SIST EN 12163:2016
(Main)Copper and copper alloys - Rod for general purposes
Copper and copper alloys - Rod for general purposes
This European Standard specifies the composition, property requirements and dimensional tolerances for copper alloy rod in the shape of circles, squares, hexagons or octagons, finally produced by drawing or extruding intended for general purposes.
The sampling procedures and the methods of test for verification of conformity to the requirements of this European Standard are also specified.
Kupfer und Kupferlegierungen - Stangen zur allgemeinen Verwendung
Diese Europäische Norm legt die Zusammensetzung, die Anforderungen an die Eigenschaften und die Grenzabmaße für durch Ziehen oder Pressen endgefertigte Stangen aus Kupferlegierungen in runder, quadratischer, sechseckiger oder achteckiger Form zur allgemeinen Verwendung fest.
Der Ablauf der Probenahme und die Prüfverfahren zur Feststellung der Übereinstimmung mit den Anforderungen dieser Norm sind ebenfalls festgelegt.
Cuivre et alliages de cuivre - Barres pour usages généraux
La présente Norme européenne spécifie la composition, les exigences de propriétés et les tolérances dimensionnelles des barres en cuivre et alliages de cuivre de forme ronde, carrée, hexagonale ou octogonale, fabriquées par étirage ou filage, destinées à des usages généraux.
Les modes opératoires d'échantillonnage et les méthodes d'essai pour la vérification de la conformité aux exigences de la présente Norme européenne sont également spécifiés.
Baker in bakrove zlitine - Palice za splošno uporabo
Ta evropski standard določa sestavo, zahteve glede značilnosti in odstopanja glede mer za palice iz bakrovih zlitin v obliki krogov, kvadratov, šesterokotnikov ali osmerokotnikov, končno izdelanih z vlečenjem ali ekstrudiranjem, namenjenih za splošno uporabo.
Določeni so tudi postopki vzorčenja in preskusne metode za preverjanje skladnosti z zahtevami tega evropskega standarda.
General Information
Relations
Standards Content (Sample)
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.Baker in bakrove zlitine - Palice za splošno uporaboKupfer und Kupferlegierungen - Stangen zur allgemeinen VerwendungCuivre et alliages de cuivre - Barres pour usages générauxCopper and copper alloys - Rod for general purposes77.150.30Bakreni izdelkiCopper productsICS:Ta slovenski standard je istoveten z:EN 12163:2016SIST EN 12163:2016en,fr,de01-oktober-2016SIST EN 12163:2016SLOVENSKI
STANDARDSIST EN 12163:20111DGRPHãþD
SIST EN 12163:2016
EUROPEAN STANDARD NORME EUROPÉENNE EUROPÄISCHE NORM
EN 12163
July
t r s x ICS
y yä s w rä u r Supersedes EN
s t s x uã t r s sEnglish Version
Copper and copper alloys æ Rod for general purposes Cuivre et alliages de cuivre æ Barres pour usages généraux
Kupfer und Kupferlegierungen æ Stangen zur allgemeinen Verwendung This European Standard was approved by CEN on
{ April
t r s xä
egulations which stipulate the conditions for giving this European Standard the status of a national standard without any alterationä Upætoædate lists and bibliographical references concerning such national standards may be obtained on application to the CENæCENELEC Management Centre or to any CEN memberä
translation under the responsibility of a CEN member into its own language and notified to the CENæCENELEC Management Centre has the same status as the official versionsä
CEN members are the national standards bodies of Austriaá Belgiumá Bulgariaá Croatiaá Cyprusá Czech Republicá Denmarká Estoniaá Finlandá Former Yugoslav Republic of Macedoniaá Franceá Germanyá Greeceá Hungaryá Icelandá Irelandá Italyá Latviaá Lithuaniaá Luxembourgá Maltaá Netherlandsá Norwayá Polandá Portugalá Romaniaá Slovakiaá Sloveniaá Spainá Swedená Switzerlandá Turkey andUnited Kingdomä
EUROPEAN COMMITTEE FOR STANDARDIZATION COMITÉ EUROPÉEN DE NORMALISATION EUROPÄISCHES KOMITEE FÜR NORMUNG
CEN-CENELEC Management Centre:
Avenue Marnix 17,
B-1000 Brussels
9
t r s x CEN All rights of exploitation in any form and by any means reserved worldwide for CEN national Membersä Refä Noä EN
s t s x uã t r s x ESIST EN 12163:2016
EN 12163:2016 (E) 2 Contents
Page European foreword . 4 Introduction . 6 1 Scope . 7 2 Normative references . 7 3 Terms and definitions . 7 4 Designations. 8 4.1 Material . 8 4.1.1 General . 8 4.1.2 Symbol . 8 4.1.3 Number . 8 4.2 Material condition . 8 4.3 Product . 8 5 Ordering information . 10 6 Requirements . 11 6.1 Composition . 11 6.2 Mechanical properties . 11 6.3 Resistance to dezincification . 11 6.4 Residual stress level . 12 6.5 Dimensions and tolerances . 12 6.5.1 Diameter or width across-flats . 12 6.5.2 Shape tolerances . 12 6.5.3 Straightness . 12 6.5.4 Length . 12 6.5.5 Corner radii . 12 6.5.6 Twist of polygonal rod . 13 6.6 Surface quality. 13 7 Sampling . 13 7.1 General . 13 7.2 Analysis . 13 7.3 Mechanical tests . 14 7.4 Dezincification resistance and stress corrosion resistance test . 14 8 Test methods . 14 8.1 Analysis . 14 8.2 Tensile test . 14 8.2.1 General . 14 8.2.2 Location of test pieces . 14 8.2.3 Shape and size of test pieces . 15 8.2.4 Procedure for testing . 15 8.2.5 Determination of results . 15 8.3 Hardness test . 15 8.4 Dezincification resistance test . 15 8.5 Stress corrosion resistance test . 15 SIST EN 12163:2016
EN 12163:2016 (E) 3 8.6 Determination of the electrical conductivity . 16 8.7 Retests . 16 8.7.1 Analysis, tensile, hardness and dezincification resistance tests and determination of the electrical conductivity . 16 8.7.2 Stress corrosion resistance test . 16 8.8 Rounding of results . 16 9 Declaration of conformity and inspection documentation . 17 9.1 Declaration of conformity . 17 9.2 Inspection documentation . 17 10 Marking, packaging, labelling . 17 Bibliography . 45
