Standard Practice for Testing and Sampling of Volatile Organic Compounds (Including Carbonyl Compounds) Emitted from Architectural Coatings Using Small-Scale Environmental Chambers

SIGNIFICANCE AND USE
5.1 Latex paints, alkyd paints, and primers are used as coatings for walls, wooden trim, and furnishings in occupied buildings. Paint may be applied to large surface areas and may be applied repeatedly during the lifetime of a building. VOCs are emitted from paint after application to surfaces.  
5.2 Many other types of architectural coatings may be used in large quantities indoors in buildings. In particular, many different types of coatings are used for floors including wood floor stains and finishes and concrete sealers, hardeners, and stains. Two component finishes are often mixed on site and are applied to floors and other surfaces to create a finished surface.  
5.3 There is a need for standardized procedures for measuring the emissions of VOCs from paint and coating samples that can be reproduced by different laboratories and that can used for the assessment of the acceptability of VOC emissions from paints and coatings that are intended for use indoors in occupied spaces. This practice describes standardized procedures that can be incorporated into test methods used for the purpose of estimating the impacts of cured paints and coatings on indoor air quality. Different procedures are required for the estimation of VOC exposures to workers applying such products.
SCOPE
1.1 This practice describes procedures for testing the emissions of volatile organic compounds (VOCs), formaldehyde, and other carbonyl compounds, from alkyd paint, latex paint, primer, and other architectural coating samples using a small-scale environmental chamber test facility.  
1.2 This practice describes the requirements for the chamber test facility, the small-scale test chamber, the clean air supply system, the environmental controls, the environmental monitoring and data acquisition system, and the chamber air sampling system.  
1.3 This practice describes procedures for documenting the paint and coating samples and for the handling and storage of these samples including splitting of samples into smaller containers for storage and subsequent testing.  
1.4 This practice identifies appropriate substrates to be used for the preparation of test specimens of paints and coatings, as well as procedures for preparing substrates for use.  
1.5 This practice provides detailed procedures for preparing test specimens of paint and coating samples.  
1.6 This practice generally describes chamber test procedures and chamber air sampling procedures. The details of these procedures are dependent upon the objectives of the test.  
1.7 This practice does not recommend specific methods for sampling and analysis of VOCs, formaldehyde, and other carbonyl compounds. The appropriate methods are dependent upon the objectives of the test.  
1.8 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.9 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.10 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

General Information

Status
Published
Publication Date
31-Jul-2019
Technical Committee
D22 - Air Quality
Drafting Committee
D22.05 - Indoor Air

Relations

Effective Date
01-Aug-2019
Effective Date
01-Jan-2024
Effective Date
01-Sep-2020
Effective Date
01-Jun-2020
Effective Date
01-Jun-2020
Effective Date
15-Mar-2020
Effective Date
01-Oct-2018
Effective Date
01-Nov-2017
Effective Date
01-Jul-2016
Effective Date
01-Nov-2015
Effective Date
15-Oct-2015
Effective Date
01-Jul-2015
Effective Date
01-Dec-2014
Effective Date
01-Dec-2014
Effective Date
15-Jun-2014

Overview

ASTM D6803-19, Standard Practice for Testing and Sampling of Volatile Organic Compounds (Including Carbonyl Compounds) Emitted from Architectural Coatings Using Small-Scale Environmental Chambers, is a widely recognized international standard developed by ASTM International. This standard outlines reproducible procedures for assessing emissions of volatile organic compounds (VOCs), formaldehyde, and other carbonyl compounds from interior paints, primers, and other architectural coatings applied in buildings. The goal is to enable consistent evaluation of products for impacts on indoor air quality, helping manufacturers, regulatory bodies, and building professionals make informed decisions regarding material selection and occupant safety.

Key Topics

  • Scope of Testing: This standard covers procedures for testing emissions from various architectural coatings, including latex and alkyd paints, primers, wood floor finishes, and concrete sealers.
  • Small-Scale Environmental Chambers: It defines requirements for chamber facilities, including clean air supply, environmental controls (temperature, humidity), and monitoring systems.
  • Sample Preparation and Handling: Provides detailed guidance on documenting, storing, and preparing paint and coating samples, ensuring accuracy and consistency in VOC measurement.
  • Substrate Selection and Preparation: Identifies appropriate substrate materials (e.g., gypsum board, wood, glass, concrete) and methods for their preparation, minimizing interference and maximizing relevance to real-world applications.
  • Test Procedures: Generalized practices for chamber operation, specimen preparation, and air sampling, allowing adaptation to different product types and objectives.
  • Data Collection and Quality Control: Emphasizes proper documentation, sample coding, storage, and conditions maintenance to ensure reliable and valid test results.

Applications

  • Indoor Air Quality Assessment: By measuring emissions from architectural coatings, organizations can predict and manage the impact of materials on indoor air quality, crucial for occupant health and regulatory compliance.
  • Product Comparison and Improvement: Standardized test methods allow manufacturers to compare VOC emissions across products, driving innovation towards lower-emitting, more environmentally friendly coatings.
  • Regulatory Approval and Labeling: Results generated using ASTM D6803-19 support claims of low-VOC or green-certified coatings and are often referenced in regulatory requirements or voluntary labeling programs.
  • Worker Exposure Evaluation: Though primarily focused on emissions after application, the practices support estimation of exposure for workers during application, informing safe handling practices.
  • Research and Development: Laboratories and institutions can use these methods to study material contributions to indoor air pollution, developing safer coatings and mitigation technologies.

Related Standards

  • ASTM D5116: Guide for Small-Scale Environmental Chamber Determinations of Organic Emissions from Indoor Materials/Products.
  • ASTM D6886: Test Method for Determination of the Weight Percent Individual Volatile Organic Compounds in Waterborne Air-Dry Coatings by Gas Chromatography.
  • ASTM D5197: Test Method for Determination of Formaldehyde and Other Carbonyl Compounds in Air (Active Sampler Methodology).
  • ASTM D1005 / D1212: Methods for measurement of dry/wet film thickness of coatings.
  • ASTM D6196 / D3686 / D3687: Practices relevant to sorbent selection, sampling, and VOC analysis in chamber emissions testing.
  • EPA TO-15 and TO-17: Compendium methods for the determination of toxic organic compounds in ambient air.
  • ASTM D8141: Guide for selecting emission testing methods for VOCs and SVOCs in the modeling of indoor environments.

Summary

ASTM D6803-19 facilitates the accurate and reproducible measurement of VOC and carbonyl compound emissions from architectural coatings. Its adoption supports improved indoor air quality, more sustainable building materials, and enhanced product stewardship. For stakeholders in coatings manufacturing, architecture, building construction, and environmental testing, adherence ensures reliable, comparable data critical for indoor environment safety and compliance.

