SIST EN 16319:2013/kFprA1:2015
(Amendment)Fertilizers and liming materials - Determination of cadmium, chromium, lead and nickel by inductively coupled plasma-atomic emission spectrometry (ICP-AES) after aqua regia dissolution
Fertilizers and liming materials - Determination of cadmium, chromium, lead and nickel by inductively coupled plasma-atomic emission spectrometry (ICP-AES) after aqua regia dissolution
EN 16319:2013 will be amended taking into account liming materials in the scope of the method. Clause 10 Pecision and Annex A Results of the inter-laboratory tests will be amended by addition of the precision data received from the inter-laboratory tests performed in 2013 analysing samples of liming materials. The main title of the document will be extended to liming materials to read: Fertilizers and liming materials.
Düngemittel und Kalkdünger - Bestimmung von Cadmium, Chrom, Blei und Nickel mit Atomemissionsspektrometrie mit induktiv gekoppeltem Plasma (ICP-AES) nach Königswasseraufschluss
Engrais et amendements minéraux basiques - Détermination du cadmium, chrome, plomb et nickel par spectrométrie d'émission atomique avec plasma induit par haute fréquence (ICP-AES) après digestion à l'eau régale
Gnojila in sredstva za apnjenje - Določevanje kadmija, kroma, svinca in niklja z atomsko emisijsko spektrometrijo z induktivno sklopljeno plazmo (ICP/AES) po raztapljanju v zlatotopki - Dopolnilo A1
General Information
- Status
- Not Published
- Public Enquiry End Date
- 08-Feb-2015
- Technical Committee
- KAT - Soil quality
- Current Stage
- 98 - Abandoned project (Adopted Project)
- Start Date
- 27-Jan-2016
- Due Date
- 01-Feb-2016
- Completion Date
- 27-Jan-2016
Relations
- Effective Date
- 01-Mar-2016
- Effective Date
- 01-Jan-2015
Overview
EN 16319:2013/prA1:2015 (CEN) is a laboratory method standard for the determination of cadmium (Cd), chromium (Cr), lead (Pb) and nickel (Ni) in fertilizers and liming materials. The amendment (prA1) extends the original method to explicitly include liming materials, and incorporates precision and reproducibility data from inter‑laboratory tests on liming material matrices carried out in 2013. The analytical technique specified is inductively coupled plasma–atomic emission spectrometry (ICP‑AES) following aqua regia (aqua regia/Königswasser) dissolution of samples.
Key topics and requirements
- Scope: Method applies to Cd, Cr, Ni and Pb in fertilizers and liming materials using ICP‑AES after aqua regia dissolution. The term “fertilizer” is to be taken as including liming materials unless otherwise stated.
- Analytical principle: Sample dissolution by aqua regia, followed by measurement with ICP‑AES.
- Performance / precision data: Amendment adds inter‑laboratory precision results for liming materials (dolomitic limestone, burnt lime, converter lime) to Clause 10 and Annex A. Example results from the 2013 trials:
- Cadmium in dolomitic limestone: mean 0.967 mg/kg; repeatability s(r) ≈ 0.039 mg/kg; reproducibility s(R) ≈ 0.25 mg/kg.
- Chromium in dolomitic limestone: mean ≈ 6.42 mg/kg; r ≈ 0.57 mg/kg; R ≈ 1.23 mg/kg.
- Lead in dolomitic limestone: mean ≈ 87.2 mg/kg; r ≈ 2.88 mg/kg; R ≈ 17.2 mg/kg.
- Terms and definitions: Uses vocabulary from EN 12944 parts 1–3; amendment adds a specific reference to Part 3 (terms relating to liming materials).
- Inter‑laboratory testing: Statistical treatment and outlier elimination procedures and the resulting tables (A.5–A.8) are included for liming material matrices.
Applications and users
This standard is aimed at users who need validated procedures for element determination in agronomic materials:
- Analytical and commercial laboratories performing compliance and quality testing of fertilizers and liming materials.
- Fertilizer and lime manufacturers for product quality control and specification verification.
- Regulatory bodies and enforcement laboratories checking compliance with limits for Cd, Cr, Pb and Ni.
- Environmental monitoring and soil amendment research where accurate trace‑metal data are needed.
Related standards
- EN 12944-1:1999 and EN 12944-2:1999 - vocabulary and related terms for fertilizers.
- EN 12944-3:2001 - terms relating to liming materials (explicitly referenced in the amendment).
- Other CEN methods for fertilizer analysis and trace‑element determination.
This amendment clarifies the method’s applicability to liming materials and provides concrete inter‑laboratory precision data, making EN 16319 a practical reference for ICP‑AES analysis, aqua regia dissolution, and trace‑metal testing of fertilizers and liming materials.
Frequently Asked Questions
SIST EN 16319:2013/kFprA1:2015 is a draft published by the Slovenian Institute for Standardization (SIST). Its full title is "Fertilizers and liming materials - Determination of cadmium, chromium, lead and nickel by inductively coupled plasma-atomic emission spectrometry (ICP-AES) after aqua regia dissolution". This standard covers: EN 16319:2013 will be amended taking into account liming materials in the scope of the method. Clause 10 Pecision and Annex A Results of the inter-laboratory tests will be amended by addition of the precision data received from the inter-laboratory tests performed in 2013 analysing samples of liming materials. The main title of the document will be extended to liming materials to read: Fertilizers and liming materials.