Figures Figure 1 — Measurement of twist of polygonal rod . 13
Tables Table 1 — Composition of low alloyed copper alloys . 18 Table 2 — Composition of copper-aluminium alloys . 19 Table 3 — Composition of copper-nickel alloys . 19 Table 4 — Composition of copper-nickel-zinc alloys . 19 Table 5 — Composition of copper-tin alloys . 20 Table 6 — Composition of copper-zinc alloys . 20 Table 7 — Composition of complex copper-zinc alloys. 22 Table 8 — Mechanical properties of rod of low alloyed copper alloys . 23 Table 9 — Mechanical properties of rod of copper-aluminium alloys . 27 Table 10 — Mechanical properties of rod of copper-nickel alloys . 29 Table 11 — Mechanical properties of rod of copper-nickel-zinc alloys . 30 Table 12 — Mechanical properties of rod of copper-tin alloys . 32 Table 13 — Mechanical properties of rod of copper-zinc alloys . 34 Table 14 — Mechanical properties of rod of complex copper-zinc alloys . 39 Table 15 — Dimensional tolerances for rod . 43 Table 16 — Tolerances on straightness of rod . 43 Table 17 — Corner radii for square and polygonal rod . 43 Table 18 — Maximum twist of square and polygonal rod . 44 Table 19 — Sampling rate . 44
SIST EN 12163:2016
EN 12163:2016 (E) 4 European foreword This document (EN 12163:2016) has been prepared by Technical Committee CEN/TC 133 “Copper and copper alloys”, the secretariat of which is held by DIN. This European Standard shall be given the status of a national standard, either by publication of an identical text or by endorsement, at the latest by January 2017, and conflicting national standards shall be withdrawn at the latest by January 2017. Attention is drawn to the possibility that some of the elements of this document may be the subject of patent rights. CEN shall not be held responsible for identifying any or all such patent rights. This document supersedes EN 12163:2011. Within its programme of work, Technical Committee CEN/TC 133 requested CEN/TC 133/WG 4 “Extruded and drawn products, forgings and scrap” to revise the following standard: — EN 12163:2011, Copper and copper alloys — Rod for general purposes. This document is one of a series of European Standards for the copper and copper alloy products rod, wire, profile and forgings. Other products are specified as follows: — EN 12164, Copper and copper alloys — Rod for free machining purposes; — EN 12165, Copper and copper alloys — Wrought and unwrought forging stock; — EN 12166, Copper and copper alloys — Wire for general purposes; — EN 12167, Copper and copper alloys — Profiles and bars for general purposes; — EN 12168, Copper and copper alloys — Hollow rod for free machining purposes; — EN 13601, Copper and copper alloys — Copper rod, bar and wire for general electrical purposes; — EN 13602, Copper and copper alloys — Drawn, round copper wire for the manufacture of electrical conductors; — EN 13605, Copper and copper alloys — Copper profiles and profiled wire for electrical purposes. In comparison with EN 12163:2011, the following significant technical changes were made: a) introduction of an optional procedure how to refer to restrictions to the chemical composition imposed by the 4 MS Common Composition List for materials used for products accepted for contact with drinking water; b) requirements and test methods for resistance of dezincification modified; c) provisions for surface quality added; d) mechanical properties for CuZn21Si3P (CW724R) modified. SIST EN 12163:2016
EN 12163:2016 (E) 5 According to the CEN-CENELEC Internal Regulations, the national standards organisations of the following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and the United Kingdom. SIST EN 12163:2016
EN 12163:2016 (E) 6 Introduction The European Committee for Standardization (CEN) draws attention to the fact that it is claimed that compliance with this document may involve the use of a patent concerning the alloy CuZn21Si3P (CW724R) given in 6.1. CEN takes no position concerning the evidence, validity and scope of this patent right. The holder of this patent right has ensured the CEN that he is willing to negotiate licenses either free of charge or under reasonable and non-discriminatory terms and conditions with applicants throughout the world. In this respect, the statement of the holder of this patent right is registered with CEN. Information may be obtained from: Wieland-Werke AG Graf Arco Straße 36 D-89079 Ulm GERMANY Attention is drawn to the possibility that some of the elements of this document may be the subject of patent rights other than those identified above. CEN shall not be held responsible for identifying any or all such patent rights. CEN and CENELEC maintain online lists of patents relevant to their standards. Users are encouraged to consult the lists for the most up to date information concerning patents (ftp://ftp.cencenelec.eu/EN/IPR/Patents/IPRdeclaration.pdf). Due to developing legislation, the composition of a material may be restricted to the composition specified in this European Standard with respect to individual uses (e.g. for the use in contact with drinking water in some Member States of the European Union). These individual restrictions are not part of this European Standard. Nevertheless, for materials for which traditional and major uses are affected, these restrictions are indicated. The absence of an indication, however, does not imply that the material can be used in any application without any legal restriction. SIST EN 12163:2016
