Fine ceramics (advanced ceramics, advanced technical ceramics) - Measurement of iso-electric point of ceramic powder

This document specifies the test method to determine the iso-electric point of fine ceramic powders, which is measured in the state of suspension.

Céramiques techniques — Mesure du point iso-électrique de poudres céramiques

General Information

Status
Published
Publication Date
26-Nov-2019
Technical Committee
ISO/TC 206 - Fine ceramics
Drafting Committee
ISO/TC 206/WG 2 - Powders
Current Stage
9093 - International Standard confirmed
Start Date
18-Apr-2025
Completion Date
13-Dec-2025

Relations

Effective Date
06-Jun-2022

Overview

ISO 21822:2019 specifies a laboratory test method to determine the iso-electric point (IEP) of fine ceramic powders measured in the state of suspension. The IEP is the pH at which dispersed ceramic particles have zero zeta potential, a critical condition affecting colloidal stability, agglomeration and processing behavior. This standard guides sample preparation, dispersion, measurement and reporting to ensure reproducible IEP determination for advanced/technical ceramics.

Key topics and technical requirements

  • Measurement principle: Zeta potential may be measured by electrophoretic light scattering (ELS), streaming potential or electroacoustic methods in accordance with ISO 13099 parts.
  • Sample preparation: Use ion-exchanged distilled water as dispersion medium and prepare a ceramic slurry; recommended mass fraction typically ranges from 1 % to 10 % depending on particle size. Specific concentrations are provided for different measurement methods (e.g., streaming potential, electroacoustic, ELS).
  • Dispersion and sonication: Tip sonicator is preferred (1–5 min sonication with stabilization) or ultrasonic bath (≥3 min under specified power). Stabilize suspensions (recommended 30 min) and sample the supernatant.
  • Chemicals and electrolyte: pH adjustment using HCl or HNO3 (acids) and NaOH or NH4OH (bases) is allowed; electrolytes such as NaCl or NH4NO3 are recommended. The standard specifies appropriate electrolyte concentrations for reliable measurements.
  • Instrumentation and calibration: Use a calibrated zeta potential analyser and pH meter (pH measuring range recommended within pH 2–10). Record instrument model, measuring principle and calibration evidence.
  • Measurement procedure: Measure zeta potential and pH across a pH range (commonly pH 2–10), plot pH versus zeta potential and read the IEP where the curve crosses zero zeta potential (to one decimal place). Note that zeta potential values near ±10 mV can have low reproducibility.
  • Reporting: Test report must include sample ID, reference to ISO 21822:2019, instrument details, electrolyte and pH-adjusting agents, dispersion conditions, stabilization time, IEP data and zeta potential–pH graph.

Applications and users

ISO 21822:2019 is practical for:

  • Ceramic materials scientists and R&D teams characterizing surface charge and dispersion behavior.
  • Quality control laboratories for powders, slurries and coatings in ceramics, pigments, catalysts and functional materials.
  • Process engineers optimizing slurry stability, milling, casting, and formulation of ceramic suspensions.
  • Instrument manufacturers and service labs validating zeta potential analysers and measurement workflows.

Keywords: ISO 21822:2019, iso-electric point, zeta potential, fine ceramics, ceramic powder, suspension measurement, zeta potential analyser.

Related standards

  • ISO 13099-1 / -2 / -3 - Methods for zeta-potential determination (electroacoustic, optical, streaming)
  • ISO 4316 - Potentiometric pH determination
  • ISO 20507 - Fine ceramics vocabulary
Standard

ISO 21822:2019 - Fine ceramics (advanced ceramics, advanced technical ceramics) — Measurement of iso-electric point of ceramic powder Released:11/27/2019

English language
7 pages
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Frequently Asked Questions

ISO 21822:2019 is a standard published by the International Organization for Standardization (ISO). Its full title is "Fine ceramics (advanced ceramics, advanced technical ceramics) - Measurement of iso-electric point of ceramic powder". This standard covers: This document specifies the test method to determine the iso-electric point of fine ceramic powders, which is measured in the state of suspension.

This document specifies the test method to determine the iso-electric point of fine ceramic powders, which is measured in the state of suspension.

