Functional pigments and extenders for special applications - Part 4: Nanoscale titanium dioxide for photocatalytic application

This document specifies requirements and corresponding test methods for nanoscale titanium dioxide (TiO2) in either powder or suspension form for photocatalytic application. This document is applicable to modified nanoscale titanium dioxide for photocatalytic application. NOTE Such modification can be surface treatment, coating, doping and combination thereof.

Pigments et matières de charge fonctionnels pour applications spéciales — Partie 4: Dioxyde de titane nanométrique pour applications photocatalytiques

Le présent document spécifie des exigences et les méthodes d’essai correspondantes pour le dioxyde de titane (TiO2) nanométrique sous forme de poudre ou de suspension, pour applications photocatalytiques. Il s'applique au dioxyde de titane (TiO2) nanométrique modifié, pour applications photocatalytiques. NOTE Cette modification peut correspondre à un traitement de surface, un revêtement, un dopage et toute combinaison de ceux-ci.

General Information

Status
Published
Publication Date
27-Feb-2022
Current Stage
6060 - International Standard published
Start Date
28-Feb-2022
Due Date
21-Oct-2022
Completion Date
28-Feb-2022

Relations

Effective Date
06-Jun-2022

Overview

ISO 18473-4:2022 specifies requirements and test methods for nanoscale titanium dioxide (TiO2) supplied as powder or suspension for photocatalytic applications. Part of the ISO 18473 series on functional pigments and extenders, this standard covers modified nano‑TiO2 (e.g., surface treatment, coating, doping) and defines classification, sampling, marking, test reporting and essential technical limits to ensure consistent performance in photocatalysis.

Key topics and technical requirements

The standard focuses on characterization and conformity testing for photocatalyst TiO2 nanoparticles. Major technical items include:

  • Classification and designation

    • Crystal structure: anatase or mainly anatase with low rutile content.
    • Designation may include the median primary particle size (d50).
  • Appearance

    • Powder: white or yellowy‑white (yellow possible with certain dopants).
  • Essential requirements (examples from Table 1)

    • Median primary particle size (d50): ≤ 100 nm (reported by TEM or suitable method).
    • Specific surface area (BET): ≥ 35 m²/g (ISO 9277).
    • Residue on 45 µm sieve: < 0.05% mass (ISO 787‑18).
    • Mass fraction of TiO2: ≥ 80% (tested after ignition; ISO 591‑1).
    • pH (4% dispersion): 1.5 to 9 (ISO 787‑9).
    • Crystal structure reported by XRD; particle size distribution reported by TEM (D10, D50, D90).
  • Additional (by agreement)

    • Powder: moisture ≤ 15%, loss on ignition ≤ 20%, elemental contents (Si, Al, Fe) and HCl content, and photocatalytic activity testing (ISO 20814 or ISO 22197‑1).
    • Suspension: solid content ≥ 20%, dispersion medium reported, and no unredispersible sediments within 24 h.
  • Other requirements

    • Sampling per ISO 15528, labelling (manufacturer, product name, batch, humidity warning), and comprehensive test reporting referencing ISO 18473‑4:2022.

Applications and who uses it

ISO 18473‑4 is aimed at manufacturers, suppliers, quality laboratories and buyers of nanoscale TiO2 photocatalysts used in:

  • Air and water purification, deodorization and pollutant decomposition
  • Self‑cleaning, antifogging and antimicrobial surface coatings
  • Photocatalytic coatings and advanced functional pigments in paints, ceramics and building materials
  • Research labs developing doped or modified nano‑TiO2 for visible‑light photocatalysis

Quality managers and regulatory teams will use the standard to define product specifications, acceptance criteria and test methods for procurement and compliance.

Related standards

Relevant cross‑references cited in ISO 18473‑4 include:

  • ISO 9277 (BET specific surface area)
  • ISO 591‑1 (TiO2 pigment analysis)
  • ISO 20814 and ISO 22197‑1 (photocatalytic activity tests)
  • ISO 15528 (sampling) and ISO 787 series (general pigment tests)

Keywords: ISO 18473‑4, nanoscale titanium dioxide, TiO2, photocatalytic, photocatalyst, BET, TEM, XRD, nanoparticle specification, functional pigments.

Standard

ISO 18473-4:2022 - Functional pigments and extenders for special applications — Part 4: Nanoscale titanium dioxide for photocatalytic application Released:2/28/2022

English language
5 pages
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Frequently Asked Questions

ISO 18473-4:2022 is a standard published by the International Organization for Standardization (ISO). Its full title is "Functional pigments and extenders for special applications - Part 4: Nanoscale titanium dioxide for photocatalytic application". This standard covers: This document specifies requirements and corresponding test methods for nanoscale titanium dioxide (TiO2) in either powder or suspension form for photocatalytic application. This document is applicable to modified nanoscale titanium dioxide for photocatalytic application. NOTE Such modification can be surface treatment, coating, doping and combination thereof.

This document specifies requirements and corresponding test methods for nanoscale titanium dioxide (TiO2) in either powder or suspension form for photocatalytic application. This document is applicable to modified nanoscale titanium dioxide for photocatalytic application. NOTE Such modification can be surface treatment, coating, doping and combination thereof.

