EN ISO 14184-3:2023

SLOVENSKI STANDARD
01-februar-2024
Tekstilije - Določevanje formaldehida - 3. del: Prosti in hidrolizirani formaldehid
(ekstrakcijska metoda) s tekočinsko kromatografijo (ISO 14184-3:2023)
Textiles - Determination of formaldehyde - Part 3: Free and hydrolysed formaldehyde
(extraction method) by liquid chromatography (ISO 14184-3:2023)
Textilien - Bestimmung des Gehaltes an Formaldehyd - Teil 3: Freier und hydrolisierter
Formaldehyd (Extraktionsverfahren) mittels Flüssigkeitschromatographie (ISO 14184-
3:2023)
Textiles - Dosage du formaldéhyde - Partie 3: Formaldéhyde libre et hydrolysé (méthode
par extraction) par chromatographie liquide (ISO 14184-3:2023)
Ta slovenski standard je istoveten z: EN ISO 14184-3:2023
ICS:
59.080.01 Tekstilije na splošno Textiles in general
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.

EN ISO 14184-3
EUROPEAN STANDARD
NORME EUROPÉENNE
December 2023
EUROPÄISCHE NORM
ICS 59.080.01
English Version
Textiles - Determination of formaldehyde - Part 3: Free
and hydrolysed formaldehyde (extraction method) by
liquid chromatography (ISO 14184-3:2023)
Textiles - Dosage du formaldéhyde - Partie 3: Textilien - Bestimmung des Gehaltes an Formaldehyd -
Formaldéhyde libre et hydrolysé (méthode par Teil 3: Freier und hydrolisierter Formaldehyd
extraction) par chromatographie liquide (ISO 14184- (Extraktionsverfahren) mittels
3:2023) Flüssigkeitschromatographie (ISO 14184-3:2023)
This European Standard was approved by CEN on 27 November 2023.

CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this
European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references
concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN
member.
This European Standard exists in three official versions (English, French, German). A version in any other language made by
translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management
Centre has the same status as the official versions.

CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,
Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway,
Poland, Portugal, Republic of North Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Türkiye and
United Kingdom.
EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION

EUROPÄISCHES KOMITEE FÜR NORMUNG

CEN-CENELEC Management Centre: Rue de la Science 23, B-1040 Brussels
© 2023 CEN All rights of exploitation in any form and by any means reserved Ref. No. EN ISO 14184-3:2023 E
worldwide for CEN national Members.

