SIST EN 17131-2:2025
(Main)Textiles and textile products - Determination of certain residual solvents - Part 2: Determination of benzene, method using headspace gas chromatography
Textiles and textile products - Determination of certain residual solvents - Part 2: Determination of benzene, method using headspace gas chromatography
This document specifies a method using headspace gas chromatography and mass selective spectroscopy (HS-GC-MS) for detection and quantification of benzene in components of textile products.
Textilien und textile Erzeugnisse - Bestimmung von bestimmten Lösemittelrückständen - Teil 2: Bestimmung von Benzol, Verfahren mittels Headspace-Gaschromatographie
Dieses Dokument legt ein Verfahren zum Nachweis und zur quantitativen Bestimmung von Benzol in Bestandteilen textiler Erzeugnisse unter Anwendung von Headspace Gaschromatographie und massenselektiver Spektroskopie (HS GC MS) fest.
Textiles et produits textiles - Détermination de certains solvants résiduels - Partie 2 : Détermination du benzène, méthode par chromatographie en phase gazeuse à espace de tête
Le présent document spécifie une méthode utilisant la chromatographie en phase gazeuse à espace de tête et la spectroscopie sélective de masse (HS-GC-MS) pour la détection et la quantification du benzène dans les composants de produits textiles.
Tekstilije in tekstilni izdelki - Določevanje nekaterih preostalih topil - 2. del: Določevanje benzena, metoda z uporabo "headspace" plinske kromatografije
Ta dokument določa metodo, ki uporablja »headspace« plinsko kromatografijo z masno spektrometrijo (HS-GC-MS) za odkrivanje in kvantifikacijo benzena v delih tekstilnih izdelkov.
General Information
- Status
- Published
- Public Enquiry End Date
- 31-Jan-2024
- Publication Date
- 08-Apr-2025
- Technical Committee
- ITEK - Textile and textile products
- Current Stage
- 6060 - National Implementation/Publication (Adopted Project)
- Start Date
- 08-Apr-2025
- Due Date
- 13-Jun-2025
- Completion Date
- 09-Apr-2025
Relations
- Effective Date
- 15-Feb-2023
Overview
SIST EN 17131-2:2025 is a European standard published by CEN that specifies a reliable method for the detection and quantification of benzene residues in textiles and textile products. It employs headspace gas chromatography combined with mass selective spectroscopy (HS-GC-MS) to accurately analyze benzene levels in various textile components. This standard replaces the earlier EN 17131-2:2019 and aligns with strict regulatory requirements such as the EU REACH regulation limiting benzene content in textiles to 5 mg/kg.
Ensuring compliance with SIST EN 17131-2:2025 is critical for manufacturers, importers, and testing laboratories handling textiles that come into contact with human skin. The standard supports safe consumer products by identifying benzene, a hazardous residual solvent, thus contributing to textile safety and environmental health.
Key Topics
Scope and Application
The method targets benzene detection in textile components using HS-GC-MS. It applies to clothing, accessories, and other textiles that are in direct or similar contact with human skin.Regulatory Background
Complies with EU Regulation 2018/1513 amending restrictions on benzene in textiles under REACH Annex XVII, which restricts benzene content to below 5 mg/kg for market placement after 1 November 2020.Analytical Principle
Benzene in the test specimen is released into the headspace of the sealed vial by heating at 160 °C. The vapor phase is then analyzed by gas chromatography with a mass selective detector to quantify benzene.Sample Preparation
Samples should be carefully wrapped and stored cold to prevent benzene loss. Textiles are cut into small pieces (0.3-0.5 cm), weighed (200 mg), and mixed with an internal standard solution in HS-GC vials for analysis.Reagents and Calibration
Uses analytical grade benzene and benzene-d6 as internal standard dissolved in methanol. Calibration involves preparing at least three standard solutions to establish response curves.Instrumental Conditions
The recommended GC column has a 60 m length with cyanopropyl/phenyl stationary phase. Helium is used as carrier gas, with split injection and selective ion monitoring for specific benzene detection.Result Expression
Benzene concentration is calculated as mg/kg in the textile material based on interpolated HS-GC-MS response and sample mass. The method achieves quantification limits down to 1 mg/kg, suitable for regulatory compliance.Safety Considerations
Handling benzene and solvents requires caution due to toxicity. Proper laboratory safety and environmental precautions must be observed.
