CEN/TS 16645:2014
(Main)Ambient air - Method for the measurement of benz[a]anthracene, benzo[b]fluoranthene, benzo[j]fluoranthene, benzo[k]fluoranthene, dibenz[a,h]anthracene, indeno[1,2,3-cd]pyrene and benzo[ghi]perylene
Ambient air - Method for the measurement of benz[a]anthracene, benzo[b]fluoranthene, benzo[j]fluoranthene, benzo[k]fluoranthene, dibenz[a,h]anthracene, indeno[1,2,3-cd]pyrene and benzo[ghi]perylene
This Technical Specification specifies a measurement method for the determination of the particle bound polycyclic aromatic hydrocarbon (PAH) compounds benz[a]anthracene (BaA), benzo[b]fluoranthene (BbF), benzo[j]fluoranthene (BjF), benzo[k]fluoranthene (BkF), dibenz[a,h]anthracene (DBahA), indeno[1,2,3-cd]pyrene (INP) and benzo[ghi]perylene (BghiP) in ambient air, which can be used in the framework of Council Directive 2008/50/EC [10] and Directive 2004/107/EC [11]. This document specifies performance characteristics and performance criteria for this measurement method. The performance characteristics of the measurement method are based on a sampling period of 24 h.
This Technical Specification describes a measurement method which comprises sampling of the selected PAH compounds as part of the PM10 particles, sample extraction and analysis by high performance liquid chromatography (HPLC) with fluorescence detector (FLD) or by gas chromatography with mass spectrometric detection (GC-MS). The method is applicable for the measurement of the PAH compounds in the concentration range from approx. 0,04 ng/m3 to approximately 20 ng/m3 for BaA, BbF, BjF, BkF, BaP, INP and BghiP and 0,02 ng/m3 to approximately 2 ng/m3 for DBahA. Table 1 shows examples for concentrations of the compounds (annual mean values) for sampling sites with different characteristics.
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The lower limit of the applicable range depends on the noise level of the detector and the variability of the laboratory filter blank.
Außenluft - Verfahren zur Messung von Benz[a]anthracen, Benzo[b]fluoranthen, Benzo[j]fluoranthen, Benzo[k]fluoranthen, Dibenz[a,h]anthracen, Indeno[1,2,3-cd]pyren und Benzo[ghi]perylen
Diese Technische Spezifikation legt ein Messverfahren zur Bestimmung der partikelgebundenen polyzyklischen aromatischen Kohlenwasserstoffverbindungen (PAH) Benz[a]anthracen (BaA), Benzo[b]fluoranthen (BbF), Benzo[j]fluoranthen (BjF), Benzo[k]fluoranthen (BkF), Dibenz[a,h]anthracen (DBahA), Indeno[1,2,3-cd]pyren (INP) und Benzo[ghi]perylen (BghiP) in Außenluft fest, das im Zusammenhang mit den Richtlinien 2008/50/EG [10] und 2004/107/EG [11] angewendet werden kann. Außerdem werden für das Mess¬verfahren Leistungskenngrößen und Leistungs¬kriterien festgelegt, die auf einer Probenahmedauer von 24 h beruhen.
Diese Technische Spezifikation beschreibt ein Messverfahren, das die Probenahme der ausgewählten PAH-Verbindungen als Bestandteil des PM10, die Probenextraktion und die Analyse mit Hochleistungs-Flüssigkeits¬chromato¬graphie (HPLC) in Kombination mit einem Fluoreszenzdetektor (FLD) oder mit Gaschromatographie in Kombination mit massen¬spektro¬metrischer Detektion (GC/MS) umfasst. Das Verfahren ist anwendbar im Konzentrationsbereich von etwa 0,04 ng/m3 bis etwa 20 ng/m3 für BaA, BbF, BjF, BkF, BaP, INP und BghiP sowie etwa 0,02 ng/m³ bis etwa 2 ng/m³ für DBahA. Tabelle 1 gibt Beispiele für die Konzentration dieser Verbindungen (Jahresmittelwerte) an unterschiedlich belasteten Probenahmestellen an.
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Die untere Grenze des Anwendungsbereichs hängt vom Rauschpegel des Detektors und der Streubreite des Laborfilterblindwerts ab.
Air ambiant - Méthode pour la mesure de benz[a]anthracène, benzo[b]fluoranthène, benzo[j]fluoranthène, benzo[k]fluoranthène, dibenz[a,h]anthracène, indeno[1,2,3-cd]pyrène et benzo[ghi]perylène
La présente Spécification technique spécifie une méthode de mesure pour la détermination de la concentration des hydrocarbures aromatiques polycycliques (HAP) particulaires suivants : benzo[a]anthracène (BaA), benzo[b]fluoranthène (BbF), benzo[j]fluoranthène (BjF), benzo[k]fluoranthène (BkF), dibenzo[a,h]anthracène (DBahA), indeno[1,2,3-cd]pyrène (INP) et benzo[ghi]pérylène (BghiP) dans l’air ambiant, qui peut être utilisée dans le cadre de la Directive 2008/50/CE [10] et de la Directive 2004/107/CE [11]. Le présent document spécifie les caractéristiques et les critères de performance relatifs à cette méthode de mesure. Les caractéristiques de performance de la méthode de mesure sont basées sur une période de prélèvement de 24 h.
