CEN/TS 17200:2018
(Main)Construction products: Assessment of release of dangerous substances - Analysis of inorganic substances in digests and eluates - Analysis by Inductively Coupled Plasma - Mass Spectrometry (ICP-MS)
Construction products: Assessment of release of dangerous substances - Analysis of inorganic substances in digests and eluates - Analysis by Inductively Coupled Plasma - Mass Spectrometry (ICP-MS)
This Technical Specification specifies the method for the determination of major, minor and trace elements in aqua regia and nitric acid digests and in eluates of construction products by Inductively Coupled Plasma - Mass Spectrometry (ICP-MS). It refers to the following 67 elements: Aluminium (Al), antimony (Sb), arsenic (As), barium (Ba), beryllium (Be), bismuth (Bi), boron (B), cadmium (Cd), calcium (Ca), cerium (Ce), cesium (Cs), chromium (Cr), cobalt (Co), copper (Cu), dysprosium (Dy), erbium (Er), europium (Eu), gadolinium (Gd), gallium (Ga), germanium (Ge), gold (Au), hafnium (Hf), holmium (Ho), indium (In), iridium (Ir), iron (Fe), lanthanum (La), lead (Pb), lithium (Li), lutetium (Lu), magnesium (Mg), manganese (Mn), mercury (Hg), molybdenum (Mo), neodymium (Nd), nickel (Ni), palladium (Pd), phosphorus (P), platinum (Pt), potassium (K), praseodymium (Pr), rubidium (Rb), rhenium (Re), rhodium (Rh), ruthenium (Ru), samarium (Sm), scandium (Sc), selenium (Se), silicon (Si), silver (Ag), sodium (Na), strontium (Sr), sulphur (S), tellurium (Te), terbium (Tb), thallium (Tl), thorium (Th), thulium (Tm), tin (Sn), titanium (Ti), tungsten (W), uranium (U), vanadium (V), ytterbium (Yb), yttrium (Y), zinc (Zn), and zirconium (Zr).
NOTE 1 Construction products include e.g. mineral-based products (S); bituminous products (B); metals (M); wood-based products (W); plastics and rubbers (P); sealants and adhesives (A); paints and coatings (C), see also CEN/TR 16045 [1].
The working range depends on the matrix and the interferences encountered.
NOTE 2 The limit of detection of most elements will be affected by their natural abundance, ionization behaviour, on abundance of isotope(s) free from isobaric interferences and by contamination (e.g. handling and airborne). Handling contaminations are in many cases more important than airborne ones.
The limit of detection will be higher in cases where the determination is likely to be interfered (see Clause 4) or in case of memory effects (see e.g. EN ISO 17294-1:2006, 8.2).
The method in this Technical Specification is applicable to construction products and validated for the product types listed in Annex B.
Bauprodukte: Beurteilung der Freisetzung von gefährlichen Stoffen - Analyse von anorganischen Stoffen in Aufschlusslösungen und Eluaten - Analyse mit Massenspektrometrie mit induktiv gekoppeltem Plasma (ICP‐MS)
Diese Technische Spezifikation legt die Analysenverfahren für die Bestimmung von Haupt-, Neben- und Spurenelementen in Königswasser und Salpetersäureaufschlusslösungen sowie Eluaten von Bauprodukten durch Massenspektrometrie mit induktiv gekoppeltem Plasma (ICP MS) fest. Sie bezieht sich auf die folgenden 67 Elemente:
Aluminium (Al), Antimon (Sb), Arsen (As), Barium (Ba), Beryllium (Be), Bismut (Bi), Bor (B), Cadmium (Cd), Calcium (Ca), Cer (Ce), Caesium (Cs), Chrom (Cr), Cobalt (Co), Kupfer (Cu), Dysprosium (Dy), Erbium (Er), Europium (Eu), Gadolinium (Gd), Gallium (Ga), Germanium (Ge), Gold (Au), Hafnium (Hf), Holmium (Ho), Indium (In), Iridium (Ir), Eisen (Fe), Lanthan (La), Blei (Pb), Lithium (Li), Lutetium (Lu), Magnesium (Mg), Mangan (Mn), Quecksilber (Hg), Molybdän (Mo), Neodym (Nd), Nickel (Ni), Palladium (Pd), Phosphor (P), Platin (Pt), Kalium (K), Praseodym (Pr), Rubidium (Rb), Rhenium (Re), Rhodium (Rh), Ruthenium (Ru), Samarium (Sm), Scandium (Sc), Selen (Se), Silicium (Si), Silber (Ag), Natrium (Na), Strontium (Sr), Schwefel (S), Tellur (Te), Terbium (Tb), Thallium (Tl), Thorium (Th), Thulium (Tm), Zinn (Sn), Titan (Ti), Wolfram (W), Uran (U), Vanadium (V), Ytterbium (Yb), Yttrium (Y), Zink (Zn) und Zirconium (Zr).
