ASTM D4615-22
(Specification)Standard Specification for n-Butyl Acetate (All Grades)
Standard Specification for <emph type="ital">n</emph>-Butyl Acetate (All Grades)
ABSTRACT
This specification establishes the properties and requirements for various grades of n-butyl acetate suitable for use as solvents in paint and related coatings. Specimens shall be sampled and tested as appropriate, and shall adhere accordingly to specified values for purity, alcohol content, color (Pt-Co units), distillation range, nonvolatile matter content, odor, water content, acidity, and apparent specific gravity.
SCOPE
1.1 This specification covers the various grades of n-butyl acetate suitable for use as solvents in paint and related coatings.
1.2 The following applies to all specified limits in this standard; for purposes of determining conformance with this standard, an observed value or a calculated value shall be rounded off “to the nearest unit” in the last right-hand digit used in expressing the specification limit, in accordance with the rounding-off method of Practice E29.
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.4 For specific hazard information and guidance, see the supplier's Material Safety Data Sheet for material listed in this specification.
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
General Information
- Status
- Published
- Publication Date
- 31-Dec-2021
- Technical Committee
- D01 - Paint and Related Coatings, Materials, and Applications
- Drafting Committee
- D01.35 - Solvents, Plasticizers, and Chemical Intermediates
Relations
- Effective Date
- 01-May-2013
- Effective Date
- 01-Jun-2012
- Effective Date
- 15-Nov-2011
- Effective Date
- 01-Jan-2010
- Effective Date
- 01-Jun-2009
- Effective Date
- 01-Apr-2009
- Effective Date
- 01-Oct-2008
- Effective Date
- 01-Nov-2007
- Effective Date
- 01-Jun-2007
- Effective Date
- 01-Jun-2007
- Effective Date
- 01-Jun-2007
- Effective Date
- 15-Nov-2006
- Effective Date
- 15-Sep-2006
- Effective Date
- 01-Jun-2006
- Effective Date
- 01-May-2006
Overview
ASTM D4615-22 - Standard Specification for n-Butyl Acetate (All Grades) sets out the quality requirements and test methods for various grades of n-butyl acetate used as solvents in paints and related coatings. Developed by ASTM International, this specification ensures that n-butyl acetate meets strict criteria for purity, chemical composition, color, and physical properties, supporting its consistent performance and safety in industrial and commercial applications.
Key Topics
- Purity and Composition: The standard outlines minimum purity levels (90-99.5% depending on grade), and specifies maximum allowable concentrations for alcohol, water, and acidity.
- Color and Odor: Limits are established for color (Platinum-Cobalt units) and odor characteristics, helping guarantee product consistency and suitability for end-use in coatings and other sensitive applications.
- Physical Properties: Requirements include specific gravity, distillation range, and nonvolatile matter content, ensuring the solvent performs as intended in manufacturing processes.
- Testing Methods: Standardized ASTM test methods must be used for evaluation, including techniques like gas chromatography, Karl Fischer titration for water content, and distillation analysis.
- Packaging and Marking: Guidelines for package sizes, carrier regulations, and marking are provided and should be agreed upon between purchaser and supplier.
- Safety and Compliance: Users are directed to consult Material Safety Data Sheets and observe applicable safety, health, and environmental regulations.
Applications
n-Butyl acetate is an important solvent in various industries, especially in:
- Paints and Coatings: Used as a primary or secondary solvent in automotive, industrial, and architectural coatings, enhancing application properties and film formation.
- Inks and Adhesives: Valued for its solvency and favorable evaporation rate, improving processability and performance.
- Chemical Manufacturing: Acts as an intermediate in producing pharmaceuticals, plastics, and other esters.
- Laboratory and Quality Control: The specified testing methods and standards ensure suppliers and users can conduct reliable, repeatable quality assessments for n-butyl acetate, supporting regulatory compliance and product safety.
Following ASTM D4615-22 helps organizations:
- Select n-butyl acetate grades tailored to specific application requirements.