Buy Documents

Standard

ASTM D6803-19 - Standard Practice for Testing and Sampling of Volatile Organic Compounds (Including Carbonyl Compounds) Emitted from Architectural Coatings Using Small-Scale Environmental Chambers

English language (7 pages)
sale 15% off
sale 15% off
Standard

REDLINE ASTM D6803-19 - Standard Practice for Testing and Sampling of Volatile Organic Compounds (Including Carbonyl Compounds) Emitted from Architectural Coatings Using Small-Scale Environmental Chambers

English language (7 pages)
sale 15% off
sale 15% off

Frequently Asked Questions

ASTM D6803-19 is a standard published by ASTM International. Its full title is "Standard Practice for Testing and Sampling of Volatile Organic Compounds (Including Carbonyl Compounds) Emitted from Architectural Coatings Using Small-Scale Environmental Chambers". This standard covers: SIGNIFICANCE AND USE 5.1 Latex paints, alkyd paints, and primers are used as coatings for walls, wooden trim, and furnishings in occupied buildings. Paint may be applied to large surface areas and may be applied repeatedly during the lifetime of a building. VOCs are emitted from paint after application to surfaces. 5.2 Many other types of architectural coatings may be used in large quantities indoors in buildings. In particular, many different types of coatings are used for floors including wood floor stains and finishes and concrete sealers, hardeners, and stains. Two component finishes are often mixed on site and are applied to floors and other surfaces to create a finished surface. 5.3 There is a need for standardized procedures for measuring the emissions of VOCs from paint and coating samples that can be reproduced by different laboratories and that can used for the assessment of the acceptability of VOC emissions from paints and coatings that are intended for use indoors in occupied spaces. This practice describes standardized procedures that can be incorporated into test methods used for the purpose of estimating the impacts of cured paints and coatings on indoor air quality. Different procedures are required for the estimation of VOC exposures to workers applying such products. SCOPE 1.1 This practice describes procedures for testing the emissions of volatile organic compounds (VOCs), formaldehyde, and other carbonyl compounds, from alkyd paint, latex paint, primer, and other architectural coating samples using a small-scale environmental chamber test facility. 1.2 This practice describes the requirements for the chamber test facility, the small-scale test chamber, the clean air supply system, the environmental controls, the environmental monitoring and data acquisition system, and the chamber air sampling system. 1.3 This practice describes procedures for documenting the paint and coating samples and for the handling and storage of these samples including splitting of samples into smaller containers for storage and subsequent testing. 1.4 This practice identifies appropriate substrates to be used for the preparation of test specimens of paints and coatings, as well as procedures for preparing substrates for use. 1.5 This practice provides detailed procedures for preparing test specimens of paint and coating samples. 1.6 This practice generally describes chamber test procedures and chamber air sampling procedures. The details of these procedures are dependent upon the objectives of the test. 1.7 This practice does not recommend specific methods for sampling and analysis of VOCs, formaldehyde, and other carbonyl compounds. The appropriate methods are dependent upon the objectives of the test. 1.8 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard. 1.9 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. 1.10 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE 5.1 Latex paints, alkyd paints, and primers are used as coatings for walls, wooden trim, and furnishings in occupied buildings. Paint may be applied to large surface areas and may be applied repeatedly during the lifetime of a building. VOCs are emitted from paint after application to surfaces. 5.2 Many other types of architectural coatings may be used in large quantities indoors in buildings. In particular, many different types of coatings are used for floors including wood floor stains and finishes and concrete sealers, hardeners, and stains. Two component finishes are often mixed on site and are applied to floors and other surfaces to create a finished surface. 5.3 There is a need for standardized procedures for measuring the emissions of VOCs from paint and coating samples that can be reproduced by different laboratories and that can used for the assessment of the acceptability of VOC emissions from paints and coatings that are intended for use indoors in occupied spaces. This practice describes standardized procedures that can be incorporated into test methods used for the purpose of estimating the impacts of cured paints and coatings on indoor air quality. Different procedures are required for the estimation of VOC exposures to workers applying such products. SCOPE 1.1 This practice describes procedures for testing the emissions of volatile organic compounds (VOCs), formaldehyde, and other carbonyl compounds, from alkyd paint, latex paint, primer, and other architectural coating samples using a small-scale environmental chamber test facility. 1.2 This practice describes the requirements for the chamber test facility, the small-scale test chamber, the clean air supply system, the environmental controls, the environmental monitoring and data acquisition system, and the chamber air sampling system. 1.3 This practice describes procedures for documenting the paint and coating samples and for the handling and storage of these samples including splitting of samples into smaller containers for storage and subsequent testing. 1.4 This practice identifies appropriate substrates to be used for the preparation of test specimens of paints and coatings, as well as procedures for preparing substrates for use. 1.5 This practice provides detailed procedures for preparing test specimens of paint and coating samples. 1.6 This practice generally describes chamber test procedures and chamber air sampling procedures. The details of these procedures are dependent upon the objectives of the test. 1.7 This practice does not recommend specific methods for sampling and analysis of VOCs, formaldehyde, and other carbonyl compounds. The appropriate methods are dependent upon the objectives of the test. 1.8 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard. 1.9 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. 1.10 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

ASTM D6803-19 is classified under the following ICS (International Classification for Standards) categories: 87.040 - Paints and varnishes. The ICS classification helps identify the subject area and facilitates finding related standards.

ASTM D6803-19 has the following relationships with other standards: It is inter standard links to ASTM D6803-13, ASTM D16-24, ASTM D1356-20a, ASTM D1212-91(2020), ASTM D1005-95(2020), ASTM D1356-20, ASTM D6886-18, ASTM D5116-17, ASTM D16-16, ASTM D6196-15, ASTM D1356-15a, ASTM D1356-15, ASTM D16-14, ASTM D1356-14b, ASTM D6886-14e1. Understanding these relationships helps ensure you are using the most current and applicable version of the standard.

ASTM D6803-19 is available in PDF format for immediate download after purchase. The document can be added to your cart and obtained through the secure checkout process. Digital delivery ensures instant access to the complete standard document.