EN 12163:2016 (E) 7 1 Scope This European Standard specifies the composition, property requirements and dimensional tolerances for copper alloy rod in the shape of circles, squares, hexagons or octagons, finally produced by drawing or extruding intended for general purposes. The sampling procedures and the methods of test for verification of conformity to the requirements of this European Standard are also specified. 2 Normative references The following documents, in whole or in part, are normatively referenced in this document and are indispensable for its application. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies. EN 1173, Copper and copper alloys - Material condition designation EN 1412, Copper and copper alloys - European numbering system EN 1655, Copper and copper alloys - Declarations of conformity EN 10204, Metallic products - Types of inspection documents EN 14977, Copper and copper alloys - Detection of tensile stress - 5 % ammonia test EN ISO 6506-1, Metallic materials - Brinell hardness test - Part 1: Test method (ISO 6506-1) EN ISO 6509-1, Corrosion of metals and alloys - Determination of dezincification resistance of copper alloys with zinc - Part 1: Test method (ISO 6509-1) EN ISO 6892-1, Metallic materials - Tensile testing - Part 1: Method of test at room temperature (ISO 6892-1) ISO 1190-1, Copper and copper alloys — Code of designation — Part 1: Designation of materials ISO 6957, Copper alloys — Ammonia test for stress corrosion resistance 3 Terms and definitions For the purposes of this document, the following terms and definitions apply. 3.1 rod straight product of uniform cross-section along its whole length 3.2 deviation from circular form difference between the maximum and the minimum diameters measured at any one cross-section of a round product SIST EN 12163:2016
EN 12163:2016 (E) 8 4 Designations 4.1 Material 4.1.1 General The material is designated either by symbol or by number (see Tables 1 to 7). 4.1.2 Symbol The material symbol designation is based on the designation system given in ISO 1190-1. NOTE Although material symbol designations used in this standard might be the same as those in other standards using the designation system given in ISO 1190-1, the detailed composition requirements are not necessarily the same. 4.1.3 Number The material number designation is in accordance with the system given in EN 1412. 4.2 Material condition For the purposes of this standard, the following designations, which are in accordance with the system given in EN 1173, apply for the material condition: M Material condition for the product as manufactured without specified mechanical properties; R. Material condition designated by the minimum value of tensile strength requirement for the product with mandatory tensile property requirements; H. Material condition designated by the minimum value of hardness requirement for the product with mandatory hardness requirements; S (suffix) Material condition for a product which is stress relieved. Products in the M, R. or H. material condition may be specially processed (i.e. mechanically or thermally stress relieved) in order to lower the residual stress level to improve the resistance to stress corrosion and the dimensional stability on machining [see Clause 5 list entry l), list entry m) and 8.4]. Exact conversion between material conditions designated R. and H. is not possible. Except when the suffix S is used, material condition is designated by only one of the above designations. 4.3 Product The product designation provides a standardized pattern of designation from which a rapid and unequivocal description of a product is conveyed in communication. It provides mutual comprehension at the international level with regard to products which meet the requirements of the relevant European Standard. The product designation is no substitute for the full content of the standard. The product designation for products to this standard shall consist of: — denomination (Rod); — number of this European Standard (EN 12163); — material designation, either symbol or number (see Tables 1 to 7); SIST EN 12163:2016
EN 12163:2016 (E) 9 — DW for compliance in the chemical composition according to the 4 MS Common Composition List. This information is mandatory in the case in which the product is used for drinking water applications according to the 4 MS Common Composition List and not to be given in other cases; — material condition designation (see Tables 8 to 14); — cross-sectional shape (the following designations shall be used, as appropriate: RND for round, SQR for square, HEX for hexagonal, OCT for octagonal); — nominal cross-sectional dimension (diameter or width across-flats); — tolerance class (see Table 15); — for polygonal rod, the corner shape (the following designations shall be used as appropriate: SH for sharp, RD for rounded), (see Table 17). The derivation of a product designation is shown in the following examples. EXAMPLE 1 Rod for general purposes conforming to this standard, in material designated either CuZn40 or CW509L, for standard applications, in material condition R410, hexagonal, nominal width across-flats 14 mm, tolerance Class B, rounded corners, will be designated as follows:
SIST EN 12163:2016
EN 12163:2016 (E) 10 EXAMPLE 2 Rod for general purposes conforming to this standard, in material designated either CuZn40 or CW509L, for drinking water applications according to the 4 MS Common Composition List, in material condition R410, hexagonal, nominal width across-flats 14 mm, tolerance Class B, rounded corners, will be designated as follows:
