ISO 10716:2022
(Main)Paper and board - Determination of alkali reserve
Paper and board - Determination of alkali reserve
This document specifies a method for the determination of the alkali reserve of papers and boards. lt is intended for products that contain alkaline pigments or other alkaline material, added to improve their resistance to acid attack (degradation). This document is not applicable to laminated, printed or otherwise processed grades that will not disintegrate completely by the procedure described. The result obtained will include alkaline pigments contained in the coating of a coated paper. NOTE Such alkaline coating will protect the core of the paper from acid substances in ambient air, but its effect on acid substances generated in the base paper itself is uncertain.
Papier et carton — Détermination de la réserve alcaline
General Information
- Status
- Published
- Publication Date
- 10-Feb-2022
- Technical Committee
- ISO/TC 6 - Paper, board and pulps
- Drafting Committee
- ISO/TC 6/WG 4 - Chemical analysis
- Current Stage
- 6060 - International Standard published
- Start Date
- 11-Feb-2022
- Due Date
- 06-Jan-2023
- Completion Date
- 11-Feb-2022
Relations
- Effective Date
- 26-Nov-2021
Overview
ISO 10716:2022 is the internationally recognized standard for the determination of alkali reserve in paper and board. Established by the International Organization for Standardization (ISO), this method is essential for assessing the alkaline content in papers and boards that contain alkaline pigments or other alkaline materials. These alkaline additives are incorporated to enhance the product’s resistance to acid attack, which can cause degradation over time. This standard ensures reliable testing of alkali reserves, supporting quality control and longevity standards in paper products.
Alkali reserve refers to the paper’s capability to neutralize acids generated either from ambient air or from aging processes. Such stability is critical for documents and products requiring long-term durability and preservation. ISO 10716:2022 focuses on papers and boards that can be fully disintegrated during testing, excluding laminated, printed, or otherwise processed grades.
Key Topics
Scope and Application
Applicable to paper and board products with alkaline fillers including calcium carbonate and other alkaline substances. Not intended for coated or processed paper grades that do not fully disintegrate.Testing Principle
The method involves digesting a representative paper sample by boiling it with a measured amount of hydrochloric acid. The remaining acid is then titrated with sodium hydroxide to determine the amount neutralized by the sample, reflecting the alkali reserve.Reagents and Apparatus
- Hydrochloric acid standard solution (0.10 mol/l)
- Sodium hydroxide titrant (0.1 mol/l)
- Methyl red indicator solution for titration endpoint
- Standard laboratory glassware and equipment
Sample Preparation
Samples must be representative of the batch, typically torn into 15 mm squares and weighed precisely. The test includes a duplicate procedure for accuracy.Calculation
Alkali reserve is calculated in moles per kilogram, providing a consistent unit irrespective of the alkaline substance type. The method specifies how to compute the reserve based on titration volumes and sample mass.Precision and Accuracy
The standard includes precision data from international interlaboratory studies, ensuring reproducibility. Duplicate test results should agree within 0.07 mol/kg for validity.Reporting Requirements
Test reports must include the test reference, sample identification, test date and location, calculated alkali reserve, and any deviations or notable observations during testing.
Applications
ISO 10716:2022 is vital for:
Paper Manufacturing and Quality Control
Ensuring the paper’s alkali content meets specifications aimed at longevity and resistance to acid degradation.Archival and Library Science
Evaluating and certifying papers intended for archival use where chemical stability is crucial.Coated Papers and Boards
Assessing coatings that include alkaline pigments to understand the protection level against atmospheric acids.Environmental Compliance and Product Development
Assisting in the formulation of papers that comply with environmental and durability requirements by selecting appropriate alkaline fillers.
Related Standards
For comprehensive quality assessment and sample handling, ISO 10716:2022 references:
ISO 186: Paper and board - Sampling to determine average quality
Guides the representative sampling of paper and board for testing.ISO 287: Paper and board - Determination of moisture content - Oven-drying method
Specifies moisture content testing, critical for sample conditioning and weight measurements.ISO 638-1: Paper, board, pulps - Determination of dry matter content by oven-drying - Part 1: Materials in solid form
Provides dry matter content determination applicable to sample preparation.
By adhering to ISO 10716:2022 and its related standards, manufacturers and testing laboratories can reliably measure the alkali reserve in paper products, promoting quality assurance and supporting paper permanence in various professional applications.
