Standard Test Method for Hydrocarbon Types in Liquid Petroleum Products by Fluorescent Indicator Adsorption

SIGNIFICANCE AND USE
5.1 The determination of the total volume % of saturates, olefins, and aromatics in petroleum fractions is important in characterizing the quality of petroleum fractions as gasoline blending components and as feeds to catalytic reforming processes. This information is also important in characterizing petroleum fractions and products from catalytic reforming and from thermal and catalytic cracking as blending components for motor and aviation fuels. This information is also important as a measure of the quality of fuels, such as specified in Specification D1655.
SCOPE
1.1 This test method covers the determination of hydrocarbon types over the concentration ranges from 5 to 99 volume % aromatics, 0.3 to 55 volume % olefins, and 1 to 95 volume % saturates in petroleum fractions that distill below 315°C. This test method may apply to concentrations outside these ranges, but the precision has not been determined. Samples containing dark-colored components that interfere in reading the chromatographic bands cannot be analyzed.
Note 1: For the determination of olefins below 0.3 volume %, other test methods are available, such as Test Method D2710.  
1.2 This test method is intended for use with full boiling range products. Cooperative data have established that the precision statement does not apply to narrow boiling petroleum fractions near the 315°C limit. Such samples are not eluted properly, and results are erratic.  
1.3 The applicability of this test method to products derived from fossil fuels other than petroleum, such as coal, shale, or tar sands, has not been determined, and the precision statement may or may not apply to such products.  
1.4 This test method has two precision statements depicted in tables. The first table is applicable to unleaded fuels that do not contain oxygenated blending components. It may or may not apply to automotive gasolines containing lead antiknock mixtures. The second table is applicable to oxygenate blended (for example, MTBE, ethanol) automotive spark ignition fuel samples with a concentration range of 13–40 volume percent aromatics, 4–33 volume percent olefins, and 45–68 volume percent saturates.  
1.5 The oxygenated blending components, methanol, ethanol, methyl-tert-butylether (MTBE),  tert-amylmethylether (TAME), and ethyl-tert-butylether (ETBE), do not interfere with the determination of hydrocarbon types at concentrations normally found in commercial blends. These oxygenated components are not detected since they elute with the alcohol desorbent. Other oxygenated compounds shall be individually verified. When samples containing oxygenated blending components are analyzed, correct the results to a total-sample basis.  
1.6 WARNING—Mercury has been designated by many regulatory agencies as a hazardous material that can cause central nervous system, kidney and liver damage. Mercury, or its vapor, may be hazardous to health and corrosive to materials. Caution should be taken when handling mercury and mercury containing products. See the applicable product Material Safety Data Sheet (MSDS) for details and EPA’s website—http://www.epa.gov/mercury/faq.htm—for additional information. Users should be aware that selling mercury and/or mercury containing products into your state or country may be prohibited by law.  
1.7 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.8 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. For specific warning statements, see Section 7, 8.1, and 10.5.

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Standards Content (Sample)

NOTICE: This standard has either been superseded and replaced by a new version or withdrawn.
Contact ASTM International (www.astm.org) for the latest information
Designation: D1319 − 14
StandardTest Method for
Hydrocarbon Types in Liquid Petroleum Products by
1
Fluorescent Indicator Adsorption
This standard is issued under the fixed designation D1319; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
This standard has been approved for use by agencies of the U.S. Department of Defense.
1. Scope* normally found in commercial blends. These oxygenated
components are not detected since they elute with the alcohol
1.1 This test method covers the determination of hydrocar-
desorbent. Other oxygenated compounds shall be individually
bontypesovertheconcentrationrangesfrom5to99volume %
verified. When samples containing oxygenated blending com-
aromatics, 0.3 to 55 volume % olefins, and 1 to 95 volume %
ponentsareanalyzed,correcttheresultstoatotal-samplebasis.
saturates in petroleum fractions that distill below 315°C. This
test method may apply to concentrations outside these ranges, 1.6 WARNING—Mercury has been designated by many
but the precision has not been determined. Samples containing regulatory agencies as a hazardous material that can cause
dark-colored components that interfere in reading the chro- central nervous system, kidney and liver damage. Mercury, or
matographic bands cannot be analyzed. its vapor, may be hazardous to health and corrosive to
materials.Cautionshouldbetakenwhenhandlingmercuryand
NOTE 1—For the determination of olefins below 0.3 volume %, other
mercury containing products. See the applicable product Ma-
test methods are available, such as Test Method D2710.
terial Safety Data Sheet (MSDS) for details and EPA’s
1.2 This test method is intended for use with full boiling
website—http://www.epa.gov/mercury/faq.htm—for addi-
range products. Cooperative data have established that the
tional information. Users should be aware that selling mercury
precisionstatementdoesnotapplytonarrowboilingpetroleum
and/or mercury containing products into your state or country
fractions near the 315°C limit. Such samples are not eluted
may be prohibited by law.
properly, and results are erratic.
1.7 The values stated in SI units are to be regarded as
1.3 The applicability of this test method to products derived
standard. No other units of measurement are included in this
from fossil fuels other than petroleum, such as coal, shale, or
standard.
tar sands, has not been determined, and the precision statement
1.8 This standard does not purport to address all of the
may or may not apply to such products.
safety concerns, if any, associated with its use. It is the
1.4 This test method has two precision statements depicted
responsibility of the user of this standard to establish appro-
in tables. The first table is applicable to unleaded fuels that do
priate safety and health practices and determine the applica-
not contain oxygenated blending components. It may or may
bility of regulatory limitations prior to use. For specific
not apply to automotive gasolines containing lead antiknock
warning statements, see Section 7, 8.1, and 10.5.
mixtures. The second table is applicable to oxygenate blended
(for example, MTBE, ethanol) automotive spark ignition fuel
2. Referenced Documents
samples with a concentration range of 13–40 volume percent
2
2.1 ASTM Standards:
aromatics, 4–33 volume percent olefins, and 45–68 volume
D86 Test Method for Distillation of Petroleum Products at
percent saturates.
Atmospheric Pressure
1.5 The oxygenated blending components, methanol,
D1655 Specification for Aviation Turbine Fuels
ethanol, methyl-tert-butylether (MTBE), tert-amylmethylether
D2710 Test Method for Bromine Index of Petroleum Hydro-
(TAME), and ethyl-tert-butylether (ETBE), do not interfere
carbons by Electrometric Titration
with the determination of hydrocarbon types at concentrations
D3663 Test Method for Surface Area of Catalysts and
Catalyst Carriers
1
This test method is under the jurisdiction of ASTM Committee D02 on
Petroleum Products, Liquid Fuels, and Lubricants and is the direct responsibility of
2
Subcommittee D02.04.0C on Liquid Chromatography. For referenced ASTM standards, visit the ASTM website, www.astm.org, or
Current edition approved Oct. 1, 2014. Published October 2014. Originally contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM
approved in 1954. Last previous edition approved in 2013 as D1319 – 13. DOI: Standards volume information, refer to the standard’s Document Summary page on
10.1520/D1319-14. the ASTM website.
*A Summary of Changes section appears at the end of this standard
Copyright © ASTM International, 100 Barr Harbor Drive, PO Bo
...