- Maintain batch-to-batch consistency and product integrity.
- Satisfy regulatory and customer requirements for chemical traceability and performance.
- Reduce risks related to impurities, improper handling, or inappropriate material selection.
Related Standards
For full compliance and accurate testing, reference the following related ASTM standards:
- ASTM D891: Test Methods for Specific Gravity of Liquid Industrial Chemicals
- ASTM D1078: Test Method for Distillation Range of Volatile Organic Liquids
- ASTM D1209: Test Method for Color of Clear Liquids (Platinum-Cobalt Scale)
- ASTM D1353: Test Method for Nonvolatile Matter in Volatile Solvents
- ASTM D1364: Test Method for Water in Volatile Solvents (Karl Fischer)
- ASTM D1613: Test Method for Acidity in Volatile Solvents
- ASTM D4052: Test Method for Density by Digital Density Meter
- ASTM D5386: Test Method for Color Using Tristimulus Colorimetry
- ASTM E1: Specification for Liquid-in-Glass Thermometers
- ASTM E29: Practice for Using Significant Digits in Test Data
- ASTM E300: Practice for Sampling Industrial Chemicals
Adopting ASTM D4615-22 and its referenced standards helps manufacturers, suppliers, and end-users achieve uniform quality and regulatory acceptance of n-butyl acetate in global markets.
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Frequently Asked Questions
ASTM D4615-22 is a technical specification published by ASTM International. Its full title is "Standard Specification for <emph type="ital">n</emph>-Butyl Acetate (All Grades)". This standard covers: ABSTRACT This specification establishes the properties and requirements for various grades of n-butyl acetate suitable for use as solvents in paint and related coatings. Specimens shall be sampled and tested as appropriate, and shall adhere accordingly to specified values for purity, alcohol content, color (Pt-Co units), distillation range, nonvolatile matter content, odor, water content, acidity, and apparent specific gravity. SCOPE 1.1 This specification covers the various grades of n-butyl acetate suitable for use as solvents in paint and related coatings. 1.2 The following applies to all specified limits in this standard; for purposes of determining conformance with this standard, an observed value or a calculated value shall be rounded off “to the nearest unit” in the last right-hand digit used in expressing the specification limit, in accordance with the rounding-off method of Practice E29. 1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard. 1.4 For specific hazard information and guidance, see the supplier's Material Safety Data Sheet for material listed in this specification. 1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. 1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
ABSTRACT This specification establishes the properties and requirements for various grades of n-butyl acetate suitable for use as solvents in paint and related coatings. Specimens shall be sampled and tested as appropriate, and shall adhere accordingly to specified values for purity, alcohol content, color (Pt-Co units), distillation range, nonvolatile matter content, odor, water content, acidity, and apparent specific gravity. SCOPE 1.1 This specification covers the various grades of n-butyl acetate suitable for use as solvents in paint and related coatings. 1.2 The following applies to all specified limits in this standard; for purposes of determining conformance with this standard, an observed value or a calculated value shall be rounded off “to the nearest unit” in the last right-hand digit used in expressing the specification limit, in accordance with the rounding-off method of Practice E29. 1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard. 1.4 For specific hazard information and guidance, see the supplier's Material Safety Data Sheet for material listed in this specification. 1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. 1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
ASTM D4615-22 is classified under the following ICS (International Classification for Standards) categories: 71.080.70 - Esters; 87.060.30 - Solvents. The ICS classification helps identify the subject area and facilitates finding related standards.
ASTM D4615-22 has the following relationships with other standards: It is inter standard links to ASTM E1-13, ASTM D1613-06(2012), ASTM D1078-11, ASTM D5386-10, ASTM D1353-09, ASTM D891-09, ASTM E29-08, ASTM E1-07, ASTM D1296-01(2007), ASTM D268-01(2007), ASTM D1364-02(2007), ASTM E29-06b, ASTM E29-06a, ASTM D3545-06, ASTM E29-06. Understanding these relationships helps ensure you are using the most current and applicable version of the standard.