Frequently Asked Questions
ISO 10716:2022 is a standard published by the International Organization for Standardization (ISO). Its full title is "Paper and board - Determination of alkali reserve". This standard covers: This document specifies a method for the determination of the alkali reserve of papers and boards. lt is intended for products that contain alkaline pigments or other alkaline material, added to improve their resistance to acid attack (degradation). This document is not applicable to laminated, printed or otherwise processed grades that will not disintegrate completely by the procedure described. The result obtained will include alkaline pigments contained in the coating of a coated paper. NOTE Such alkaline coating will protect the core of the paper from acid substances in ambient air, but its effect on acid substances generated in the base paper itself is uncertain.
This document specifies a method for the determination of the alkali reserve of papers and boards. lt is intended for products that contain alkaline pigments or other alkaline material, added to improve their resistance to acid attack (degradation). This document is not applicable to laminated, printed or otherwise processed grades that will not disintegrate completely by the procedure described. The result obtained will include alkaline pigments contained in the coating of a coated paper. NOTE Such alkaline coating will protect the core of the paper from acid substances in ambient air, but its effect on acid substances generated in the base paper itself is uncertain.
ISO 10716:2022 is classified under the following ICS (International Classification for Standards) categories: 85.060 - Paper and board. The ICS classification helps identify the subject area and facilitates finding related standards.
ISO 10716:2022 has the following relationships with other standards: It is inter standard links to ISO 10716:1994. Understanding these relationships helps ensure you are using the most current and applicable version of the standard.
ISO 10716:2022 is available in PDF format for immediate download after purchase. The document can be added to your cart and obtained through the secure checkout process. Digital delivery ensures instant access to the complete standard document.
Standards Content (Sample)
INTERNATIONAL ISO
STANDARD 10716
Second edition
2022-02
Paper and board — Determination of
alkali reserve
Papier et carton — Détermination de la réserve alcaline
Reference number
© ISO 2022
All rights reserved. Unless otherwise specified, or required in the context of its implementation, no part of this publication may
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Published in Switzerland
ii
Contents Page
Foreword .iv
Introduction .v
1 Scope . 1
2 Normative references . 1
3 Terms and definitions . 1
4 Principle . 1
5 Reagents . 1
5.1 Hydrochloric acid . 2
5.2 Sodium hydroxide solution . 2
5.3 Methyl red . 2
6 Apparatus . 2
7 Sampling and preparation of test pieces . 2
8 Procedure .2
9 Calculation . 3
10 Precision . 3
11 Test report . 3
Annex A (informative) Precision . 4
iii
Foreword
ISO (the International Organization for Standardization) is a worldwide federation of national standards
bodies (ISO member bodies). The work of preparing International Standards is normally carried out
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ISO collaborates closely with the International Electrotechnical Commission (IEC) on all matters of
electrotechnical standardization.
The procedures used to develop this document and those intended for its further maintenance are
described in the ISO/IEC Directives, Part 1. In particular, the different approval criteria needed for the
different types of ISO documents should be noted. This document was drafted in accordance with the
editorial rules of the ISO/IEC Directives, Part 2 (see www.iso.org/directives).
Attention is drawn to the possibility that some of the elements of this document may be the subject of
patent rights. ISO shall not be held responsible for identifying any or all such patent rights. Details of
any patent rights identified during the development of the document will be in the Introduction and/or
on the ISO list of patent declarations received (see www.iso.org/patents).
Any trade name used in this document is information given for the convenience of users and does not
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For an explanation of the voluntary nature of standards, the meaning of ISO specific terms and
expressions related to conformity assessment, as well as information about ISO's adherence to
the World Trade Organization (WTO) principles in the Technical Barriers to Trade (TBT), see
www.iso.org/iso/foreword.html.
This document was prepared by Technical Committee ISO/TC 6, Paper, board and pulps.
This second edition cancels and replaces the first edition (ISO 10716:1994), of which it constitutes a
minor revision. The main changes are as follows.
— Clause 2 has been updated.
Any feedback or questions on this document should be directed to the user’s national standards body. A
complete listing of these bodies can be found at www.iso.org/members.html.
iv
Introduction
Papers produced to be stable for long time periods normally contain some alkaline filler, such as calcium
carbonate, as an alkali reserve to prevent attack from acid substances in ambient air or formed by
deterioration of substances in the paper. Specifications for paper permanence can require a minimum
alkali reserve.
The required alkali reserve is obtained by adding some form of calcium carbonate to the paper furnish
but other substances can also be used for this purpose. By expressing the test results in moles per
kilogram of alkaline substances and not as a calcium carbonate content, no confusion arises when
alkaline substances other than calcium carbonate a
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