Construction products: Assessment of release of dangerous substances - Sampling and quantitative determination of asbestos in construction products

This document summarizes methods for sampling, sample preparation and identification of asbestos in construction products. This document specifies appropriate sample preparation procedures for the quantitative analysis of the asbestos mass fraction in natural, manufactured or recycled large mineral aggregates and construction products of fine mineral particle size materials. This document describes the identification of asbestos by polarized light microscopy (PLM) and dispersion staining, scanning electron microscopy (SEM) with energy dispersive X-ray analysis or transmission electron microscopy (TEM) with energy dispersive X-ray and electron diffraction analysis.
NOTE   This document is intended for microscopists familiar with polarized light, transmission electron- and scanning electron microscopy methods and the other analytical techniques specified (see ISO 10312, ISO 13794, ISO 14966, [McCrone et al., 1984], [Su et al., 1995]). It is not the intention of this document to provide instructions on basic analytical techniques.

Bauprodukte: Bewertung der Freisetzung von gefährlichen Stoffen - Probenahme und quantitative Bestimmung von Asbest in Bauprodukten

Dieses Dokument fasst die Probenahmeverfahren, die Probenvorbereitung und die Identifizierung von Asbest in Bauprodukten zusammen. Dieses Dokument legt geeignete Verfahren zur Probenvorbereitung für die quantitative Analyse des Massenanteils von Asbest in natürlichen, hergestellten oder rezyklierten großen mineralischen Gesteinskörnungen und Bauprodukten aus mineralischen Feinkornmaterialien fest. Dieses Dokument beschreibt die Identifizierung von Asbest durch Polarisationsmikroskopie (PLM) und Dispersionsfärbung, Rasterelektronenmikroskopie (REM) mit energiedispersiver Röntgenanalyse oder Transmissionselektronenmikroskopie (TEM) mit energiedispersiver Röntgen- und Elektronenbeugungsanalyse.
ANMERKUNG   Dieses Dokument richtet sich an Mikroskopiker, die mit den Verfahren der Polarisations-, Transmissions- und Rasterelektronenmikroskopie und den anderen festgelegten Analyseverfahren vertraut sind (siehe ISO 10312, ISO 13794, ISO 14966, [McCrone et al., 1984], [Su et al., 1995]). Es ist nicht Zweck dieses Dokuments, Anleitungen zu grundlegenden Analyseverfahren zu geben.

Produits de construction: Evaluation de l'émission de substances dangereuses - Échantillonnage et dosage qualitatif de l’amiante dans les produits de construction

Gradbeni proizvodi - Ocenjevanje sproščanja nevarnih snovi - Vzorčenje in kvantitativno določanje azbesta v gradbenih proizvodih

General Information

Status
Published
Publication Date
19-Mar-2024
Current Stage
6060 - Definitive text made available (DAV) - Publishing
Start Date
20-Mar-2024
Due Date
13-Mar-2022
Completion Date
20-Mar-2024

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SLOVENSKI STANDARD
kSIST-TS FprCEN/TS 18020:2023
01-december-2023
Gradbeni proizvodi - Ocenjevanje sproščanja nevarnih snovi - Vzorčenje in
kvantitativno določanje azbesta v gradbenih proizvodih
Construction products: Assessment of release of dangerous substances - Sampling and
quantitative determination of asbestos in construction products
Bauprodukte: Bewertung der Freisetzung von gefährlichen Stoffen - Probenahme und
qualitative Bestimmung von Asbest in Bauprodukten
Produits de construction: Evaluation de l'émission de substances dangereuses -
Échantillonnage et dosage qualitatif de lamiante dans les produits de construction
Ta slovenski standard je istoveten z: FprCEN/TS 18020
ICS:
13.300 Varstvo pred nevarnimi Protection against dangerous
izdelki goods
91.100.01 Gradbeni materiali na Construction materials in
splošno general
kSIST-TS FprCEN/TS 18020:2023 en
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.

kSIST-TS FprCEN/TS 18020:2023
kSIST-TS FprCEN/TS 18020:2023
FINAL DRAFT
TECHNICAL SPECIFICATION
FprCEN/TS 18020
SPÉCIFICATION TECHNIQUE
TECHNISCHE SPEZIFIKATION
October 2023
ICS 13.300; 91.100.01
English Version
Construction products: Assessment of release of
dangerous substances - Sampling and quantitative
determination of asbestos in construction products
Produits de construction: Evaluation de l'émission de Bauprodukte: Bewertung der Freisetzung von
substances dangereuses - Échantillonnage et dosage gefährlichen Stoffen - Probenahme und qualitative
qualitatif de l¿amiante dans les produits de Bestimmung von Asbest in Bauprodukten
construction
This draft Technical Specification is submitted to CEN members for Vote. It has been drawn up by the Technical Committee
CEN/TC 351.
CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,
Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway,
Poland, Portugal, Republic of North Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Türkiye and
United Kingdom.
Recipients of this draft are invited to submit, with their comments, notification of any relevant patent rights of which they are
aware and to provide supporting documentation.

Warning : This document is not a Technical Specification. It is distributed for review and comments. It is subject to change
without notice and shall not be referred to as a Technical Specification.

EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION

EUROPÄISCHES KOMITEE FÜR NORMUNG

CEN-CENELEC Management Centre: Rue de la Science 23, B-1040 Brussels
© 2023 CEN All rights of exploitation in any form and by any means reserved Ref. No. FprCEN/TS 18020:2023 E
worldwide for CEN national Members.

kSIST-TS FprCEN/TS 18020:2023
FprCEN/TS 18020:2023 (E)
Contents Page
European foreword . 4
Introduction . 5
1 Scope . 7
2 Normative references . 7
3 Terms and definitions . 7
4 Abbreviations . 13
5 Principle . 13
6 Asbestos . 14
6.1 Regulated asbestos minerals . 14
6.2 Physical and morphological properties of asbestos minerals. 15
6.3 Naturally occurring asbestos (NOA) . 16
6.4 Asbestos containing construction products . 16
7 Method detection limit . 17
8 Limit of quantification . 18
9 Requirements for sampling, sample preparation and analysis . 18
9.1 Requirements for sampling . 18
9.2 Requirements for sample preparation . 19
9.3 Requirements for analysis . 20
10 Representative sample . 22
11 Sampling . 22
11.1 General. 22
11.2 Safety precaution . 23
11.3 Sampling of large mineral aggregates . 23
11.4 Sampling of construction products of mineral aggregates of fine grain size . 24
11.5 Sampling of construction products of monolithic natural stones . 24
11.6 Sample taking . 24
11.7 Sample protocol . 24
11.8 Storage and transport . 25
12 Sample preparation . 25
12.1 General. 25
12.2 Sample preparation of construction products of fine grain size material . 25
12.3 Sample preparation of large mineral aggregates . 29
12.4 Sample preparation of construction products of natural stones . 31
13 Identification of asbestos . 31
13.1 General. 31
13.2 Reference materials . 31
13.3 Identification of asbestos by polarized light microscopy . 32
13.4 Identification of asbestos by scanning electron microscopy and EDXA. 33
13.5 Identification of asbestos by transmission electron microscopy . 35
14 Quantitative determination of asbestos mass fraction . 36
kSIST-TS FprCEN/TS 18020:2023
FprCEN/TS 18020:2023 (E)
14.1 Quantitative determination of asbestos mass fraction from pulverised test sample on
a filter preparation . 36
14.2 Determination of asbestos mass fraction of sieve fraction from mineral aggregates
................................................................................................................................................................... 38
15 The comparability of the analytical methods . 39
16 Test report . 41
Annex A (informative) Types of commercial asbestos-containing material and optimum
analytical procedures . 43
Annex B (informative) Energy dispersive X-ray spectrum obtained from UICC reference
standard . 50
Annex C (informative) Criteria for interpretation of EDXA spectra . 54
Annex D (informative) Range of variation in the composition of asbestos . 55
Annex E (informative) Example of report on determination of asbestos mass fraction from
fibre measurement. 56
Annex F (informative) Example of report on determination of asbestos mass fraction in
samples from aggregates and recycled aggregates . 57
Annex G (informative) Report on determination of the limit of detection according to
VDI 3866-5 . 59
Bibliography . 62

kSIST-TS FprCEN/TS 18020:2023
FprCEN/TS 18020:2023 (E)
European foreword
This document (FprCEN/TS 18020:2023) has been prepared by Technical Committee CEN/TC 351
“Construction products: Assessment of release of dangerous substances”, the secretariat of which is held
by NEN.
This document is currently submitted to the Vote on TS.
This document has been prepared under a Standardization Request given to CEN by the European
Commission and the European Free Trade Association.
kSIST-TS FprCEN/TS 18020:2023
FprCEN/TS 18020:2023 (E)
Introduction
Under regulation (EC) No 1272/2008 (the CLP regulation) of the European Union, asbestos is classified
as a carcinogen of group 1A [EC 1272/2008]. The REACH Regulation (EC) No. 1907/2006 prohibits the
placing on the market and use of asbestos fibres and of articles containing these fibres added intentionally
[EC 1907/2006]. Asbestos was banned in the 1990s at the international level in several European
countries and, since 2005, it has been completely banned within the European Union. Asbestos was used
in very large quantities for decades and was incorporated into many construction products which were
used in the construction of buildings and structures, as well as in industrial applications. Depending on
the country, buildings and structures constructed before 2005 may contain a variety of asbestos-
containing materials that still may pose a risk to building occupants and persons involved in construction
and demolition work [1999/77/EC].
Asbestos is a generic term encompassing six hydrated silicates with fibrous morphology comprising
chrysotile, amosite, crocidolite, anthophyllite, tremolite and actinolite, which are regulated by the
European Union through the REACH Regulation [EC 1907/2006]. Chrysotile, amosite, crocidolite or
anthophyllite were the asbestos types which were intentionally added in the past to construction
products. Chrysotile accounted for approximately 95 % of commercial asbestos consumption, and
amosite and crocidolite accounted for almost all of the remaining asbestos use. Tremolite asbestos and
actinolite asbestos were not extensively used commercially, however can appear as natural contaminants
in construction products (see ISO 22262-1).
Although the EU has now prohibited all asbestos use, there are several situations, however, which require
special attention to avoid “new construction products” which may contain asbestos being distributed in
the EU market. Several non-EU countries (primarily the Russian Federation, Kazakhstan, and China) still
mine and export asbestos and asbestos-containing products. Consequently, asbestos-containing products
manufactured in those countries and other countries where the importation of asbestos has not been
prohibited may enter the European market illegally. Naturally occurring asbestos (NOAs), which are not
technically enriched and processed, may be present as impurities in mineral raw materials, which are
used to manufacture new construction products. Even though European countries implement strict
quality control systems to prevent materials containing asbestos from re-entering new construction
products in the course of waste recycling [Cinderela, 2021], asbestos contamination may be found in
some cases. If a comprehensive asbestos survey and the consequent removal of all asbestos is not
conducted prior to demolition of a building or structure from the critical construction period (depending
on the country up to 2005), asbestos-containing materials (ACMs) may be present in the resulting
construction and dem
...

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