5 Ordering information In order to facilitate the enquiry, order and confirmation of order procedures between the purchaser and the supplier, the purchaser shall state on his enquiry and order the following information: a) mass of product required; b) denomination (Rod); c) number of this European Standard (EN 12163); d) material designation (see Tables 1 to 7); e) material condition designation (see 4.2 and Tables 8 to 14) if it is other than M; f) DW for compliance in the chemical composition according to the 4 MS Common Composition List. This information is mandatory in the case in which the product is used for drinking water applications according to the 4 MS Common Composition List and not to be given in other cases; g) cross-sectional shape; h) nominal cross-sectional dimension (diameter or width across-flats); i) whether other than class A tolerances are required (see Table 15); j) for polygonal rod: whether “sharp” or “rounded” corners are required unless the corner radii shall be left to the discretion of the supplier (see 6.5.5 and Table 17); SIST EN 12163:2016
EN 12163:2016 (E) 11 k) length and length tolerance (see 6.5.4). It is recommended that the product designation, as described in 4.3, is used for items b) to k). In addition, the purchaser shall also state on the enquiry and order any or the following, if required: l) whether the products are required to pass a stress corrosion resistance test. If so, which test method shall be used (see 8.5) if the choice is not to be left to the discretion of the supplier. If the purchaser chooses ISO 6957, the pH value for the test solution shall be selected; m) whether the products shall be supplied in a thermally stress relieved material condition; n) whether special surface quality is required (see 6.6); o) whether a declaration of conformity is required (see 9.1); p) whether an inspection document is required, and if so, which type (see 9.2); q) whether there are any special requirements for marking, packaging or labelling (see Clause 10). EXAMPLE Ordering details for 500 kg rod for general purposes conforming to EN 12163, in material designated either CuZn40 or CW509L, for drinking water application according to the 4 MS Common Composition List, in material condition R410, hexagonal, nominal width across-flats 14 mm, tolerance class B, rounded corners, length 3 000 mm ± 100 mm:
500 kg Rod EN 12163 — CuZn40 — DW — R410 — HEX14B — RD
— length 3 000 mm ± 100 mm
or
500 kg Rod EN 12163 — CW509L — DW — R410 — HEX14B — RD
— length 3 000 mm ± 100 mm 6 Requirements 6.1 Composition The composition shall conform to the requirements for the appropriate material given in Tables 1 to 7. Due to developing legislation, specific applications (see 4.3) may require restrictions in the chemical composition. In this case the limitations shall be specified in the ordering information [see Clause 5, list entry f)]. 6.2 Mechanical properties The tensile or the hardness properties shall conform to the appropriate requirements given in Tables 8 to 14. The tests shall be carried out in accordance with 8.2 or 8.3. 6.3 Resistance to dezincification The maximum depth of dezincification, in any direction, of CuZn38As (CW511L) and CuZn21Si3P (CW724R)) products shall be 100 µm. The test shall be carried out in accordance with 8.4. SIST EN 12163:2016
EN 12163:2016 (E) 12 NOTE Shape and distribution of beta phase aggregates can influence the dezincification resistance of products. Special requirements relating to shape and distribution of ß phase aggregates are subject to agreement between purchaser and supplier. Products in alloy CuZn38As (CW511L) may be subjected to heat treatment in the range 500 °C to 550 °C during manufacture. If the user needs to heat the material above 530 °C during subsequent processing then advice should be sought from the supplier. 6.4 Residual stress level Products ordered and supplied in the stress relieved condition (see 4.2, 2nd paragraph) shall show no evidence of cracking when tested. The tests shall be carried out in accordance with 8.5. 6.5 Dimensions and tolerances 6.5.1 Diameter or width across-flats The diameter or width across-flats shall conform to the tolerances given in Table 15. NOTE The diameter of round rod is calculated as the mean of one or more pairs of measurements taken at right angles at the same cross-section of the rod. 6.5.2 Shape tolerances 6.5.2.1 Round rod The deviation from circular form shall not exceed half the range of the tolerance on diameter given in Table 15. 6.5.2.2 Polygonal rod The width across-flats, measured at the centre of the faces at any one cross-section, shall not differ by more than half the range of the tolerance given for the size in Table 15. 6.5.3 Straightness For rod of diameter, or width across-flats, from 10 mm up to and including 50 mm, and of length 1 000 mm or over, the deviation from straightness, defined as the curvature (depth of arc) against a datum line when the product is lying flat in a horizontal plane, shall conform to the tolerances given in Table 16. NOTE Outside this range, the deviation from straightness is subject to agreement between the purchaser and the supplier. 6.5.4 Length The length and length tolerance shall conform to the requirements stated on the enquiry and order [see Clause 5 list entry k)]. 6.5.5 Corner radii The corner radii of polygonal rod shall conform to Table 17 [see Clause 5 list entry j)]. Except in cases of dispute, the corners should be measured directly, either by use of a gauge or an optical projector. In cases of dispute, the method by optical projector should be used. SIST EN 12163:2016
EN 12163:2016 (E) 13 6.5.6 Twist of polygonal rod The maximum permitted twist V (see Figure 1) of polygonal rod, as measured between two cross-sections along the rod, shall conform to Table 18.
