EN 62321-3-1:2014

SLOVENSKI STANDARD
01-junij-2014
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SIST EN 62321:2009
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Determination of certain substances in electrotechnical products - Part 3-1: Screening
test methods - Screening of electrotechnical products for lead, mercury, cadmium, total
chromium and total bromine using X-ray fluorescence spectrometry
Verfahren zur Bestimmung von bestimmten Substanzen in Produkten der Elektrotechnik
- Teil 3-1: Ermittlung von Blei (Pb), Quecksilber (Hg), Cadmium (Cd), Gesamtchrom (Cr)
und Brom (Br) durch Röntgenfluoreszenz-Spektrometrie in elektrotechnischen Produkten
Détermination de certaines substances dans les produits électrotechniques -- Partie 3-1:
Détection du plomb, du mercure, du cadmium, du chrome total et du brome total dans
les produits électrotechniques par spectrométrie par fluorescence X
Ta slovenski standard je istoveten z: EN 62321-3-1:2014
ICS:
29.020 Elektrotehnika na splošno Electrical engineering in
general
31.020 Elektronske komponente na Electronic components in
splošno general
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.

EUROPEAN STANDARD
EN 62321-3-1
NORME EUROPÉENNE
April 2014
EUROPÄISCHE NORM
ICS 13.020; 43.040.10 Supersedes EN 62321:2009 (partially)

English version
Determination of certain substances in electrotechnical products -
Part 3-1: Screening -
Lead, mercury, cadmium, total chromium and total bromine by X-ray
fluorescence spectrometry
(IEC 62321-3-1:2013)
Détermination de certaines substances Verfahren zur Bestimmung von
dans les produits électrotechniques - bestimmten Substanzen in Produkten der
Partie 3-1: Méthodes d'essai - Elektrotechnik -
Plomb, du mercure, du cadmium, du Teil 3-1: Screening -
chrome total et du brome total par la Blei, Quecksilber, Cadmium,
spectrométrie par fluorescence X Gesamtchrom und Gesamtbrom durch
(CEI 62321-3-1:2013) Röntgenfluoreszenz-Spektrometrie
(IEC 62321-3-1:2013)
This European Standard was approved by CENELEC on 2013-11-15. CENELEC members are bound to comply
with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European Standard
the status of a national standard without any alteration.

Up-to-date lists and bibliographical references concerning such national standards may be obtained on
application to the CEN-CENELEC Management Centre or to any CENELEC member.

This European Standard exists in three official versions (English, French, German). A version in any other
language made by translation under the responsibility of a CENELEC member into its own language and notified
to the CEN-CENELEC Management Centre has the same status as the official versions.

CENELEC members are the national electrotechnical committees of Austria, Belgium, Bulgaria, Croatia, Cyprus,
the Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany,
Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, the Netherlands, Norway, Poland,
Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and the United Kingdom.

CENELEC
European Committee for Electrotechnical Standardization
Comité Européen de Normalisation Electrotechnique
Europäisches Komitee für Elektrotechnische Normung

CEN-CENELEC Management Centre: Avenue Marnix 17, B - 1000 Brussels

© 2014 CENELEC - All rights of exploitation in any form and by any means reserved worldwide for CENELEC members.
Ref. No. EN 62321-3-1:2014 E
Foreword
The text of document 111/298/FDIS, future edition 1 of IEC 62321-3-1, prepared by IEC/TC 111
"Environmental standardization for electrical and electronic products and systems" was submitted to the
IEC-CENELEC parallel vote and approved by CENELEC as EN 62321-3-1:2014.
The following dates are fixed:
(dop) 2014-10-25
• latest date by which the document has
to be implemented at national level by
publication of an identical national
standard or by endorsement
• latest date by which the national (dow) 2016-11-15
standards conflicting with the

document have to be withdrawn
generally replacing Clauses 6 and Annex D.
Future parts in the EN 62321 series will gradually replace the corresponding clauses in EN 62321:2009.
Until such time as all parts are published, however, EN 62321:2009 remains valid for those clauses not
yet re-published as a separate part.
Attention is drawn to the possibility that some of the elements of this document may be the subject of
patent rights. CENELEC [and/or CEN] shall not be held responsible for identifying any or all such patent
rights.
Endorsement notice
The text of the International Standard IEC 62321-3-1:2013 was approved by CENELEC as a European
Standard without any modification.

