Textiles - Methods for determination of certain aromatic amines derived from azo colorants - Part 1: Detection of the use of certain azo colorants accessible with and without extracting the fibres (ISO 14362-1:2017)

ISO 14362-1:2017 describes a method to detect the use of certain azo colorants that may not be used in the manufacture or treatment of certain commodities made of textile fibres and that are accessible to reducing agent with and without extraction.
Azo colorants accessible to reducing agent without extraction are those used to colour with pigments or to dye
-      cellulosic fibres (e.g. cotton, viscose),
-      protein fibres (e.g. wool, silk), and
-      synthetic fibres (e.g. polyamide, acrylic).
Azo colorants accessible with extraction are those used to dye man-made fibres with disperse dyes. The following man-made fibres can be dyed with disperse dyes: polyester, polyamide, acetate, triacetate, acrylic and chlorofibre.
The method is relevant for all coloured textiles, e.g. dyed, printed and coated textiles.

Textilien - Verfahren für die Bestimmung gewisser aromatischer Amine aus Azofarbstoffen - Teil 1: Nachweis der Verwendung gewisser Azofarbstoffe mit und ohne Extraktion der Fasern (ISO 14362-1:2017)

Textiles - Méthodes de détermination de certaines amines aromatiques dérivées de colorants azoïques - Partie 1: Détection de l'utilisation de certains colorants azoïques accessibles avec ou sans extraction (ISO 14362-1:2017)

ISO 14362-1:2017 spécifie une méthode permettant de détecter l'utilisation de certains colorants azoïques qui ne peuvent pas être utilisés dans la fabrication ou le traitement de certains articles en fibres textiles et accessibles aux agents réducteurs avec ou sans extraction.
Les colorants azoïques accessibles aux agents réducteurs sans extraction sont ceux utilisés pour colorer avec des pigments ou pour teindre:
-      des fibres cellulosiques (par exemple le coton, la viscose);
-      des fibres animales (par exemple la laine, la soie); et
-      des fibres synthétiques (par exemple le polyamide, l'acrylique).
Les colorants azoïques accessibles avec extraction sont ceux utilisés pour teindre les fibres chimiques au moyen de colorants dispersés. Les fibres chimiques suivantes peuvent être teintes au moyen de colorants dispersés: polyester, polyamide, acétate, triacétate, acrylique et chlorofibre.
La méthode est adaptée à tous les textiles colorés, par exemple les textiles teints, imprimés et enduits.

Tekstilije - Metode za določevanje nekaterih aromatskih aminov, izvirajočih iz azo barvil - 1. del: Zaznavanje prisotnosti določenih azo barvil, dostopnih z ekstrahiranjem vlaken in brez njega (ISO 24362-1:2017)

Ta del standarda ISO 24362 opisuje postopek za zaznavanje prisotnosti določenih azo barvil,
ki jih ni dovoljeno uporabljati pri proizvodnji ali obdelavi nekaterih izdelkov iz tekstilnih vlaken in ki so
dostopna reducentom z ekstrahiranjem ali brez njega.
Azo barvila, reducentom dostopna brez ekstrahiranja, so tista barvila, ki se uporabljajo za barvanje:
– celuloznih vlaken (npr. bombaž, viskoza);
– proteinskih vlaken (npr. volna, svila);
– sintetičnih vlaken (npr. poliamidna, akrilna vlakna);
Azo barvila, reducentom dostopna z ekstrahiranjerm, so tista barvila, ki se uporabljajo za barvanje kemičnih vlaken z disperznimi barvili. Kemična vlakna, ki se lahko barvajo z disperznimi barvili so naslednja: poliestrska, poliamidna, acetatna, triacetatna, akrilna, modakrilna in aramidna vlakna ter klorovlakna.
Pri nekaterih izdelkih iz mešanice celuloznih in/ali proteinskih vlaken ter kemičnih vlaken je najprej potrebna ekstrakcija barvila.
Metoda je primerna za vse vrste barvanega tekstila, npr. barvan, tiskan in prevlečen tekstil.

General Information

Status
Published
Publication Date
07-Feb-2017
Withdrawal Date
30-Aug-2017
Current Stage
6060 - Definitive text made available (DAV) - Publishing
Start Date
08-Feb-2017
Due Date
06-Jun-2017
Completion Date
08-Feb-2017

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SLOVENSKI STANDARD
01-april-2017
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SIST EN 14362-1:2012
7HNVWLOLMH0HWRGH]DGRORþHYDQMHQHNDWHULKDURPDWVNLKDPLQRYL]YLUDMRþLKL]D]R
EDUYLOGHO=D]QDYDQMHSULVRWQRVWLGRORþHQLKD]REDUYLOGRVWRSQLK]
HNVWUDKLUDQMHPYODNHQLQEUH]QMHJD ,62
Textiles - Methods for determination of certain aromatic amines derived from azo
colorants - Part 1: Detection of the use of certain azo colorants accessible with and
without extracting the fibres (ISO 24362-1:2017)
Textilien - Verfahren für die Bestimmung gewisser aromatischer Amine aus
Azofarbstoffen - Teil 1: Nachweis der Verwendung gewisser Azofarbstoffe mit und ohne
Extraktion der Fasern (ISO 24362-1:2017)
Textiles - Méthodes de détermination de certaines amines aromatiques dérivées de
colorants azoïques - Partie 1 : Détection de l'utilisation de certains azo-colorants
accessibles avec ou sans extraction (ISO 24362-1:2017)
Ta slovenski standard je istoveten z: EN ISO 14362-1:2017
ICS:
59.080.01 Tekstilije na splošno Textiles in general
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.