Standards Content (Sample)


This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the
Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
Designation: D6803 − 19
Standard Practice for
Testing and Sampling of Volatile Organic Compounds
(Including Carbonyl Compounds) Emitted from Architectural
Coatings Using Small-Scale Environmental Chambers
This standard is issued under the fixed designation D6803; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope priate safety, health, and environmental practices and deter-
mine the applicability of regulatory limitations prior to use.
1.1 This practice describes procedures for testing the emis-
1.10 This international standard was developed in accor-
sions of volatile organic compounds (VOCs), formaldehyde,
dance with internationally recognized principles on standard-
and other carbonyl compounds, from alkyd paint, latex paint,
ization established in the Decision on Principles for the
primer, and other architectural coating samples using a small-
Development of International Standards, Guides and Recom-
scale environmental chamber test facility.
mendations issued by the World Trade Organization Technical
1.2 Thispracticedescribestherequirementsforthechamber
Barriers to Trade (TBT) Committee.
test facility, the small-scale test chamber, the clean air supply
system, the environmental controls, the environmental moni- 2. Referenced Documents
toring and data acquisition system, and the chamber air 2
2.1 ASTM Standards:
sampling system.
D16 TerminologyforPaint,RelatedCoatings,Materials,and
1.3 This practice describes procedures for documenting the Applications
paint and coating samples and for the handling and storage of D1005 Test Method for Measurement of Dry-Film Thick-
these samples including splitting of samples into smaller ness of Organic Coatings Using Micrometers
containers for storage and subsequent testing. D1212 Test Methods for Measurement of Wet Film Thick-
ness of Organic Coatings
1.4 This practice identifies appropriate substrates to be used
D1356 Terminology Relating to Sampling and Analysis of
for the preparation of test specimens of paints and coatings, as
Atmospheres
well as procedures for preparing substrates for use.
D3687 Practice for Analysis of Organic Compound Vapors
1.5 This practice provides detailed procedures for preparing
Collected by the Activated Charcoal Tube Adsorption
test specimens of paint and coating samples.
Method
1.6 This practice generally describes chamber test proce- D5116 Guide for Small-Scale Environmental Chamber De-
terminations of Organic Emissions from Indoor Materials/
dures and chamber air sampling procedures. The details of
these procedures are dependent upon the objectives of the test. Products
D5197 Test Method for Determination of Formaldehyde and
1.7 This practice does not recommend specific methods for
OtherCarbonylCompoundsinAir(ActiveSamplerMeth-
sampling and analysis of VOCs, formaldehyde, and other
odology)
carbonyl compounds. The appropriate methods are dependent
D5466 Test Method for Determination of Volatile Organic
upon the objectives of the test.
Compounds in Atmospheres (Canister Sampling Method-
1.8 The values stated in SI units are to be regarded as
ology)
standard. No other units of measurement are included in this
D6196 Practice for Choosing Sorbents, Sampling Param-
standard.
eters and Thermal Desorption Analytical Conditions for
1.9 This standard does not purport to address all of the Monitoring Volatile Organic Chemicals in Air
safety concerns, if any, associated with its use. It is the
responsibility of the user of this standard to establish appro-
This practice is under the jurisdiction ofASTM Committee D22 on Air Quality
and is the direct responsibility of Subcommittee D22.05 on Indoor Air. For referenced ASTM standards, visit the ASTM website, www.astm.org, or
Current edition approved Aug. 1, 2019. Published September 2019. Originally contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM
approved in 2002. Last previous edition approved in 2013 as D6803 – 13. DOI: Standards volume information, refer to the standard’s Document Summary page on
10.1520/D6803-19. the ASTM website.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
D6803 − 19
D6886 Test Method for Determination of theWeight Percent compounds. These procedures expand upon the best practices
Individual Volatile Organic Compounds in Waterborne for small-scale chamber emission testing described in Guide
Air-Dry Coatings by Gas Chromatography D5116.
D8141 Guide for Selecting Volatile Organic Compounds
4.3 Requirements are defined for an appropriate chamber
(VOCs) and Semi-Volatile Organic Compounds (SVOCs)
testfacilitythatincludesoneormoresmall-scaletestchambers
Emission Testing Methods to Determine Emission Param-
and the associated clean air supply system, the environmental
eters for Modeling of Indoor Environments
control and monitoring systems, and the system for sampling
E355 Practice for Gas Chromatography Terms and Relation-
chamber exhaust air for VOCs.
ships
4.4 Procedures are defined for documenting representative
samples of paints and coatings and for their handling in the
3. Terminology
laboratory prior to conducting emission tests.
3.1 Definitions—For definitions and terms used in this
4.5 VOC emissions from paints and coatings often are
practice, refer to Terminology D1356, Terminology D16, and
strongly influenced by the substrate to which they are applied.
PracticeE355.Fordefinitionsandtermsrelatedtotestmethods
In order to assess potential impacts of VOC emissions on
using small-scale environmental chambers, refer to Guide
indoor air quality, substrates should be representative of how
D5116.
the products are typically used. This practice identifies repre-
3.1.1 chamber loading ratio, n—the total amount of test
sentative substrates and application procedures for several
specimen exposed in the chamber divided by the net or
common types of interior paints and coatings.
corrected internal air volume of the chamber. D5116
4.6 This practice generally describes chamber test proce-
3.2 Definitions of Terms Specific to This Standard:
dures and chamber air sampling procedures but does not
3.2.1 alkyd paint, n—a paint, also referred to as oil paint,
recommend specific methods for sampling and analysis of
that contains drying oil or oil varnish as the basic ingredient.
VOCs, formaldehyde, and other carbonyl compounds.
3.2.2 clean air, n—air that does not contain any airborne
4.7 This practice does not extend to the measurement of
contaminants in excess of defined limits.
emissionsofsemi-volatileorganiccompounds(SVOCs).Refer
to Guide D8141 for a discussion of methods appropriate for
3.2.3 environmental enclosure, n—a temperature controlled
SVOCs.
enclosure of sufficient size to contain the test chamber(s) and
allow adequate access to conduct testing.
5. Significance and Use
3.2.4 latex paint, n—a paint containing a stable aqueous
5.1 Latex paints, alkyd paints, and primers are used as
dispersion of synthetic resin, produced by emulsion
coatings for walls, wooden trim, and furnishings in occupied
polymerization, as the principal constituent of the binder and
buildings. Paint may be applied to large surface areas and may
other potential modifying resins.
be applied repeatedly during the lifetime of a building. VOCs
are emitted from paint after application to surfaces.
3.2.5 primer, n—a paint used as a preparatory coating that is
applied to materials to facilitate adhesion of a finish coating to
5.2 Many other types of architectural coatings may be used
the surface.
in large quantities indoors in buildings. In particular, many
different types of coatings are used for floors including wood
3.2.6 coverage rate, n—the area covered by a unit volume
2 2
floor stains and finishes and concrete sealers, hardeners, and
of coating material expressed as m /L or cm /mL.
stains. Two component finishes are often mixed on site and are
3.2.7 test specimen, n—a subsample of a paint sample
applied to floors and other surfaces to create a finished surface.
applied to a substrate such as gypsum wallboard, wood,
5.3 There is a need for standardized procedures for measur-
engineered wood products, or metal and used for testing in an
ing the emissions ofVOCs from paint and coating samples that
environmental chamber.
can be reproduced by different laboratories and that can used
for the assessment of the acceptability of VOC emissions from
4. Summary of Practice
paints and coatings that are intended for use indoors in
4.1 Large quantities of architectural coatings are used in-
occupied spaces. This practice describes standardized proce-
doors in buildings. Primers and various types of paint are
dures that can be incorporated into test methods used for the
applied to walls and other large surface areas. Wood floors and
purpose of estimating the impacts of cured paints and coatings
concrete floors are finished with different types of architectural
