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ASTM D1976-02

(Test Method)

Standard Test Method for Elements in Water by Inductively-Coupled Argon Plasma Atomic Emission Spectroscopy

Standard Test Method for Elements in Water by Inductively-Coupled Argon Plasma Atomic Emission Spectroscopy

SCOPE
1.1 This test method covers the determination of dissolved, total-recoverable, or total elements in drinking water, surface water, domestic, or industrial wastewaters.
1.2 It is the user's responsibility to ensure the validity of the test method for waters of untested matrices.
1.3 Table 1 lists elements for which this test method applies, with recommended wavelengths and typical estimated instrumental detection limits using conventional pneumatic nebulization. Actual working detection limits are sample dependent and as the sample matrix varies, these detection limits may also vary. In time, other elements may be added as more information becomes available and as required.
1.4  This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. For specific hazard statements, see Note 2 and Section 9.

General Information

Status
Historical
Publication Date
09-May-2002
ICS
71.040.50 - Physicochemical methods of analysis
Technical Committee
D19 - Water
Drafting Committee
D19.05 - Inorganic Constituents in Water
Current Stage
Ref Project

Relations

Replaces
ASTM D1976-96 - Standard Test Method for Elements in Water by Inductively-Coupled Argon Plasma Atomic Emission Spectroscopy
Effective Date
10-May-2002
Replaced By
ASTM D1976-07 - Standard Test Method for Elements in Water by Inductively-Coupled Argon Plasma Atomic Emission Spectroscopy
Effective Date
01-Aug-2007
Referred By
ASTM D3373-17 - Standard Test Method for Vanadium in Water
Effective Date
10-May-2002
Referred By
ASTM D3920-18 - Standard Test Method for Strontium in Water
Effective Date
10-May-2002
Referred By
ASTM D8506-23 - Standard Guide for Microbial Contamination and Biodeterioration in Turbine Oils and Turbine Oil Systems
Effective Date
10-May-2002
Referred By
ASTM D1691-17 - Standard Test Methods for Zinc in Water
Effective Date
10-May-2002
Referred By
ASTM D7728-18 - Standard Guide for Selection of ASTM Analytical Methods for Implementation of International Cyanide Management Code Guidance
Effective Date
10-May-2002
Referred By
ASTM D858-17 - Standard Test Methods for Manganese in Water
Effective Date
10-May-2002
Referred By
ASTM D1971-16(2021)e1 - Standard Practices for Digestion of Water Samples for Determination of Metals by Flame Atomic Absorption, Graphite Furnace Atomic Absorption, Plasma Emission Spectroscopy, or Plasma Mass Spectrometry
Effective Date
10-May-2002
Referred By
ASTM D8006-16 - Standard Guide for Sampling and Analysis of Residential and Commercial Water Supply Wells in Areas of Exploration and Production (E&P) Operations
Effective Date
10-May-2002
Referred By
ASTM D1687-17 - Standard Test Methods for Chromium in Water
Effective Date
10-May-2002
Referred By
ASTM D4309-18 - Standard Practice for Sample Digestion Using Closed Vessel Microwave Heating Technique for the Determination of Total Metals in Water
Effective Date
10-May-2002
Referred By
ASTM E2941-21 - Standard Practices for Extraction of Elements from Ores and Related Metallurgical Materials by Acid Digestion
Effective Date
10-May-2002
Referred By
ASTM D3866-18 - Standard Test Methods for Silver in Water
Effective Date
10-May-2002
Referred By
ASTM A1095-15(2019) - Standard Specification for High-Silicon Molybdenum Ferritic Iron Castings
Effective Date
10-May-2002

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ASTM D1976-02 - Standard Test Method for Elements in Water by Inductively-Coupled Argon Plasma Atomic Emission SpectroscopyASTM D1976-02 - Standard Test Method for Elements in Water by Inductively-Coupled Argon Plasma Atomic Emission Spectroscopy
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ASTM D1976-02 - Standard Test Method for Elements in Water by Inductively-Coupled Argon Plasma Atomic Emission Spectroscopy
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Standards Content (Sample)