ISO 18473-4:2022 is classified under the following ICS (International Classification for Standards) categories: 87.060.10 - Pigments and extenders. The ICS classification helps identify the subject area and facilitates finding related standards.

ISO 18473-4:2022 has the following relationships with other standards: It is inter standard links to ISO 12224-2:2024. Understanding these relationships helps ensure you are using the most current and applicable version of the standard.

ISO 18473-4:2022 is available in PDF format for immediate download after purchase. The document can be added to your cart and obtained through the secure checkout process. Digital delivery ensures instant access to the complete standard document.

Standards Content (Sample)


INTERNATIONAL ISO
STANDARD 18473-4
First edition
2022-02
Functional pigments and extenders for
special applications —
Part 4:
Nanoscale titanium dioxide for
photocatalytic application
Reference number
© ISO 2022
All rights reserved. Unless otherwise specified, or required in the context of its implementation, no part of this publication may
be reproduced or utilized otherwise in any form or by any means, electronic or mechanical, including photocopying, or posting on
the internet or an intranet, without prior written permission. Permission can be requested from either ISO at the address below
or ISO’s member body in the country of the requester.
ISO copyright office
CP 401 • Ch. de Blandonnet 8
CH-1214 Vernier, Geneva
Phone: +41 22 749 01 11
Email: copyright@iso.org
Website: www.iso.org
Published in Switzerland
ii
Contents Page
Foreword .iv
Introduction .v
1 Scope . 1
2 Normative references . 1
3 Terms and definitions . 2
4 Classification and designation . 2
4.1 Classification . 2
4.2 Designation . 2
5 Requirements and test methods . 3
5.1 Appearance . 3
5.2 Technical requirements . 3
6 Sampling . 4
7 Marking and labelling . 4
8 Test report . 4
Bibliography . 5
iii
Foreword
ISO (the International Organization for Standardization) is a worldwide federation of national standards
bodies (ISO member bodies). The work of preparing International Standards is normally carried out
through ISO technical committees. Each member body interested in a subject for which a technical
committee has been established has the right to be represented on that committee. International
organizations, governmental and non-governmental, in liaison with ISO, also take part in the work.
ISO collaborates closely with the International Electrotechnical Commission (IEC) on all matters of
electrotechnical standardization.
The procedures used to develop this document and those intended for its further maintenance are
described in the ISO/IEC Directives, Part 1. In particular, the different approval criteria needed for the
different types of ISO documents should be noted. This document was drafted in accordance with the
editorial rules of the ISO/IEC Directives, Part 2 (see www.iso.org/directives).
Attention is drawn to the possibility that some of the elements of this document may be the subject of
patent rights. ISO shall not be held responsible for identifying any or all such patent rights. Details of
any patent rights identified during the development of the document will be in the Introduction and/or
on the ISO list of patent declarations received (see www.iso.org/patents).
Any trade name used in this document is information given for the convenience of users and does not
constitute an endorsement.
For an explanation of the voluntary nature of standards, the meaning of ISO specific terms and
expressions related to conformity assessment, as well as information about ISO's adherence to
the World Trade Organization (WTO) principles in the Technical Barriers to Trade (TBT), see
www.iso.org/iso/foreword.html.
This document was prepared by Technical Committee ISO/TC 256, Pigments, dyestuffs and extenders.
A list of all parts in the ISO 18473 series can be found on the ISO website.
Any feedback or questions on this document should be directed to the user’s national standards body. A
complete listing of these bodies can be found at www.iso.org/members.html
iv
Introduction
Metal nanoparticles are promising materials as the heterogeneous catalyst in a variety of organic
transformations. Their catalytic properties are functions of their size and crystal lattice parameters,
and they show amazing levels of performance in terms of selectivity, activity and improved yield of
products. In particular, nanoscale titanium dioxide (TiO ) particles exhibited many special properties
because the band gap of the nanoparticles increased with the decrease in size. The use of TiO
nanoparticles has received considerable attention in green synthetic organic chemistry, decomposition
and removal of air and water contaminants, deodorization, and antibacterial, antifungal, self-cleaning
and antifogging actions.
v
INTERNATIONAL STANDARD ISO 18473-4:2022(E)
Functional pigments and extenders for special
applications —
Part 4:
Nanoscale titanium dioxide for photocatalytic application
1 Scope
This document specifies requirements and corresponding test methods for nanoscale titanium dioxide
(TiO ) in either powder or suspension form for photocatalytic application.
This document is applicable to modified nanoscale titanium dioxide for photocatalytic application.
NOTE Such modification can be surface treatment, coating, doping and combination thereof.
2 Normative references
The following documents are referred to in the text in such a way that some or all of their content
constitutes requirements of this document. For dated references, only the edition cited applies. For
undated references, the latest edition of the referenced document (including any amendments) applies.
ISO 591-1:2000, Titanium dioxide pigments for paints — Part 1: Specifications and methods of test
ISO 787-2, General methods of test for pigments and extenders — Part 2: Determination of matter volatile
at 105 °C
ISO 787-9, General methods o
...

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