on indoor air quality. Different procedures are required for the
coatings. Surfaces may be re-coated relatively frequently often
estimation of VOC exposures to workers applying such prod-
while buildings are in use and occupied. There is a need for
ucts.
standardized procedures to qualitatively and quantitatively
6. Apparatus
characterize the emissions of VOCs from such coatings as
these emissions have impacts on indoor air quality and
6.1 This practice requires the use of an environmental
potential inhalation exposures of building occupants.
chamber testing facility and an air sample collection system.
4.2 The purpose of this practice is to define standardized 6.2 Environmental Chamber Testing Facility—The facility
procedures for testing paints and other architectural coatings consists of a test chamber, a controlled-temperature environ-
fortheiremissionsofVOCs,formaldehyde,andothercarbonyl mental enclosure, a system for supplying clean air to the
D6803 − 19
chamber, a humidification system, and a manifold on the controlled to the desired set point within 65 % RH with an
chamber exhaust outlet for the collection of air samples. All accuracy of 65 %. This is often achieved by splitting the inlet
materials and components in contact with the test specimen or airflow rate 50/50 between dry air and air that passes through
air prior to sample collection shall be chemically inert and a water bubbler held at the same temperature as the chamber.
6.2.4 Environmental Measurement System—A data acquisi-
accessible for cleaning. Suitable materials include stainless
steel and glass. All gaskets and flexible components shall be tion system consisting of hardware and software shall be used
to measure and record the temperature, RH, inlet airflow rate,
made from chemically inert materials. General guidance for
design, construction, configuration, and validation of a test and sampling airflow rates throughout each test. A system for
relatively high frequency recording of the data is required.
chamber facility is provided in Guide D5116.
Samplingatonehertzwithrecordingofaveragesatone-minute
6.2.1 Test Chamber—The test chamber shall be constructed
intervals is recommended. At a minimum, data shall be
of inert materials, either electro-polished stainless steel or
recorded every five minutes.
glass. The chamber shall be of sufficient size to hold the test
specimen. Chambers may range in size from a few litres to a
6.3 Air Sampling System—An air sampling system consist-
few cubic metres as described in Guide D5116. A volume of
ing of a sampling manifold, a vacuum pump(s), and airflow
0.053 m is used in this practice only for discussion and
controllers/meters shall be used. Airflow controllers shall
illustrative purposes. Small-scale chambers of different sizes
control the sampling airflow rates to within 62 % of the
andshapesmaybeusedifthetestconditionscanbemaintained specified values with an accuracy of 62 %. It is recommended
and chamber performance at these conditions can be demon-
that sampling airflow rates be controlled using calibrated
strated. The chamber shall be equipped with an opening large electronic mass flow controllers. Sampling airflow rates shall
enough for loading the test specimen and for cleaning the
be referenced to standard temperature and pressure, typically
chamber. The chamber shall be equipped with a port to supply 25°C, 101 kPa. Sampling initiation and termination times can
airtothechamber,anairoutletfromthechamber,andportsfor
be programmed and controlled with solenoid values operated
temperatureandrelativehumidityprobes.Thechambermaybe by the data acquisition system.
equipped with a fan to promote mixing in the chamber and to 6.3.1 All system components between the chamber and the
achieve the desired air speed across the surface of the test sampling media shall be constructed of chemically inert
specimen. See Guide D5116, Section 5.3.3, for additional materials.Aglassorstainless-steelmanifoldshallbeconnected
guidance on the use of fans. The performance of the chamber to the outlet of the chamber for collection of air samples. The
shall be evaluated prior to its use to determine airtightness, manifold shall be designed for collection of multiple samples
surface adsorption effects and air mixing. If a fan is used, the simultaneously. The manifold shall be maintained at the same
air speed at 1 cm above the surface of the substrate shall be temperatureasthechamber.Itisrecommendedthattheexhaust
from the manifold be vented into a laboratory fume hood or
demonstrated to be in the range of 0.1 m/s to 0.3 m/s. The
chamber performance for air mixing (and air speed if a fan is other appropriate exhaust to minimize contamination of the air
in the environmental enclosure.
used) shall be evaluated with representative substrate in place.
The chamber performance shall be tested and demonstrated 6.3.2 Avacuum pump shall be used to draw air through the
sampling media. The required airflow rate is a function of the
following the guidelines presented in Guide D5116.
type of sampler used, the air change rate and the chemical
6.2.2 Environmental Enclosure—The chamber shall be
source strength. The total airflow rate through the samplers
maintained in an enclosure that is of sufficient size to accom-
generally shall not exceed 50 % of the airflow rate from the
modate one or more test chambers and that is capable of
chamber exhaust or shall be demonstrated to not reduce the
maintaining the desired temperature of the chamber(s) within
positive pressurization of the chamber. For collection of VOC
61°C. The enclosure shall be constructed of inert materials
samples, the typical sampling airflow rate range is 10 to 200
and be easily accessible for air sampling
cm /min. For collection of air samples for analysis of formal-
6.2.3 Clean Air Supply System—A controlled flow of clean
dehyde and other low molecular weight carbonyl compounds,
air shall be supplied to the test chamber, as described in Guide
the typical sampling airflow rate is 100 to 1000 cm /min.
D5116. The system shall incorporate hardware for removing
6.3.3 Provisions shall be made to collect multiple air
particles,ozone,andVOCsfromthesupplyair.Concentrations
samplesofeachtypeateachtimepoint.Replicatesamplesmay
ofVOCsandaldehydesmeasuredatthechamberinletshallnot
be required for quality control purposes and also to accommo-
3 3
exceed 2 µg/m for any single target compound and 20 µg/m
date potentially large concentration differences among analytes
for the sum of all measurable VOCs. The flow rate of the air
of interest at early time points.
supplied to the chamber shall be controlled within 62%ofthe
set-point airflow rate with an accuracy of 62%.Itis
7. Procedure for Paint and Coating Selection, Handling,
recommended that inlet airflow rate be controlled using a
and Storage
calibrated electronic mass flow controller(s). The airflow rate
shall be referenced to standard temperature and pressure, 7.1 Procedures for selection of the paint or coating sample
typically 25°C, 101 kPa for indoor air applications. The to be tested are a function of the study objectives. Paint and
chamber system shall be designed such that a positive pressur- coating samples may be procured from manufacturers,
ization of the chamber of ≤10 Pa relative to the environmental distributors, retailers, or other sources. Record pertinent infor-
enclosure is maintained throughout the test. The relative mation upon receipt of the sample including date of
humidity (RH) of the air supplied to the chamber(s) shall be acquisition, source of the sample, manufacturer, container size,
D6803 − 19
gloss level, intended application(s), date of manufacturing (if proper curing typically are applied to stainless-steel or glass
available), lot number, and other relevant information. Obtain plates. Higher gloss levels of wall paints may be applied to
andreviewtheSafetyDataSheet(SDS)andtheTechnicalData such plates.
Sheet (TDS) for the paint or coating. The density of the paint
8.1.3 Wood finishes that rely on penetration into wood for
or coating and the recommended coverage rate are required for
proper curing may be applied to solid wood substrates. Kiln
preparation of representative test specimens. It is recom-
dried maple and oak, which typically have low VOC
mended that two containers of the same lot number be
emissions, are suitable wood substrates. Each lot of a wood
procured, that is, one to test and one to archive.
substrate shall be tested for emissions of VOCs prior to use.
8.1.4 Commercial unglazed, low fire, clay tiles may be used
7.2 Upon receipt of a sample, it may be advantageous to
for floor finishes that require penetration into concrete for
split the sample into multiple storage vials, for example if
proper curing. Substrate specimens also may be prepared from
multiple emission tests or VOC content tests are required. The
ready mixed concrete material. Concrete s
...