La présente Spécification technique décrit une méthode de mesure qui comprend l’échantillonnage des HAP faisant partie intégrante des particules PM10, l’extraction et l’analyse des échantillons par chromatographie liquide haute performance (HPLC) avec détection par fluorescence (FLD) ou par chromatographie en phase gazeuse avec détection par spectroscopie de masse (GC-MS). La méthode est applicable au mesurage des HAP dans la gamme de concentration d’environ 0,04 ng/m3 à environ 20 ng/m3 pour le BaA, le BbF, le BjF, le BkF, le BaP, l’INP et le BghiP et de 0,02 ng/m3 à environ 2 ng/m3 pour le DBahA. Le Tableau 1 illustre des exemples de concentrations des composés (valeurs moyennes annuelles) sur des sites de prélèvement ayant des caractéristiques différentes.
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La limite inférieure de la gamme applicable dépend du niveau de bruit du détecteur et de la variabilité du blanc de filtre de laboratoire.
Zunanji zrak - Metoda za določevanje benzo[a]antracena, benzo[b]fluorantena, benzo[j]fluorantena, benzo[k]fluorantena, dibenzo[a,h]antracena, indeno[1,2,3-cd]pirena in benzo[ghi]perilena
CEN/TS 16645 podaja merilno metodo za določevanje vezanih policikličnih aromatskih spojin ogljikovodika (PAH), benzo[a]antracen (BaA), benzo[b]fluorantena (BbF), benzo[j]fluorantena (BjF), benzo[k]fluoranten (BkF), dibenzo[a,h]antracen (DBahA), indeno[1,2,3-cd]piren (INP) in benzo[ghi]perilen (BghiP) v zunanjem zraku, ki se lahko uporabi v okviru Direktive Sveta 2008/50/ES [10] in Direktive Sveta 2004/107/ES [11]. Ta dokument podaja značilnosti in kriterije glede zmogljivosti za to merilno metodo. Značilnosti glede zmogljivosti merilne metode so osnovane na obdobju vzorčenja 24 ur. Ta tehnična specifikacija opisuje merilno metodo, ki je sestavljena iz vzorčenja izbranih spojin ogljikovodika (PAH) kot del delcev PM10, vzorčne ekstrakcije in analize z visokozmogljivo tekočinsko kromatografijo (HPLC) s fluorescenčnim detektorjem (FLD) ali s plinsko kromatografijo z zaznavanjem masne spektrometrije (GC-MS). Ta metoda velja za merjenje spojin ogljikovodika (PAH) v razponu koncentracij od približno 0,04 ng/m3 do približno 20 ng/m3 za BaA, BbF, BjF, BkF, BaP, INP in BghiP ter od 0,02 ng/m3 do približno 2 ng/m3 za DBahA. Tabela 1 prikazuje primere koncentracij za spojine (letne povprečne vrednosti) za mesta vzorčenja z različnimi lastnostmi.
General Information
Standards Content (Sample)
SLOVENSKI STANDARD
01-julij-2014
=XQDQML]UDN0HWRGD]DGRORþHYDQMHEHQ]R>D@DQWUDFHQDEHQ]R>E@IOXRUDQWHQD
EHQ]R>M@IOXRUDQWHQDEHQ]R>N@IOXRUDQWHQDGLEHQ]R>DK@DQWUDFHQDLQGHQR>FG@
SLUHQDLQEHQ]R>JKL@SHULOHQD
Ambient air - Method for the measurement of benz[a]anthracene, benzo[b]fluoranthene,
benzo[j]fluoranthene, benzo[k]fluoranthene, dibenz[a,h]anthracene, indeno[1,2,3-cd]
pyrene and benzo[ghi]perylene
Außenluft - Verfahren zur Messung von Benz[a]anthracen, Benzo[b]fluoranthen, Benzo[j]
fluoranthen, Benzo[k]fluoranthen, Dibenz[a,h]anthracen, Indeno[1,2,3-cd]pyren und
Benzo[ghi]perylen
Air ambiant - Méthode pour la mesure de benz[a]anthracène, benzo[b]fluoranthène,
benzo[j]fluoranthène, benzo[k]fluoranthène, dibenz[a,h]anthracène, indeno[1,2,3-cd]
pyrène et benzo[ghi]perylène
Ta slovenski standard je istoveten z: CEN/TS 16645:2014
ICS:
13.040.20 Kakovost okoljskega zraka Ambient atmospheres
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.
