EN ISO 16000-10:2006

SLOVENSKI STANDARD
01-maj-2006
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SIST ENV 13419-2:2000
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Indoor air - Part 10: Determination of the emission of volatile organic compounds from
building products and furnishing - Emission test cell method (ISO 16000-10:2006)
Innenraumluftverunreinigungen - Teil 10: Bestimmung der Emission von flüchtigen
organischen Verbindungen aus Bauprodukten und Einrichtungsgegenständen -
Emissionsprüfzellen-Verfahren (ISO 16000-10:2006)
Air intérieur - Partie 10: Dosage de l'émission de composés organiques volatils de
produits de construction et d'objets d'équipement - Méthode de la cellule d'essai
d'émission (ISO 16000-10:2006)
Ta slovenski standard je istoveten z: EN ISO 16000-10:2006
ICS:
13.040.20 Kakovost okoljskega zraka Ambient atmospheres
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.

EUROPEAN STANDARD
EN ISO 16000-10
NORME EUROPÉENNE
EUROPÄISCHE NORM
February 2006
ICS 13.040.20 Supersedes ENV 13419-2:1999
English Version
Indoor air - Part 10: Determination of the emission of volatile
organic compounds from building products and furnishing -
Emission test cell method (ISO 16000-10:2006)
Air intérieur - Partie 10: Dosage de l'émission de composés Innenraumluftverunreinigungen - Teil 10: Bestimmung der
organiques volatils de produits de construction et d'objets Emission von flüchtigen organischen Verbindungen aus
d'équipement - Méthode de la cellule d'essai d'émission Bauprodukten und Einrichtungsgegenständen -
(ISO 16000-10:2006) Emissionsprüfzellen-Verfahren (ISO 16000-10:2006)
This European Standard was approved by CEN on 16 January 2006.
CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European
Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national
standards may be obtained on application to the Central Secretariat or to any CEN member.
This European Standard exists in three official versions (English, French, German). A version in any other language made by translation
under the responsibility of a CEN member into its own language and notified to the Central Secretariat has the same status as the official
versions.
CEN members are the national standards bodies of Austria, Belgium, Cyprus, Czech Republic, Denmark, Estonia, Finland, France,
Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania,
Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom.
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EUROPÄISCHES KOMITEE FÜR NORMUNG
Management Centre: rue de Stassart, 36  B-1050 Brussels
© 2006 CEN All rights of exploitation in any form and by any means reserved Ref. No. EN ISO 16000-10:2006: E
worldwide for CEN national Members.

Foreword
This document (EN ISO 16000-10:2006) has been prepared by Technical Committee CEN/TC
264 "Air quality", the secretariat of which is held by DIN, in collaboration with Technical
Committee ISO/TC 146 "Air quality".

This European Standard shall be given the status of a national standard, either by publication of
an identical text or by endorsement, at the latest by August 2006, and conflicting national
standards shall be withdrawn at the latest by August 2006.

This document supersedes ENV 13419-2:1999.

According to the CEN/CENELEC Internal Regulations, the national standards organizations of
the following countries are bound to implement this European Standard: Austria, Belgium,
Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary,
Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland,
Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom.

INTERNATIONAL ISO
STANDARD 16000-10
First edition
2006-02-01
Indoor air —
Part 10:
Determination of the emission of volatile
organic compounds from building
products and furnishing — Emission test
cell method
Air intérieur —
Partie 10: Dosage de l'émission de composés organiques volatils de
produits de construction et d'objets d'équipement — Méthode de la
cellule d'essai d'émission
Reference number
ISO 16000-10:2006(E)
©
ISO 2006
ISO 16000-10:2006(E)
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ii © ISO 2006 – All rights reserved

