Corrosion protection of metals - Non-electrolytically applied zinc flake coatings on iron or steel components

This European Standard specifies requirements for non-electrolytically applied coatings, composed mainly of zinc flakes, for protection against corrosion of steel components, excluding threaded fasteners. These coatings may also be provided with integral lubricant if needed.
NOTE 1  Requirements for threaded fasteners are given in EN ISO 10683.
The temperature and duration of curing the coating can influence the mechanical properties of components because of their change of metallurgical conditions. These coatings should not be applied to components that can be used at temperatures higher than the curing temperature, unless specifically ordered.
NOTE 2   If aluminium flakes, when added to zinc flake dispersion, form a continuous bond, a high risk of hydrogen embrittlement for steels of tensile strength over 1 800 MPa may exist because of the sacrificial action of the coating during corrosion reactions in storage and/or in service.

Korrosionsschutz von Metallen - Nicht elektrolytisch aufgebrachte schuppenförmige Zinküberzüge auf Werkstücken aus Eisen oder Stahl

Protection des métaux contre la corrosion - Revetements non électrolytiques de lamelles de zinc sur des composants en fer ou en acier

La présente Norme européenne spécifie les exigences relatives aux revêtements non électrolytiques composés principalement de lamelles de zinc, destinés à la protection des composants en acier contre la corrosion, à l’exclusion des éléments de fixation filetés. Ces revêtements peuvent également être fournis avec un lubrifiant intégré si nécessaire.
NOTE 1   Les exigences relatives aux éléments de fixation filetés sont spécifiées dans l’EN ISO 10683.
La température et la durée de cuisson du revêtement peuvent avoir une incidence sur les propriétés mécaniques des composants en raison du changement d’état métallurgique de ceux-ci. Sauf spécification contraire, il convient que ces revêtements ne soient pas appliqués sur des composants pouvant être utilisés à des températures plus élevées que la température de cuisson.
NOTE 2   Si les lamelles d’aluminium, lorsqu’elles sont ajoutées à la dispersion des lamelles de zinc, forment une liaison continue, il peut y avoir un risque important de fragilisation par l’hydrogène des aciers dont la résistance à la traction est supérieure à 1 800 MPa, en raison de l’action sacrificielle du revêtement pendant le processus de corrosion au stockage et/ou en service.

Antikorozijska zaščita kovin - S cinkovo lamelno prevleko, ki ni izdelana z elektrolizo, na železnih ali jeklenih komponentah

General Information

Status
Published
Publication Date
31-Jan-2007
Current Stage
6060 - National Implementation/Publication (Adopted Project)
Start Date
01-Feb-2007
Due Date
01-Feb-2007
Completion Date
01-Feb-2007

Relations

Effective Date
22-Dec-2008

Overview

EN 13858:2006 - "Corrosion protection of metals - Non‑electrolytically applied zinc flake coatings on iron or steel components" is a CEN European Standard that specifies requirements for cold‑applied zinc‑flake coating systems used to protect steel parts from corrosion. The standard covers coating types applied by immersion or pneumatic/electrostatic spray, optional integral lubricants and supplementary treatments (sealants, paints, colours), and requirements for appearance, thickness, adhesion and accelerated corrosion testing. Threaded fasteners are excluded (see EN ISO 10683).

Key topics and technical requirements

  • Scope and designation
    • Applies to non‑electrolytically applied zinc flake coatings on iron/steel (designation format e.g. EN 13858 – Fe/iflZn4/yc).
    • Coating sequences and thickness (µm) are part of the designation.
  • Coating types & processes
    • Immersion (cold) and pneumatic/electrostatic gun spraying.
    • Coatings may contain zinc flakes, optionally aluminium flakes, chromates, and/or lubricants; supplementary layers (paints, sealants, oils) are allowed.
  • Surface preparation & heat treatment
    • Surfaces must be clean, dry and free of defects. For high‑strength steels (Rm ≥ 1 000 MPa) mechanical cleaning is preferred to reduce hydrogen embrittlement risk.
    • Stress relief heat treatment is required for parts with tensile stresses (see purchaser requirements).
  • Curing
    • Curing influences coating properties and base‑metal metallurgy; curing temperatures are typically above 180 °C with curing times about 15–60 min. Coated components must not be used above the curing temperature unless specifically ordered.
  • Hydrogen embrittlement
    • If aluminium flakes form a continuous bond, there is a high hydrogen embrittlement risk for steels > 1 800 MPa.
  • Acceptance tests & measurement
    • Appearance per EN ISO 16348; thickness measured by EN ISO 1463 / EN ISO 2064 / EN ISO 2178 / EN ISO 3882 methods.
    • Adhesion tests referenced to EN ISO 2819 or Annex B of EN 13858.
    • Accelerated corrosion (neutral salt spray) per EN ISO 9227 with specified durations by minimum thickness and chromate presence; mass→thickness conversion factors given (chromate: 4.5 g/m² = 1 µm; non‑chromate: 3.8 g/m² = 1 µm).
  • Sampling & inspection
    • Sampling in accordance with ISO 2859 and ISO 4519.