This document is not an ASTM standard and is intended only to provide the user of an ASTM standard an indication of what changes have been made to the previous version. Because
it may not be technically possible to adequately depict all changes accurately, ASTM recommends that users consult prior editions as appropriate. In all cases only the current version
of the standard as published by ASTM is to be considered the official document.
Designation: D6803 − 13 D6803 − 19
Standard Practice for
Testing and Sampling of Volatile Organic Compounds
(Including Carbonyl Compounds) Emitted from Paint
Architectural Coatings Using SmallSmall-Scale
Environmental Chambers
This standard is issued under the fixed designation D6803; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope
1.1 This practice providesdescribes procedures for preparing test samples of alkyd primer, alkyd paint, latex primer, or latex
paint applied to building materials such as gypsum wallboard, wood, or engineered wood products and procedures for sampling
testing the emissions of volatile organic compounds (VOCs) emitted from those test samples. Emissions are sampled from small
environmental chambers operated under controlled conditions.(VOCs), formaldehyde, and other carbonyl compounds, from alkyd
paint, latex paint, primer, and other architectural coating samples using a small-scale environmental chamber test facility.
1.2 This practice describes the requirements for the chamber test facility, the small-scale test chamber, the clean air supply
system, the environmental controls, the environmental monitoring and data acquisition system, and the chamber air sampling
system.
1.3 This practice describes procedures for preparation of test specimens by application of primer or paint to common building
materials. Use of the procedures described in this practice for tests with other application methods or substrates may affect the
results and not meet the criteria recommended in the practice.documenting the paint and coating samples and for the handling and
storage of these samples including splitting of samples into smaller containers for storage and subsequent testing.
1.4 This practice describes procedures for collection of VOCs on sorbent tubes and carbonyl compounds on silica gel treated
with 2,4-dinitrophenylhydrazine (DNPH) that require analytical methods for measurement of individual organic compound
concentrations. This practice does not describe the detailed procedures of analytical methods, but refers to published methods for
these analyses.identifies appropriate substrates to be used for the preparation of test specimens of paints and coatings, as well as
procedures for preparing substrates for use.
1.5 This practice provides detailed procedures for preparing test specimens of paint and coating samples.
1.6 This practice describes procedures for testing and sampling VOCs emitted from paint under controlled conditions. The test
conditions, when combined with analytical data, can be used to calculate emission rates. This practice does not recommend a
method for the calculations.generally describes chamber test procedures and chamber air sampling procedures. The details of these
procedures are dependent upon the objectives of the test.
1.7 This practice does not recommend specific methods for sampling and analysis of VOCs, formaldehyde, and other carbonyl
compounds. The appropriate methods are dependent upon the objectives of the test.
1.8 Values stated in the International System of Units (SI) The values stated in SI units are to be regarded as the standard. No
other units of measurement are included in this standard.
1.9 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility
of the user of this standard to establish appropriate safety safety, health, and healthenvironmental practices and determine the
applicability of regulatory limitations prior to use.
1.10 This international standard was developed in accordance with internationally recognized principles on standardization
established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued
by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
This practice is under the jurisdiction of ASTM Committee D22 on Air Quality and is the direct responsibility of Subcommittee D22.05 on Indoor Air.
Current edition approved April 1, 2013Aug. 1, 2019. Published April 2013September 2019. Originally approved in 2002. Last previous edition approved in 20072013 as
D6803 – 02 (2007).D6803 – 13. DOI: 10.1520/D6803-13.10.1520/D6803-19.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
D6803 − 19
2. Referenced Documents
2.1 ASTM Standards:
D16 Terminology for Paint, Related Coatings, Materials, and Applications
D1005 Test Method for Measurement of Dry-Film Thickness of Organic Coatings Using Micrometers
D1212 Test Methods for Measurement of Wet Film Thickness of Organic Coatings
D1356 Terminology Relating to Sampling and Analysis of Atmospheres
D3686 Practice for Sampling Atmospheres to Collect Organic Compound Vapors (Activated Charcoal Tube Adsorption Method)
D3687 Practice for Analysis of Organic Compound Vapors Collected by the Activated Charcoal Tube Adsorption Method
D5116 Guide for Small-Scale Environmental Chamber Determinations of Organic Emissions from Indoor Materials/Products
D5197 Test Method for Determination of Formaldehyde and Other Carbonyl Compounds in Air (Active Sampler Methodology)
D5466 Test Method for Determination of Volatile Organic Compounds in Atmospheres (Canister Sampling Methodology)
D6196 Practice for Choosing Sorbents, Sampling Parameters and Thermal Desorption Analytical Conditions for Monitoring
Volatile Organic Chemicals in Air
D6345 Guide for Selection of Methods for Active, Integrative Sampling of Volatile Organic Compounds in Air (Withdrawn
2018)
For referenced ASTM standards, visit the ASTM website, www.astm.org, or contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM Standards
volume information, refer to the standard’s Document Summary page on the ASTM website.
D6803 − 19
D6886 Test Method for Determination of the Weight Percent Individual Volatile Organic Compounds in Waterborne Air-Dry
Coatings by Gas Chromatography
D8141 Guide for Selecting Volatile Organic Compounds (VOCs) and Semi-Volatile Organic Compounds (SVOCs) Emission
Testing Methods to Determine Emission Parameters for Modeling of Indoor Environments
E355 Practice for Gas Chromatography Terms and Relationships
2.2 Other Referenced Document:
Compendium of Methods for the Determination of Toxic Organic Compounds in Ambient Air, Compendium Methods TO-15
and TO-17, EPA/625/R-96-010b, January 1999, (NTIS No. PB99-172355)
3. Terminology
3.1 Definitions—For definitions and terms used in this practice, refer to Terminology D1356, Terminology D16, and Practice
E355. For definitions and terms related to test methods using small-scale environmental chambers, refer to Guide D5116.
3.1 Definitions—For definitions and terms used in this practice, refer to Terminology D1356, Terminology D16, and Practice
E355. For definitions and terms related to test methods using small-scale environmental chambers, refer to Guide D5116.
3.1.1 chamber loading ratio, n—the total amount of test specimen exposed in the chamber divided by the net or corrected
internal air volume of the chamber. D5116
3.2 Definitions of Terms Specific to This Standard:
3.2.1 alkyd paint—paint, n—a paint, also referred to as oil paint, it is a paint that contains drying oil or oil varnish as the basic
vehicle ingredient.
2 3
