EN 15527:2008
(Main)Characterization of waste - Determination of polycyclic aromatic hydrocarbons (PAH) in waste using gas chromatography mass spectrometry (GC/MS)
Characterization of waste - Determination of polycyclic aromatic hydrocarbons (PAH) in waste using gas chromatography mass spectrometry (GC/MS)
This European Standard specifies the quantitative determination of 16 polynuclear aromatic hydrocarbons (PAH) according to the priority list of the Environmental Protection Agency (EPA, 1982). This European Standard is applicable for wastes such as contaminated soil, sludge and rubble, bitumen or waste containing bitumen.
This European Standard describes a gas chromatographic method with mass spectrometric detection (GC-MS). Under the conditions specified in this document, a typical lower limit of application of 0,1 mg/kg for each individual PAH can be achieved.
NOTE 1 This method may be applied to the analysis of other PAH compounds not specified in the scope provided its applicability has been proven by proper in-house validation experiments.
NOTE 2 For some materials, e. g. bitumen, the lower limit of application of 0,1 mg/kg cannot be achieved due to interferences.
NOTE 3 Under certain circumstances the method may be applicable to PAH concentrations lower than 0,1 mg/kg but it is in the responsibility of the laboratory to provide proper validation data for such low concentrations.
Charakterisierung von Abfällen - Bestimmung von polycyclischen aromatischen Kohlenwasserstoffen (PAK) in Abfall mittels Gaschromatographie-Massenspektrometrie (GC/MS)
Diese Europäische Norm legt die quantitative Bestimmung von 16 polycyclischen aromatischen Kohlenwasserstoffen
(PAK) entsprechend der Prioritätenliste der Environmental Protection Agency (EPA, US-Umweltschutzbehörde,
1982) fest. Diese Europäische Norm gilt für Abfälle wie z. B. kontaminierten Boden,
Schlamm und (Bau)Schutt, Bitumen oder bitumenhaltigen Abfall.
Diese Europäische Norm beschreibt ein gaschromatographisches Verfahren mit massenspektrometrischer
Detektion (GC-MS). Unter den in diesem Dokument festgelegten Bedingungen kann für jeden einzelnen PAK
eine typische untere Anwendungsgrenze von 0,1 mg/kg erzielt werden.
ANMERKUNG 1 Dieses Verfahren darf auf die Analyse weiterer, nicht im Anwendungsbereich festgelegter PAK-Verbindungen
angewendet werden, vorausgesetzt seine Anwendbarkeit wurde in den entsprechenden laborinternen Validierungsversuchen
nachgewiesen.
ANMERKUNG 2 Bei einigen Materialien, wie z. B. Bitumen, kann aufgrund von Interferenzen die untere Anwendungsgrenze
von 0,1 mg/kg nicht erreicht werden.
ANMERKUNG 3 Unter bestimmten Umständen kann das Verfahren auf PAK-Konzentrationen unter 0,1 mg/kg anwendbar
sein; es liegt jedoch in der Verantwortung des Laboratoriums, die entsprechenden Validierungsdaten für derartig
niedrige Konzentrationen zu liefern.
Caractérisation des déchets - Dosage des hydrocarbures aromatiques polycycliques (HAP) dans les déchets par chromatographie en phase gazeuse/spectrométrie de masse (CG/SM)
La présente Norme européenne spécifie le dosage quantitatif de 16 hydrocarbures aromatiques polynucléaires (HAP) selon la liste de polluants prioritaires établie par l’Agence de protection de l’environnement (États-Unis) [Environmental Protection Agency (EPA), 1982]. La présente norme européenne est applicable aux déchets tels que sol contaminé, boues et gravats, bitume ou déchets bitumineux.
La présente norme européenne décrit une méthode par chromatographie en phase gazeuse couplée à une détection par spectrométrie de masse (CG-SM). Dans les conditions spécifiées dans le présent document, une limite inférieure d’application type de 0,1 mg/kg pour chacun des HAP peut être atteinte.
NOTE 1 La présente méthode peut être appliquée à l’analyse d’autres composés HAP non spécifiés dans le domaine d’application, à condition que son applicabilité ait pu être prouvée par des expériences de validation interne.
NOTE 2 Pour certains matériaux, par exemple le bitume, la limite inférieure d’application de 0,1 mg/kg ne peut être atteinte en raison d’interférences.
NOTE 3 Dans certaines circonstances, la méthode peut être applicable à des concentrations en HAP inférieures à 0,1 mg/kg, mais il est de la responsabilité du laboratoire de fournir des données de validation correctes pour ces faibles concentrations.