ISO 21822:2019 is classified under the following ICS (International Classification for Standards) categories: 81.060.30 - Advanced ceramics. The ICS classification helps identify the subject area and facilitates finding related standards.

ISO 21822:2019 has the following relationships with other standards: It is inter standard links to ISO 11403-3:2021. Understanding these relationships helps ensure you are using the most current and applicable version of the standard.

You can purchase ISO 21822:2019 directly from iTeh Standards. The document is available in PDF format and is delivered instantly after payment. Add the standard to your cart and complete the secure checkout process. iTeh Standards is an authorized distributor of ISO standards.

Standards Content (Sample)


INTERNATIONAL ISO
STANDARD 21822
First edition
2019-11
Fine ceramics (advanced ceramics,
advanced technical ceramics) —
Measurement of iso-electric point of
ceramic powder
Céramiques techniques — Mesure du point iso-électrique de poudres
céramiques
Reference number
©
ISO 2019
© ISO 2019
All rights reserved. Unless otherwise specified, or required in the context of its implementation, no part of this publication may
be reproduced or utilized otherwise in any form or by any means, electronic or mechanical, including photocopying, or posting
on the internet or an intranet, without prior written permission. Permission can be requested from either ISO at the address
below or ISO’s member body in the country of the requester.
ISO copyright office
CP 401 • Ch. de Blandonnet 8
CH-1214 Vernier, Geneva
Phone: +41 22 749 01 11
Fax: +41 22 749 09 47
Email: copyright@iso.org
Website: www.iso.org
Published in Switzerland
ii © ISO 2019 – All rights reserved

Contents Page
Foreword .iv
1 Scope . 1
2 Normative references . 1
3 Terms and definitions . 1
4 Principle . 3
5 Apparatus and calibration . 3
5.1 Zeta potential analyser and calibration . 3
5.2 pH meter . 3
5.3 Sample dispersion vessel . 3
5.4 Sonicator . 4
5.5 Balance . 4
5.6 Temperature-control device . 4
5.7 Magnetic stirrer . 4
6 Operational procedures . 4
6.1 Dispersion solution . 4
6.2 pH-adjusting acid or base and electrolyte solution . 4
6.3 Sample preparation and dispersion . 4
6.3.1 Preparation . 4
6.3.2 Dispersion . 4
6.3.3 Stabilization . 5
7 Measurement . 5
8 Determination of the iso-electric point . 5
9 Test report . 6
Bibliography . 7
Foreword
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electrotechnical standardization.
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different types of ISO documents should be noted. This document was drafted in accordance with the
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iso/ foreword .html.
This document was prepared by Technical Committee ISO/TC 206, Fine ceramics.
Any feedback or questions on this document should be directed to the user’s national standards body. A
complete listing of these bodies can be found at www .iso .org/ members .html.
iv © ISO 2019 – All rights reserved

INTERNATIONAL STANDARD ISO 21822:2019(E)
Fine ceramics (advanced ceramics, advanced technical
ceramics) — Measurement of iso-electric point of
ceramic powder
1 Scope
This document specifies the test method to determine the iso-electric point of fine ceramic powders,
which is measured in the state of suspension.
2 Normative references
The following documents are referred to in the text in such a way that some or all of their content
constitutes requirements of this document. For dated references, only the edition cited applies. For
undated references, the latest edition of the referenced document (including any amendments) applies.
ISO 4316, Surface active agents — Determination of pH of aqueous solutions — Potentiometric method
ISO 13099-1, Colloidal systems — Methods for zeta-potential determination — Part 1: Electroacoustic and
electrokinetic phenomena
ISO 13099-2, Colloidal systems — Methods for zeta-potential determination — Part 2: Optical methods
ISO 13099-3, Colloidal systems — Methods for zeta potential determination — Part 3: Acoustic methods
3 Terms and definitions
For the purposes of this document, the terms and definitions given in ISO 13099-1, ISO 13099-2 and
ISO 13099-3 and the following apply.
ISO and IEC maintain terminological databases for use in standardization at the following addresses:
— ISO Online browsing platform: available at https:// www .iso .org/ obp
— IEC Electropedia: available at http:// www .electropedia .org/
3.1
zeta potential
ζ-potential
difference between the electric potential at the slipping plane and that of the bulk
...

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