3.2.2 chamber loading (m /m )—the exposed surface area of the test specimen coated with paint divided by the test chamber
volume.
3.2.2 clean air—air, n—air that does not contain any individual VOC at a concentration airborne contaminants in excess of 2
3 3
μg/mdefined limits. and does not contain greater than 10 μg/m for the sum of the VOCs measurable in the sample. The air should
be conditioned to remove particulates and ozone.
3.2.3 environmental enclosure—enclosure, n—a temperature controlled enclosure of sufficient size to contain the test
chamber(s) and allow adequate access to it to conduct the testing.
3.2.4 latex paint—paint, n—a paint containing a stable aqueous dispersion of synthetic resin, produced by emulsion
polymerization, as the principal constituent of the binder. Modifying resins may be present. binder and other potential modifying
resins.
3.2.5 primer—primer, n—the first of two or more coats of a paint.a paint used as a preparatory coating that is applied to materials
to facilitate adhesion of a finish coating to the surface.
3.2.6 spreading rate—coverage rate, n—the area covered by a unit volume of coating material (for example, squareexpressed
2 2
as m metres per litre /L or cm /mL). It may also be referred to as /mL.coverage or coverage rate on paint container labels.
3.2.7 test specimen—specimen, n—a specimensubsample of thea paint sample applied to a substrate such as gypsum wallboard,
wood, or engineered wood products. engineered wood products, or metal and used for testing in an environmental chamber.
4. Summary of Practice
4.1 Large quantities of architectural coatings are used indoors in buildings. Primers and various types of paint are applied to
walls and other large surface areas. Wood floors and concrete floors are finished with different types of architectural coatings.
Surfaces may be re-coated relatively frequently often while buildings are in use and occupied. There is a need for standardized
procedures to qualitatively and quantitatively characterize the emissions of VOCs from such coatings as these emissions have
impacts on indoor air quality and potential inhalation exposures of building occupants.
4.2 This practice describes The purpose of this practice is to define standardized procedures for testing and sampling paints and
other architectural coatings for their emissions of VOCs, including formaldehyde formaldehyde, and other carbonyl compounds,
from paint applied to building materials such as gypsum wallboard, wood, and engineered wood products. Emissions tests are
conducted using small environmental chambers operated in a dynamic mode with continuous flow of humidified VOC-free air
through the chambers. The environmental chambers are operated at designated conditions of airflow rate, temperature, and relative
humidity. The VOCs in the emissions are sampled by adsorption on an appropriate single, or multiple sorbent media that can be
analyzed by thermal desorption and combined gas chromatography/mass spectrometry (GC/MS) or GC/flame ionization detection
(GC/FID). Other VOC sampling methods such as the collection of whole air samples in passivated canisters by Test Method
compounds. These procedures expand upon the best practices D5466 may offer advantages for some applications. Refer to for
small-scale chamber emission testing described in Guide D6345D5116 for a discussion of the relative merits of different methods
of active, integrative VOC sampling. Formaldehyde and other carbonyl compounds are collected on silica gel coated with DNPH
reagent that can be analyzed by high performance liquid chromatography (HPLC).
D6803 − 19
4.3 Requirements are defined for an appropriate chamber test facility that includes one or more small-scale test chambers and
the associated clean air supply system, the environmental control and monitoring systems, and the system for sampling chamber
exhaust air for VOCs.
4.4 Procedures are defined for documenting representative samples of paints and coatings and for their handling in the
laboratory prior to conducting emission tests.
4.5 VOC emissions from paints and coatings often are strongly influenced by the substrate to which they are applied. In order
to assess potential impacts of VOC emissions on indoor air quality, substrates should be representative of how the products are
typically used. This practice identifies representative substrates and application procedures for several common types of interior
paints and coatings.
4.6 This practice generally describes chamber test procedures and chamber air sampling procedures but does not recommend
specific methods for sampling and analysis of VOCs, formaldehyde, and other carbonyl compounds.
4.7 This practice describes the procedures for handling and storage of paint, setup of small test chambers, preparation does not
extend to the measurement of emissions of semi-volatile organic compounds (SVOCs). Refer to Guide D8141of test specimens,
chamber performance tests, sampling and reporting. for a discussion of methods appropriate for SVOCs.
5. Significance and Use
5.1 Latex and alkyd paints paints, alkyd paints, and primers are used as coatings for walls, wooden trim, and furnishings in
occupied buildings. Paint may be applied to large surface areas and may be applied repeatedly during the lifetime of a building.
VOCs are emitted from paint after application to surfaces.
5.2 Many other types of architectural coatings may be used in large quantities indoors in buildings. In particular, many different
types of coatings are used for floors including wood floor stains and finishes and concrete sealers, hardeners, and stains. Two
component finishes are often mixed on site and are applied to floors and other surfaces to create a finished surface.
5.3 There is a need for data on emissions from paint. The data can be used to compare emissions from different products. The
data may be used to assist manufacturers in reducing or eliminatingstandardized procedures for measuring the emissions of VOCs
from paint and coating samples that can be reproduced by different laboratories and that can used for the assessment of the
acceptability of VOC emissions from their products. The data may be used to predict concentrations of VOCs in a room or building
when used with appropriate indoor air quality models. paints and coatings that are intended for use indoors in occupied spaces.
This practice describes standardized procedures that can be incorporated into test methods used for the purpose of estimating the
impacts of cured paints and coatings on indoor air quality. Different procedures are required for the estimation of VOC exposures
to workers applying such products.
5.3 Standard test practices and procedures are needed for the comparison of emissions data from different laboratories.
6. Apparatus
6.1 This practice requires the use of an environmental chamber testing facility and an air sample collection systems.system.
6.2 Environmental Chamber Testing Facility, Facility—consisting The facility consists of a test chamber, a controlled-
temperature environmental enclosure, a system for supplying clean and conditioned air to the chamber, and fittings and manifolds
a humidification system, and a manifold on the chamber exhaust outlet for the collection of air samples. All materials and
components in contact with the test specimen or air prior to sample collection shouldshall be chemically inert and accessible for
cleaning. Suitable materials include stainless steel and glass. All gaskets and flexible components shouldshall be made from