Practical applications

  • Corrosion protection for stamped, machined or formed steel components in automotive, industrial, electronic and fastening sub‑assemblies (excluding threaded fasteners unless otherwise specified).
  • Used where galvanic (sacrificial) protection and barrier properties are required together with controlled friction or lubrication.
  • Appropriate for complex geometries (immersion process provides full coverage).

Who uses this standard

  • Coating processors, system suppliers and applicators
  • Design and procurement engineers
  • Quality and corrosion engineers
  • OEMs (automotive, industrial equipment) specifying corrosion protection systems

Related standards

  • EN ISO 10683 - threaded fasteners
  • EN ISO 9227 - neutral salt spray test
  • EN ISO 2064, EN ISO 16348, EN ISO 2819, EN ISO 1463, EN ISO 2178, EN ISO 3882, ISO 2859, ISO 4519

This summary helps engineers and procurement teams quickly assess EN 13858:2006 requirements for implementing non‑electrolytically applied zinc flake coatings as a corrosion protection solution.

Frequently Asked Questions

SIST EN 13858:2007 is a standard published by the Slovenian Institute for Standardization (SIST). Its full title is "Corrosion protection of metals - Non-electrolytically applied zinc flake coatings on iron or steel components". This standard covers: This European Standard specifies requirements for non-electrolytically applied coatings, composed mainly of zinc flakes, for protection against corrosion of steel components, excluding threaded fasteners. These coatings may also be provided with integral lubricant if needed. NOTE 1 Requirements for threaded fasteners are given in EN ISO 10683. The temperature and duration of curing the coating can influence the mechanical properties of components because of their change of metallurgical conditions. These coatings should not be applied to components that can be used at temperatures higher than the curing temperature, unless specifically ordered. NOTE 2 If aluminium flakes, when added to zinc flake dispersion, form a continuous bond, a high risk of hydrogen embrittlement for steels of tensile strength over 1 800 MPa may exist because of the sacrificial action of the coating during corrosion reactions in storage and/or in service.

This European Standard specifies requirements for non-electrolytically applied coatings, composed mainly of zinc flakes, for protection against corrosion of steel components, excluding threaded fasteners. These coatings may also be provided with integral lubricant if needed. NOTE 1 Requirements for threaded fasteners are given in EN ISO 10683. The temperature and duration of curing the coating can influence the mechanical properties of components because of their change of metallurgical conditions. These coatings should not be applied to components that can be used at temperatures higher than the curing temperature, unless specifically ordered. NOTE 2 If aluminium flakes, when added to zinc flake dispersion, form a continuous bond, a high risk of hydrogen embrittlement for steels of tensile strength over 1 800 MPa may exist because of the sacrificial action of the coating during corrosion reactions in storage and/or in service.

SIST EN 13858:2007 is classified under the following ICS (International Classification for Standards) categories: 25.220.40 - Metallic coatings. The ICS classification helps identify the subject area and facilitates finding related standards.

SIST EN 13858:2007 has the following relationships with other standards: It is inter standard links to SIST EN 13858:2004. Understanding these relationships helps ensure you are using the most current and applicable version of the standard.

SIST EN 13858:2007 is available in PDF format for immediate download after purchase. The document can be added to your cart and obtained through the secure checkout process. Digital delivery ensures instant access to the complete standard document.

Standards Content (Sample)


2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.Corrosion protection of metals - Non-electrolytically applied zinc flake coatings on iron or steel componentsProtection des métaux contre la corrosion - Revetements non électrolytiques de lamelles de zinc sur des composants en fer ou en acierKorrosionsschutz von Metallen - Nicht elektrolytisch aufgebrachte schuppenförmige Zinküberzüge auf Werkstücken aus Eisen oder StahlTa slovenski standard je istoveten z:EN 13858:2006SIST EN 13858:2007en25.220.40Kovinske prevlekeMetallic coatingsICS:SIST EN 13858:20041DGRPHãþDSLOVENSKI
STANDARDSIST EN 13858:200701-februar-2007

EUROPEAN STANDARDNORME EUROPÉENNEEUROPÄISCHE NORMEN 13858November 2006ICS 25.220.40Supersedes EN 13858:2003
English VersionCorrosion protection of metals - Non-electrolytically applied zincflake coatings on iron or steel componentsProtection des métaux contre la corrosion - Revêtementsnon électrolytiques de lamelles de zinc sur des composantsen fer ou en acierKorrosionsschutz von Metallen - Nicht elektrolytischaufgebrachte schuppenförmige Zinküberzüge aufWerkstücken aus Eisen oder StahlThis European Standard was approved by CEN on 6 October 2006.CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this EuropeanStandard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such nationalstandards may be obtained on application to the Central Secretariat or to any CEN member.This European Standard exists in three official versions (English, French, German). A version in any other language made by translationunder the responsibility of a CEN member into its own language and notified to the Central Secretariat has the same status as the officialversions.CEN members are the national standards bodies of Austria, Belgium, Cyprus, Czech Republic, Denmark, Estonia, Finland, France,Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania,Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom.EUROPEAN COMMITTEE FOR STANDARDIZATIONCOMITÉ EUROPÉEN DE NORMALISATIONEUROPÄISCHES KOMITEE FÜR NORMUNGManagement Centre: rue de Stassart, 36
B-1050 Brussels© 2006 CENAll rights of exploitation in any form and by any means reservedworldwide for CEN national Members.Ref. No. EN 13858:2006: E

