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CEN

EN 16476:2014

(Main)

Liquid petroleum products - Determination of Sodium, Potassium, Calcium, Phosphorus, Copper and Zinc contents in diesel fuel - Method via Inductively Coupled Plasma Optical Emission Spectrometry (ICP OES)

Liquid petroleum products - Determination of Sodium, Potassium, Calcium, Phosphorus, Copper and Zinc contents in diesel fuel - Method via Inductively Coupled Plasma Optical Emission Spectrometry (ICP OES)

This European Standard specifies an inductively coupled plasma optical emission spectrometry (ICP OES) method for the determination of sodium, potassium, calcium, phosphorus, copper and zinc concentrations of diesel fuels, including those containing up to 30 % (V/V) fatty acid methyl ester (FAME), in the range detailed in Table 1. These six elements are considered as the most essential ash forming elements.

Flüssige Mineralölerzeugnisse - Bestimmung des Gehalts an Natrium, Kalium, Calcium, Phosphor, Kupfer, Zink in Dieselkraftstoffen - Direkte Bestimmung durch optische Emissionsspektrometrie mit induktiv gekoppeltem Plasma (ICP OES)

Diese Europäische Norm legt ein Verfahren zur Bestimmung der Konzentrationen von Natrium, Kalium, Calcium, Phosphor, Kupfer und Zink von Dieselkraftstoffen im in Tabelle 1 angegebenen Bereich durch optische Emissionsspektrometrie mit induktiv gekoppeltem Plasma (ICP OES) fest, einschließlich solchen, die bis zu 30 % (V/V) Fettsäuremethylester (FAME) enthalten. Diese sechs Elemente gelten als die wichtigsten Asche bildenden Elemente.
ANMERKUNG   Für die Anwendung der vorliegenden Europäischen Norm wird der Ausdruck „% (V/V)“ verwendet, um den Volumenanteil  darzustellen.
WARNUNG  Die Anwendung dieser Europäischen Norm kann den Einsatz gefährlicher Stoffe, Arbeitsgänge und Geräte mit sich bringen. Diese Europäische Norm gibt nicht vor, alle mit ihrer Anwendung verbundenen Sicherheitsprobleme anzusprechen. Der Anwender dieser Europäischen Norm ist dafür verantwortlich, vorher angemessene Maßnahmen in Hinblick auf Sicherheit

Produits pétroliers liquides - Détermination des concentrations en sodium, potassium, calcium, phosphore, cuivre et zinc dans le gazole - Méthode par spectrométrie d’émission atomique par plasma à couplage inductif (ICP OES)

Tekoči naftni proizvodi - Določevanje natrija, kalija, kalcija, fosforja, bakra in cinka v dizelskem gorivu - Metoda z optično emisijsko spektrometrijo z induktivno sklopljeno plazmo (ICP-OES)

Standard EN 16476 določa metodo optične emisijske spektrometrije z induktivno sklopljeno plazmo (ICP OES) za določevanje koncentracije natrija, kalija, kalcija, fosforja, bakra in cinka v dizelskih gorivih, vključno s tistimi, ki vsebujejo do 30 % (V/V) metilnih estrov maščobnih kislin (FAME), v mejah, določenih v tabeli 1. Teh šest elementov je ključnih pri ustvarjanju pepela.

General Information

Status
Published
Publication Date
06-May-2014
Withdrawal Date
29-Nov-2014
ICS
75.160.20 - Liquid fuels
Technical Committee
CEN/TC 19 - Petroleum products, lubricants and related products
Drafting Committee
CEN/TC 19/WG 27 - Elemental analysis of petroleum and related products
Current Stage
9093 - Decision to confirm - Review Enquiry
Completion Date
03-Dec-2019
Ref Project
SIST EN 16476:2014 - Liquid Petroleum products - Determination of Sodium, Potassium, Calcium, Phosphorus, Copper and Zinc contents in diesel fuel - Method via Inductively Coupled Plasma Optical Emission Spectrometry (ICP-OES)

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2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.LQGXNWLYQRFlüssige Mineralölerzeugnisse - Bestimmung des Gehalts an Natrium, Kalium, Calcium, Phosphor, Kupfer, Zink in Dieselkraftstoffen - Direkte Bestimmung durch optische Emissionsspektrometrie mit induktiv gekoppeltem Plasma (ICP-OES)Produits pétroliers liquides - Détermination des teneurs en Sodium, Potassium, Calcium, Phosphore, Cuivre et Zinc dans le gazole - Méthode par spectrométrie d'émission atomique à couplage inductif par plasma (ICP OES)Liquid Petroleum products - Determination of Sodium, Potassium, Calcium, Phosphorus, Copper and Zinc contents in diesel fuel - Method via Inductively Coupled Plasma Optical Emission Spectrometry (ICP-OES)75.160.20Liquid fuels71.040.50Fizikalnokemijske analitske metodePhysicochemical methods of analysisICS:Ta slovenski standard je istoveten z:EN 16476:2014SIST EN 16476:2014en,fr,de01-julij-2014SIST EN 16476:2014SLOVENSKI
STANDARD
EUROPEAN STANDARD NORME EUROPÉENNE EUROPÄISCHE NORM
EN 16476
May 2014 ICS 75.160.20 English Version
Liquid petroleum products - Determination of Sodium, Potassium, Calcium, Phosphorus, Copper and Zinc contents in diesel fuel - Method via Inductively Coupled Plasma Optical Emission Spectrometry (ICP OES)
Produits pétroliers liquides - Détermination des concentrations en sodium, potassium, calcium, phosphore, cuivre et zinc dans le gazole - Méthode par spectrométrie d'émission atomique par plasma à couplage inductif (ICP OES)
Flüssige Mineralölerzeugnisse - Bestimmung des Gehalts an Natrium, Kalium, Calcium, Phosphor, Kupfer, Zink in Dieselkraftstoffen - Direkte Bestimmung durch optische Emissionsspektrometrie mit induktiv gekoppeltem Plasma (ICP OES) This European Standard was approved by CEN on 20 March 2014.
CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN member.
This European Standard exists in three official versions (English, French, German). A version in any other language made by translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management Centre has the same status as the official versions.
CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and United Kingdom.
EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION EUROPÄISCHES KOMITEE FÜR NORMUNG
CEN-CENELEC Management Centre:
Avenue Marnix 17,
B-1000 Brussels © 2014 CEN All rights of exploitation in any form and by any means reserved worldwide for CEN national Members. Ref. No. EN 16476:2014 ESIST EN 16476:2014

Page Foreword . 3 Introduction . 4 1 Scope . 5 2 Normative references . 5 3 Principle . 5 4 Reagents . 5 5 Apparatus . 6 6 Sampling . 8 7 Preparation of calibration solutions . 8 7.1 General . 8 7.2 Internal Standard solution . 8 7.3 Calibration solutions . 8 7.4 Calibration check solution . 9 8 Calibration . 9 8.1 General . 9 8.2 Calibration of the ICP OES spectrometer . 9 8.3 Procedure A . 10 8.4 Procedure B . 10 8.5 Check of calibration . 10 9 Sample analysis . 11 9.1 Sample preparation . 11 9.2 Sample measurement . 11 10 Calculation . 12 11 Expression of result . 12 12 Precision . 12 12.1 General . 12 12.2 Repeatability . 12 12.3 Reproducibility . 12 13 Test report . 13 Bibliography . 14
...

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