SIST EN 15837:2010
(Main)Ethanol as a blending component for petrol - Determination of phosphorus, copper and sulfur content - Inductively coupled plasma optical emission spectrometric direct method
Ethanol as a blending component for petrol - Determination of phosphorus, copper and sulfur content - Inductively coupled plasma optical emission spectrometric direct method
This European Standard specifies an inductively coupled plasma optical emission spectrometry (ICP-OES) method for the direct determination of elements content in ethanol, namely phosphorus in the range (0,13 to 1,90) mg/kg, copper in the range (0,050 to 0,300) mg/kg, and sulfur in the range (2,0 to 15,0) mg/kg.
WARNING - The use of this method may involve hazardous equipment, materials and operations. This method does not purport to address to all of the safety problems associated with its use, but it is the responsibility of the user to search and establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.
NOTE For the purposes of this document, the terms "% (m/m)" and "% (V/V)" are used to represent respectively the mass fraction (w) and volume fraction (greek symbol phi).
Ethanol zum Blendung in Benzin - Bestimmung des Gehalts von Fosfor, Kupfer und Schwefel - Induktiv gekoppeltes Plasma Optisch-Emissionspektrometrisches direktes Prüfverfahren
Diese Europäische Norm legt ein Verfahren zur direkten Bestimmung von Elementen in Ethanol, und zwar
Phosphor im Bereich (0,13 bis 1,90) mg/kg, Kupfer im Bereich (0,050 bis 0,300) mg/kg und Schwefel im
Bereich (2,0 bis 15,0) mg/kg mittels optischer Emissionsspektrometrie mit induktiv gekoppeltem Plasma
(ICP OES) fest.
WARNUNG — Die Anwendung dieses Verfahrens kann den Einsatz gefährlicher Stoffe, Arbeitsgänge
und Geräte mit sich bringen. Diese Norm gibt nicht vor, alle mit ihrer Anwendung verbundenen
Sicherheitsprobleme anzusprechen. Der Anwender dieser Norm ist dafür verantwortlich, vorher
angemessene Maßnahmen hinsichtlich Sicherheit und Gesundheit zu ergreifen und die Anwendbarkeit
einschränkender Vorschriften zu ermitteln.
ANMERKUNG Für die Zwecke dieses Dokuments wird zur Angabe des Massenanteils einer Substanz der Ausdruck
„% (m/m)“ und für den Volumenanteil einer Substanz der Ausdruck „% (V/V)“ verwendet.
Ethanol comme constituant d'essence - Détermination de la teneur de fosfore, coupre et sulphur - Méthode spectrometrique optique directe par inductiv-couple plasme
La présente Norme européenne prescrit une méthode par spectrométrie d’émission atomique par plasma à couplage inductif (ICP-OES) pour la détermination directe de la teneur en éléments dans l’éthanol, les teneurs notamment en phosphore, dans la plage comprise entre (0,13 et 1,90) mg/kg, en cuivre, dans la plage comprise entre (0,050 et 0,300) mg/kg, et en soufre, dans la plage comprise entre (2,0 et 15,0) mg/kg.
AVERTISSEMENT - L'utilisation de la présente Norme européenne peut impliquer l'intervention de produits, d'opérations et d'équipements à caractère dangereux. La présente norme européenne n'est pas censée aborder tous les problèmes de sécurité concernés par son usage. Il est de la responsabilité de l'utilisateur de consulter et d'établir des règles de sécurité et d'hygiène appropriées et de déterminer l'applicabilité des restrictions réglementaires avant utilisation.
NOTE Pour les besoins du présent document, les termes "% (m/m)" et "% (V/V)" représentent la fraction massique (w) et la fraction volumique (.
Etanol kot komponenta za dodajanje motornemu bencinu - Določevanje fosforja, bakra in žvepla - Metoda z direktno spektrometrijo optične emisije z induktivno sklopljeno plazmo
Ta evropski standard opredeljuje metodo z direktno spektrometrijo optične emisije z induktivno sklopljeno plazmo (ICP OES) za neposredno določevanje vsebnosti elementov v etanolu, od tega fosforja v razponu (0,13 do 1,90) mg/kg, bakra v razponu (0,050 do 0,300) mg/kg in žvepla v razponu (2,0 do 15,0) mg/kg.