Key 1 reference plane V twist W width across-flats Figure 1 — Measurement of twist of polygonal rod 6.6 Surface quality The surfaces shall be clean and smooth. The rods may have a superficial film of drawing lubricant or, if anneale
...
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.Baker in bakrove zlitine - Palice za splošno uporaboKupfer und Kupferlegierungen - Stangen zur allgemeinen VerwendungCopper and copper alloys - Rod for general purposes77.150.30Bakreni izdelkiCopper productsICS:Ta slovenski standard je istoveten z:FprEN 12163kSIST FprEN 12163:2015en,fr,de01-december-2015kSIST FprEN 12163:2015SLOVENSKI
STANDARD
kSIST FprEN 12163:2015
EUROPEAN STANDARD NORME EUROPÉENNE EUROPÄISCHE NORM
FINAL DRAFT
FprEN 12163
October
t r s w ICS
y yä s w rä u r Will supersede EN
s t s x uã t r s sEnglish Version
Copper and copper alloys æ Rod for general purposes
Kupfer und Kupferlegierungen æ Stangen zur allgemeinen Verwendung This draft European Standard is submitted to CEN members for unique acceptance procedureä It has been drawn up by the
If this draft becomes a European Standardá CEN members are bounwhich stipulate the conditions for giving this European Standard the status of a national standard without any alterationä
This draft European Standard was established by CEN in three ofer language made by translation under the responsibility of a CEN member into its own language and notified to the CENæCENELEC Management Centre has the same status as the official versionsä
CEN members are the national standards bodies of Austriaá Belgiumá Bulgariaá Croatiaá Cyprusá Czech Republicá Denmarká Estoniaá Finlandá Former Yugoslav Republic of Macedoniaá Franceá Germanyá Greeceá Hungaryá Icelandá Irelandá Italyá Latviaá Lithuaniaá Luxembourgá Maltaá Netherlandsá Norwayá Polandá Portugalá Romaniaá Slovakiaá Sloveniaá Spainá Swedená Switzerlandá Turkey and United Kingdomä
Recipients of this draft are invited to submitá with their commentsá notification of any relevant patent rights of which they are aware and to provide supporting documentationä
Warning ã This document is not a European Standardä It is distributed for review and commentsä It is subject to change without notice and shall not be referred to as a European Standardä
EUROPEAN COMMITTEE FOR STANDARDIZATION COMITÉ EUROPÉEN DE NORMALISATION EUROPÄISCHES KOMITEE FÜR NORMUNG
CEN-CENELEC Management Centre:
Avenue Marnix 17,
B-1000 Brussels
9
t r s w CEN All rights of exploitation in any form and by any means reserved worldwide for CEN national Membersä Refä Noä FprEN
s t s x uã t r s w EkSIST FprEN 12163:2015
FprEN 12163:2015 (E) 2 Contents Page European foreword . 4 Introduction . 5 1 Scope . 6 2 Normative references . 6 3 Terms and definitions . 6 4 Designations. 7 4.1 Material . 7 4.1.1 General . 7 4.1.2 Symbol . 7 4.1.3 Number . 7 4.2 Material condition . 7 4.3 Product . 7 5 Ordering information . 9 6 Requirements . 10 6.1 Composition . 10 6.2 Mechanical properties . 10 6.3 Resistance to dezincification . 10 6.4 Residual stress level . 11 6.5 Dimensions and tolerances . 11 6.5.1 Diameter or width across-flats . 11 6.5.2 Shape tolerances . 11 6.5.3 Straightness . 11 6.5.4 Length . 11 6.5.5 Corner radii . 11 6.5.6 Twist of polygonal rod . 11 6.6 Surface quality. 12 7 Sampling . 12 7.1 General . 12 7.2 Analysis . 12 7.3 Mechanical tests . 13 7.4 Dezincification resistance and stress corrosion resistance test . 13 8 Test methods . 13 8.1 Analysis . 13 8.2 Tensile test . 13 8.2.1 General . 13 8.2.2 Location of test pieces . 13 8.2.3 Shape and size of test pieces . 14 8.2.4 Procedure for testing . 14 8.2.5 Determination of results . 14 8.3 Hardness test . 14 8.4 Dezincification resistance test . 14 8.5 Stress corrosion resistance test . 14 kSIST FprEN 12163:2015
FprEN 12163:2015 (E) 3 8.6 Determination of the electrical conductivity . 15 8.7 Retests . 15 8.7.1 Analysis, tensile, hardness and dezincification resistance tests and determination of the electrical conductivity . 15 8.7.2 Stress corrosion resistance test . 15 8.8 Rounding of results . 15 9 Declaration of conformity and inspection documentation . 16 9.1 Declaration of conformity . 16 9.2 Inspection documentation . 16 10 Marking, packaging, labelling . 16 Bibliography . 39
Figures Figure 1 — Measurement of twist of polygonal rod . 12
Tables Table 1 — Composition of low alloyed copper alloys . 17 Table 2 — Composition of copper-aluminium alloys . 18 Table 3 — Composition of copper-nickel alloys . 18 Table 4 — Composition of copper-nickel-zinc alloys . 18 Table 5 — Composition of copper-tin alloys . 19 Table 6 — Composition of copper-zinc alloys . 19 Table 7 — Composition of complex copper-zinc alloys. 20 Table 8 — Mechanical properties of rod of low alloyed copper alloys . 21 Table 9 — Mechanical properties of rod of copper-aluminium alloys . 24 Table 10 — Mechanical properties of rod of copper-nickel alloys . 25 Table 11 — Mechanical properties of rod of copper-nickel-zinc alloys . 26 Table 12 — Mechanical properties of rod of copper-tin alloys . 28 Table 13 — Mechanical properties of rod of copper-zinc alloys . 30 Table 14 — Mechanical properties of rod of complex copper-zinc alloys . 34 Table 15 — Dimensional tolerances for rod . 37 Table 16 — Tolerances on straightness of rod . 37 Table 17 — Corner radii for square and polygonal rod . 37 Table 18 — Maximum twist of square and polygonal rod . 38 Table 19 — Sampling rate . 38
