EN 17131-1:2025
(Main)Textiles and textile products - Determination of certain residual solvents - Part 1: Determination of aprotic solvents, method using gas chromatography
Textiles and textile products - Determination of certain residual solvents - Part 1: Determination of aprotic solvents, method using gas chromatography
This document specifies a method using gas chromatography with mass selective detector (GC-MS) for detection and quantification of extractable N,N-dimethylformamide (DMF), N,N-dimethylacetamide (DMAC), N-methyl-2-pyrrolidone (NMP) and N-ethyl-2-pyrrolidone (NEP) in filaments and coatings of textile products.
Textilien und textile Erzeugnisse - Bestimmung bestimmter Lösungsmittelrückstände – Teil 1: Bestimmung aprotischer Lösemittel, Verfahren mittels Gaschromatographie
Dieses Dokument legt ein Verfahren zum Nachweis und zur quantitativen Bestimmung von extrahierbarem N,N Dimethylformamid (DMF), N,N Dimethylacetamid (DMAC), N Methyl 2 pyrrolidon (NMP) und N Ethyl 2 pyrrolidon (NEP) in Filamenten und Beschichtungen von textilen Erzeugnissen unter Anwendung von Gaschromatographie mit massenselektivem Detektor (GC MS, en: gas chromatography with mass selective detector) fest.
Textiles et produits textiles - Détermination de certains solvants résiduels - Partie 1 : Détermination des solvants aprotiques, méthode par chromatographie en phase gazeuse
Le présent document spécifie une méthode utilisant la chromatographie en phase gazeuse à détecteur sélectif de masse (CG SM) pour la détection et la quantification de N,N-diméthylformamide (DMF), de N,N diméthylacétamide (DMAC), de N-méthyl-2-pyrrolidone (NMP) et de N éthyl 2 pyrrolidone (NEP) extractibles dans les filaments et revêtements de produits textiles.
Tekstilije in tekstilni izdelki - Ugotavljanje nekaterih preostalih topil - 1. del: Ugotavljanje aprotičnih topil, metoda z uporabo plinske kromatografije
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Standards Content (Sample)
SLOVENSKI STANDARD
01-februar-2026
Tekstilije in tekstilni izdelki - Ugotavljanje nekaterih preostalih topil - 1. del:
Ugotavljanje aprotičnih topil, metoda z uporabo plinske kromatografije
Textiles and textile products - Determination of certain residual solvents - Part 1:
Determination of aprotic solvents, method using gas chromatography
Textilien und textile Erzeugnisse - Bestimmung bestimmter Lösungsmittelrückstände –
Teil 1: Bestimmung aprotischer Lösungsmittel, Verfahren mittels Gaschromatographie
Textiles et produits textiles - Détermination de certains solvants résiduels - Partie 1 :
Détermination des solvants aprotiques, méthode par chromatographie en phase gazeuse
Ta slovenski standard je istoveten z: EN 17131-1:2025
ICS:
59.080.01 Tekstilije na splošno Textiles in general
71.040.50 Fizikalnokemijske analitske Physicochemical methods of
metode analysis
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.
EN 17131-1
EUROPEAN STANDARD
NORME EUROPÉENNE
December 2025
EUROPÄISCHE NORM
ICS 59.080.01 Supersedes EN 17131:2019
English Version
Textiles and textile products - Determination of certain
residual solvents - Part 1: Determination of aprotic
solvents, method using gas chromatography
Textiles et produits textiles - Détermination de certains Textilien und textile Erzeugnisse - Bestimmung
solvants résiduels - Partie 1 : Détermination des bestimmter Lösungsmittelrückstände - Teil 1:
solvants aprotiques, méthode par chromatographie en Bestimmung aprotischer Lösemittel, Verfahren mittels
phase gazeuse Gaschromatographie
This European Standard was approved by CEN on 19 October 2025.
CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this
European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references
concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN
member.
This European Standard exists in three official versions (English, French, German). A version in any other language made by
translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management
Centre has the same status as the official versions.
CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,
Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway,
Poland, Portugal, Republic of North Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Türkiye and
United Kingdom.
EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION
EUROPÄISCHES KOMITEE FÜR NORMUNG
CEN-CENELEC Management Centre: Rue de la Science 23, B-1040 Brussels
© 2025 CEN All rights of exploitation in any form and by any means reserved Ref. No. EN 17131-1:2025 E
worldwide for CEN national Members.
