EN 17197:2023
(Main)Construction products: Assessment of release of dangerous substances - Analysis of inorganic substances in eluates and digests - Analysis by inductively coupled plasma optical emission spectrometry (ICP-OES)
Construction products: Assessment of release of dangerous substances - Analysis of inorganic substances in eluates and digests - Analysis by inductively coupled plasma optical emission spectrometry (ICP-OES)
This document specifies the method for the determination of major, minor and trace elements in eluates and in aqua regia and nitric acid digests of construction products by inductively coupled plasma optical emission spectrometry (ICP-OES). It refers to the following 44 elements:
Aluminium (Al), antimony (Sb), arsenic (As), barium (Ba), beryllium (Be), bismuth (Bi), boron (B), cadmium (Cd), calcium (Ca), cerium (Ce), chromium (Cr), cobalt (Co), copper (Cu), iron (Fe), lanthanum (La), lead (Pb), lithium (Li), magnesium (Mg), manganese (Mn), mercury (Hg), molybdenum (Mo), neodymium (Nd), nickel (Ni), phosphorus (P), potassium (K), praseodymium (Pr), samarium (Sm), scandium (Sc), selenium (Se), silicon (Si), silver (Ag), sodium (Na), strontium (Sr), sulphur (S), tellurium (Te), thallium (Tl), thorium (Th), tin (Sn), titanium (Ti), tungsten (W), uranium (U), vanadium (V), zinc (Zn), and zirconium (Zr).
For the determination of low levels of As, Hg, Se and Sb, chemical vapour generation systems can be applied. This method is described in Annex E (normative).
NOTE Construction products include e.g. mineral-based products (S); bituminous products (B); metals (M); wood-based products (W); plastics and rubbers (P); sealants and adhesives (A); paints and coatings (C), see also CEN/TR 16045.
The method in this document is applicable to construction products and validated for the product types listed in Annex C (informative).
Bauprodukte: Bewertung der Freisetzung von gefährlichen Stoffen - Analyse von anorganischen Stoffen in Aufschlusslösungen und Eluaten - Analyse mit induktiv gekoppeltem Plasma - Optische Emissionsspektrometrie (ICP-OES)
Dieses Dokument legt ein Verfahren zur Bestimmung von Haupt-, Neben- und Spurenelementen in Eluaten und in Königswasser- und Salpetersäureaufschlusslösungen von Bauprodukten mittels optischer Emissionsspektrometrie mit induktiv gekoppeltem Plasma (ICP OES) fest. Es bezieht sich auf die folgenden 44 Elemente:
Aluminium (Al), Antimon (Sb), Arsen (As), Barium (Ba), Beryllium (Be), Bismut (Bi), Blei (Pb), Bor (B), Cadmium (Cd), Calcium (Ca), Cer (Ce), Chrom (Cr), Eisen (Fe), Kalium (K), Kobalt (Co), Kupfer (Cu), Lanthan (La), Lithium (Li), Magnesium (Mg), Mangan (Mn), Molybdän (Mo), Natrium (Na), Neodym (Nd), Nickel (Ni), Phosphor (P), Praseodym (Pr), Quecksilber (Hg), Samarium (Sm), Scandium (Sc), Schwefel (S), Selen (Se), Silber (Ag), Silicium (Si), Strontium (Sr), Tellur (Te), Thallium (Tl), Thorium (Th), Titan (Ti), Uran (U), Vanadium (V), Wolfram (W), Zink (Zn), Zinn (Sn) und Zirconium (Zr).
Zur Bestimmung geringer Gehalte von As, Hg, Se und Sb können chemische Dampferzeugungssysteme eingesetzt werden. Dieses Verfahren wird in Anhang E (normativ) beschrieben.
ANMERKUNG Bauprodukte umfassen z. B. mineralische Produkte (S), bituminöse Produkte (B), Metalle (M), Holzprodukte (W), Kunststoffe und Gummi (P), Dichtstoffe und Klebstoffe (A), Farben und Beschichtungen (C), siehe auch CEN/TR 16045.
Das in diesem Dokument beschriebene Verfahren ist für Bauprodukte anwendbar und ist für die in Anhang C (informativ) aufgeführten Produkttypen validiert.
