SIST EN 16516:2018

SLOVENSKI STANDARD
oSIST prEN 16516:2015
01-junij-2015
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Construction products: Assessment of release of dangerous substances - Determination
of emissions into indoor air
Bauprodukte - Bewertung der Freisetzung von gefährlichen Stoffen - Bestimmung von
Emissionen in die Innenraumluft
Produits de construction: Evaluation de l'émission de substances dangereuses -
Détermination des émissions dans l'air intérieur
Ta slovenski standard je istoveten z: prEN 16516
ICS:
13.040.20 Kakovost okoljskega zraka Ambient atmospheres
91.100.01 Gradbeni materiali na Construction materials in
splošno general
oSIST prEN 16516:2015 en,fr,de
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.

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oSIST prEN 16516:2015

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oSIST prEN 16516:2015

EUROPEAN STANDARD
DRAFT
prEN 16516
NORME EUROPÉENNE

EUROPÄISCHE NORM

May 2015
ICS 13.040.20; 91.100.01 Will supersede CEN/TS 16516:2013
English Version
Construction products: Assessment of release of dangerous
substances - Determination of emissions into indoor air
Produits de construction: Evaluation de l'émission de
substances dangereuses - Détermination des émissions
dans l'air intérieur
This draft European Standard is submitted to CEN members for enquiry. It has been drawn up by the Technical Committee CEN/TC 351.

If this draft becomes a European Standard, CEN members are bound to comply with the CEN/CENELEC Internal Regulations which
stipulate the conditions for giving this European Standard the status of a national standard without any alteration.

This draft European Standard was established by CEN in three official versions (English, French, German). A version in any other language
made by translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management
Centre has the same status as the official versions.

CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,
Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania,
Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and United
Kingdom.

Recipients of this draft are invited to submit, with their comments, notification of any relevant patent rights of which they are aware and to
provide supporting documentation.

Warning : This document is not a European Standard. It is distributed for review and comments. It is subject to change without notice and
shall not be referred to as a European Standard.


EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION

EUROPÄISCHES KOMITEE FÜR NORMUNG

CEN-CENELEC Management Centre: Avenue Marnix 17, B-1000 Brussels
© 2015 CEN All rights of exploitation in any form and by any means reserved Ref. No. prEN 16516:2015 E
worldwide for CEN national Members.

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Contents Page
Foreword .5
Introduction .6
1 Scope .8
2 Normative references .8
3 Terms, definitions and abbreviations .8
3.1 Terms relating to sampling and products .9
3.2 Terms relating to emissions into indoor air and associated laboratory testing . 10
3.3 Terms relating to determination of emitted substances. 13
3.4 Abbreviations . 14
4 Intended conditions of use, emission scenarios and European reference room . 14
4.1 Intended conditions of use and emission scenario . 14
4.2 Reference room and emission scenario . 15
4.2.1 General . 15
4.2.2 Dimensions and loading factors in the reference room . 15
4.2.3 Ventilation in the reference room . 15
4.2.4 Climate conditions in the reference room . 16
4.3 Time schedule of emission(s) determination . 16
5 Product sampling and transport to the laboratory . 16
5.1 General . 16
5.2 Objective of sampling . 16
5.3 Preparation of a sampling plan and sampling strategy . 16
5.3.1 General . 16
5.3.2 Sampling approach. 16
5.3.3 Population and sub-population . 17
5.3.4 Scale . 17
5.3.5 Size of samples, of increments when relevant, and sampling techniques . 17
5.3.6 Sampling location and moment . 18
5.4 Information from the testing laboratory needed to complement the product sampling plan . 18
5.5 Packaging and transport of laboratory sample . 18
5.6 Sample description, marking of laboratory samples and the sampling report . 19
5.7 Chain of custody report . 19
5.8 Dispatch of product samples, time schedule . 19
6 Handling of product samples in the laboratory . 20
6.1 Storage of sample in the testing laboratory . 20
6.2 Preparation of the test specimen . 20
7 Test chamber conditions . 21
7.1 Principles . 21
7.2 Dimensions of test specimen . 21
7.3 Loading factor . 21
7.4 Ventilation . 21
7.5 Air velocity . 22
7.6 Cleanliness of test chamber . 22
7.7 Testing climate (temperature, relative humidity of supply air) . 22
7.8 Storage of test specimen . 22
7.9 Large products or inhomogeneous products . 22
7.10 Volume of test chamber . 23
7.11 Placement of test specimen in test chamber . 23
8 Determination of vapour-phase organic compounds in test chamber air . 23
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8.1 Common requirements . 23
8.2 Determination of VOCs and SVOCs in test chamber air . 24
8.2.1 General . 24
8.2.2 Analytical system . 24
8.2.3 Tube conditioning and laboratory blank tubes . 27
8.2.4 Sampling test chamber air. 27
8.2.5 Identification, calibration and analysis . 28
8.2.6 Total volatile organic compounds (TVOC) and total semi-volatile organic compounds