ISO 16000-10:2006(E)
Contents Page
Foreword. iv
Introduction . vi
1 Scope .1
2 Normative references .1
3 Terms and definitions .1
4 Symbols and abbreviated terms .3
5 Principle.4
6 Emission test cell system .4
7 Apparatus .5
8 Test conditions .5
9 Verification of the test conditions.6
10 Test specimens.7
11 Emission test cell preparation.7
12 Test method.8
13 Calculation of area specific emission rates and expression of results.8
14 Performance characteristics .9
15 Test report .9
Annex A (normative) System for quality assurance/quality control.11
Annex B (informative) Examples of area specific air flow rates in a model room.13
Annex C (informative) Example of an emission test cell.14
Bibliography .16

ISO 16000-10:2006(E)
Foreword
ISO (the International Organization for Standardization) is a worldwide federation of national standards bodies
(ISO member bodies). The work of preparing International Standards is normally carried out through ISO
technical committees. Each member body interested in a subject for which a technical committee has been
established has the right to be represented on that committee. International organizations, governmental and
non-governmental, in liaison with ISO, also take part in the work. ISO collaborates closely with the
International Electrotechnical Commission (IEC) on all matters of electrotechnical standardization.
International Standards are drafted in accordance with the rules given in the ISO/IEC Directives, Part 2.
The main task of technical committees is to prepare International Standards. Draft International Standards
adopted by the technical committees are circulated to the member bodies for voting. Publication as an
International Standard requires approval by at least 75 % of the member bodies casting a vote.
Attention is drawn to the possibility that some of the elements of this document may be the subject of patent
rights. ISO shall not be held responsible for identifying any or all such patent rights.
ISO 16000-10 was prepared by the European Committee for Standardization (CEN) Technical Committee
CEN/TC 264, Air quality, in collaboration with Technical Committee ISO/TC 146, Air quality, Subcommittee
SC 6, Indoor air, in accordance with the Agreement on technical cooperation between ISO and CEN (Vienna
Agreement).
ISO 16000 consists of the following parts, under the general title Indoor air:
— Part 1: General aspects of sampling strategy
— Part 2: Sampling strategy for formaldehyde
— Part 3: Determination of formaldehyde and other carbonyl compounds — Active sampling method
— Part 4: Determination of formaldehyde — Diffusive sampling method
— Part 5: Measurement strategy for volatile organic compounds (VOCs)
— Part 6: Determination of volatile organic compounds in indoor and test chamber air by active sampling on
Tenax TA sorbent, thermal desorption and gas chromatography using MS/FID
— Part 7: Sampling strategy for determination of airborne asbestos fibre concentrations
— Part 8: Determination of local mean ages of air in buildings for characterizing ventilation conditions
— Part 9: Determination of the emission of volatile organic compounds from building products and
furnishing — Emission test chamber method
— Part 10: Determination of the emission of volatile organic compounds from building products and
furnishing — Emission test cell method
— Part 11: Determination of the emission of volatile organic compounds from building products and
furnishing — Sampling, storage of samples and preparation of test specimens
The following parts are under preparation:
— Part 12: Sampling strategy for polycyclic aromatic hydrocarbons (PAHs), polychlorinated dibenzo-p-
dioxins (PCDDs), polychlorinated dibenzo-furans (PCDFs) and polychlorinated biphenyls (PCBs)
iv © ISO 2006 – All rights reserved

ISO 16000-10:2006(E)
— Part 13: Determination of total (gas and particle-phase) polychlorinated dioxin-like biphenyls and
polychlorinated dibenzo-p-dioxins/dibenzofurans — Collection on sorbent-backed filters with high-
resolution gas chromatographic/mass spectrometric analysis
— Part 14: Sampling strategy for nitrogen dioxide (NO )
— Part 15: Measurement of nitrogen dioxide (NO )
— Part 16: Detection and enumeration of moulds — Sampling of moulds by filtration
— Part 17: Detection and enumeration of moulds — Culture-based method
ISO 16000-10:2006(E)
Introduction
The determination of volatile organic compounds (VOCs) emitted from building products using emission test
cells in conjunction with the standardised sampling, storage of samples and preparation of test specimens has
objectives such as:
⎯ to provide manufacturers, builders, and end users with emission data useful for the evaluation of the
impact of building products on the indoor air quality;
⎯ to promote the development of improved products;
⎯ on-site investigation of building product surfaces.
The method can in principle be used for most building products used indoors.

