/TS into an EN is reached.

CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,
Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania,
Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland,
Turkey and United Kingdom.
EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION

EUROPÄISCHES KOMITEE FÜR NORMUNG

CEN-CENELEC Management Centre: Rue de la Science 23, B-1040 Brussels
© 2018 CEN All rights of exploitation in any form and by any means reserved Ref. No. CEN/TS 17195:2018 E
worldwide for CEN national Members.

Contents Page
European foreword . 3
Introduction . 4
1 Scope . 5
2 Normative references . 5
3 Terms and definitions . 6
4 Abbreviations . 8
5 Sample pre-treatment . 8
6 Selection of suitable analytical test method . 9
6.1 Table of test methods . 9
6.2 General validation information . 9
7 Method performance . 11
8 Expression of results . 11
9 Test report . 11
10 Test performance . 12
Annex A (informative) Validation of analytical methods for eluates of waste . 13
A.1 General . 13
A.2 Interlaboratory study . 13
Annex B (informative) Additional validation data for Ba, Cd, Cr, Mo, Sb and Se in eluates
using hydride generation . 19
B.1 General . 19
B.2 Round robin samples . 19
B.3 Results of the round robin test . 20
B.4 Conclusion from the round robin test . 24
Bibliography . 25

European foreword
This document (CEN/TS 17195:2018) has been prepared by Technical Committee CEN/TC 351
“Construction products: Assessment of release of dangerous substances”, the secretariat of which is
held by NEN.
Attention is drawn to the possibility that some of the elements of this document may be the subject of
patent rights. CEN shall not be held responsible for identifying any or all such patent rights.
This document has been prepared under a mandate given to CEN by the European Commission and the
European Free Trade Association.
A similar standard has been developed for eluates from different types of waste, see Annex A.
According to the CEN/CENELEC Internal Regulations, the national standards organisations of the
following countries are bound to announce this Technical Specification: Austria, Belgium, Bulgaria,
Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia,
France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta,
Netherlands, Norway, Poland, Portugal, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland,
Turkey and the United Kingdom.
Introduction
Following an extended evaluation of available methods for content analysis in construction products
(CEN/TR 16045, [1]) it was concluded that eluate analysis methods are very similar to analytical
methods used to determine content after digestion of a solid matrix.
This document has been adopted from the work carried out in the context of CEN/TC 292 and is very
similar to EN 16192 Characterization of waste – Analysis of waste eluates [2].
This Technical Specification is part of a modular horizontal approach which was adopted in
CEN/TC 351. 'Horizontal' means that the methods can be used for a wide range of materials and
products with certain properties. 'Modular' means that a test standard developed in this approach
concerns a specific step in assessing a property and not the whole chain of measurement (from
sampling to analyses). Beneficial features of this approach are that modules can be replaced by better
ones without jeopardizing the standard chain and duplication of work of in different Technical
Committees for Products can be avoided as far as possible.
The modules that relate to the standards developed in CEN/TC 351 are specified in CEN/TR 16220 [3],
which distinguishes between the modules. This Technical Specification belongs to the analytical step.
The use of modular horizontal standards implies the drawing of test schemes as well. Before executing a
test on a certain construction product to determine certain characteristics it is necessary to draw up a
protocol in which the adequate modules are selected and together form the basis for the entire test
procedure.
1 Scope
This Technical Specification specifies analytical methods for the determination of major, minor and
trace elements and of anions in aqueous eluates from construction products. It refers to the following
67 elements:
Aluminium (Al), antimony (Sb), arsenic (As), barium (Ba), beryllium (Be), bismuth (Bi), boron (B),