Contents Page
European foreword . 3

European foreword
This document (EN ISO 14184-3:2023) has been prepared by Technical Committee ISO/TC 38
"Textiles" in collaboration with Technical Committee CEN/TC 248 “Textiles and textile products” the
secretariat of which is held by BSI.
This European Standard shall be given the status of a national standard, either by publication of an
identical text or by endorsement, at the latest by June 2024, and conflicting national standards shall be
withdrawn at the latest by June 2024.
Attention is drawn to the possibility that some of the elements of this document may be the subject of
patent rights. CEN shall not be held responsible for identifying any or all such patent rights.
Any feedback and questions on this document should be directed to the users’ national standards
body/national committee. A complete listing of these bodies can be found on the CEN website.
According to the CEN-CENELEC Internal Regulations, the national standards organizations of the
following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria,
Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland,
Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Republic of
North Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Türkiye and the
United Kingdom.
Endorsement notice
The text of ISO 14184-3:2023 has been approved by CEN as EN ISO 14184-3:2023 without any
modification.
INTERNATIONAL ISO
STANDARD 14184-3
First edition
2023-12
Textiles — Determination of
formaldehyde —
Part 3:
Free and hydrolysed formaldehyde
(extraction method) by liquid
chromatography
Textiles — Dosage du formaldéhyde —
Partie 3: Formaldéhyde libre et hydrolysé (méthode par extraction)
par chromatographie liquide
Reference number
ISO 14184-3:2023(E)
ISO 14184-3:2023(E)
© ISO 2023
All rights reserved. Unless otherwise specified, or required in the context of its implementation, no part of this publication may
be reproduced or utilized otherwise in any form or by any means, electronic or mechanical, including photocopying, or posting on
the internet or an intranet, without prior written permission. Permission can be requested from either ISO at the address below
or ISO’s member body in the country of the requester.
ISO copyright office
CP 401 • Ch. de Blandonnet 8
CH-1214 Vernier, Geneva
Phone: +41 22 749 01 11
Email: copyright@iso.org
Website: www.iso.org
Published in Switzerland
ii
ISO 14184-3:2023(E)
Contents Page
Foreword .iv
1 Scope . 1
2 Normative references . 1
3 Terms and definitions . 1
4 Conformity . . 1
5 Principle . 1
6 Reagents . 2
7 Apparatus . 3
8 Preparation of test specimen . 3
9 Procedure .3
9.1 Formaldehyde stock solution . . 3
9.1.1 Preparation of formaldehyde stock solution . 3
9.1.2 Determination of the formaldehyde concentration in the stock solution . 4
9.2 Determination of formaldehyde . 4
9.2.1 Calibration of LC . 4
9.2.2 Extraction of the test specimen . 5
9.2.3 Derivatization with DNPH and analysis . 5
10 Expression of results . 6
10.1 Calculation of the formaldehyde content in textile test specimen . 6
10.2 Spiking — Determination of recovery rate . 6
10.3 Precision of the test method . 6
11 Test report . 7
Annex A (informative) Information on precision of the test method . 8
Annex B (informative) Examples of chromatographic and spectroscopic conditions .10
Bibliography .13
iii
ISO 14184-3:2023(E)
Foreword
ISO (the International Organization for Standardization) is a worldwide federation of national standards
bodies (ISO member bodies). The work of preparing International Standards is normally carried out
through ISO technical committees. Each member body interested in a subject for which a technical
committee has been established has the right to be represented on that committee. International
organizations, governmental and non-governmental, in liaison with ISO, also take part in the work.
ISO collaborates closely with the International Electrotechnical Commission (IEC) on all matters of
electrotechnical standardization.
The procedures used to develop this document and those intended for its further maintenance are
described in the ISO/IEC Directives, Part 1. In particular, the different approval criteria needed for the
different types of ISO document should be noted. This document was drafted in accordance with the
editorial rules of the ISO/IEC Directives, Part 2 (see www.iso.org/directives).
ISO draws attention to the possibility that the implementation of this document may involve the use
of (a) patent(s). ISO takes no position concerning the evidence, validity or applicability of any claimed
patent rights in respect thereof. As of the date of publication of this document, ISO had not received
notice of (a) patent(s) which may be required to implement this document. However, implementers are
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database available at www.iso.org/patents. ISO shall not be held responsible for identifying any or all
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Any trade name used in this document is information given for the convenience of users and does not
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www.iso.org/iso/foreword.html.
This document was prepared by Technical Committee ISO/TC 38, Textiles, in collaboration with the
European Committee for Standardization (CEN) Technical Committee CEN/TC 248, Textiles and textile
products, in accordance with the Agreement on technical cooperation between ISO and CEN (Vienna
Agreement).
A list of all parts in the ISO 14184 series can be found on the ISO website.
Any feedback or questions on this document should be directed to the user’s national standards body. A
complete listing of these bodies can be found at www.iso.org/members.html.
iv
INTERNATIONAL STANDARD ISO 14184-3:2023(E)
Textiles — Determination of formaldehyde —
Part 3:
Free and hydrolysed formaldehyde (extraction method) by
liquid chromatography
WARNING — The use of this document can involve hazardous materials, operations and
equipment. It does not purport to address all of the safety or environmental problems associated
with its use. It refers only to technical suitability. It is the responsibility of the user to determine
any legal obligations relating to health and safety, at any stage, prior to use. It has been assumed
in the drafting of this document that the execution of its provisions is entrusted to appropriately
qualified and exper
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