SIGNIFICANCE AND USE
5.1 Peroxy esters are widely used as chemical intermediates, catalysts, and initiators. This test method provides a procedure for assaying peroxy esters to determine if they are suitable for their intended use.
SCOPE
1.1 This test method covers the assay of organic peroxides of the peroxy ester type.  
Note 1: Other test methods for the assay of organic peroxides are given in Test Methods E298, E475, and E755.  
1.2 Review the current safety data sheets (SDS) for detailed information concerning toxicity, first aid procedures, and safety precautions.  
1.3 The values stated in SI units are to be regarded as the standard. No other units of measurement are included in this test method.  
1.4 In determining the conformance of the test results using this method to applicable specifications, results shall be rounded off in accordance with the rounding-off method of Practice E29.  
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. Specific hazards statements are given in Section 9.  
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

  • Standard
    4 pages
    English language
    sale 15% off
  • Standard
    4 pages
    English language
    sale 15% off

ABSTRACT
This specification establishes the properties and requirements for various grades of n-butyl acetate suitable for use as solvents in paint and related coatings. Specimens shall be sampled and tested as appropriate, and shall adhere accordingly to specified values for purity, alcohol content, color (Pt-Co units), distillation range, nonvolatile matter content, odor, water content, acidity, and apparent specific gravity.
SCOPE
1.1 This specification covers the various grades of n-butyl acetate suitable for use as solvents in paint and related coatings.  
1.2 The following applies to all specified limits in this standard; for purposes of determining conformance with this standard, an observed value or a calculated value shall be rounded off “to the nearest unit” in the last right-hand digit used in expressing the specification limit, in accordance with the rounding-off method of Practice E29.  
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.4 For specific hazard information and guidance, see the supplier's Material Safety Data Sheet for material listed in this specification.  
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

  • Technical specification
    2 pages
    English language
    sale 15% off

SIGNIFICANCE AND USE
5.1 The regulatory candidate list classifies substances by CAS number. Complex branched phthalates, such as DINP or DIDP, manufactured with a defined alcohol distribution and registered by CAS number with a chemical description of the composition, shall be considered a single substance with that composition as described.  
5.2 It is possible for the alcohols used in the manufacture of complex branched phthalates to vary in isomer composition. Care must be used to ensure a representative standard is used to the quantitation of the level of a complex branched phthalate.  
5.3 This guide is intended to provide a method on how to interpret and determine data from an analysis involving complex branched phthalates with defined CAS numbers. The test procedure employed shall be used to provide speciation information to assist use of the schematic flow diagram.
Note 3: A discussion on analytical challenges in complex branched phthalate analysis is found in: “Analytical Challenges in Detecting Regulated Phthalates in Flexible PVC Products,” SPI Flexible Vinyl Products Division, 23rd Annual Compounding Conference, July 17, 2012.
SCOPE
1.1 This guide is established in response to regulatory requirements for the determination of complex branched phthalates by CAS numbers. This guide is intended to provide information on how to interpret and analyze data from a chromatographic analysis involving complex phthalates with defined CAS numbers.  
1.2 This guide provides a logical approach to determine levels of complex branched phthalates meeting regulatory and CAS number requirements.  
1.3 The specific complex phthalates covered within this guide are DINP and DIDP.  
1.4 Limitations—This guide does not recommend any specific test method. In some cases, it is necessary to deduce the quantity of substance present through the analysis and quantification of its components. Although this approach is routinely used some degree of uncertainty exists in the final result due to the reduced accuracy of the method.  
1.5 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.6 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.7 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