This document is not an ASTM standard and is intended only to provide the user of an ASTM standard an indication of what changes have been made to the previous version. Because
it may not be technically possible to adequately depict all changes accurately, ASTM recommends that users consult prior editions as appropriate. In all cases only the current version
of the standard as published by ASTM is to be considered the official document.
Designation: D1319 − 13 D1319 − 14
Standard Test Method for
Hydrocarbon Types in Liquid Petroleum Products by
1
Fluorescent Indicator Adsorption
This standard is issued under the fixed designation D1319; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
This standard has been approved for use by agencies of the U.S. Department of Defense.
1. Scope*
1.1 This test method covers the determination of hydrocarbon types over the concentration ranges from 5 to 99 volume %
aromatics, 0.3 to 55 volume % olefins, and 1 to 95 volume % saturates in petroleum fractions that distill below 315°C. This test
method may apply to concentrations outside these ranges, but the precision has not been determined. Samples containing
dark-colored components that interfere in reading the chromatographic bands cannot be analyzed.
NOTE 1—For the determination of olefins below 0.3 volume %, other test methods are available, such as Test Method D2710.
1.2 This test method is intended for use with full boiling range products. Cooperative data have established that the precision
statement does not apply to narrow boiling petroleum fractions near the 315°C limit. Such samples are not eluted properly, and
results are erratic.
1.3 The applicability of this test method to products derived from fossil fuels other than petroleum, such as coal, shale, or tar
sands, has not been determined, and the precision statement may or may not apply to such products.
1.4 This test method has two precision statements depicted in tables. The first table is applicable to unleaded fuels that do not
contain oxygenated blending components. It may or may not apply to automotive gasolines containing lead antiknock mixtures.
The second table is applicable to oxygenate blended (for example, MTBE, ethanol) automotive spark ignition fuel samples with
a concentration range of 13–40 volume percent aromatics, 4–33 volume percent olefins, and 45–68 volume percent saturates.
1.5 The oxygenated blending components, methanol, ethanol, methyl-tert-butylether (MTBE), tert-amylmethylether (TAME),
and ethyl-tert-butylether (ETBE), do not interfere with the determination of hydrocarbon types at concentrations normally found
in commercial blends. These oxygenated components are not detected since they elute with the alcohol desorbent. Other
oxygenated compounds shall be individually verified. When samples containing oxygenated blending components are analyzed,
correct the results to a total-sample basis.
1.6 WARNING—Mercury has been designated by many regulatory agencies as a hazardous material that can cause central
nervous system, kidney and liver damage. Mercury, or its vapor, may be hazardous to health and corrosive to materials. Caution
should be taken when handling mercury and mercury containing products. See the applicable product Material Safety Data Sheet
(MSDS) for details and EPA’s website—http://www.epa.gov/mercury/faq.htm—for additional information. Users should be aware
that selling mercury and/or mercury containing products into your state or country may be prohibited by law.
1.7 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.8 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility
of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory
limitations prior to use. For specific warning statements, see Section 7, 8.1, and 10.5.
1
This test method is under the jurisdiction of ASTM Committee D02 on Petroleum Products, Liquid Fuels, and Lubricants and is the direct responsibility of Subcommittee
D02.04.0C on Liquid Chromatography.
In the IP, this test method is under the jurisdiction of the Standardization Committee. This test method has been approved by the sponsoring committees and accepted by
the cooperating societies in accordance with established procedures.
Current edition approved May 1, 2013Oct. 1, 2014. Published June 2013October 2014. Originally approved in 1954. Last previous edition approved in 20102013 as
D1319 – 10.D1319 – 13. DOI: 10.1520/D1319-13.10.1520/D1319-14.
*A Summary of Changes section appears at the end of this standard
Copyright © ASTM International, 100 B
...

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