General Information
- Status
- Published
- Public Enquiry End Date
- 30-Sep-2008
- Publication Date
- 01-Feb-2010
- Technical Committee
- NAD - Petroleum products, lubricants and related products
- Current Stage
- 6060 - National Implementation/Publication (Adopted Project)
- Start Date
- 07-Jan-2010
- Due Date
- 14-Mar-2010
- Completion Date
- 02-Feb-2010
Overview
SIST EN 15837:2010 is a European Standard issued by CEN that specifies a precise analytical method for determining the content of phosphorus, copper, and sulfur in ethanol used as a blending component for petrol. Utilizing Inductively Coupled Plasma Optical Emission Spectrometry (ICP OES), this standard provides a direct quantitative approach to measure these elemental concentrations within defined ranges:
- Phosphorus: 0.13 to 1.90 mg/kg
- Copper: 0.050 to 0.300 mg/kg
- Sulfur: 2.0 to 15.0 mg/kg
The method ensures accurate quality control and compliance in fuel ethanol production and blending industries. It also emphasizes safety precautions inherent in using specialized instrumentation and volatile materials.
Key Topics
- ICP OES Technique: The standard focuses on ICP OES, a sensitive, direct emission spectrometry technique ideal for detecting trace elements in ethanol fuel blends.
- Elemental Determination Ranges: Specifies exact concentration ranges for phosphorus, copper, and sulfur relevant to fuel-grade ethanol.
- Sampling and Sample Preparation: Details sample collection using HDPE containers and preparation steps to avoid contamination, including ultrasonic homogenization.
- Calibration Procedures: Defines the preparation of calibration solutions with certified standards and the construction of calibration curves to achieve high accuracy and repeatability.
- Instrumental Parameters: Guidance on optimal wavelengths and background correction to minimize measurement interferences, crucial for reproducible results.
- Precision and Reproducibility: Provides statistical bounds for repeatability and inter-laboratory reproducibility to validate test performance.
- Safety and Compliance: Highlights the need for responsible use of hazardous materials and compliance with regulatory safety requirements.
Applications
SIST EN 15837:2010 is essential for laboratories, fuel manufacturers, and quality control entities involved in the production and use of ethanol as a petrol blending agent. This standard helps to:
- Verify the chemical purity of ethanol by quantifying impurity elements that may affect engine performance or emission standards.
- Support regulatory compliance by reliably measuring phosphorus, copper, and sulfur, which can influence catalyst poisoning and pollutant emissions.
- Improve fuel blend quality assurance, ensuring consistent additive composition in biofuel formulations.
- Facilitate inter-laboratory consistency by standardizing analytical methods for ethanol fuel testing across European nations and beyond.
Related Standards
SIST EN 15837:2010 complements various international and European standards related to petroleum fuel analysis and sampling, including but not limited to:
- EN ISO 3170 - Petroleum liquids Manual Sampling
- EN ISO 3675 and EN ISO 12185 - Density determination methods for petroleum products
- EN ISO 3696 - Specifications for laboratory-grade water used in analytical procedures
- EN ISO 4259 - Statistical methods for evaluating precision of test methods
These standards collectively ensure the reliability and comparability of test data for ethanol and related liquid fuels within fuel quality management frameworks.
Keywords: SIST EN 15837:2010, ethanol testing standard, ICP OES, phosphorus content, copper determination, sulfur analysis, fuel ethanol quality, petrol blending component, inductively coupled plasma optical emission spectrometry, ethanol fuel impurities, European fuel standards, fuel additive analysis, elemental impurity measurement, ethanol density, laboratory ethanol testing, precision in fuel analysis
Frequently Asked Questions
SIST EN 15837:2010 is a standard published by the Slovenian Institute for Standardization (SIST). Its full title is "Ethanol as a blending component for petrol - Determination of phosphorus, copper and sulfur content - Inductively coupled plasma optical emission spectrometric direct method". This standard covers: This European Standard specifies an inductively coupled plasma optical emission spectrometry (ICP-OES) method for the direct determination of elements content in ethanol, namely phosphorus in the range (0,13 to 1,90) mg/kg, copper in the range (0,050 to 0,300) mg/kg, and sulfur in the range (2,0 to 15,0) mg/kg. WARNING - The use of this method may involve hazardous equipment, materials and operations. This method does not purport to address to all of the safety problems associated with its use, but it is the responsibility of the user to search and establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. NOTE For the purposes of this document, the terms "% (m/m)" and "% (V/V)" are used to represent respectively the mass fraction (w) and volume fraction (greek symbol phi).