Produits de construction : Évaluation de l'émission de substances dangereuses - Analyse des substances inorganiques dans les éluats et les digestats - Analyse par spectrométrie d'émission optique avec plasma à couplage inductif (ICP-OES)
Le présent document spécifie la méthode de détermination des éléments majeurs, mineurs et des éléments traces dans les éluats et dans les digestats d'eau régale et d'acide nitrique de produits de construction par spectroscopie d'émission optique avec plasma à couplage inductif (ICP-OES). Il fait référence aux 44 éléments suivants :
Aluminium (Al), antimoine (Sb), arsenic (As), baryum (Ba), béryllium (Be), bismuth (Bi), bore (B), cadmium (Cd), calcium (Ca), cérium (Ce), chrome (Cr), cobalt (Co), cuivre (Cu), fer (Fe), lanthane (La), plomb (Pb), lithium (Li), magnésium (Mg), manganèse (Mn), mercure (Hg), molybdène (Mo), néodyme (Nd), nickel (Ni), phosphore (P), potassium (K), praséodyme (Pr), samarium (Sm), scandium (Sc), sélénium (Se), silicium (Si), argent (Ag), sodium (Na), strontium (Sr), soufre (S), tellure (Te), thallium (Tl), thorium (Th), étain (Sn), titane (Ti), tungstène (W), uranium (U), vanadium (V), zinc (Zn) et zirconium (Zr).
Pour la détermination de faibles concentrations de As, Hg, Se et Sb, la génération de vapeur chimique (usuellement appelé générateur d'hydrures) peut être appliquée. Cette méthode est décrite à l'Annexe E (normative).
NOTE Les produits de construction comprennent par exemple les produits à base de minéraux (S) ; les produits bitumineux (B) ; les métaux (M) ; les produits à base de bois (W) ; les plastiques et les caoutchoucs (P) ; les produits d'étanchéité et les adhésifs (A) ; les peintures et les revêtements (C), voir également le CEN/TR 16045.
La méthode présentée dans le présent document est applicable aux produits de construction et validée pour les types de produits énumérés à l'Annexe C (informative).
Gradbeni proizvodi - Ocenjevanje sproščanja nevarnih snovi - Analiza anorganskih snovi po razklopu in v izlužkih - Analiza z optično emisijsko spektrometrijo z induktivno sklopljeno plazmo (ICP-OES)
Ta evropski standard opisuje metodo za določanje glavnih in stranskih elementov ter elementov v sledovih v zlatotopki in izvlečku dušikove kisline ter v izlužkih gradbenih proizvodov z optično emisijsko spektrometrijo z induktivno sklopljeno plazmo (ICP/OES). Sklicuje se na naslednjih 44 elementov:
aluminij (Al), antimon (Sb), arzen(As), barij (Ba), berilij (Be), bizmut (Bi), bor (B), kadmij (Cd), kalcij (Ca), cerij (Ce), krom (Cr), kobalt (Co), baker (Cu), železo (Fe), lantan (La), svinec (Pb), litij (Li), magnezij (Mg), mangan (Mn), živo srebro (Hg), molibden (Mo), neodim (Nd), nikelj (Ni), fosfor (P), kalij (K), prazeodim (Pr), samarij (Sm), skandij (Sc), selen (Se), silicij (Si), srebro (Ag), natrij (Na), stroncij (Sr), žveplo (S), telurij (Te), talij (Tl), torij (Th), kositer (Sn), titan (Ti), volfram (W), uran (U), vanadij (V), cink (Zn) in cirkonij (Zr).
Za določanje nizke ravni As, Se in Sb se lahko uporabi hidridna metoda. Ta metoda je opisana v dodatku D.
OPOMBA: Gradbeni proizvodi vključujejo npr. mineralne proizvode (S); bitumenske proizvode (B); kovine (M); lesne proizvode (W); plastične mase in gume (P); tesnila in lepila (A); barve in premaze (C), glej tudi CEN/TR 16045.
Ta metoda v tem evropskem standardu se uporablja za gradbene proizvode in je potrjena za vrste proizvodov, navedene v dodatku D.
General Information
Relations
Standards Content (Sample)
SLOVENSKI STANDARD
01-april-2024
Nadomešča:
SIST-TS CEN/TS 17197:2019+AC:2019
Gradbeni proizvodi - Ocenjevanje sproščanja nevarnih snovi - Analiza
anorganskih snovi po razklopu in v izlužkih - Analiza z optično emisijsko
spektrometrijo z induktivno sklopljeno plazmo (ICP-OES)
Construction products - Assessment of release of dangerous substances - Analysis of
inorganic substances in digests and eluates - Analysis by inductively coupled plasma
optical emission spectrometry (ICP-OES)
Bauprodukte - Bewertung der Freisetzung von gefährlichen Stoffen - Analyse von
anorganischen Stoffen in Aufschlusslösungen und Eluaten - Analyse mit induktiv
gekoppeltem Plasma - Optische Emissionsspektrometrie (ICP-OES)
Produits de construction - Évaluation de l'émission de substances dangereuses -
Analyse des substances inorganiques dans les éluats et les digestats - Analyse par
spectrométrie d'émission optique avec plasma à couplage inductif (ICP-OES)
Ta slovenski standard je istoveten z: EN 17197:2023
ICS:
13.020.99 Drugi standardi v zvezi z Other standards related to
varstvom okolja environmental protection
71.040.50 Fizikalnokemijske analitske Physicochemical methods of
metode analysis
91.100.01 Gradbeni materiali na Construction materials in
splošno general
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.