Contents Page
European foreword . 3
Introduction . 5
1 Scope . 6
2 Normative references . 6
3 Terms and definitions . 6
4 Principle . 6
5 Reagents . 6
6 Apparatus . 7
7 Preparation of test samples . 8
7.1 Sampling . 8
7.2 Preparation of test specimens . 8
8 Procedure. 8
8.1 Extraction . 8
8.2 Determination with GC-MS . 8
8.2.1 Preparation of the calibration solutions . 8
8.2.2 Determination with GC-MS . 8
9 Expression of results . 8
9.1 Calculation . 8
9.2 Limits of quantification of the test method . 9
9.3 Reliability of the test method . 9
10 Test report . 9
Annex A (informative) Example of instrumental conditions . 10
A.1 Measuring technique . 10
A.2 Chromatographic conditions . 10
A.3 MS conditions . 10
Annex B (informative) Reliability of the method . 12
Bibliography . 13
European foreword
This document (EN 17131-1:2025) has been prepared by Technical Committee CEN/TC 248 “Textiles
and textile products”, the secretariat of which is held by BSI.
This European Standard shall be given the status of a national standard, either by publication of an
identical text or by endorsement, at the latest by June 2026, and conflicting national standards shall be
withdrawn at the latest by June 2026.
Attention is drawn to the possibility that some of the elements of this document may be the subject of
patent rights. CEN shall not be held responsible for identifying any or all such patent rights.
This document supersedes EN 17131:2019.
This document includes the following significant technical changes with respect to EN 17131:2019:
— the title has been changed;
— N,N-dimethylacetamide (DMAC) and N-methyl-2-pyrrolidone (NMP) have been included in the
Introduction;
— Clause 1: The scope has been extended to include the analytes DMAC, NMP and N-ethyl-2-
pyrrolidone (NEP);
— Clause 5: DMAC, NMP and NEP have been added;
— 5.7: The descriptions of the preparation of stock solutions have been changed in order to consider
the additional analytes DMAC, NMP and NEP;
— 8.2: The description of the determination with GC-MS has been changed in order to consider the
additional analytes DMAC, NMP and NEP;
— 9.1: The headline has been added and the description of the calculation has been changed in order to
consider the additional analytes DMAC, NMP and NEP;
— 9.2 and 9.3: Precision of the method including the limit of quantification of the test method has been
added;
— Clause 10 has been rephrased;
— Annex A has been extended to include the analytes DMAC, NMP and NEP;
— Annex B: Reliability of the method has been added including certain statistical data of an
interlaboratory trial to determine the reliability of the method.
This document is Part 1 of the EN 17131 series of standards under the title Textiles and textile products
— Determination of certain residual solvents:
— Part 1: Determination of aprotic solvents, method using gas chromatography (this document);
— Part 2: Determination of benzene, method using headspace gas chromatography.
A list of all parts in a series can be found on the CEN website: www.cencenelec.eu.
Any feedback and questions on this document should be directed to the users’ national standards body.
A complete listing of these bodies can be found on the CEN website.
According to the CEN-CENELEC Internal Regulations, the national standards organisations of the
following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria, Croatia,
Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland,
Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Republic of North
Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Türkiye and the United
Kingdom.
Introduction
In Europe according to Regulation (EU) 2018/1513 amending Annex XVII to Regulation (EC) No
1907/2006 (REACH) by Entry 72 [1], (a) clothing or related accessories; (b) textiles other than clothing
which, under normal or reasonably foreseeable conditions of use, come into contact with human skin to
an extent similar to clothing; (c) footwear are not to be placed on the market after 1 November 2020, if
they contain more than 3 000 mg/kg of N,N-dimethylformamide (DMF), N,N-dimethylacetamide (DMAC)
or N-methyl-2-pyrrolidone (NMP).
This restriction does not apply to: (a) clothing, related accessories or footwear, or parts of clothing,
related accessories or footwear, made exclusively of natural leather, fur or hide; (b) non-textile fasteners
and non-textile decorative attachments; (c) second-hand clothing, related accessories, textiles other than
clothing or footwear; (d) wall-to-wall carpets and textile floor coverings for indoor use, rugs and runners.
It also does not apply to clothing, related accessories, textiles other than clothing, or footwear within the
scope of Regulation (EU) 2016/425 on personal protective equipment or Regulation (EU) 2017/745 on
medical devices. The restriction on textiles other than clothing does not apply to disposable textiles.
“Disposable textiles” means textiles that are designed to be used only once or for a limited time and are
not intended for subsequent use for the same or a similar purpose.
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