- 3 - EN 62321-3-1:2014
Annex ZA
(normative)
Normative references to international publications
with their corresponding European publications

The following documents, in whole or in part, are normatively referenced in this document and are
indispensable for its application. For dated references, only the edition cited applies. For undated
references, the latest edition of the referenced document (including any amendments) applies.

NOTE  When an international publication has been modified by common modifications, indicated by (mod), the relevant EN/HD
applies.
Publication Year Title EN/HD Year

IEC 62321-1 - Determination of certain substances in EN 62321-1 -
electrotechnical products -
Part 1: Introduction and overview

IEC 62321-2 - Determination of certain substances in EN 62321-2 -
electrotechnical products -
Part 2: Disassembly, disjunction and
mechanical sample preparation
ISO/IEC Guide 98-1 - Uncertainty of measurement - - -
Part 1: Introduction to the expression of
uncertainty in measurement
IEC 62321-3-1 ®
Edition 1.0 2013-06
INTERNATIONAL
STANDARD
NORME
INTERNATIONALE
colour
inside
Determination of certain substances in electrotechnical products –

Part 3-1: Screening – Lead, mercury, cadmium, total chromium and total bromine

by X-ray fluorescence spectrometry

Détermination de certaines substances dans les produits électrotechniques –

Partie 3-1: Méthodes d'essai – Plomb, du mercure, du cadmium, du chrome total

et du brome total par la spectrométrie par fluorescence X

INTERNATIONAL
ELECTROTECHNICAL
COMMISSION
COMMISSION
ELECTROTECHNIQUE
PRICE CODE
INTERNATIONALE
CODE PRIX X
ICS 13.020; 43.040.10 ISBN 978-2-83220-839-7

– 2 – 62321-3-1 © IEC:2013
CONTENTS
FOREWORD . 5
INTRODUCTION . 7
1 Scope . 8
2 Normative references . 10
3 Terms, definitions and abbreviations . 10
4 Principle . 10
4.1 Overview . 10
4.2 Principle of test . 11
4.3 Explanatory comments . 11
5 Apparatus, equipment and materials . 12
5.1 XRF spectrometer . 12
5.2 Materials and tools . 12
6 Reagents . 12
7 Sampling . 12
7.1 General . 12
7.2 Non-destructive approach . 12
7.3 Destructive approach. 12
8 Test procedure . 13
8.1 General . 13
8.2 Preparation of the spectrometer . 13
8.3 Test portion . 14
8.4 Verification of spectrometer performance . 14
8.5 Tests . 15
8.6 Calibration . 15
9 Calculations . 16
10 Precision . 17
10.1 General . 17
10.2 Lead . 17
10.3 Mercury . 17
10.4 Cadmium . 17
10.5 Chromium . 18
10.6 Bromine. 18
10.7 Repeatability statement for five tested substances sorted by type of tested
material . 18
10.7.1 General . 18
10.7.2 Material: ABS (acrylonitrile butadiene styrene), as granules and
plates . 18
10.7.3 Material: PE (low density polyethtylene), as granules . 19
10.7.4 Material: PC/ABS (polycarbonate and ABS blend), as granules . 19
10.7.5 Material: HIPS (high impact polystyrene) . 19
10.7.6 Material: PVC (polyvinyl chloride), as granules . 19
10.7.7 Material: Polyolefin, as granules . 19
10.7.8 Material: Crystal glass . 20
10.7.9 Material: Glass . 20
10.7.10 Material: Lead-free solder, chips . 20

62321-3-1 © IEC:2013 – 3 –
10.7.11 Material: Si/Al Alloy, chips . 20
10.7.12 Material: Aluminum casting alloy, chips . 20
10.7.13 Material: PCB – Printed circuit board ground to less than 250 µm . 20
10.8 Reproducibility statement for five tested substances sorted by type of tested
material . 20
10.8.1 General . 20
10.8.2 Material: ABS (Acrylonitrile butadiene styrene), as granules and
plates . 21
10.8.3 Material: PE (low density polyethtylene), as granules . 21
10.8.4 Material: PC/ABS (Polycarbonate and ABS blend), as granules . 21
10.8.5 Material: HIPS (high impact polystyrene) . 21
10.8.6 Material: PVC (polyvinyl chloride), as granules . 22
10.8.7 Material: Polyolefin, as granules . 22
10.8.8
...