ANMERKUNG 1 Bauprodukte umfassen z. B. mineralische Produkte (S), bituminöse Produkte (B), Metalle (M), Holzprodukte (W), Kunststoffe und Gummi (P), Dichtstoffe und Kleber (A), Farben und Beschichtungen (C), siehe auch CEN/TR 16045 [1].
Der Arbeitsbereich hängt von der Matrix und den zu erwartenden Interferenzen ab.
ANMERKUNG 2 Die Nachweisgrenze der meisten Elemente wird durch deren natürliche Häufigkeit, Ionisationsverhalten, Häufigkeit von Isotop(en) frei von isobaren Interferenzen und durch Kontamination (z. B. durch Handhabung und Luft) beeinflusst. Handhabungsbedingte Kontaminationen sind in den meisten Fällen von größerer Bedeutung als luftgetragene Kontaminationen.
Die Nachweisgrenze wird höher ausfallen, wenn bei der Bestimmung Interferenzen möglich sind (siehe Abschnitt 4) oder Memoryeffekte auftreten (siehe z. B. EN ISO 17294 1:2006, 8.2).
Die in dieser Technischen Spezifikation beschriebenen Verfahren sind für Bauprodukte geeignet und für die in Anhang B aufgeführten Produkttypen validiert.
Produits de construction: Évaluation des émissions de substances dangereuses - Analyse des substances inorganiques dans les digestats et les éluats - Analyse par spectrométrie de masse avec plasma à couplage inductif
Gradbeni proizvodi - Ocenjevanje sproščanja nevarnih snovi - Analiza anorganskih snovi po razklopu in v izlužkih - Analiza z masno spektrometrijo z induktivno sklopljeno plazmo (ICP/MS)
Ta tehnična dokumentacija podaja metodo za določanje glavnih in stranskih elementov ter elementov v sledovih v zlatotopki in izvlečku dušikove kisline ter v izlužkih gradbenih proizvodov z masno spektrometrijo z induktivno sklopljeno plazmo (ICP/MS). Sklicuje se na naslednjih 67 elementov: aluminij (Al), antimon (Sb), arzen (As), barij (Ba), berilij (Be), bizmut (Bi), bor (B), kadmij (Cd), kalcij (Ca), cerij (Ce), cezij (Cs), krom (Cr), kobalt (Co), baker (Cu), disprozij (Dy), erbij (Er), evropij (Eu), gadolinij (Gd), galij (Ga), germanij (Ge), zlato (Au), hafnij (Hf), holmij (Ho), indij (In), iridij (Ir), železo (Fe), lantan (La), svinec (Pb), litij (Li), lutecij (Lu), magnezij (Mg), mangan (Mn), živo srebro (Hg), molibden (Mo), neodim (Nd), nikelj (Ni), paladij (Pd), fosfor (P), platina (Pt), kalij (K), prazeodim (Pr), rubidij (Rb), renij (Re), rodij (Rh), rutenij (Ru), samarij (Sm), skandij (Sc), selen (Se), silicij (Si), srebro (Ag), natrij (Na), stroncij (Sr), žveplo (S), telurij (Te), terbij (Tb), talij (Tl), torij (Th), tulij (Tm), kositer (Sn), titan (Ti), volfram (W), uran (U), vanadij (V), iterbij (Yb), itrij (Y), cink (Zn) in cirkonij (Zr).