(TSVOC) . 31
8.3 Determination of formaldehyde and some other volatile carbonyl compounds in test

chamber air . 32
8.3.1 General . 32
8.3.2 Analytical system . 32
8.3.3 Sampling test chamber air. 32
8.3.4 Blank tubes . 32
8.3.5 Identification, calibration and analysis . 32
8.4 Other general aspects of quality control . 33
8.4.1 Laboratory quality checks . 33
8.4.2 External references . 33
9 Calculation of specific emission rates and expression of results at the reference room . 33
10 Reporting for the horizontal reference method . 36
10.1 General . 36
10.2 Sampling. 36
10.3 Handling of samples in the laboratory, preparation of test specimen . 37
10.4 Test chamber conditions . 37
10.5 Determination of vapour-phase organic compounds in test chamber air . 37
10.6 Calculation and reporting of test results . 37
11 Indirect methods . 38
Annex A (informative) Repeatability and reproducibility . 39
A.1 Repeatability . 39
A.2 Reproducibility . 39
Annex B (informative) Examples of indirect methods (also called simplified, screening,

secondary, derived or alternative methods) . 41
B.1 General . 41
B.2 Indirect methods relative to testing devices for generating emissions . 41
B.2.1 Emission cell . 41
B.2.2 Micro-chamber . 41
B.2.3 Thermal extraction . 41
B.3 Indirect methods specifying alternative procedures . 42
B.3.1 Headspace and in-can VOC determination . 42
B.3.2 VOC content determination . 42
B.3.3 Formaldehyde specific methods . 42
B.4 Other secondary methods . 42
B.4.1 Prediction of results at specified time . 42
Annex C (informative) Information on very volatile organic compound (VVOC) testing . 43
Annex D (informative) Example of a form for the sampling report . 44
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Annex E (informative) Example form for a chain of custody report . 45
Annex F (informative) Benzene artefact generation on Tenax . 46
Annex G (normative) List of VOCs . 47
G.1 List of non-carcinogenic VOCs . 47
G.2 List of carcinogenic VOCs . 53
Bibliography . 56