ASTM D4615-22 is available in PDF format for immediate download after purchase. The document can be added to your cart and obtained through the secure checkout process. Digital delivery ensures instant access to the complete standard document.
Standards Content (Sample)
This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the
Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
Designation: D4615 −22
Standard Specification for
n-Butyl Acetate (All Grades)
This standard is issued under the fixed designation D4615; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
This standard has been approved for use by agencies of the U.S. Department of Defense.
1. Scope Chemical Intermediates for Use in Paint and Related
Coatings and Material
1.1 This specification covers the various grades of n-butyl
D891 TestMethodsforSpecificGravity,Apparent,ofLiquid
acetate suitable for use as solvents in paint and related
Industrial Chemicals
coatings.
D1078 Test Method for Distillation Range of Volatile Or-
1.2 The following applies to all specified limits in this
ganic Liquids
standard; for purposes of determining conformance with this
D1209 Test Method for Color of Clear Liquids (Platinum-
standard, an observed value or a calculated value shall be
Cobalt Scale)
rounded off “to the nearest unit” in the last right-hand digit
D1296 Test Method for Odor of Volatile Solvents and
used in expressing the specification limit, in accordance with
Diluents (Withdrawn 2021)
the rounding-off method of Practice E29.
D1353 Test Method for Nonvolatile Matter in Volatile Sol-
1.3 The values stated in SI units are to be regarded as
vents for Use in Paint, Varnish, Lacquer, and Related
standard. No other units of measurement are included in this
Products
standard.
D1364 Test Method for Water in Volatile Solvents (Karl
Fischer Reagent Titration Method)
1.4 For specific hazard information and guidance, see the
D1613 Test Method for Acidity in Volatile Solvents and
supplier’s Material Safety Data Sheet for material listed in this
Chemical Intermediates Used in Paint, Varnish, Lacquer,
specification.
and Related Products
1.5 This standard does not purport to address all of the
D3545 Test Method for Alcohol Content and Purity of
safety concerns, if any, associated with its use. It is the
Acetate Esters by Gas Chromatography (Withdrawn
responsibility of the user of this standard to establish appro-
2021)
priate safety, health, and environmental practices and deter-
D4052 Test Method for Density, Relative Density, and API
mine the applicability of regulatory limitations prior to use.
Gravity of Liquids by Digital Density Meter
1.6 This international standard was developed in accor-
D5386 Test Method for Color of Liquids Using Tristimulus
dance with internationally recognized principles on standard-
Colorimetry
ization established in the Decision on Principles for the
E1 Specification for ASTM Liquid-in-Glass Thermometers
Development of International Standards, Guides and Recom-
E29 Practice for Using Significant Digits in Test Data to
mendations issued by the World Trade Organization Technical
Determine Conformance with Specifications
Barriers to Trade (TBT) Committee.
E300 Practice for Sampling Industrial Chemicals
2. Referenced Documents
2.2 U.S. Federal Specification:
PPP-C-2020 Chemicals, Liquid, Dry, and Paste: Packaging
2.1 ASTM Standards:
of
D268 Guide for Sampling and Testing Volatile Solvents and
3. Properties
This specification is under the jurisdiction of ASTM Committee D01 on Paint
3.1 n-Butyl acetate shall conform to one of the requirements
and Related Coatings, Materials, andApplications and is the direct responsibility of
of one of the grades in Table 1.
Subcommittee D01.35 on Solvents, Plasticizers, and Chemical Intermediates.
Current edition approved Jan. 1, 2022. Published January 2022. Originally
approved in 1986. Last previous edition approved in 2012 as D4615 – 12 which was
withdrawn January 2021 and reinstated in January 2022. DOI: 10.1520/D4615-22.
2 3
For referenced ASTM standards, visit the ASTM website, www.astm.org, or The last approved version of this historical standard is referenced on
contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM www.astm.org.
Standards volume information, refer to the standard’s Document Summ
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