Natural rubber latex concentrate - Determination of total phosphate content by spectrophotometric method

This document specifies a method for the determination of total phosphate content of natural rubber latex concentrate. This method is not necessarily suitable for latex from natural sources other than the Hevea brasiliensis.

Concentré de latex de caoutchouc naturel — Détermination de la teneur totale en phosphate par méthode spectrophotométrique

General Information

Status
Published
Publication Date
02-May-2023
Current Stage
6060 - International Standard published
Start Date
03-May-2023
Due Date
08-Jun-2023
Completion Date
03-May-2023

Relations

Effective Date
06-Jun-2022

Overview - ISO 19043:2023 (Natural rubber latex concentrate - Total phosphate)

ISO 19043:2023 specifies a spectrophotometric method for the determination of total phosphate content in natural rubber latex concentrate (principally from Hevea brasiliensis). The standard describes sample preparation, reagents, apparatus, calibration, measurement at 470 nm, calculation and reporting rules. It is intended for quality control, specification testing and laboratory analysis of concentrated natural rubber latex.

Key topics and technical requirements

  • Scope limitation: Method is not necessarily suitable for latex from species other than Hevea brasiliensis.
  • Principle: Coagulate ~20 g of concentrated latex with hydrochloric acid, separate serum, react residual phosphate with vanadate–molybdate reagent and measure absorbance at 470 nm.
  • Reagents: Analytical-grade reagents including HCl (370 g/kg), vanadate molybdate reagent, and a potassium dihydrogen phosphate (KH2PO4) stock solution (500 mg·dm‑3) - commercially supplied or prepared.
  • Apparatus: Analytical balance (0.1 mg), Class A volumetric pipettes (ISO 648), spectrophotometer set to 470 nm, and 8 µm filter paper (e.g., Whatman No.40).
  • Calibration: Prepare a calibration curve from standard phosphate solutions (0–20 mg·dm‑3 final concentrations after reagent addition) and determine slope (S) for calculation.
  • Procedure controls: Duplicate determinations from the same homogenized sample; the difference between duplicates shall not exceed 30 mg/kg. Results are reported as the mean of duplicate determinations.
  • Expression & calculation: Phosphate content is calculated using measured absorbance, calibration slope, sample mass, total solids content and volumetric factors as specified in the standard.
  • Precision: Annex A summarizes interlaboratory precision (ITP) data (ten labs in China and India, 2022) with repeatability/day‑to‑day repeatability and reproducibility figures.

Practical applications

  • Quality control and specification testing in rubber manufacturing and latex concentrate production.
  • Incoming raw-material inspection by rubber processors, latex concentrate suppliers, and independent testing laboratories.
  • R&D and regulatory compliance where phosphate content affects stability, coagulation behaviour, or downstream processing of natural rubber latex.

Who should use ISO 19043:2023

  • Laboratory analysts in rubber and latex testing labs
  • QA/QC managers at latex concentrate producers and rubber goods manufacturers
  • Technical staff in procurement and compliance evaluating latex feedstocks

Related standards

  • ISO 124 - Latex, rubber - Determination of total solids content (used within ISO 19043 for solids correction)
  • ISO 648 - Laboratory glassware - Single-volume pipettes (class A requirements)
  • ISO 19983 - Determination of precision of test methods (precision evaluation referenced in Annex A)

Note: Users should observe normal laboratory safety practices and verify patent or proprietary reagent considerations where applicable.

Standard

ISO 19043:2023 - Natural rubber latex concentrate — Determination of total phosphate content by spectrophotometric method Released:3. 05. 2023

English language
7 pages
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Frequently Asked Questions

ISO 19043:2023 is a standard published by the International Organization for Standardization (ISO). Its full title is "Natural rubber latex concentrate - Determination of total phosphate content by spectrophotometric method". This standard covers: This document specifies a method for the determination of total phosphate content of natural rubber latex concentrate. This method is not necessarily suitable for latex from natural sources other than the Hevea brasiliensis.

This document specifies a method for the determination of total phosphate content of natural rubber latex concentrate. This method is not necessarily suitable for latex from natural sources other than the Hevea brasiliensis.

ISO 19043:2023 is classified under the following ICS (International Classification for Standards) categories: 83.040.10 - Latex and raw rubber. The ICS classification helps identify the subject area and facilitates finding related standards.

ISO 19043:2023 has the following relationships with other standards: It is inter standard links to ISO 19043:2015. Understanding these relationships helps ensure you are using the most current and applicable version of the standard.

You can purchase ISO 19043:2023 directly from iTeh Standards. The document is available in PDF format and is delivered instantly after payment. Add the standard to your cart and complete the secure checkout process. iTeh Standards is an authorized distributor of ISO standards.