This European Standard specifies an inductively coupled plasma optical emission spectrometry (ICP-OES) method for the direct determination of elements content in ethanol, namely phosphorus in the range (0,13 to 1,90) mg/kg, copper in the range (0,050 to 0,300) mg/kg, and sulfur in the range (2,0 to 15,0) mg/kg. WARNING - The use of this method may involve hazardous equipment, materials and operations. This method does not purport to address to all of the safety problems associated with its use, but it is the responsibility of the user to search and establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. NOTE For the purposes of this document, the terms "% (m/m)" and "% (V/V)" are used to represent respectively the mass fraction (w) and volume fraction (greek symbol phi).
SIST EN 15837:2010 is classified under the following ICS (International Classification for Standards) categories: 71.080.60 - Alcohols. Ethers; 75.160.20 - Liquid fuels. The ICS classification helps identify the subject area and facilitates finding related standards.
SIST EN 15837:2010 is associated with the following European legislation: EU Directives/Regulations: 98/70/EC; Standardization Mandates: M/344. When a standard is cited in the Official Journal of the European Union, products manufactured in conformity with it benefit from a presumption of conformity with the essential requirements of the corresponding EU directive or regulation.
You can purchase SIST EN 15837:2010 directly from iTeh Standards. The document is available in PDF format and is delivered instantly after payment. Add the standard to your cart and complete the secure checkout process. iTeh Standards is an authorized distributor of SIST standards.
Standards Content (Sample)
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.Ethanol zum Blendung in Benzin - Bestimmung des Gehalts von Fosfor, Kupfer und Schwefel - Induktiv gekoppeltes Plasma Optisch-Emissionspektrometrisches direktes PrüfverfahrenEthanol comme constituant d'essence - Détermination de la teneur de fosfore, coupre et sulphur - Méthode spectrometrique optique directe par inductiv-couple plasmeEthanol as a blending component for petrol - Determination of phosphorus, copper and sulfur content - Inductively coupled plasma optical emission spectrometric direct method75.160.20Liquid fuels71.080.60Alkoholi. EtriAlcohols. EthersICS:Ta slovenski standard je istoveten z:EN 15837:2009SIST EN 15837:2010en,fr,de01-marec-2010SIST EN 15837:2010SLOVENSKI
STANDARD
EUROPEAN STANDARD NORME EUROPÉENNE EUROPÄISCHE NORM
EN 15837
December 2009 ICS 75.160.20 English Version
Ethanol as a blending component for petrol - Determination of phosphorus, copper and sulfur content - Direct method by inductively coupled plasma optical emission spectrometry (ICP OES)
Ethanol comme base de mélange à l'essence - Détermination de la teneur en phosphore, en cuivre et en soufre - Méthode directe par spectrométrie d'émission atomique par plasma à couplage inductif (ICP OES)
Ethanol zur Verwendung als Blendkomponente in Ottokraftstoff - Bestimmung des Gehalts an Phosphor, Kupfer und Schwefel - Direktes Verfahren durch optische Emissionsspektrometrie mit induktiv gekoppeltem Plasma (ICP OES) This European Standard was approved by CEN on 7 November 2009.
CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national standards may be obtained on application to the CEN Management Centre or to any CEN member.
This European Standard exists in three official versions (English, French, German). A version in any other language made by translation under the responsibility of a CEN member into its own language and notified to the CEN Management Centre has the same status as the official versions.
CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom.
EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION EUROPÄISCHES KOMITEE FÜR NORMUNG
Management Centre:
Avenue Marnix 17,
B-1000 Brussels © 2009 CEN All rights of exploitation in any form and by any means reserved worldwide for CEN national Members. Ref. No. EN 15837:2009: ESIST EN 15837:2010
Ethanol density . 10Bibliography . 11 SIST EN 15837:2010
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