kSIST FprEN 12163:2015
FprEN 12163:2015 (E) 4 European foreword This document (FprEN 12163:2015) has been prepared by Technical Committee CEN/TC 133 “Copper and copper alloys”, the secretariat of which is held by DIN. This document is currently submitted to the Unique Acceptance Procedure. This document will supersede EN 12163:2011. Within its programme of work, Technical Committee CEN/TC 133 requested CEN/TC 133/WG 4 “Extruded and drawn products, forgings and scrap” to revise the following standard: — EN 12163:2011, Copper and copper alloys — Rod for general purposes. This document is one of a series of European Standards for the copper and copper alloy products rod, wire, profile and forgings. Other products are specified as follows: — EN 12164, Copper and copper alloys — Rod for free machining purposes; — EN 12165, Copper and copper alloys — Wrought and unwrought forging stock; — EN 12166, Copper and copper alloys — Wire for general purposes; — EN 12167, Copper and copper alloys — Profiles and bars for general purposes; — EN 12168, Copper and copper alloys — Hollow rod for free machining purposes; — EN 13601, Copper and copper alloys — Copper rod, bar and wire for general electrical purposes; — EN 13602, Copper and copper alloys — Drawn, round copper wire for the manufacture of electrical conductors; — EN 13605, Copper and copper alloys — Copper profiles and profiled wire for electrical purposes. In comparison with EN 12163:2011, the following significant technical changes were made: a) introduction of an optional procedure how to refer to restrictions to the chemical composition imposed by the 4 MS Common Composition List for materials used for products accepted for contact with drinking water; b) requirements and test methods for resistance of dezincification modified; c) provisions for surface quality added; d) mechanical properties for CuZn21Si3P (CW724R) modified. kSIST FprEN 12163:2015
FprEN 12163:2015 (E) 5 Introduction The European Committee for Standardization (CEN) draws attention to the fact that it is claimed that compliance with this document may involve the use of a patent concerning the alloy CuZn21Si3P (CW724R) given in 6.1. CEN takes no position concerning the evidence, validity and scope of this patent right. The holder of this patent right has ensured the CEN that he is willing to negotiate licenses either free of charge or under reasonable and non-discriminatory terms and conditions with applicants throughout the world. In this respect, the statement of the holder of this patent right is registered with CEN. Information may be obtained from: Wieland-Werke AG Graf Arco Straße 36 D-89079 Ulm GERMANY Attention is drawn to the possibility that some of the elements of this document may be the subject of patent rights other than those identified above. CEN shall not be held responsible for identifying any or all such patent rights. CEN and CENELEC maintain online lists of patents relevant to their standards. Users are encouraged to consult the lists for the most up to date information concerning patents (ftp://ftp.cencenelec.eu/EN/IPR/Patents/IPRdeclaration.pdf). Due to developing legislation, the composition of a material may be restricted to the composition specified in this European Standard with respect to individual uses (e.g. for the use in contact with drinking water in some Member States of the European Union). These individual restrictions are not part of this European Standard. Nevertheless, for materials for which traditional and major uses are affected, these restrictions are indicated. The absence of an indication, however, does not imply that the material can be used in any application without any legal restriction. kSIST FprEN 12163:2015
FprEN 12163:2015 (E) 6 1 Scope This European Standard specifies the composition, property requirements and dimensional tolerances for copper alloy rod in the shape of circles, squares, hexagons or octagons, finally produced by drawing or extruding intended for general purposes. The sampling procedures and the methods of test for verification of conformity to the requirements of this European Standard are also specified. 2 Normative references The following documents, in whole or in part, are normatively referenced in this document and are indispensable for its application. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies. EN 1173, Copper and copper alloys — Material condition designation EN 1412, Copper and copper alloys — European numbering system EN 1655, Copper and copper alloys — Declarations of conformity EN 10204, Metallic products
— Types of inspection documents EN 14977, Copper and copper alloys — Detection of tensile stress — 5 % ammonia test EN ISO 6506-1, Metallic materials — Brinell hardness test — Part 1: Test method (ISO 6506-1) EN ISO 6509-1, Corrosion of metals and alloys — Determination of dezincification resistance of copper alloys with zinc — Part 1: Test method (ISO 6509-1) EN ISO 6892-1, Metallic materials — Tensile testing — Part 1: Method of test at room temperature (ISO 6892-1) ISO 1190-1, Copper and copper alloys — Code of designation — Part 1: Designation of materials ISO 6957, Copper alloys — Ammonia test for stress corrosion resistance 3 Terms and definitions For the purposes of this document, the following terms and definitions apply. 3.1 rod straight product of uniform cross-section along its whole length 3.2 deviation from circular form difference between the maximum and the minimum diameters measured at any one cross-section of a round product kSIST FprEN 12163:2015