Standards Content (Sample)


INTERNATIONAL ISO
STANDARD 19043
Second edition
2023-05
Natural rubber latex concentrate —
Determination of total phosphate
content by spectrophotometric
method
Concentré de latex de caoutchouc naturel — Détermination de la
teneur totale en phosphate par méthode spectrophotométrique
Reference number
© ISO 2023
All rights reserved. Unless otherwise specified, or required in the context of its implementation, no part of this publication may
be reproduced or utilized otherwise in any form or by any means, electronic or mechanical, including photocopying, or posting on
the internet or an intranet, without prior written permission. Permission can be requested from either ISO at the address below
or ISO’s member body in the country of the requester.
ISO copyright office
CP 401 • Ch. de Blandonnet 8
CH-1214 Vernier, Geneva
Phone: +41 22 749 01 11
Email: copyright@iso.org
Website: www.iso.org
Published in Switzerland
ii
Contents Page
Foreword .iv
1 Scope . 1
2 Normative references . 1
3 Terms and definitions . 1
4 Principle . 1
5 Apparatus . 1
6 Reagents . 2
7 Procedure .2
7.1 General . 2
7.2 Determination of total solids content . 2
7.3 Preparation of standard phosphate solutions . 2
7.4 Determination of phosphate content . 3
8 Expression of results . 3
9 Precision data .4
10 Test report . 4
Annex A (informative) Precision data . 5
Bibliography . 7
iii
Foreword
ISO (the International Organization for Standardization) is a worldwide federation of national standards
bodies (ISO member bodies). The work of preparing International Standards is normally carried out
through ISO technical committees. Each member body interested in a subject for which a technical
committee has been established has the right to be represented on that committee. International
organizations, governmental and non-governmental, in liaison with ISO, also take part in the work.
ISO collaborates closely with the International Electrotechnical Commission (IEC) on all matters of
electrotechnical standardization.
The procedures used to develop this document and those intended for its further maintenance are
described in the ISO/IEC Directives, Part 1. In particular, the different approval criteria needed for the
different types of ISO document should be noted. This document was drafted in accordance with the
editorial rules of the ISO/IEC Directives, Part 2 (see www.iso.org/directives).
ISO draws attention to the possibility that the implementation of this document may involve the use
of (a) patent(s). ISO takes no position concerning the evidence, validity or applicability of any claimed
patent rights in respect thereof. As of the date of publication of this document, ISO had not received
notice of (a) patent(s) which may be required to implement this document. However, implementers are
cautioned that this may not represent the latest information, which may be obtained from the patent
database available at www.iso.org/patents. ISO shall not be held responsible for identifying any or all
such patent rights.
Any trade name used in this document is information given for the convenience of users and does not
constitute an endorsement.
For an explanation of the voluntary nature of standards, the meaning of ISO specific terms and
expressions related to conformity assessment, as well as information about ISO's adherence to
the World Trade Organization (WTO) principles in the Technical Barriers to Trade (TBT), see
www.iso.org/iso/foreword.html.
This document was prepared by Technical Committee ISO/TC 45, Rubber and rubber products,
Subcommittee SC 3, Raw materials (including latex) for use in the rubber industry.
This second edition cancels and replaces the first edition (ISO 19043:2015), which has been technically
revised.
The main changes are as follows:
— the CAS numbers of the chemicals have been added;
— in 6.4, the requirement for potassium dihydrogen phosphate (stock solution) has been changed to
include both the commercially available standard solution and the prepared one;
— in 7.1, "The difference between two readings” has been changed into "The difference between the
results of duplicate determinations";
— in Clause 8, “Report the result as the mean of the duplicate determinations" has been added;
— in Annex A, the precision data have been updated by the results of an ITP evaluated in accordance
with ISO 19983.
Any feedback or questions on this document should be directed to the user’s national standards body. A
complete listing of these bodies can be found at www.iso.org/members.html.
iv
INTERNATIONAL STANDARD ISO 19043:2023(E)
Natural rubber latex concentrate — Determination of total
phosphate content by spectrophotometric method
WARNING — Persons using this document should be familiar with normal laboratory practice.
This document does not purport to address all of the safety problems, if any, associated with its
use. It is the responsibility of the user to establish appropriate safety and health practices.
1 Scope
This document specifies a method for the determination of total phosphate content of natural rubber
latex concentrate. This method is not necessarily suitable for latex from natural sources other than the
Hevea brasiliensis.
2 Normative references
The following documents are referred to in the text in such a way that some or all of their content
constitutes requirements of this document. For dated references, only the edition cited applies. For
undated references, the latest edition of the referenced document (including any amendments) applies.
ISO 124, Latex, rubber — Determination of total solids content
ISO 648, Laboratory glassware — Single-volume pipettes
3 Terms and definitions
No terms and definitio
...

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