vi © ISO 2006 – All rights reserved

INTERNATIONAL STANDARD ISO 16000-10:2006(E)

Indoor air —
Part 10:
Determination of the emission of volatile organic compounds
from building products and furnishing — Emission test cell
method
1 Scope
This part of ISO 16000 specifies a general laboratory test method for determination of the area specific
emission rate of volatile organic compounds (VOCs) from newly produced building products or furnishing
under defined climate conditions. The method can in principle also be applied to aged products. The emission
data obtained can be used to calculate concentrations in a model room.
According to the definition of an emission test cell, it is also possible to perform non-destructive emission
measurements on building products on-site in buildings. However, the procedure for such measurements is
not described in this part of ISO 16000.
Sampling, transport and storage of materials to be tested, and preparation of test specimens are described in
ISO 16000-11. Air sampling and analytical methods for the determination of VOCs are described in
[20]
ISO 16000-6 and ISO 16017-1 .
An example of an emission test cell is described in Annex C of this part of ISO 16000.
[21]
For the determination of formaldehyde emissions from wood-based panels, refer to EN 717-1:2004 and
[1]
ISO 12460-1 . However, this part of ISO 16000 is also applicable to wood-based panels and other building
products in order to determine the emission rate of formaldehyde. The measurement procedure for
[2]
formaldehyde is described in ISO 16000-3 .
2 Normative references
The following referenced documents are indispensable for the application of this document. For dated
references, only the edition cited applies. For undated references, the latest edition of the referenced
document (including any amendments) applies.
ISO 554:1976, Standard atmospheres for conditioning and/or testing — Specifications
ISO 16000-11, Indoor air — Part 11: Determination of the emission of volatile organic compounds from
building products and furnishing — Sampling, storage of samples and preparation of test specimens
3 Terms and definitions
For the purposes of this document, the following terms and definitions apply.
3.1
air change rate
ratio of the volume of clean air brought into the emission test chamber per hour and the free emission test
chamber volume measured in identical units
ISO 16000-10:2006(E)
3.2
air flow rate
air volume entering into the emission test cell per time
3.3
air velocity
air speed over the surface of the test specimen
3.4
area specific air flow rate
ratio between the supply air flow rate and the area of the test specimen
3.5
building product
product produced for incorporation in a permanent manner in construction works
3.6
emission test cell
a small chamber for the determination of volatile organic compounds emitted from indoor materials/products
that is placed on the surface of the test specimen and is designed so that the surface of the test specimen
becomes a part of the emission cell
3.7
emission test cell concentration
concentration of a specific volatile organic compound, VOC , (or groups of volatile organic compounds)
x
measured in the emission test cell outlet
3.8
product loading factor
ratio of exposed surface area of the test specimen and the free emission test cell volume
3.9
recovery
measured mass of a target volatile organic compound in the air leaving the emission test cell during a given
time period divided by the mass of target volatile organic compound added to the emission test cell in the
same time period, expressed in percent
NOTE The recovery provides information about the performance of the entire method.
3.10
sample
part or piece of a building product that is representative of the production
3.11
specific emission rate
q
m
product specific rate describing the mass of a volatile organic compound emitted from a product per time at a
given time from the start of the test
NOTE 1 Area specific emission rate, q , is used in this part of ISO 16000. It describes the emitted volatile organic
A
compounds per exposed area per time. (For other specific emission rates see Clause 4.)
NOTE 2 The term area specific emission rate is sometimes used in parallel with the term emission factor.
3.12
target volatile organic compound
product specific volatile organic compound
2 © ISO 2006 – All rights reserved