FprEN 12163:2015 (E) 7 4 Designations 4.1 Material 4.1.1 General The material is designated either by symbol or by number (see Tables 1 to 7). 4.1.2 Symbol The material symbol designation is based on the designation system given in ISO 1190-1. NOTE Although material symbol designations used in this standard might be the same as those in other standards using the designation system given in ISO 1190-1, the detailed composition requirements are not necessarily the same. 4.1.3 Number The material number designation is in accordance with the system given in EN 1412. 4.2 Material condition For the purposes of this standard, the following designations, which are in accordance with the system given in EN 1173, apply for the material condition: M Material condition for the product as manufactured without specified mechanical properties; R. Material condition designated by the minimum value of tensile strength requirement for the product with mandatory tensile property requirements; H. Material condition designated by the minimum value of hardness requirement for the product with mandatory hardness requirements; S (suffix)
Material condition for a product which is stress relieved.
Products in the M, R. or H. material condition may be specially processed (i.e. mechanically or thermally stress relieved) in order to lower the residual stress level to improve the resistance to stress corrosion and the dimensional stability on machining [see Clause 5 list entry l), list entry m) and 8.4]. Exact conversion between material conditions designated R. and H. is not possible. Except when the suffix S is used, material condition is designated by only one of the above designations. 4.3 Product The product designation provides a standardized pattern of designation from which a rapid and unequivocal description of a product is conveyed in communication. It provides mutual comprehension at the international level with regard to products which meet the requirements of the relevant European Standard. The product designation is no substitute for the full content of the standard. The product designation for products to this standard shall consist of: — denomination (Rod); — number of this European Standard (EN 12163); kSIST FprEN 12163:2015
FprEN 12163:2015 (E) 8 — material designation, either symbol or number (see Tables 1 to 7); — DW for compliance in the chemical composition according to 4 MS Common Composition List. This information is mandatory in the case in which the product is used for drinking water applications according to 4 MS Common Composition List and not to be given in other cases; — material condition designation (see Tables 8 to 14); — cross-sectional shape (the following designations shall be used, as appropriate: RND for round, SQR for square, HEX for hexagonal, OCT for octagonal); — nominal cross-sectional dimension (diameter or width across-flats); — tolerance class (see Table 15); — for polygonal rod, the corner shape (the following designations shall be used as appropriate: SH for sharp, RD for rounded), (see Table 17). The derivation of a product designation is shown in the following examples. EXAMPLE 1 Rod for general purposes conforming to this standard, in material designated either CuZn40 or CW509L, for standard applications, in material condition R410, hexagonal, nominal width across-flats 14 mm, tolerance Class B, rounded corners, will be designated as follows: Rod EN 12163 — CuZn40 — R410 — HEX14B — RD or Rod EN 12163 — CW509L — R410 — HEX14B — RD Denomination Number of this European Standard Material designation Material condition designation Cross-sectional shape, nominal cross-sectional dimension in millimetres, tolerance class Corner designation kSIST FprEN 12163:2015
FprEN 12163:2015 (E) 9 EXAMPLE 2 Rod for general purposes conforming to this standard, in material designated either CuZn40 or CW509L, for drinking water applications according to 4 MS Common Composition List, in material condition R410, hexagonal, nominal width across-flats 14 mm, tolerance Class B, rounded corners, will be designated as follows: Rod EN 12163 — CuZn40 — DW — R410 — HEX14B — RD or Rod EN 12163 — CW509L — DW — R410 — HEX14B — RD Denomination Number of this European Standard Material designation For the use in contact with drinking water according to 4 MS Common Composition List, (restriction in chemical composition) Material condition designation Cross-sectional shape, nominal cross-sectional dimension in millimetres, tolerance class Corner designation 5 Ordering information In order to facilitate the enquiry, order and confirmation of order procedures between the purchaser and the supplier, the purchaser shall state on his enquiry and order the following information: a) mass of product required; b) denomination (Rod); c) number of this European Standard (EN 12163); d) material designation (see Tables 1 to 7); e) material condition designation (see 4.2 and Tables 8 to 14) if it is other than M; f) DW for compliance in the chemical composition according to 4 MS Common Composition List. This information is mandatory in the case in which the product is used for drinking water applications according to 4 MS Common Composition List and not to be given in other cases; g) cross-sectional shape; h) nominal cross-sectional dimension (diameter or width across-flats); i) whether other than class A tolerances are required (see Table 15); j) for polygonal rod: whether “sharp” or “rounded” corners are required unless the corner radii shall be left to the discretion of the supplier (see 6.5.5 and Table 17); k) length and length tolerance (see 6.5.4). kSIST FprEN 12163:2015