  • Guide
    24 pages
    English language
    sale 15% off

SIGNIFICANCE AND USE
5.1 This test method is used to measure the reactivity of different lots of unsaturated polyester and vinyl ester resins. The information provided by this test is often used for assessing the predicted performance of a resin when used in elevated temperature as part of the process used to convert the resin into a finished product.  
5.2 The method is used in research and development by companies that manufacture resins and for incoming quality control companies using these polymers as raw materials for production. The method is based on the methods which were previously outlined in the Handbook of Reinforced Plastics, “Procedure for Running Exotherm Curves Using the Block Test Method” published by the Society of the Plastics Industry.
SCOPE
1.1 This standard provides a standardized test method for determining the gelation and exotherm curve of unsaturated polyester and vinyl ester resins. This method provides guidance for measurement of the “Standard 180°F (82.2°C) Exotherm Curve” along with information on potential variances of the measurement for some special resins. This test method provides information concerning the reactivity of unsaturated polyester and vinyl ester resins as they go through polymerization after mixing with the initiator.
Note 1: There is no known ISO equivalent to this standard, although ISO 584 is similar.  
1.2 The values stated in either SI units or inch-pound units are to be regarded separately as standard. The values stated in each system are not necessarily equivalents; therefore, each system shall be used independently of the other. Combining values from the two systems has the potential to result in nonconformance with the standard.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

  • Standard
    5 pages
    English language
    sale 15% off
  • Standard
    5 pages
    English language
    sale 15% off

SCOPE
1.1 This test method covers determination of the hydrolyzable chloride content of peroxy esters and peroxy dicarbonates.  Note-There are no ISO standards covering the primary subject of this test method.
1.2 The values stated in SI units are to be regarded as the standard.
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. Specific hazards statements are given in Section 8.

  • Standard
    2 pages
    English language
    sale 15% off

The free alcohol is reacted with vanadium(V) sodium salt of quinolin-8-ol(8-hydroxyquinoline) to form a coloured complex. The complex is extracted with toluene and then treated with dichloroacetic acid. The spectrometric measurement is carried out at a wavelength of about 620 nm. The method is applicable to products having free alcohol contents between 0,01 and 5,0 % (m/m).

  • Standard
    2 pages
    English language
    sale 15% off
  • Standard
    3 pages
    French language
    sale 15% off
  • Standard
    3 pages
    French language
    sale 15% off

Gives general instructions and specifies methods of analysis for these chemical products. The methods are the following: determination of density at 20 °C; determination of dry residue after evaporation on a water bath; measurement of colour; determination of distillation characteristics; determination of water content; determination of acidity; and determination of ester content (titrimetric method). - Cancels and replaces ISO Recommendation R 1386-1970 and constitutes a technical revision thereof.

  • Standard
    4 pages
    English language
    sale 15% off
  • Standard
    4 pages
    French language
    sale 15% off
  • Standard
    4 pages
    French language
    sale 15% off

The principle consists in titration of the acidity in a test portion, in ethanolic medium, with standard volumetric sodium hydroxide solution using phenolphthalein as indicator. - ISO 1385, Part 1 to Part 5 replace ISO Recommendation R 1385-1970.

  • Standard
    2 pages
    English language
    sale 15% off
  • Standard
    2 pages
    French language
    sale 15% off
  • Standard
    2 pages
    French language
    sale 15% off

The method is not applicable to diallyl phthalate because of the risk of explosive polymerization. The procedure is carried out by the method specified in ISO 2211. The result is expressed in Hazen units (platinum-cobalt scale). - ISO 1385, Part 1 to Part 5 replace ISO Recommendation R 1385-1970.

  • Standard
    1 page
    English language
    sale 15% off
  • Standard
    1 page
    French language
    sale 15% off
  • Standard
    1 page
    French language
    sale 15% off

With diallyl phthalate, this method of test should be carried out cautiously and only small amounts should be ignited at one time because of the risk of explosive polymerization. The principle consists in burning of a test portion and heating in an electric furnace at (600 30) °C to constant mass. - ISO 1385, Part 1 to Part 5 replace ISO Recommendation R 1385-1970.