chemically inert materials. General guidance for design, construction, configuration, and validation of a test chamber facility is
provided in Guide D5116.
6.2.1 Test Chamber, Chamber—The test chamber shall be constructed of inert materials materials, either electro-polished
stainless steel or glass. The chamber shall be of sufficient size to hold the test specimen. Small test chambers Chambers may range
in size from a few litres to 5 ma few . Procedures recommended in this cubic metres as described in Guide D5116practice have
been evaluated using test chambers with a . A volume of 0.053 m . This volume is used in thethis practice only for discussion and
illustrative purposes. Chambers Small-scale chambers of different sizesizes and shapeshapes may be used if the standard test
chamber conditions can be maintained and chamber performance at these conditions can be demonstrated. The chamber
shouldshall be equipped with an opening large enough for loading the test specimen and for cleaning the chamber. The chamber
willshall be equipped with a port to supply air to the chamber, an air outlet from the chamber, and ports for temperature and relative
humidity probes. The chamber may be equipped with a fan to promote mixing in the chamber and to achieve the desired air
velocityspeed across the surface of the test specimen. See Guide D5116, Section 5.3.3, for additional guidance on the use of fans.
The performance of the chamber shouldshall be evaluated prior to its use to determine air-tightness,airtightness, surface adsorption
effects, air mixing, and air velocity at effects and air mixing. If a fan is used, the air speed at 1 cm above the surface of the substrate.
Some of the chamber performance (that is, air mixing and air velocity) should substrate shall be demonstrated to be in the range
D6803 − 19
of 0.1 m/s to 0.3 m/s. The chamber performance for air mixing (and air speed if a fan is used) shall be evaluated with an uncoated
test representative substrate in place. The chamber performance shouldshall be tested and demonstrated following the guidelines
presented in Guide D5116.
6.2.2 Environmental Enclosure, Enclosure—The chamber shall be maintained in an enclosure that is of sufficient size to
accommodate the test chamber and one or more test chambers and that is capable of maintaining the desired temperature within
0.5°C.of the chamber(s) within 61°C. The enclosure shall be constructed of inert materials and be easily accessible for air
sampling
6.2.3 Clean Air Supply System, System—capable of supplying a A controlled flow of clean, humidified air into clean air shall
be supplied to the test chamber, as described in Guide D5116. The system shouldshall incorporate hardware for removing particles,
ozone, and VOCs from the air supplied to the chamber(s). supply air. Concentrations of VOCs and aldehydes measured at the
3 3
chamber inlet shouldshall not exceed 2 μg/m for any single target compound or 10and 20 μg/m for the sum of all measurable
VOCs in the sample. The relative humidity (RH) of the air supplied to the chamber(s) should be controlled to the desired set point
within 65 % RH. The VOCs. The flow rate of the air supplied to the chamber shouldshall be controlled within 65 % 62 % of
the set-point airflow rate. Ideally, the chamber system willrate with an accuracy of 62 %. It is recommended that inlet airflow rate
be controlled using a calibrated electronic mass flow controller(s). The airflow rate shall be referenced to standard temperature and
pressure, typically 25°C, 101 kPa for indoor air applications. The chamber system shall be designed such that a positive
pressurization of the chamber of approximately 10 ≤10 Pa relative to the environmental enclosure will be maintained and
monitored at all times during the test.is maintained throughout the test. The relative humidity (RH) of the air supplied to the
chamber(s) shall be controlled to the desired set point within 65 % RH with an accuracy of 65 %. This is often achieved by
splitting the inlet airflow rate 50/50 between dry air and air that passes through a water bubbler held at the same temperature as
the chamber.
6.2.4 Environmental Measurement System, System—A data acquisition system consisting of hardware and software shall be used
to measure and record the temperature, RH, and airflow rates during operation of the test system. inlet airflow rate, and sampling
airflow rates throughout each test. A system for continuous relatively high frequency recording of the data is recommend-
ed.required. Sampling at one hertz with recording of averages at one-minute intervals is recommended. At a minimum, data shall
be recorded every five minutes.
6.3 Air Sampling Systems, System—consisting of sorbent tubes and DNPH-silica gel cartridges, An air sampling system
consisting of a sampling manifold, a vacuum pumps,pump(s), and airflow controllers/meters. controllers/meters shall be used.
Airflow controllers shouldshall control the airflow rate through the sampling system to within 5 %sampling airflow rates to within
62 % of the specified value. All system components between the chamber and the sampling media should be constructed of
chemically inert materials.values with an accuracy of 62 %. It is recommended that sampling airflow rates be controlled using
calibrated electronic mass flow controllers. Sampling airflow rates shall be referenced to standard temperature and pressure,
typically 25°C, 101 kPa. Sampling initiation and termination times can be programmed and controlled with solenoid values
operated by the data acquisition system.
6.3.1 All system components between the chamber and the sampling media shall be constructed of chemically inert materials.
A glass or stainless steel stainless-steel manifold shouldshall be connected to the outlet of the chamber for collection of air samples.
The manifold shouldshall be designed for collection of multiple samples simultaneously. The manifold shall be maintained at the
same temperature as the chamber. It is recommended that the exhaust from the manifold should be vented into a laboratory fume
hood or other appropriate exhaust device to preventminimize contamination of the air in the laboratory or environmental enclosure.
6.3.2 Vacuum pumps should A vacuum pump shall be used to draw air through the sorbent tubes.sampling media. The required
airflow rate is a function of the type of sampler used, the size of the chamber, air change rate and the air change rate.chemical
source strength. The total airflow rate through the samplers generally shouldshall not exceed 50 % 50 % of the flowairflow rate
from the chamber outlet. exhaust or shall be demonstrated to not reduce the positive pressurization of the chamber. For collection
of VOCs on sorbent tubes, the pump should be capable of maintaining a constant flow in the range ofVOC samples, the typical
sampling airflow rate range is 10 to 200 mL/min.cm /min. For collection of air samples on DNPH-silica gel cartridges, the pump
should be capable of maintaining a constant flow in the range of 100 to 500 mL/min.for analysis of formaldehyde and other low
molecular weight carbonyl compounds, the typical sampling airflow rate is 100 to 1000 cm /min.
6.3.3 For collection of VOCs during the emissions test, tubes containing single or multiple sorbents may be used. The sorbents
may be porous polymers or graphitized carbon blacks. Select an appropriate single or multi-layered sorbent tube following the
procedures in Practice D6196, Guide D6345, and EPA Method TO-17. Recommendations on the use of sorbent tubes from