cadmium (Cd), calcium (Ca), cerium (Ce), cesium (Cs), chromium (Cr), cobalt (Co), copper (Cu),
dysprosium (Dy), erbium (Er), europium (Eu), gadolinium (Gd), gallium (Ga), germanium (Ge), gold
(Au), hafnium (Hf), holmium (Ho), indium (In), iridium (Ir), iron (Fe), lanthanum (La), lead (Pb), lithium
(Li), lutetium (Lu), magnesium (Mg), manganese (Mn), mercury (Hg), molybdenum (Mo), neodymium
(Nd), nickel (Ni), palladium (Pd), phosphorus (P), platinum (Pt), potassium (K), praseodymium (Pr),
rubidium (Rb), rhenium (Re), rhodium (Rh), ruthenium (Ru), samarium (Sm), scandium (Sc), selenium
(Se), silicon (Si), silver (Ag), sodium (Na), strontium (Sr), sulphur (S), tellurium (Te), terbium (Tb),
thallium (Tl), thorium (Th), thulium (Tm), tin (Sn), titanium (Ti), tungsten (W), uranium (U), vanadium
- -
(V), ytterbium (Yb), yttrium (Y), zinc (Zn), and zirconium (Zr) and to the following four anions: Cl , Br ,
- 2-
F , SO .
The Technical Specification also describes how to measure general parameters like pH, electrical
conductivity, DOC/TOC.
The methods in this Technical Specification are applicable to construction products.
NOTE Construction products include e.g. mineral-based products (S); bituminous products (B); metals (M);
wood-based products (W); plastics and rubbers (P); sealants and adhesives (A); paints and coatings (C), see also
CEN/TR 16045.
The selection of analytical methods to be applied is based on the required sensitivity of the method,
which is provided for all substance - analytical procedure combinations.
2 Normative references
The following documents are referred to in the text in such a way that some or all of their content
constitutes requirements of this document. For dated references, only the edition cited applies. For
undated references, the latest edition of the referenced document (including any amendments) applies.
CEN/TS 17197, Construction products: Assessment of release of dangerous substances — Analysis of
major, minor and trace elements in digests and eluates by Inductively Coupled Plasma — Optical Emission
Spectrometry (ICP-OES)
CEN/TS 17200, Construction products: Assessment of release of dangerous substances — Analysis of
major, minor and trace elements in digests and eluates by Inductively Coupled Plasma — Mass
Spectrometry (ICP-MS)
EN 1484, Water analysis — Guidelines for the determination of total organic carbon (TOC) and dissolved
organic carbon (DOC)
EN 27888, Water quality — Determination of electrical conductivity (ISO 7888)
EN ISO 5667-3, Water quality — Sampling — Part 3: Preservation and handling of water samples (ISO
5667-3)
EN ISO 10304-1, Water quality — Determination of dissolved anions by liquid chromatography of ions —
Part 1: Determination of bromide, chloride, fluoride, nitrate, nitrite, phosphate and sulfate (ISO 10304-1)
EN ISO 10523, Water quality — Determination of pH (ISO 10523)
EN ISO 12846, Water quality — Determination of mercury — Method using atomic absorption
spectrometry (AAS) with and without enrichment (ISO 12846)
EN ISO 15586, Water quality — Determination of trace elements using atomic absorption spectrometry
with graphite furnace (ISO 15586)
EN ISO/IEC 17025, General requirements for the competence of testing and calibration laboratories
(ISO/IEC 17025)
EN ISO 17852, Water quality — Determination of mercury — Method using atomic fluorescence
spectrometry (ISO 17852)
ISO 10359-1, Water quality — Determination of fluoride — Part 1: Electrochemical probe method for
potable and lightly polluted water
ISO 17378-1, Water quality — Determination of arsenic and antimony — Part 1: Method using hydride
generation atomic fluorescence spectrometry (HG-AFS)
ISO 17378-2, Water quality — Determination of arsenic and antimony — Part 2: Method using hydride
generation atomic absorption spectrometry (HG-AAS)
ISO/TS 13530, Water quality — Guidance on analytical quality control for chemical and physicochemical
water analysis
ISO/TS 17379-1, Water quality — Determination of selenium — Part 1: Method using hydride generation
atomic fluorescence spectrometry (HG-AFS)
ISO/TS 17379-2, Water quality — Determination of selenium — Part 2: Method using hydride generation
atomic absorption spectrometry (HG-AAS)
3 Terms and definitions
For the purposes of this document, the following terms and definitions apply.
ISO and IEC maintain terminological databases for use in standardizat
...