OPOMBA 1: Gradbeni proizvodi vključujejo npr. mineralne proizvode (S), bitumenske proizvode (B), kovine (M), lesne proizvode (W), plastične mase in gume (P), tesnila in lepila (A), barve in premaze (C), glej tudi CEN/TR 16045 [1].
Delovni razpon je odvisen od matrice in motenj, ki se pojavijo.
OPOMBA 2: Na mejo detekcije za večino elementov bo vplival njihov delež v naravi, proces ionizacije ali delež izotopov brez izobaričnih interferenc ter onesnaženje (npr. pri ravnanju, v zraku). Onesnaženja pri ravnanju so v veliko primerih pomembnejše od onesnaženja v zraku.
Meja detekcije bo višja v primerih, ko obstaja možnost motnje določevanja (glej točko 4), ali v primeru spominskih učinkov (glej npr. EN ISO 17294-1:2006, 8.2).
Metoda v tej tehnični specifikaciji se uporablja pri gradbenih proizvodih in je potrjena za vrste proizvodov, navedene v dodatku B.
General Information
Relations
Standards Content (Sample)
SLOVENSKI STANDARD
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Construction products - Assessment of release of dangerous substances - Analysis of
inorganic substances in digests and eluates - Analysis by Inductively Coupled Plasma -
Mass Spectrometry (ICP-MS)
Bauprodukte - Beurteilung der Freisetzung von gefährlichen Stoffen - Analyse von
anorganischen Stoffen in Aufschlusslösungen und Eluaten - Analyse mit induktiv
gekoppeltem Plasma - Massenspektrometrie (ICP-MS)
Produits de construction - Évaluation des émissions de substances dangereuses -
Analyse des substances inorganiques dans les digestats et les éluats - Analyse par
spectrométrie de masse avec plasma à couplage inductif
Ta slovenski standard je istoveten z: CEN/TS 17200:2018
ICS:
13.020.99 Drugi standardi v zvezi z Other standards related to
varstvom okolja environmental protection
91.100.01 Gradbeni materiali na Construction materials in
splošno general
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.
CEN/TS 17200
TECHNICAL SPECIFICATION
SPÉCIFICATION TECHNIQUE
July 2018
TECHNISCHE SPEZIFIKATION
ICS 91.100.01
English Version
Construction products: Assessment of release of
dangerous substances - Analysis of inorganic substances in
digests and eluates - Analysis by Inductively Coupled
Plasma - Mass Spectrometry (ICP-MS)
Produits de construction: Évaluation des émissions de Bauprodukte: Beurteilung der Freisetzung von
substances dangereuses - Analyse des substances gefährlichen Stoffen - Analyse von anorganischen
inorganiques dans les digestats et les éluats - Analyse Stoffen in Aufschlusslösungen und Eluaten - Analyse
par spectrométrie de masse avec plasma à couplage mit induktiv gekoppeltem Plasma -
inductif Massenspektrometrie (ICP-MS)
This Technical Specification (CEN/TS) was approved by CEN on 2 April 2018 for provisional application.
The period of validity of this CEN/TS is limited initially to three years. After two years the members of CEN will be requested to
submit their comments, particularly on the question whether the CEN/TS can be converted into a European Standard.
CEN members are required to announce the existence of this CEN/TS in the same way as for an EN and to make the CEN/TS
available promptly at national level in an appropriate form. It is permissible to keep conflicting national standards in force (in
parallel to the CEN/TS) until the final decision about the possible conversion of the CEN/TS into an EN is reached.
CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,
Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania,
Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland,
Turkey and United Kingdom.
EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION
EUROPÄISCHES KOMITEE FÜR NORMUNG
CEN-CENELEC Management Centre: Rue de la Science 23, B-1040 Brussels
© 2018 CEN All rights of exploitation in any form and by any means reserved Ref. No. CEN/TS 17200:2018 E
worldwide for CEN national Members.