NOTICE: This standard has either been superseded and replaced by a new version or withdrawn.
Contact ASTM International (www.astm.org) for the latest information
Designation:D 1976–02
Standard Test Method for
Elements in Water by Inductively-Coupled Argon Plasma
1
Atomic Emission Spectroscopy
This standard is issued under the fixed designation D 1976; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (e) indicates an editorial change since the last revision or reapproval.
TABLE 1 Suggested Wavelengths and Estimated
1. Scope
4
Detection Limits
1.1 This test method covers the determination of dissolved,
Estimated detection limit,µ
A
Element Wavelength, nm
total-recoverable, or total elements in drinking water, surface
B
g/L
,
2 3
water, domestic, or industrial wastewaters.
Aluminum 308.215 45
1.2 It is the user’s responsibility to ensure the validity of the
Arsenic 193.696 53
test method for waters of untested matrices. Antimony 206.833 32
Beryllium 313.042 0.3
1.3 Table1listselementsforwhichthistestmethodapplies,
Boron 249.773 5
with recommended wavelengths and typical estimated instru-
Cadmium 226.502 4
Chromium 267.716 7
mental detection limits using conventional pneumatic nebuli-
Cobalt 228.616 7
4
zation. Actual working detection limits are sample dependent
Copper 324.754 6
andasthesamplematrixvaries,thesedetectionlimitsmayalso
Iron 259.940 7
Lead 220.353 42
vary. In time, other elements may be added as more informa-
Magnesium 279.079 30
tion becomes available and as required.
Manganese 257.610 2
1.4 This standard does not purport to address all of the
Molybdenum 202.030 8
Nickel 231.604 15
safety concerns, if any, associated with its use. It is the
Selenium 196.026 75
responsibility of the user of this standard to establish appro-
Silver 328.068 7
priate safety and health practices and determine the applica-
Thallium 190.864 40
Vanadium 292.402 8
bility of regulatory limitations prior to use. For specific hazard
Zinc 213.856 2
statements, see Note 2 and Section 9.
A
The wavelengths listed are recommended because of their sensitivity and
overall acceptance. Other wavelengths may be substituted if they can provide the
2. Referenced Documents
needed sensitivity and are treated with the same corrective techniques for spectral
2.1 ASTM Standards: interference (see 6.1.1).
B 4
5
The estimated detection limits as shown are taken from Winge, Fassel, et al.
D 1066 Practice for Sampling Steam
They are given as a guide for approximate detection limits for the listed wave-
5
D 1129 Terminology Relating to Water
lengths. The actual test method instrumental detection limits are sample-
dependent and may vary as the sample matrix varies (see 3.1.4).
D 1192 Specification for Equipment for Sampling Water
5
and Steam in Closed Conduits
5
5
Applicable Test Methods of Committee D-19 on Water
D 1193 Specification for Reagent Water
5
D3370 PracticesforSamplingWaterfromClosedConduits
D 2777 Practice for Determination of Precision and Bias of
D 4841 Practice for Estimation of Holding Time for Water
5
Samples Containing Organic and Inorganic Constituents
1 3
This test method is under the jurisdiction of ASTM Committee D19 on Water
D 5810 Guide for Spiking into Aqueous Samples
and is the direct responsibility of Subcommittee D19.05 on Inorganic Constituents
D 5847 Practice for the Writing Quality Control Specifica-
in Water.
6
tions for Standard Test Methods for Water Analysis
Current edition approved May 10, 2002. Published June 2002. Originally
published as D 1976 – 91. Last previous edition D 1976 – 96.
2
3. Terminology
The detailed report of EPA Method Study 27, Method 200.7 is available from
theNationalTechnicalInformationService,5285PortRoyalRoad,Springfield,VA.
3.1 Definitions of Terms Specific to This Standard:
A summary of the project is available from the U.S. Environmental Protection
3.1.1 calibration blank, n—a volume of water containing
Agency, Environmental Monitoring and Support Laboratory, Cincinnati, OH.
3
Fishman, M. J. and Friedman, L., “Methods for Determination of Inorganic the same acid matrix as the calibration standards (see 11.1).
Substances in Water and Fluvial Sediments”, U.S. Geological Survey Techniques of
3.1.2 calibration standards, n—a series of known standard
Water-Resources Investigations, Book 5, Chapter , Open File Report 85-495, 1985,
solutions used by the analyst for calibration of the instrument
p. 659–671.
4
(preparation of the analytical curve) (see 8.11).
Winge, R. K., Fassel, V. A., Peterson, V. J. and Floyd, M. A.,“ Inductively
Coupled Plasma-Atomic Emission Spectroscopy,” An Atlas of Spectral Information,
Elsevier Science Publishing Co., Inc., New York, NY, 1985.
5 6
Annual Book of ASTM Standards, Vol 11.01. Annual Book of ASTM Standards, Vol 11.02.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700
...