EN ISO 14362-1
EUROPEAN STANDARD
NORME EUROPÉENNE
February 2017
EUROPÄISCHE NORM
ICS 59.060.01 Supersedes EN 14362-1:2012
English Version
Textiles - Methods for determination of certain aromatic
amines derived from azo colorants - Part 1: Detection of
the use of certain azo colorants accessible with and
without extracting the fibres (ISO 14362-1:2017)
Textiles - Méthodes de détermination de certaines Textilien - Verfahren für die Bestimmung gewisser
amines aromatiques dérivées de colorants azoïques - aromatischer Amine aus Azofarbstoffen - Teil 1:
Partie 1: Détection de l'utilisation de certains colorants Nachweis der Verwendung gewisser Azofarbstoffe mit
azoïques accessibles avec ou sans extraction (ISO und ohne Extraktion der Fasern (ISO 14362-1:2017)
14362-1:2017)
This European Standard was approved by CEN on 21 December 2016.

CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this
European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references
concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN
member.
This European Standard exists in three official versions (English, French, German). A version in any other language made by
translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management
Centre has the same status as the official versions.

CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,
Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania,
Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland,
Turkey and United Kingdom.
EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION

EUROPÄISCHES KOMITEE FÜR NORMUNG

CEN-CENELEC Management Centre: Avenue Marnix 17, B-1000 Brussels
© 2017 CEN All rights of exploitation in any form and by any means reserved Ref. No. EN ISO 14362-1:2017 E
worldwide for CEN national Members.

Contents Page
European foreword . 3

European foreword
This document (EN ISO 14362-1:2017) has been prepared by Technical Committee ISO/TC 38
"Textiles" in collaboration with Technical Committee CEN/TC 248 “Textiles and textile products” the
secretariat of which is held by BSI.
This European Standard shall be given the status of a national standard, either by publication of an
identical text or by endorsement, at the latest by August 2017, and conflicting national standards shall
be withdrawn at the latest by August 2017.
Attention is drawn to the possibility that some of the elements of this document may be the subject of
patent rights. CEN [and/or CENELEC] shall not be held responsible for identifying any or all such patent
rights.
This document supersedes EN 14362-1:2012.
According to the CEN-CENELEC Internal Regulations, the national standards organizations of the
following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria,
Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia,
France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta,
Netherlands, Norway, Poland, Portugal, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland,
Turkey and the United Kingdom.
Endorsement notice
The text of ISO 14362-1:2017 has been approved by CEN as EN ISO 14362-1:2017 without any
modification.
INTERNATIONAL ISO
STANDARD 24362-1
First edition
2014-02-01
Textiles — Methods for determination
of certain aromatic amines derived
from azo colorants —
Part 1:
Detection of the use of certain azo
colorants accessible with and without
extracting the fibres
Textiles — Méthodes de détermination de certaines amines
aromatiques dérivées de colorants azoïques —
Partie 1: Détection de l’utilisation de certains colorants azoïques
accessibles avec ou sans extraction
Reference number
ISO 24362-1:2014(E)
©
ISO 2014
ISO 24362-1:2014(E)
© ISO 2014
All rights reserved. Unless otherwise specified, no part of this publication may be reproduced or utilized otherwise in any form
or by any means, electronic or mechanical, including photocopying, or posting on the internet or an intranet, without prior
written permission. Permission can be requested from either ISO at the address below or ISO’s member body in the country of
the requester.
ISO copyright office
Case postale 56 • CH-1211 Geneva 20
Tel. + 41 22 749 01 11
Fax + 41 22 749 09 47
E-mail copyright@iso.org
Web www.iso.org
Published in Switzerland
ii © ISO 2014 – All rights reserved

ISO 24362-1:2014(E)
Contents Page
Foreword .iv
Introduction .v
1 Scope . 1
2 Normative references . 1
3 General . 1
4 Principle . 3
5 Safety precautions . 3
6 Reagents . 3
7 Apparatus . 5
8 Test specimen sampling and preparation . 6
8.1 General . 6
8.2 Textile article . 6
8.3 Fibre composition . 7
8.4 Case of the fibre blends. 7
8.5 Printed materials . 7
8.6 Colours . 7
9 Procedure. 8
9.1 Colorant extraction for disperse dyes . 8
9.2 Textiles dyed with dyes other than disperse dyes . 8
9.3 Reductive cleavage . 8
9.4 Separation and concentration of the amines . 9
9.5 Amine detection and quantification . 9
9.6 Check procedure . 9
10 Evaluation .11
10.1 General .11
10.2 Calculation of amine in the sample .11
10.3 Reliability of the method .11
11 Test report .11
Annex A (informative) Chromatographic analyses .12
Annex B (informative) Reliability of the method .16
Annex C (informative) Assessment guide — Interpretation of analytical results .17
Annex D (informative) Explanatory table of dyestuffs used in various textile materials .19
Annex E (informative) Procedure for liquid-liquid-extraction without diatomaceous earth.21
Annex F (normative) Colorants-Methods for determination of certain aromatic amines .24
Bibliography .25
ISO 24362-1:2014(E)
Foreword
ISO (the International Organization for Standardization) is a worldwide federation of national standards
bodies (ISO member bodies). The work of preparing International Standards is normally carried out
through ISO technical committees. Each member body interested in a subject for which a technical
committee has been established has the right to be represented on that committee. International
organizations, governmental and non-governmental, in liaison with ISO, also take part in the work.
ISO collaborates closely with the International Electrotechnical Commission (IEC) on all matters of
electrotechnical standardization.
The procedures used to develop this document and those intended for its further maintenance are
described in the ISO/IEC Directives, Part 1. In particular the different approval criteria needed for the
different types of ISO documents should be noted. This document was drafted in accord
...

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