Karakterizacija odpadkov - Določevanje policikličnih aromatskih ogljikovodikov (PAH) v odpadkih z uporabo plinske kromatografije z masno spektrometrijo (GC-MS)
General Information
Relations
Standards Content (Sample)
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.JOMLNRYRGLNRY06Charakterisierung von Abfällen - Bestimmung von polycyclischen aromatischen Kohlenwasserstoffen (PAK) in Abfall mittels Gaschromatographie-Massenspektrometrie (GC/MS)Caractérisation des déchets - Dosage des hydrocarbures aromatiques polycycliques (HAP) dans les déchets par chromatographie en phase gazeuse/spectrométrie de masse (CG/SM)Characterization of waste - Determination of polycyclic aromatic hydrocarbons (PAH) in waste using gas chromatography mass spectrometry (GC/MS)71.040.50Fizikalnokemijske analitske metodePhysicochemical methods of analysis13.030.01Odpadki na splošnoWastes in generalICS:Ta slovenski standard je istoveten z:EN 15527:2008SIST EN 15527:2009en,fr,de01-junij-2009SIST EN 15527:2009SLOVENSKI
STANDARD
EUROPEAN STANDARDNORME EUROPÉENNEEUROPÄISCHE NORMEN 15527July 2008ICS 13.030.01; 71.040.50 English VersionCharacterization of waste - Determination of polycyclic aromatichydrocarbons (PAH) in waste using gas chromatography massspectrometry (GC/MS)Caractérisation des déchets - Dosage des hydrocarburesaromatiques polycycliques (HAP) dans les déchets parchromatographie en phase gazeuse/spectrométrie demasse (CG/SM)Charakterisierung von Abfällen - Bestimmung vonpolycyclischen aromatischen Kohlenwasserstoffen (PAK) inAbfall mittels Gaschromatographie-Massenspektrometrie(GC/MS)This European Standard was approved by CEN on 29 May 2008.CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this EuropeanStandard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such nationalstandards may be obtained on application to the CEN Management Centre or to any CEN member.This European Standard exists in three official versions (English, French, German). A version in any other language made by translationunder the responsibility of a CEN member into its own language and notified to the CEN Management Centre has the same status as theofficial versions.CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Cyprus, Czech Republic, Denmark, Estonia, Finland,France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal,Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom.EUROPEAN COMMITTEE FOR STANDARDIZATIONCOMITÉ EUROPÉEN DE NORMALISATIONEUROPÄISCHES KOMITEE FÜR NORMUNGManagement Centre: rue de Stassart, 36
B-1050 Brussels© 2008 CENAll rights of exploitation in any form and by any means reservedworldwide for CEN national Members.Ref. No. EN 15527:2008: ESIST EN 15527:2009
Representative chromatograms.23 Annex B (informative)
Additional validation data.32 Annex C (informative)
Summary of general requirements and recommendations.36 Bibliography.37
Introduction Polynuclear aromatic hydrocarbons (PAH) are ubiquitous because of the fact that they are released in appreciable quantities every year into the environment through the combustion of organic materials such as coal, fuel oils, petrol, wood, refuse and plant materials. Since some of these PAH compounds are carcinogenic or mutagenic, their presence in the environment (air, water, soil, sediment and waste) are regularly monitored and controlled. At present, the determination of PAH is carried out in these matrices in most of the routine laboratories following the preceding steps for sampling, pre-treatment, extraction, clean-up by measurement of specific PAH by means of gas chromatography in combination with mass spectrometric detection(GC-MS) or by HPLC in combination with UV-DAD- or Fluorescence-detection (HPLC-UV-DAD/FLD). However, the different matrices covered in this standard may contain a lot of contaminants. For this reason, the GC-MS method seems to be most appropriate for waste analysis. SIST EN 15527:2009
1 Scope This European Standard specifies the quantitative determination of 16 polynuclear aromatic hydrocarbons (PAH) according to the priority list of the Environmental Protection Agency (EPA, 1982). This European Standard is applicable for wastes such as contaminated soil, sludge and rubble, bitumen or waste containing bitumen. This European Standard describes a gas chromatographic method with mass spectrometric detection (GC-MS). Under the conditions specified in this document, a typical lower limit of application of 0,1 mg/kg for each individual PAH can be achieved.
NOTE 1 This method may be applied to the analysis of other PAH compounds not specified in the scope provided its applicability has been proven by proper in-house validation experiments. NOTE 2 For some materials, e. g. bitumen, the lower limit of application of 0,1 mg/kg cannot be achieved due to interferences. NOTE 3 Under certain circumstances the method may be applicable to PAH concentrations lower than 0,1 mg/kg but it is in the responsibility of the laboratory to provide proper validation data for such low concentrations. 2 Normative references The following referenced documents are indispensable for the application of this document. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies. EN 14346, Characterization of waste — Calculation of dry matter by determination of dry residue or water content EN 15002, Characterization of waste — Preparation of test portions from the laboratory sample ISO 14507, Soil quality — Pretreatment of samples for determination of organic contaminants 3 Terms and definitions For the purposes of this document, the following terms and definitions apply. 3.1 analyte selected polynuclear aromatic hydrocarbons (PAH) with 2 to 6 condensed aromatic rings (see Table 1) 3.2 calibration standard solution of PAH prepared from a secondary standard and/or stock solutions of native PAH and deuterated PAH used to calibrate the response of the instrument 3.3 extraction standard deuterated PAH or native (unlabeled) PAH of medium volatility that are unlikely to be present in waste added to the sample before extraction and used for control of the extraction efficiency SIST EN 15527:2009
...
Questions, Comments and Discussion
Ask us and Technical Secretary will try to provide an answer. You can facilitate discussion about the standard in here.