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Standard Test Method for Elements in Water by Inductively-Coupled Plasma Atomic Emission Spectroscopy

SIGNIFICANCE AND USE
5.1 This test method is useful for the determination of element concentrations in many natural waters and wastewaters. It has the capability for the simultaneous determination of up to 29 elements. High sensitivity analysis and larger dynamic range can be achieved for some elements that are difficult to determine by other techniques such as Flame Atomic Absorption.  
5.2 The test method is useful for multi-element analysis of domestic and commercial well produced drinking water for metals and nonmetals for use in baseline analysis and monitoring during exploration, hydraulic fracturing, production, closure and reclamation activities related to oil and gas operations (see Guide D8006).  
5.2.1 Minimum analyses include arsenic, barium, iron, magnesium, sodium, calcium, manganese, and lead.  
5.2.2 Boron, potassium, chromium, selenium, cadmium, and strontium may be required on a site specific basis.  
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5.5 The test method is also useful for testing leachates and effluents for ore and mining and metallurgical waste characterization tests including Test Methods D6234, E2242, D5744, and solutions from the Biological Acid Production Potential and Peroxide Acid Generation Methods in the Appendix of Test Methods E1915.
SCOPE
1.1 This test method covers the determination of dissolved, total-recoverable, or total elements in drinking water, ground water, surface water, domestic, commercial or industrial wastewaters,2,3 within the following concentration ranges of Table 1.  
1.2 It is the user’s responsibility to ensure the validity of the test method for waters of untested matrices.  
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. For specific hazard statements, see Note 2  and Section 9.  
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ASTM D5739-06(2020)(Practice)
Standard Practice for Oil Spill Source Identification by Gas Chromatography and Positive Ion Electron Impact Low Resolution Mass Spectrometry

SIGNIFICANCE AND USE
4.1 This practice is useful for assessing the source for an oil spill. Other less complex analytical procedures (Test Methods D3328, D3414, D3650, and D5037) may provide all of the necessary information for ascertaining an oil spill source; however, the use of a more complex analytical strategy may be necessary in certain difficult cases, particularly for significantly weathered oils. This practice provides the user with a means to this end.  
4.1.1 This practice presumes that a “screening” of possible suspect sources has already occurred using less intensive techniques. As a result, this practice focuses directly on the generation of data using preselected targeted compound classes. These targets are both petrogenic and pyrogenic and can constitute both major and minor fractions of petroleum oils; they were chosen in order to develop a practice that is universally applicable to petroleum oil identification in general and is also easy to handle and apply. This practice can accommodate light oils and cracked products (exclusive of gasoline) on the one hand, as well as residual oils on the other.  
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Standard Terminology Used with Ion-Selective Electrodes

SCOPE
1.1 This terminology covers those terms recommended by the International Union of Pure and Applied Chemistry (IUPAC),2 and is intended to provide guidance in the use of ion-selective electrodes for analytical measurement of species in water, wastewater, and brines.  
1.2 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

  • Standard
    7 pages
    English language
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  • Standard
    7 pages
    English language
    sale 15% off