  • Standard
    1 page
    English language
    sale 15% off
  • Standard
    1 page
    French language
    sale 15% off
  • Standard
    1 page
    French language
    sale 15% off

The principle consists in the saponification of ester in a test portion, using a measured excess of potassium hydroxide ethanolic solution, followed by back-titration with standard volumetric hydrochloric acid solution in the presence of phenolphthalein as indicator. - ISO 1385, Part 1 to Part 5 replace ISO Recommendation R 1385-1970

  • Standard
    2 pages
    English language
    sale 15% off
  • Standard
    2 pages
    French language
    sale 15% off
  • Standard
    2 pages
    French language
    sale 15% off

The document also specifies the methods to be used for the following tests: measurements of colour; determination of density at 20 °C; determination of water content; determination of iodine value (applicable to diallyl phthalate only); determination of refractive index; determination of flash point; determination of viscosity (not applicable to diallyl phthalate). - ISO 1385, Part 1 to Part 5 replace ISO Recommendation R 1385-1970.

  • Standard
    2 pages
    English language
    sale 15% off
  • Standard
    2 pages
    French language
    sale 15% off
  • Standard
    2 pages
    French language
    sale 15% off

The method specified determines only those phenols capable of reacting at the 2nd, 4th and 6th position (-OH = 1). The procedure consists in extraction of free phenols from a test portion with sodium hydroxide solution. Bromination of these phenols with potassium bromide-bromate solution in an acid medium and determination of the excess bromine after reaction with potassium iodide by titration with standard volumetric sodium thiosulphate solution.

  • Standard
    2 pages
    English language
    sale 15% off
  • Standard
    2 pages
    French language
    sale 15% off
  • Standard
    2 pages
    French language
    sale 15% off

The method is applicable to simple and mixed alcohol esters that are liquid at ambient temperature. The principle of analysis consists in burning a test portion in a platinum or silica dish and ignition in a muffle furnace controlled at (600 30) 0C. Weighing of the residue.

  • Standard
    2 pages
    English language
    sale 15% off
  • Standard
    2 pages
    French language
    sale 15% off
  • Standard
    2 pages
    French language
    sale 15% off

Specifies the titration of any acidity present in an ethanolic solution with standard volumetric sodium hydoxide solution in the presence of phenol red as indicator. The end point of the titration corresponds to the formation of the salt Na2 HPO4 .

  • Standard
    2 pages
    English language
    sale 15% off
  • Standard
    2 pages
    French language
    sale 15% off
  • Standard
    2 pages
    French language
    sale 15% off
  • Standard
    2 pages
    English language
    sale 15% off
  • Standard
    2 pages
    French language
    sale 15% off
  • Standard
    2 pages
    French language
    sale 15% off

Specifies the sampling, the determination of the density at 20 0C, of the water content, of the acidity to phenol red, of apparent free phenols content and the measurement of colour in Hazen units.

  • Standard
    1 page
    English language
    sale 15% off
  • Standard
    1 page
    French language
    sale 15% off
  • Standard
    1 page
    French language
    sale 15% off

The method is applicable to simple and mixed alcohol esters that are liquid at ambient temperature. The following principle is specified: Saponification of the ester using potassium hydroxide in ethanolic solution followed by titration with standard volumetric hydrochloric acid solution in the presence of phenolphthalein as indicator. In the case of mixed alcohol esters the relative molar mass of which can only be estimated the saponification and ester values are used to express the result.

  • Standard
    3 pages
    English language
    sale 15% off
  • Standard
    3 pages
    French language
    sale 15% off
  • Standard
    3 pages
    French language
    sale 15% off

The method specified is applicable to simple and mixed alcohol esters that are liquid at ambient temperature. The heat treatment is carried out in a tube of borosilicate glass in an oil bath at a temperature of (180 2) 0C for 2 h. Measurement of the colour of the heat-treated sample by the method specified in ISO 2211.

  • Standard
    2 pages
    English language
    sale 15% off
  • Standard
    2 pages
    French language
    sale 15% off
  • Standard
    2 pages
    French language
    sale 15% off

Specifies the sampling, the determination of the density at 20 0C, of the water content, of the acidity to phenolphthalein, of the ash and esther contents, the measurement of colour in Hazen units and of the colour after the heat treatment.

  • Standard
    1 page
    English language
    sale 15% off
  • Standard
    1 page
    French language
    sale 15% off
  • Standard
    1 page
    French language
    sale 15% off