ISO 16000-10:2006(E)
3.13
test specimen
part of the sample specially prepared for emission testing in an emission test cell in order to simulate the
emission behaviour of the material or product that is tested
3.14
total volatile organic compounds
TVOC
sum of the concentrations of identified and unidentified volatile organic compounds eluting between and
including n-hexane and n-hexadecane
NOTE 1 For quantification of the identified compounds, their individual responses are used. The areas of the
[3]
unidentified peaks are converted on molecular mass basis to concentrations using the toluene response factor .
NOTE 2 Due to practical reasons to taken into account for emission test chambers, this definition differs slightly from
®1)
that in ISO 16000-6:2004. In ISO 16000-6, TVOC are related to the sampling medium Tenax TA on which the TVOC
are adsorbed.
3.15
volatile organic compound
VOC
organic compound that is emitted from the test specimen and all those detected in the test cell outlet air
NOTE 1 Due to practical reasons to be taken into account for emission test chambers, this definition differs from that in
ISO 16000-6:2004. In ISO 16000-6, the definition is based on the boiling point range (50 °C to 100 °C) to (240 °C to
260 °C).
NOTE 2 The emission test method described in this part of ISO 16000 is optimum for the range of compounds
specified by the definition of total volatile organic compounds (TVOC).
4 Symbols and abbreviated terms
The symbols and abbreviated terms used in this part of ISO 16000 are given below.
Symbol Name Unit
ρ mass concentration of a VOC in the emission test cell micrograms per cubic metre
x x
L product loading factor square metres per cubic metre
n air change rate changes per hour
q area specific air flow rate (= n/L) cubic metres per square metre and hour
q area specific emission rate micrograms per square metre and hour
A
q length specific emission rate micrograms per metre and hour
l
q mass specific emission rate micrograms per gram and hour
m
q volume specific emission rate micrograms per cubic metre and hour
V
q unit specific emission rate micrograms per unit and hour
u
t time after start of the test hours or days
®
1) Tenax TA is the trade name of a product manufactured by Supelco, Inc. This information is given for the
convenience of users of this part of ISO 16000 and does not constitute an endorsement by ISO of the product named.
Equivalent products may be used if they can be shown to lead to the same results.
ISO 16000-10:2006(E)
5 Principle
The principle of the test is to determine the area specific emission rates of VOCs emitted from the surface of a
product test specimen. The test is performed in an emission test cell at constant temperature, relative air
humidity, and area specific air flow rate. Measurements of the VOC concentration in the air at the outlet are
representative of the air in the emission test cell.
Area specific emission rates at a given time, t, are calculated from the emission test cell air concentrations
and the area specific air flow rate, q (see Clause 13).
With knowledge of the concentration in the air, the air flow through the emission test cell, and the surface area
of the test specimen, the area specific emission rates of VOCs from the product under test can be determined.
6 Emission test cell system
6.1 General
An emission test cell system designed and operated to determine area specific emission rates of VOCs from
building products shall contain the following: emission test cell, clean air generation and humidification
system, monitoring and control systems, to ensure that the test is carried out according to specified
[4], [5], [6], [7]
conditions .
For solid products with smooth surface, the emission test cell is placed directly against the surface of the
product test specimen. To secure air tightness, other products shall be placed in specially constructed test
specimen holders.
General specifications and requirements that apply to all types of emission test cells in this part of ISO 16000
are given in 6.2 to 6.6 below.
Quality assurance / quality control activities shall be carried out as in Annex A.
6.2 Emission test cell materials
The emission test cell and the parts of the sampling system coming in contact with the emitted VOCs (all
tubings and couplings) are normally made of surface treated (polished) stainless steel or glass. However, in all
cases the requirements in 6.3 and 6.5 shall be fulfilled.
The sealing material that links together the emission test cell and the test specimen shall be low emitting and
low adsorbing and shall not contribute to the emission test cell background concentration.
6.3 Air supply
The emission test cell shall be supplied with pure and humidified air and have a device for controlling the air
flow rate with an accuracy of ± 5 %.
6.4 Air tightness
The emission test cell shall be airtight in order to avoid uncontrolled air exchange with external air.
The emission test cell shall be operated slightly above atmospheric pressure to avoid any influence from the
laboratory atmosphere.
The emission test cell is considered sufficiently tight if the inlet and outlet air f
...