Additional information concerning coatings.10 Annex B (normative)
Adhesion test methods.11 Annex C (normative)
Sampling.12 Bibliography.13

Mechanical cleaning methods of the metal surfaces are preferred for steels parts having a tensile strength of 1 000 MPa and greater (Rm ≥ 1 000 MPa) to avoid the risk of hydrogen embrittlement.
If acid chemical cleaning methods are used, stress relief heat treatment is required for high strength steels (Rm ≥ 1 000 MPa) if they contain tensile stresses (see Clause 6.1.2). Zinc protects steel by galvanic action, i.e. sacrificial action takes place to protect steel when it is in close contact with the steel, and after weathering, zinc oxides are formed on the coating surface. These oxides are voluminous and plug the pores in the coating to provide barrier protection. Apart from cathodic corrosion protection, the zinc flakes also provide barrier properties due to the platelet structures. Artificial atmosphere corrosion tests of these coatings can provide some measure of guidance for corrosion protection. However, the duration and results of accelerated corrosion tests, such as the neutral salt spray test, have no direct relation to the corrosion protection in other environments. WARNING —This European Standard calls for the use of substances and/or procedures that may be injurious to health if adequate safety measures are not taken. This European Standard does not address any health hazards, safety matters or environmental conditions associated with its use. It is the responsibility of the user of this European Standard to establish appropriate health and safety practices and take suitable actions for any national and International regulations.

1 Scope This European Standard specifies requirements for non-electrolytically applied coatings, composed mainly of zinc flakes, for protection against corrosion of steel components, excluding threaded fasteners. These coatings may also be provided with integral lubricant if needed. NOTE 1
Requirements for threaded fasteners are given in EN ISO 10683. The temperature and duration of curing the coating can influence the mechanical properties of components because of their change of metallurgical conditions. These coatings should not be applied to components that can be used at temperatures higher than the curing temperature, unless specifically ordered. NOTE 2 If aluminium flakes, when added to zinc flake dispersion, form a continuous bond, a high risk of hydrogen embrittlement for steels of tensile strength over 1 800 MPa may exist because of the sacrificial action of the coating during corrosion reactions in storage and/or in service.
2 Normative references The following referenced documents are indispensable for the application of this document. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies. EN 60454-2, Specifications for pressure-sensitive adhesive tapes for electrical purposes — Part 2: Methods of test (IEC 60454-2:1994) EN ISO 2064:2000, Metallic and other inorganic coatings — Definitions and conventions concerning the measurement of thickness (ISO
2064:1996) EN ISO 9227, Corrosion tests in artificial atmospheres — Salt spray tests (ISO 9227:2006) EN ISO 16348:2003, Metallic and other inorganic coatings — Definitions and conventions concerning appearance (ISO
16348:2003) ISO 2859 (all parts), Sampling procedures and tables for inspection by attributes ISO 4519, Electrodeposited metallic coatings and related finishes — Sampling procedures for inspection by attributes 3 Terms and definitions For the purposes of this European Standard, the terms and definitions given in EN ISO 2064:2000 and EN ISO 16348:2003 apply.

c) specification and metallurgical condition of the component (heat treatment, hardness and/or other characteristics), which may be influenced by the coating process, and any process temperature limitation; d) significant surface and the requirement of coating thickness on the significant surface, including the coating of holes, recesses and presence of rack marks;
NOTE Requirements for coating thickness on the non-significant surface and the presence of uncoated areas can also be specified (see 6.2.1); e) requirement of dimensional tolerances including any excesses of coatings in complicated shapes of components;
these areas shall be agreed between supplier and purchaser; f) tensile strength of the component and requirement of stress relief heat treatment; g) requirements of the type of coating processes (see Annex A), type of coating (with aluminium flakes or without aluminium flakes, see 6.1.3), coating thickness (see Table 1) and coating adhesion (see
6.2.3); h) requirement of supplementary coating, e.g. sealants, lubricants, colours, etc. (see 6.2.4); i) requirement of accelerated corrosion test (see clause 6.3); j) requirement of any additional tests or performance tests for lubricated coatings whether using integral coating lubricants, or lubricants applied after coatings; k) sampling and inspection requirements (see clause 7).
5 Designations 5.1 General The designation shall consist of the following: a) term “non-electrolytically applied”; b) number of this European Standard, EN 13858; c) hyphen (-); d) chemical symbol of the basis metal; e) stroke (/); f) symbols for the zinc flake coating and the method of application (see 5.4.1), as well as any coatings that may be applied prior to or after deposition, separated by strokes for each stage in the coating sequence in the order of application. The coating designation includes the thickness of the coating in micrometers (µm).
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