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Foreword
This document (prEN 16516:2015) has been prepared by Technical Committee CEN/TC 351 “Construction
products - Assessment of release of dangerous substances”, the secretariat of which is held by NEN.
This document is currently submitted to the CEN Enquiry.
This document will supersede CEN/TS 16516:2013.
This document has been prepared under a mandate given to CEN by the European Commission and the
European Free Trade Association.
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Introduction
This European Standard was developed under the remit of Mandate M/366 “Development of horizontal
standardized assessment methods for harmonised approaches relating to dangerous substances under the
Construction Products Regulation (CPR)” addressing the preparation of horizontal measurement/test methods
for the determination of emission of regulated dangerous substances from construction products into indoor
air. This mandate is a complement to the product mandates granted by the European Commission to CEN
under the Construction Products Regulation. The harmonized products standards (hEN) developed in CEN
under mandates from the European Commission specify construction product(s) as put on the market and
address their intended conditions of use.
Details of relevant European or national regulations are available in the “TRIS database” [1].
This European Standard has gone through a robustness validation for identifying how small changes in
specific testing parameters can influence the test result. This study also delivered data on repeatability within
one testing laboratory (see Annex A) and has since been expanded to include reproducibility data from further
round robin tests between different laboratories (see Annex A).
The responsibility for product specification lies with the product TCs, as described in CEN/TR 16496. This
determination of emission into indoor air is to be carried out on products under their intended conditions of
use. The intended use of a construction product is generally specified in the corresponding harmonized
product standard. The specific emission rates determined using this European Standard are associated with
application of the product in a defined European Reference Room under specified climate (temperature and
humidity) and ventilation conditions. The reference room is needed since it is not possible to evaluate
emissions in all possible use scenarios.
The reference room dimensions, associated product loading factors, as well as climate and ventilation
conditions are selected to represent the general indoor environment (see Clause 4). Based on the huge
amount of available European experience, it was possible to identify one emission scenario and one reference
room and associated set of product loading factors to be used.
This European Standard specifies the horizontal reference method for testing the emission (release) of
dangerous substances from construction products into indoor air. This method uses a test chamber in which
emissions are generated under conditions which are kept constant during the test. These conditions are
selected so that the test results can be expressed in terms of concentrations of dangerous substances in the
air of the reference room (see Clause 7 and Clause 9). It should be noted that the test chamber is defined in
terms of performance requirements. This responds to the requirement of Mandate M/366 for a horizontal
approach while maintaining sufficient flexibility on chamber dimensions to ensure representative samples of
different materials can be accommodated (see Clause 5). Clause 8 of this European Standard specifies how
emitted regulated dangerous substances should be analysed.
This European Standard also addresses separately (see Clause 11 and Annex B) indirect methods that
provide a result that is comparable or that correlates with the result of the reference method within their
specified field of application. Such methods may be easier and/or cheaper to apply. They are in accordance
with mandate M/366 provided that their comparability or correlation to the reference test method has been
demonstrated in their specific field of application. They are especially suitable for Factory Production Control
testing (FPC).
The selection of one emission scenario and one reference room for evaluating emissions to indoor air is in
general accordance with the approach taken in existing European national regulations and voluntary schemes
relating to emissions from construction products into indoor air. It also accords with the horizontal
requirements of mandate M/366. The aim of this European Standard is not to develop a new testing method
but to combine by normative references the use of existing standards. This approach is complemented, when
necessary, with additional and/or modified requirements to ensure all construction products are evaluated
under comparable conditions as required by the horizontal concept specified in mandate M/366.
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In summary, the horizontal test method specified in this European Standard determines the specific emission
rate of volatile organic compounds from a construction product into indoor air. This can be converted into a
concentration in the air of the reference room by calculation.
This European Standard has not been evaluated for the determination of 'steady-state' concentration of
formaldehyde.
NOTE A European Standard (EN 717–1) exists for the determination of formaldehyde emissions from wood-based
panels, in terms of 'steady-state' concentrations.
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1 Scope
This European Standard specifies a horizontal reference method for the determination of emissions of
regulated dangerous substances from construction products into indoor air. This method is applicable to
volatile organic compounds, semi-volatile organic compounds, and volatile aldehydes. It is based on the use
of a test chamber and subsequent analysis of the organic compounds by GC-MS or HPLC.
NOTE 1 Supplemental information is given on indirect test methods (see Annex B) and on measuring very volatile
organic compounds (see Annex C).
NOTE 2 This European Standard describes the overall procedure and makes use of existing standards mainly by
normative reference, complemented when necessary with additional or modified normative requirements.
2 Normative references
The following documents, in whole or in part, are normatively referenced in this document and are
indispensable for its application. For dated references, only the edition cited applies. For undated references,
the latest edition of the referenced document (including any amendments) applies.
CEN/TR 16220:2011, Construction products — Assessment of release of dangerous substances —
Complement to sampling
CEN/TR 16496, Construction Products — Assessment of release of dangerous substances — Use of
harmonised horizontal assessment methods
EN 16687, Construction products — Assessment of release of dangerous substances — Terminology
EN ISO 13137, Workplace atmospheres — Pumps for personal sampling of chemical and biological agents —
Requirements and test methods (ISO 13137)
EN ISO 16000-9:2006, Indoor air — Part 9: Determination of the emission of volatile organic compounds from
building products and furnishing — Emission test chamber method (ISO 16000-9:2006)
EN ISO 16000-11:2006, Indoor air — Part 11: Determination of the emission of volatile organic compounds
from building products and furnishing — Sampling, storage of samples and preparation of test specimens
(ISO 16000-11:2006)
EN ISO 16017-1, Indoor, ambient and workplace air — Sampling and analysis of volatile organic compounds
by sorbent tube/thermal desorption/capillary gas chromatography — Part 1: Pumped sampling (ISO 16017-1)
ISO 554, Standard atmospheres for conditioning and/or testing — Specifications
ISO 16000-3, Indoor air — Part 3: Determination of formaldehyde and other carbonyl compounds in indoor air
and test chamber air — Active sampling method
ISO 16000-6, Indoor air — Part 6: Determination of volatile organic compounds in indoor and test chamber air
by active sampling on Tenax TA sorbent, thermal desorption and gas chromatography using MS or MS-FID
3 Terms, definitions and abbreviations
For the purposes of this document, the terms and definitions given in EN 16687 and the following apply. In the
event of any conflict between the definitions of terms in the cited normative reference documents and those in
EN 16687 or in this document, the definitions given in EN 16687 and this document shall have precedence.
NOTE Several of the defined terms on product sampling are closely related, which is also depicted in Figure 1. This
figure and the relevant definitions are taken from CEN/TR 16220:2011.
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3.1 Terms relating to sampling and products