FprEN 12163:2015 (E) 10 It is recommended that the product designation, as described in 4.3, is used for items b) to k). In addition, the purchaser shall also state on the enquiry and order any or the following, if required: l) whether the products are required to pass a stress corrosion resistance test. If so, which test method shall be used (see 8.5) if the choice is not to be left to the discretion of the supplier. If the purchaser chooses ISO 6957, the pH value for the test solution shall be selected; m) whether the products shall be supplied in a thermally stress relieved material condition; n) whether special surface quality is required (see 6.6); o) whether a declaration of conformity is required (see 9.1); p) whether an inspection document is required, and if so, which type (see 9.2); q) whether there are any special requirements for marking, packaging or labelling (see Clause 10). EXAMPLE Ordering details for 500 kg rod for general purposes conforming to EN 12163, in material designated either CuZn40 or CW509L, for drinking water application according to 4 MS Common Composition List, in material condition R410, hexagonal, nominal width across-flats 14 mm, tolerance class B, rounded corners, length 3 000 mm ± 100 mm:
500 kg Rod EN 12163 — CuZn40 — DW — R410 — HEX14B — RD
— length 3 000 mm ± 100 mm
or
500 kg Rod EN 12163 — CW509L — DW — R410 — HEX14B — RD
— length 3 000 mm ± 100 mm 6 Requirements 6.1 Composition The composition shall conform to the requirements for the appropriate material given in Tables 1 to 7. Due to developing legislation, specific applications (see 4.3) may require restrictions in the chemical composition. In this case the limitations shall be specified in the ordering information [see Clause 5, list entry f)]. 6.2 Mechanical properties The tensile or the hardness properties shall conform to the appropriate requirements given in Tables 8 to 14. The tests shall be carried out in accordance with 8.2 or 8.3. 6.3 Resistance to dezincification The maximum depth of dezincification, in any direction, of CuZn38As (CW511L) and CuZn21Si3P (CW724R)) products shall be 100 µm. The test shall be carried out in accordance with 8.4. NOTE Shape and distribution of ß phase aggregates can influence the dezincification resistance of products. Special requirements relating to shape and distribution of ß phase aggregates are subject to agreement between purchaser and supplier. kSIST FprEN 12163:2015
FprEN 12163:2015 (E) 11 Products in alloy CuZn38As (CW511L) may be subjected to heat treatment in the range 500 °C to 550 °C during manufacture. If the user needs to heat the material above 530 °C during subsequent processing then advice should be sought from the supplier. 6.4 Residual stress level Products ordered and supplied in the stress relieved condition (see 4.2, 2nd paragraph) shall show no evidence of cracking when tested. The tests shall be carried out in accordance with 8.5. 6.5 Dimensions and tolerances 6.5.1 Diameter or width across-flats The diameter or width across-flats shall conform to the tolerances given in Table 15. NOTE The diameter of round rod is calculated as the mean of one or more pairs of measurements taken at right angles at the same cross-section of the rod. 6.5.2 Shape tolerances 6.5.2.1 Round rod The deviation from circular form shall not exceed half the range of the tolerance on diameter given in Table 15. 6.5.2.2 Polygonal rod The width across-flats, measured at the centre of the faces at any one cross-section, shall not differ by more than half the range of the tolerance given for the size in Table 15. 6.5.3 Straightness For rod of diameter, or width across-flats, from 10 mm up to and including 50 mm, and of length 1 000 mm or over, the deviation from straightness, defined as the curvature (depth of arc) against a datum line when the product is lying flat in a horizontal plane, shall conform to the tolerances given in Table 16. NOTE Outside this range, the deviation from straightness is subject to agreement between the purchaser and the supplier. 6.5.4 Length The length and length tolerance shall conform to the requirements stated on the enquiry and order [see Clause 5 list entry k)]. 6.5.5 Corner radii The corner radii of polygonal rod shall conform to Table 17 [see Clause 5 list entry j)]. Except in cases of dispute, the corners should be measured directly, either by use of a gauge or an optical projector. In cases of dispute, the method by optical projector should be used. 6.5.6 Twist of polygonal rod The maximum permitted twist V (see Figure 1) of polygonal rod, as measured between two cross-sections along the rod, shall conform to Table 18. kSIST FprEN 12163:2015
FprEN 12163:2015 (E) 12
Key 1 reference plane V twist
W width across-flats Figure 1 — Measurement of twist of polygonal rod 6.6 Surf
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