Contents Page
European foreword . 4
Introduction . 5
1 Scope . 6
2 Normative references . 6
3 Terms and definitions . 7
4 Symbols and abbreviations . 9
5 Principle . 9
6 Interferences . 9
6.1 General . 9
6.2 Spectral interferences . 9
6.2.1 Isobaric elemental interferences . 9
6.2.2 Isobaric molecular and doubly charged ion interferences . 10
6.3 Non spectral interferences . 10
7 Reagents . 10
8 Apparatus . 13
9 Procedure. 14
9.1 Test sample . 14
9.2 Test portion . 14
9.3 Instrument set up . 14
9.4 Calibration . 15
9.4.1 Calibration function . 15
9.4.2 Standard addition calibration . 15
9.4.3 Determination of correction factors . 16
9.4.4 Variable isotope ratio . 16
9.5 Sample measurement . 16
10 Calculation . 16
10.1 Calculation for digests of construction products . 16
10.2 Calculation for eluates of construction products . 17
11 Expression of results . 17
12 Performance characteristics . 17
12.1 General . 17
12.2 Blank . 17
12.3 Calibration check . 17
12.4 Internal standard response . 17
12.5 Interference . 17
12.6 Recovery . 17
12.7 Precision . 17
13 Test report . 18
Annex A (informative) Method detection limit (MDL) and precision data for soil, sludge
and biowaste . 20
Annex B (informative) Validation results for construction products . 28
B.1 Introduction. 28
B.2 Performance data . 28
Bibliography . 29
European foreword
This document (CEN/TS 17200:2018) has been prepared by Technical Committee CEN/TC 351
“Construction products - Assessment of release of dangerous substances”, the secretariat of which is
held by NEN.
Attention is drawn to the possibility that some of the elements of this document may be the subject of
patent rights. CEN shall not be held responsible for identifying any or all such patent rights.
This document has been prepared under a mandate given to CEN by the European Commission and the
European Free Trade Association.
A similar document has been developed for drinking water, surface water and waste water and
different types of waste respectively, see Annex A.
According to the CEN/CENELEC Internal Regulations, the national standards organisations of the
following countries are bound to announce this Technical Specification: Austria, Belgium, Bulgaria,
Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia,
France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta,
Netherlands, Norway, Poland, Portugal, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland,
Turkey and the United Kingdom.
Introduction
Following an extended evaluation of available methods for content and eluate analysis in construction
products (CEN/TR 16045; [1]) it was concluded that multi element analysis methods have preference
over methods developed for single elements or small groups of elements. This implies that for inorganic
substances ICP methods are preferred for the analysis of extracts obtained from digestion or eluates
obtained from leaching.
This standard has been adopted from the work carried out in the context of CEN/TC 400 (project
HORIZONTAL) and is very similar to EN 16171, Sludge, treated biowaste and soil - Determination of
elements using inductively coupled plasma mass spectrometry (ICP-MS) [2].
This Technical Specification is part of a modular horizontal approach which was adopted in
CEN/TC 351. 'Horizontal' means that the methods can be used for a wide range of materials and
products with certain properties. 'Modular' means that a test standard developed in this approach
concerns a specific step in assessing a property and not the whole chain of measurement (from
sampling to analyses). Beneficial features of this approach are that modules can be replaced by better
ones without jeopardizing the standard chain and duplication of work of in different Technical
Committees for Products can be avoided as far as possible.
The modules that relate to the standards developed in CEN/TC 351 are specified in CEN/TR 16220,
Construction products: Assessment of release of dangerous substances – Complement to sampling [3]
which distinguishes between the modules. This Technical Specification belongs to the analytical step.
The use of modular horizontal standards implies the drawing of test schemes as well. Before executing a
test on a certain construction product to determine certain characteristics it is necessary to draw up a
protocol in which the adequate modules are selected and together form the basis for the entire test
procedure.
1 Scope
This Technical Specification specifies the method for the determination of major, minor and trace
elements in aqua regia and nitric acid digests and in eluates of construction products by Inductively
Coupled Plasma - Mass Spectrometry (ICP-MS). It refers to the following 67 elements: Aluminium (Al),
antimony (Sb), arsenic (As), barium (Ba), beryllium (Be), bismuth (Bi), boron (B), cadmium (Cd),
calcium (Ca), cerium (Ce),
...
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