Figure 1 — Relation between the key terms of product sampling
3.1.1
composite sample
average sample, aggregated sample
sample that consists of two or more increments, put together in appropriate portions, from which the mean
value of a desired characteristic may be obtained
[SOURCE: adapted from ISO 11074:2005, 4.3.3]
3.1.2
curing
hardening of freshly prepared mixtures under well-defined conditions (time, temperature, humidity, etc.)
specified in harmonised product standards
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3.1.3
curing time
minimal time defined necessary for curing before an emission test can be executed to obtain test results that
are relevant to in use conditions
3.1.4
increment
individual portion of product collected by a single operation
[SOURCE: adapted from ISO 11074:2005, 4.1.8 as in CEN/TR 16220:2011, 2.4.5]
3.1.5
laboratory sample
sample or sub-sample(s) sent to or received by the laboratory
Note 1 to entry: The laboratory sample is the final sample from the point of view of sample collection but it is the initial
sample from the point of view of the laboratory.
[SOURCE: IUPAC, 2.5.5]
3.1.6
population
totality of products under consideration
[SOURCE: adapted from ISO 11074:2005, 4.1.11 as in CEN/TR 16220:2011, 2.4.3]
3.1.7
sample
representative portion of product or material selected from a larger quantity of product or material
[SOURCE: IUPAC, 2.1.1]
3.1.8
sampling plan
predetermined procedure for the selection, withdrawal, preservation and transportation of product samples
[SOURCE: CEN/TR 16220:2011, 2.3]
3.1.9
scale
minimum quantity (mass, volume or units) of the product for which representative test results can be obtained
[SOURCE: CEN/TR 16220:2011, 2.4.4]
3.1.10
sub-population
defined part of the population that is targeted for the purposes of testing
[SOURCE: adapted from ISO 11074:2005, 4.1.29 as in CEN/TR 16220:2011, 2.4.3]
3.2 Terms relating to emissions into indoor air and associated laboratory testing
3.2.1
air change rate
ratio of the volume of air brought into the test chamber per hour and the volume of the empty test chamber
−1
Note 1 to entry: Air change rate is expressed as h .
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[SOURCE: adapted from EN ISO 16000-9:2006, 3.1]
3.2.2
air flow rate
ventilation rate
air volume entering into the emission test chamber per unit of time
[SOURCE: adapted from EN ISO 16000-9:2006, 3.2]
3.2.3
chamber blank value
test result obtained by carrying out the test procedure in the absence of a test portion/specimen
3.2.4
compound recovery
measured mass concentration of a target volatile organic compound in the air leaving the emission test
chamber during a given time period divided by the actual mass concentration of the same target volatile
organic compound added to the e
...