Applications
Textile Quality Control
Laboratories testing raw materials or final textile products for residual benzene to ensure consumer safety and regulatory compliance.Regulatory Compliance Testing
Enabling manufacturers and importers to verify their textile products meet EU and international benzene limits before market entry.Research and Development
Monitoring solvent residues during textile processing and finishing for process optimization and safer chemical management.Certification and Labeling
Providing analytical evidence for product certifications related to chemical safety and environmental standards in textiles.Customs and Market Surveillance
Assisting authorities in screening imported textile goods for hazardous solvent content.
Related Standards
EN 17131-1:2025
Determination of aprotic residual solvents in textiles by gas chromatography-complements Part 2 for a comprehensive solvent residue analysis.EN ISO 4787
Laboratory glassware volumetric performance-ensures accuracy in sample and reagent preparation critical for chromatography methods.EU Regulation 2018/1513 (REACH Amendment)
Legal limit framework for hazardous substances like benzene in textiles placed on the European market.EN ISO 17025
General requirements for testing laboratories-applicable for laboratories implementing this benzene determination method.
By adopting the SIST EN 17131-2:2025 standard, stakeholders in the textile industry benefit from a validated, reproducible method ensuring product safety, enhancing regulatory adherence, and protecting consumer health against hazardous solvent residues such as benzene.
Frequently Asked Questions
SIST EN 17131-2:2025 is a standard published by the Slovenian Institute for Standardization (SIST). Its full title is "Textiles and textile products - Determination of certain residual solvents - Part 2: Determination of benzene, method using headspace gas chromatography". This standard covers: This document specifies a method using headspace gas chromatography and mass selective spectroscopy (HS-GC-MS) for detection and quantification of benzene in components of textile products.
This document specifies a method using headspace gas chromatography and mass selective spectroscopy (HS-GC-MS) for detection and quantification of benzene in components of textile products.
SIST EN 17131-2:2025 is classified under the following ICS (International Classification for Standards) categories: 59.080.01 - Textiles in general; 71.040.50 - Physicochemical methods of analysis. The ICS classification helps identify the subject area and facilitates finding related standards.
SIST EN 17131-2:2025 has the following relationships with other standards: It is inter standard links to SIST EN 17131:2019. Understanding these relationships helps ensure you are using the most current and applicable version of the standard.
SIST EN 17131-2:2025 is associated with the following European legislation: EU Directives/Regulations: 1907/2006. When a standard is cited in the Official Journal of the European Union, products manufactured in conformity with it benefit from a presumption of conformity with the essential requirements of the corresponding EU directive or regulation.
You can purchase SIST EN 17131-2:2025 directly from iTeh Standards. The document is available in PDF format and is delivered instantly after payment. Add the standard to your cart and complete the secure checkout process. iTeh Standards is an authorized distributor of SIST standards.
Standards Content (Sample)
SLOVENSKI STANDARD
01-junij-2025
Tekstilije in tekstilni izdelki - Določevanje nekaterih preostalih topil - 2. del:
Določevanje benzena, metoda z uporabo "headspace" plinske kromatografije
Textiles and textile products - Determination of certain residual solvents - Part 2:
Determination of benzene, method using headspace gas chromatography
Textilien und textile Erzeugnisse - Bestimmung von bestimmten Lösemittelrückständen -
Teil 2: Bestimmung von Benzol, Verfahren mittels Headspace-Gaschromatographie
Textiles et produits textiles - Détermination de certains solvants résiduels - Partie 2 :
Détermination du benzène, méthode par chromatographie en phase gazeuse à espace
de tête
Ta slovenski standard je istoveten z: EN 17131-2:2025
ICS:
59.080.01 Tekstilije na splošno Textiles in general
71.040.50 Fizikalnokemijske analitske Physicochemical methods of
metode analysis
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.
EN 17131-2
EUROPEAN STANDARD
NORME EUROPÉENNE
April 2025
EUROPÄISCHE NORM
ICS 59.080.01 Supersedes EN 17131:2019
English Version
Textiles and textile products - Determination of certain
residual solvents - Part 2: Determination of benzene,
method using headspace gas chromatography
Textiles et produits textiles - Détermination de certains Textilien und textile Erzeugnisse - Bestimmung
solvants résiduels - Partie 2 : Détermination du bestimmter Lösemittelrückstände - Teil 2: Bestimmung
benzène, méthode par chromatographie en phase von Benzol, Verfahren mittels Headspace-
gazeuse à espace de tête Gaschromatographie
This European Standard was approved by CEN on 13 January 2025.
CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this
European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references
concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN
member.
This European Standard exists in three official versions (English, French, German). A version in any other language made by
translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management
Centre has the same status as the official versions.
CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,
Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway,
Poland, Portugal, Republic of North Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Türkiye and
United Kingdom.
EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION
EUROPÄISCHES KOMITEE FÜR NORMUNG
CEN-CENELEC Management Centre: Rue de la Science 23, B-1040 Brussels
© 2025 CEN All rights of exploitation in any form and by any means reserved Ref. No. EN 17131-2:2025 E
worldwide for CEN national Members.
Contents Page
European foreword . 3
Introduction . 4
1 Scope . 5
2 Normative references . 5
3 Terms and definitions . 5
4 Principle . 5
5 Reagents . 5
6 Apparatus . 6
7 Preparation of test samples . 7
7.1 Sampling . 7
7.2 Preparation of test specimens . 7
7.3 Preparation of a blank . 7
8 Procedure. 7
8.1 Determination with HS-GC-MS . 7
8.2 Calibration . 7
8.3 Determination with HS-GC-MS . 7
9 Expression of results . 7
9.1 Calculation . 7
9.2 Reliability of the method . 8
10 Test report . 8
Annex A (informative) Example of instrumental conditions. 9
Annex B (informative) Reliability of the method. 10
Bibliography . 11
European foreword
This document (EN 17131-2:2025) has been prepared by Technical Committee CEN/TC 248 “Textiles
and textile products”, the secretariat of which is held by BSI.
This European Standard shall be given the status of a national standard, either by publication of an
identical text or by endorsement, at the latest by October 2025, and conflicting national standards shall
be withdrawn at the latest by October 2025.
Attention is drawn to the possibility that some of the elements of this document may be the subject of
patent rights. CEN shall not be held responsible for identifying any or all such patent rights.
This document supersedes EN 17131-2:2019.
This document is Part 2 of the EN 17131 series of standards under the title Textiles and textile products
— Determination of certain residual solvents:
— Part 1: Determination of aprotic solvents, method using gas chromatography;
— Part 2: Determination of benzene, method using headspace gas chromatography (this document).
Any feedback and questions on this document should be directed to the users’ national standards body.
A complete listing of these bodies can be found on the CEN website.
According to the CEN-CENELEC Internal Regulations, the national standards organisations of the
following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria, Croatia,
Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland,
Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Republic of North
Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Türkiye and the United
Kingdom.
Introduction
In Europe, according to Regulation (EU) 2018/1513 amending Annex XVII to Regulation (EC) No
1907/2006 (REACH) by Entry 72 [1], (a) clothing or related accessories; (b) textiles other than clothing
which, under normal or reasonably foreseeable conditions of use, come into contact with human skin to
an extent similar to clothing; (c) footwear, are not to be placed on the market after 1 November 2020, if
they contain more than 5 mg/kg of benzene.
This restriction does not apply to: (a) clothing, related accessories or footwear, or parts of clothing,
related accessories or footwear, made exclusively of natural leather, fur or hide; (b) non-textile fasteners
and non-textile decorative attachments; (c) second-hand clothing, related accessories, textiles other than
clothing or footwear; (d) wall-to-wall carpets and textile floor coverings for indoor use, rugs and runners.
It also does not apply to clothing, related accessories, textiles other than clothing, or footwear within the
scope of Regulation (EU) 2016/425 on personal protective equipment or Regulation (EU) 2017/745 on
medical devices. The restriction on textiles other than clothing does not apply to disposable textiles.
“Disposable textiles” means textiles that are designed to be used only once or for a limited time and are
not intended for subsequent use for the same or a similar purpose.
Although the Regulation [1] excludes non-textile fastenings and decorative items, this method is also
suitable for such components.
WARNING — The use of this document involves hazardous materials. It does not purport to
address all of the safety or environmental problems associated with its use. It is the responsibility
of users of this document to take appropriate measures to ensure the safety and health of
personnel and the environment prior to application of the document and fulfil statutory and
regulatory requirements for this purpose.
1 Scope
This document specifies a method using headspace gas chromatography and mass selective spectroscopy
(HS-GC-MS) for detection and quantification of benzene in components of textile products.
2 Normative references
The following documents are referred to in the text in such a way that some or all of their content
...










Questions, Comments and Discussion
Ask us and Technical Secretary will try to provide an answer. You can facilitate discussion about the standard in here.
Loading comments...