EN 16319:2013 will be amended taking into account liming materials in the scope of the method. Clause 10 Pecision and Annex A Results of the inter-laboratory tests will be amended by addition of the precision data received from the inter-laboratory tests performed in 2013 analysing samples of liming materials. The main title of the document will be extended to liming materials to read: Fertilizers and liming materials.
SIST EN 16319:2013/kFprA1:2015 is classified under the following ICS (International Classification for Standards) categories: 65.080 - Fertilizers. The ICS classification helps identify the subject area and facilitates finding related standards.
SIST EN 16319:2013/kFprA1:2015 has the following relationships with other standards: It is inter standard links to SIST EN 16319:2013+A1:2016, SIST EN 16319:2013. Understanding these relationships helps ensure you are using the most current and applicable version of the standard.
SIST EN 16319:2013/kFprA1:2015 is associated with the following European legislation: Standardization Mandates: M/418. When a standard is cited in the Official Journal of the European Union, products manufactured in conformity with it benefit from a presumption of conformity with the essential requirements of the corresponding EU directive or regulation.
SIST EN 16319:2013/kFprA1:2015 is available in PDF format for immediate download after purchase. The document can be added to your cart and obtained through the secure checkout process. Digital delivery ensures instant access to the complete standard document.
Standards Content (Sample)
SLOVENSKI STANDARD
SIST EN 16319:2013/oprA1:2015
01-januar-2015
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Fertilizers and liming materials - Determination of cadmium, chromium, lead and nickel
by inductively coupled plasma-atomic emission spectrometry (ICP-AES) after aqua regia
dissolution
Düngemittel und Kalkdünger - Bestimmung von Cadmium, Chrom, Blei und Nickel mit
Atomemissionsspektrometrie mit induktiv gekoppeltem Plasma (ICP-AES) nach
Königswasseraufschluss
Engrais et amendements minéraux basiques - Détermination du cadmium, chrome,
plomb et nickel par spectrométrie d'émission atomique avec plasma induit par haute
fréquence (ICP-AES) après digestion à l'eau régale
Ta slovenski standard je istoveten z: EN 16319:2013/prA1
ICS:
65.080 Gnojila Fertilizers
SIST EN 16319:2013/oprA1:2015 en,fr,de
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.
SIST EN 16319:2013/oprA1:2015
SIST EN 16319:2013/oprA1:2015
EUROPEAN STANDARD
DRAFT
EN 16319:2013
NORME EUROPÉENNE
EUROPÄISCHE NORM
prA1
October 2014
ICS 65.080
English Version
Fertilizers and liming materials - Determination of cadmium,
chromium, lead and nickel by inductively coupled plasma-atomic
emission spectrometry (ICP-AES) after aqua regia dissolution
Engrais et amendements minéraux basiques - Düngemittel und Kalkdünger - Bestimmung von Cadmium,
Détermination du cadmium, chrome, plomb et nickel par Chrom, Blei und Nickel mit Atomemissionsspektrometrie mit
spectrométrie d'émission atomique avec plasma induit par induktiv gekoppeltem Plasma (ICP-AES) nach
haute fréquence (ICP-AES) après digestion à l'eau régale Königswasseraufschluss
This draft amendment is submitted to CEN members for enquiry. It has been drawn up by the Technical Committee CEN/TC 260.
This draft amendment A1, if approved, will modify the European Standard EN 16319:2013. If this draft becomes an amendment, CEN
members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for inclusion of this amendment
into the relevant national standard without any alteration.
This draft amendment was established by CEN in three official versions (English, French, German). A version in any other language made
by translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management Centre has
the same status as the official versions.
CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,
Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania,
Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and United
Kingdom.
Recipients of this draft are invited to submit, with their comments, notification of any relevant patent rights of which they are aware and to
provide supporting documentation.
Warning : This document is not a European Standard. It is distributed for review and comments. It is subject to change without notice and
shall not be referred to as a European Standard.
EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION
EUROPÄISCHES KOMITEE FÜR NORMUNG
CEN-CENELEC Management Centre: Avenue Marnix 17, B-1000 Brussels
© 2014 CEN All rights of exploitation in any form and by any means reserved Ref. No. EN 16319:2013/prA1:2014 E
worldwide for CEN national Members.
SIST EN 16319:2013/oprA1:2015
EN 16319:2013/prA1:2014 (E)
Contents
Page
Foreword .3
1 Modification to the Title .4
2 Modifications to Clause 1, Scope .4
3 Modification to Clause 2 .4
4 Modification to Clause 3, Terms and definitions .4
5 Modification to Clause 10, Precision, Table 3 .4
6 Modification to Clause 10, Precision, Table 4 .5
7 Modification to Clause 10, Precision, Table 5 .5
8 Modification to Clause 10, Precision, Table 6 .5
9 Modification to Annex A.1 .5
10 Modification to Annex A.2 .6
11 Modification to Annex A .6
SIST EN 16319:2013/oprA1:2015
EN 16319:2013/prA1:2014 (E)
Foreword
This document (EN 16319:2013/prA1:2014) has been prepared by Technical Committee CEN/TC 260
“Fertilizers and liming materials”, the secretariat of which is held by DIN.
This document is currently submitted to the CEN Enquiry.
This document has been prepared under a mandate given to CEN by the European Commission and the
European Free Trade Association.
SIST EN 16319:2013/oprA1:2015
EN 16319:2013/prA1:2014 (E)
1 Modification to the Title
Delete "Determination of trace elements" and insert "liming materials" after fertili
...
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