TECHNICAL SPECIFICATION
CEN/TS 16645
SPÉCIFICATION TECHNIQUE
TECHNISCHE SPEZIFIKATION
April 2014
ICS 13.040.20
English Version
Ambient air - Method for the measurement of benz[a]anthracene,
benzo[b]fluoranthene, benzo[j]fluoranthene,
benzo[k]fluoranthene, dibenz[a,h]anthracene, indeno[1,2,3-
cd]pyrene and benzo[ghi]perylene
Air ambiant - Méthode pour la mesure de Außenluft - Verfahren zur Messung von Benz[a]anthracen,
benz[a]anthracène, benzo[b]fluoranthène, Benzo[b]fluoranthen, Benzo[j]fluoranthen,
benzo[j]fluoranthène, benzo[k]fluoranthène, Benzo[k]fluoranthen, Dibenz[a,h]anthracen, Indeno[1,2,3-
dibenz[a,h]anthracène, indeno[1,2,3-cd]pyrène et cd]pyren und Benzo[ghi]perylen
benzo[ghi]perylène
This Technical Specification (CEN/TS) was approved by CEN on 16 December 2013 for provisional application.
The period of validity of this CEN/TS is limited initially to three years. After two years the members of CEN will be requested to submit their
comments, particularly on the question whether the CEN/TS can be converted into a European Standard.
CEN members are required to announce the existence of this CEN/TS in the same way as for an EN and to make the CEN/TS available
promptly at national level in an appropriate form. It is permissible to keep conflicting national standards in force (in parallel to the CEN/TS)
until the final decision about the possible conversion of the CEN/TS into an EN is reached.
CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,
Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania,
Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and United
Kingdom.
EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION
EUROPÄISCHES KOMITEE FÜR NORMUNG
CEN-CENELEC Management Centre: Avenue Marnix 17, B-1000 Brussels
© 2014 CEN All rights of exploitation in any form and by any means reserved Ref. No. CEN/TS 16645:2014 E
worldwide for CEN national Members.
Contents Page
Foreword . 4
Introduction . 5
1 Scope . 6
2 Normative references . 7
3 Terms and definitions . 7
4 Symbols and abbreviations . 9
4.1 Symbols . 9
4.2 Abbreviations . 10
5 Principle of the method . 10
6 Requirements . 10
6.1 Siting requirements . 10
6.2 Sampling requirements . 11
6.3 Analysis . 11
7 Reagents and gases . 13
7.1 Solvents . 13
7.2 Gases . 13
7.3 External standard . 13
7.4 Internal standard . 13
7.5 Surrogate standard . 13
7.6 Stock standard solution . 13
7.7 Certified reference material . 13
8 Apparatus . 14
8.1 Sampling equipment . 14
8.2 Sample preparation/extraction . 14
8.3 Laboratory apparatus . 14
9 Sampling . 15
9.1 Preparation of the equipment before sampling . 15
9.2 Handling of filters . 15
9.3 Preparation of filters . 15
9.4 Sample collection, transport and storage . 16
10 Sample preparation . 16
10.1 Cleaning of the laboratory apparatus . 16
10.2 Extraction . 16
11 Analysis . 17
11.1 General . 17
11.2 HPLC/FLD analysis . 17
11.3 GC-MS analysis . 18
12 Quantification . 19
12.1 HPLC/FLD analysis . 19
12.2 GC-MS Analysis . 21
12.3 Concentration of the PAH compounds in ambient air . 22
13 Quality control . 23
13.1 Reagent blank check . 23
13.2 Calibration drift check. 23
13.3 Control solutions . 23
13.4 Recovery efficiency check . 23
13.5 Chromatographic interference check . 23
13.6 Laboratory filter blank check . 24
13.7 Field filter blank check . 24
13.8 External quality assessment . 24
14 Determination of measurement uncertainty . 24
14.1 Introduction . 24
14.2 Parameters contributing to measurement uncertainty . 25
14.3 Recommendations for use . 27
15 Interferences . 27
15.1 General . 27
15.2 HPLC/FLD method . 27
15.3 GC-MS method . 28
16 Reporting of results . 28
Annex A (informative) Sampling systems with oxidant denuder . 30
Annex B (informative) Extraction methods (examples of experimental conditions) . 33
Annex C (informative) Example for clean-up procedure . 35
Annex D (informative) Parameters for analysis (examples) . 36
Annex E (informative) Assessment of performance indicators and uncertainty contributions . 38
Annex F (informative) Calculation of uncertainty using interlaboratory comparison and field
validation data .
Bibliography . 51
Foreword
This document (CEN/TS 16645:2014) has been prepared by Technical Committee CEN/TC 264 “Air quality”,
the secretariat of which is held by DIN.
Attention is drawn to the possibility that some of the elements of this document may be the subject of patent
rights. CEN [and/or CENELEC] shall not be held responsible for identifying any or all such patent rights.
According to the CEN-CENELEC Internal Regulations, the national standards organizations of the following
countries are bound to announce this Technical Specification: Austria, Belgium, Bulgaria, Croatia, Cyprus,
Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany,
Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland,
Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and the United Kingdom.
Introduction
The measurement methods specified in this document are based on methods that were wo
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