EN 17197
EUROPEAN STANDARD
NORME EUROPÉENNE
November 2023
EUROPÄISCHE NORM
ICS 91.100.01 Supersedes CEN/TS 17197:2018+AC:2018
English Version
Construction products: Assessment of release of
dangerous substances - Analysis of inorganic substances in
eluates and digests - Analysis by inductively coupled
plasma optical emission spectrometry (ICP-OES)
Produits de construction : Évaluation de l'émission de Bauprodukte: Bewertung der Freisetzung von
substances dangereuses - Analyse des substances gefährlichen Stoffen - Analyse von anorganischen
inorganiques dans les éluats et les digestats - Analyse Stoffen in Aufschlusslösungen und Eluaten - Analyse
par spectrométrie d'émission optique avec plasma à mit induktiv gekoppeltem Plasma - Optische
couplage inductif (ICP-OES) Emissionsspektrometrie (ICP-OES)
This European Standard was approved by CEN on 14 August 2023.
CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this
European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references
concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN
member.
This European Standard exists in three official versions (English, French, German). A version in any other language made by
translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management
Centre has the same status as the official versions.
CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,
Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway,
Poland, Portugal, Republic of North Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Türkiye and
United Kingdom.
EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION
EUROPÄISCHES KOMITEE FÜR NORMUNG
CEN-CENELEC Management Centre: Rue de la Science 23, B-1040 Brussels
© 2023 CEN All rights of exploitation in any form and by any means reserved Ref. No. EN 17197:2023 E
worldwide for CEN national Members.
Contents Page
European foreword . 4
Introduction . 5
1 Scope . 6
2 Normative references . 6
3 Terms and definitions . 6
4 Abbreviations . 8
5 Principle . 9
6 Interferences . 9
6.1 General . 9
6.2 Spectral interferences . 9
6.2.1 Background emission and stray light . 9
6.2.2 Spectral overlaps .10
6.3 Non-spectral interferences .10
6.3.1 Physical interferences .10
6.3.2 Chemical interferences .10
6.3.3 Memory interferences .10
7 Reagents .10
8 Apparatus .12
9 Procedure.13
9.1 Test sample .13
9.2 Test portion .13
9.3 Instrument set up .13
9.3.1 General requirements .13
9.3.2 Inter-element correction .14
9.3.3 Internal standard .14
9.3.4 Instrument performance check .14
9.4 Calibration .14
9.4.1 Linear calibration function .14
9.4.2 Nonlinear calibration function .15
9.4.3 Standard addition calibration .15
9.5 Sample measurement .15
10 Calculation .16
10.1 Calculation for digests of construction products .16
10.2 Calculation for eluates of construction products .16
11 Expression of results .16
12 Performance characteristics .16
12.1 General .16
12.2 Blank .16
12.3 Calibration check .16
12.4 Interference .16
12.5 Recovery . 17
12.6 Indicative values for MDL . 17
13 Test performance . 17
14 Test report . 18
Annex A (informative) Wavelengths, spectral interferences and estimated method
detection limits . 19
Annex B (informative) Indicative values for MDL . 23
Annex C (informative) Validation results for analysis of inorganic substances in digest and
eluates from construction products . 24
C.1 General . 24
C.2 Precision data for analysis of eluates from construction products . 24
C.3 Precision data for analysis of aqua regia digests from construction products . 31
Annex D (informative) Inter element correction (IEC) . 38
Annex E (normative) Determination of arsenic, antimony, mercury and selenium using
chemical vapour generation ICP-OES . 40
E.1 Scope . 40
E.2 Principle . 40
E.3 Apparatus . 40
E.4 Reagents . 41
E.5 Procedure . 42
E.6 Calculation . 43
Bibliography . 44
European foreword
This document (EN 17197:2023) has been prepared by Technical Committee CEN/TC 351 “Construction
products: Assessment of release of dangerous substances”, the secretariat of which is held by NEN.
This European Standard shall be given the status of a national standard, either by publication of an
identical text or by endorsement, at the latest by May 2024, and conflicting national standards shall be
withdrawn at the latest by May 2024.
Attention is drawn to the possibility that some of the elements of this document may be the subject of
patent rights. CEN shall not be held responsible for identifying any or all such patent rights.
This document supersedes CEN/TS 17197:2018+AC:2018.
In comparison with the previous edition, the following technical modifications have been made:
— the addition of performance data and data from intercomparison validation;
— alignment of terms and definitions within the working groups of CEN/TC 351, i.e. through the revised
version of EN 16687.
This document has been prepared under a Standardization Request given to CEN by the European
Commission and the European Free Trade Association.
Any feedback and questions on this document should be directed to the users’ national standards body.
A complete listing of these bodies can be found on the CEN website.
According to the CEN-CENELEC Internal Regulations, the national standards organisations of the
following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria, Croatia,
Cyprus, Czech Republic, Denmark, Estonia, Finla
...
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