manufacturers or suppliers should be followed in selecting the sampling airflow rate and sampling period to avoid breakthrough
of VOCs through the sorbent tube. The required air sampling volume at each collection time point should be determined through
consideration of the safe sampling volume (SSV, see Practice D6196) of the VOC with the lowest retention volume, concentrations
to be measured, and detection limits of the analytical method.
6.3.4 For collection of VOCs during the first 10 to 20 h following application of alkyd primer or paint, charcoal sorbents
(Practice D3686) may be used due to the high concentrations of VOCs in the chamber air.
6.3.5 For collection of formaldehyde and other carbonyl compounds, DNPH-silica gel cartridges should be used following the
Test Method D5197.
D6803 − 19
6.3.3 An airflow meter/controller should be used to control and measure the airflow rate during sample collection. The controller
may consist of a precision flow control valve, a critical orifice, or a mass flow controller. The measurement device may consist
of soap film bubble meter, calibrated high precision rotameter, or mass flow meter. A mass flow meter/controller is recommended
for use during sample collection. All flow measurements should be referenced to standard temperature and pressure.Provisions
shall be made to collect multiple air samples of each type at each time point. Replicate samples may be required for quality control
purposes and also to accommodate potentially large concentration differences among analytes of interest at early time points.
7. ProceduresProcedure for Paint and Coating Selection, Handling, and Storage
7.1 Procedures for selection of the paint or coating sample to be tested are a function of the objectives of the tests. Paint study
objectives. Paint and coating samples may be procured from clients, manufacturers, distributors, retailers, or retailers. other
sources. Record pertinent information upon receipt of the paintsample including date of acquisition, source of the paint,sample,
manufacturer, container size, gloss level, intended application(s), date of manufacturing (if available), lot number, and other
relevant information on the label. information. Obtain and review the Material Safety Data Sheet (MSDS) for the paint. At least
(SDS) and the Technical Data Sheet (TDS) for the paint or coating. The density of the paint or coating and the recommended
coverage rate are required for preparation of representative test specimens. It is recommended that two containers of the same lot
number of paint should be procured (one for testing be procured, that is, one to test and one to archive).archive.
7.2 Upon receipt of the paint, it should be split into storage vials for handling and testing. The paint should be mixed in the
original container on a paint shaker before the split.
7.2 Split the paint into aliquots. Special care should be taken to minimize the loss of volatile compounds during the process.
Paint containers should not be left open except when required for transfer to storage vials. The size of the aliquot and storage vial
is a function of the amount of paint required for the test. Vials of 40 to 60 mL volumes hold sufficient paint for GC/MS analyses
of the liquid product or preparation of test specimens of 256 cmUpon receipt of a sample, it may area for chamber tests. Store
paint in clean amber glass vials that can be sealed with caps that have Teflon liners. Clean vials with alkaline detergent, rinse
thoroughly with deionized water, then dry before use. Individual vials of paint are used for testing to minimize losses of volatile
compounds during handling and preparation of test specimens. Repeated opening of a large container of paint will result in losses
of VOCs.be advantageous to split the sample into multiple storage vials, for example if multiple emission tests or VOC content
tests are required. The sample shall be mixed in the original container, typically on a paint shaker, before the split.
7.2.1 Special care should be taken to minimize the loss of volatile compounds during the splitting process. Sample containers
shall not be left open except when required for transfer of their content to storage vials.
7.2.2 The size of the aliquot and the storage vial is a function of the amount of product required for each test. Vials of 100-mL
volume hold sufficient material for analysis of VOC content by Test Method D6886 or for preparation of test specimens of
~250-cm area for emission tests. Use clean amber glass vials sealed with polytetrafluoroethylene-lined caps. Prior to use, clean
vials with dilute alkaline detergent and rinse thoroughly with deionized water.
7.2.3 Pour the mixed paint or coating sample into the vials, filling the vials to near the top to minimize the headspace volume.
Place two, or more, clean glass or stainless-steel balls in the vial to aid in mixing prior to use of the sample. Prepare a sufficient
number of sample vials for all planned tests. Label the vials individually with a sample code and the date of preparation.
7.2.4 Store the vials of the samples and the original containers of the paint or coating sample in the dark at room temperature.
7.4 Pour the mixed paint into the vials, filling the vial to near the top to minimize the volume of headspace and loss of VOCs
when the vial is opened. Two or more clean stainless steel balls may be placed in the vial to aid in mixing prior to use of the sample.
Prepare a sufficient number of sample vials for all analyses and tests planned for the paint. Label the vials individually with a
sample code and the date of preparation.
7.5 Store the vials of the paint samples and the original containers of the paint in the dark at room temperature.
7.3 Use the paint or coating sample within the manufacturer’s specified shelf-life time. It is recommended that VOC
concentrations should be measured by GC/MS or GC/FID after extended periods of storage to verify that they have not changed
during storage, for example, by Test Method D6886. Compare the concentrations of the VOCs to results from the original analyses
performed immediatelysoon after the paintsample was obtained.
8. ProceduresProcedure for Preparation of Test SpecimensSubstrate Materials
8.1 Procure the and cut a substrate material that is appropriate for testing theVOC emissions from the paint. The substrate should
not emit any of the compounds that are to be quantified in the emissions from the paint or compounds that may interfere with
quantification of the emissions from the paint. Cut the substrate material to an appropriate size (for example, 16 cm by 16 cm for
2 3 3
a loading of 0.5 mpaint or coating. /m in a 0.053 m chamber). Use an appropriate cutting device to obtain smooth edges. If
necessary, sand wood substrate to provide a smooth surface.
8.1.1 Wall paints typically are applied to gypsum board. Use standard, untreated gypsum board with a thickness of
approximately 16-mm thick. Apply the paint to the finished surface side. Each lot of gypsum board shall be tested for emissions
of VOCs prior to use. Note that some gypsum board emits formaldehyde at a rate that may result in the chamber concentration
of formaldehyde exceeding the background requirement.
D6803 − 19
8.1.2 Paints and coatings that are intended for non-porous surfaces or that do not require penetration int
...

Questions, Comments and Discussion

Ask us and Technical Secretary will try to provide an answer. You can facilitate discussion about the standard in here.

Loading comments...