EN ISO 4829-1:2018

SLOVENSKI STANDARD
01-julij-2018
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SIST EN 24829-1:1997
SIST EN 24829-1:1997/AC:1997
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Steel and cast iron - Determination of total silicon contents - Reduced molybdosilicate
spectrophotometric method - Part 1: Silicon contents between 0,05 % and 1,0 % (ISO
4829-1:2018)
Stahl- und Gusseisen - Bestimmung des Gesamtsiliciumanteils - Spektrophotometrische
Methode mit reduziertem Molybdatosilicat - Teil 1: Siliciumanteile zwischen 0,05 % und
1,0 % (ISO 4829-1:2018)
Aciers et fontes - Détermination du silicium total - Méthode spectrophotométrique au
silicomolybdate réduit - Partie 1: Teneurs en silicium comprises entre 0,05 % et 1,0 %
(ISO 4829-1:2018)
Ta slovenski standard je istoveten z: EN ISO 4829-1:2018
ICS:
77.040.30 Kemijska analiza kovin Chemical analysis of metals
77.080.01 Železne kovine na splošno Ferrous metals in general
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.

EN ISO 4829-1
EUROPEAN STANDARD
NORME EUROPÉENNE
May 2018
EUROPÄISCHE NORM
ICS 77.080.01 Supersedes EN 24829-1:1990
English Version
Steel and cast iron - Determination of total silicon contents
- Reduced molybdosilicate spectrophotometric method -
Part 1: Silicon contents between 0,05 % and 1,0 % (ISO
4829-1:2018)
Aciers et fontes - Détermination du silicium total - Stahl- und Gusseisen - Bestimmung des
Méthode spectrophotométrique au silicomolybdate Gesamtsiliciumanteils - Spektrophotometrische
réduit - Partie 1: Teneurs en silicium comprises entre Methode mit reduziertem Molybdatosilicat - Teil 1:
0,05 % et 1,0 % (ISO 4829-1:2018) Siliciumanteile zwischen 0,05 % und 1,0 % (ISO 4829-
1:2018)
This European Standard was approved by CEN on 6 March 2018.

CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this
European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references
concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN
member.
This European Standard exists in three official versions (English, French, German). A version in any other language made by
translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management
Centre has the same status as the official versions.

CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,
Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania,
Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland,
Turkey and United Kingdom.
EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION

EUROPÄISCHES KOMITEE FÜR NORMUNG

CEN-CENELEC Management Centre: Rue de la Science 23, B-1040 Brussels
© 2018 CEN All rights of exploitation in any form and by any means reserved Ref. No. EN ISO 4829-1:2018 E
worldwide for CEN national Members.

Contents Page
European foreword . 3

European foreword
This document (EN ISO 4829-1:2018) has been prepared by Technical Committee ISO/TC 17 "Steel" in
collaboration with Technical Committee ECISS/TC 102 “Methods of chemical analysis for iron and steel”
the secretariat of which is held by SIS.
This European Standard shall be given the status of a national standard, either by publication of an
identical text or by endorsement, at the latest by November 2018, and conflicting national standards
shall be withdrawn at the latest by November 2018.
Attention is drawn to the possibility that some of the elements of this document may be the subject of
patent rights. CEN shall not be held responsible for identifying any or all such patent rights.
This document supersedes EN 24829-1:1990.
According to the CEN-CENELEC Internal Regulations, the national standards organizations of the
following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria,
Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia,
France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta,
Netherlands, Norway, Poland, Portugal, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland,
Turkey and the United Kingdom.
Endorsement notice
The text of ISO 4829-1:2018 has been approved by CEN as EN ISO 4829-1:2018 without any
modification.
INTERNATIONAL ISO
STANDARD 4829-1
Second edition
2018-03
Steel and cast iron — Determination
of total silicon contents — Reduced
molybdosilicate spectrophotometric
method —
Part 1:
Silicon contents between 0,05 % and
1,0 %
Aciers et fontes — Détermination du silicium total — Méthode
spectrophotométrique au silicomolybdate réduit —
Partie 1: Teneurs en silicium comprises entre 0,05 % et 1,0 %
Reference number
ISO 4829-1:2018(E)
©
ISO 2018
ISO 4829-1:2018(E)
© ISO 2018
All rights reserved. Unless otherwise specified, or required in the context of its implementation, no part of this publication may
be reproduced or utilized otherwise in any form or by any means, electronic or mechanical, including photocopying, or posting
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Published in Switzerland
ii © ISO 2018 – All rights reserved

ISO 4829-1:2018(E)
Contents Page
Foreword .iv
1 Scope . 1
2 Normative references . 1
3 Terms and definitions . 1
4 Principle . 1
5 Reagents . 2
6 Apparatus . 3
7 Sampling . 4
8 Procedure. 4
8.1 Test portion . 4
8.2 Blank test . 4
8.3 Determination . 4
8.3.1 Dissolution of the test portion . 4
8.3.2 Treatment of insoluble residue . 5
8.3.3 Preparation of the test solution . 5
8.3.4 Development of the colour . 5
8.3.5 Spectrophotometric measurements . 6
8.4 Establishment of the calibration curve . 6
8.4.1 Preparation of the calibration solutions . 6
8.4.2 Spectrophotometric measurements . 6
8.4.3 Plotting of the calibration curves . 6
9 Expression of results . 7
9.1 Method of calculation . 7
9.2 Precision . 8
10 Test report . 8
Annex A (informative) Additional information on the international interlaboratory test.9
Annex B (informative) Graphical representation of precision data .10
Bibliography .11
ISO 4829-1:2018(E)
Foreword
ISO (the International Organization for Standardization) is a worldwide federation of national standards
bodies (ISO member bodies). The work of preparing International Standards is normally carried out
through ISO technical committees. Each member body interested in a subject for which a technical
committee has been established has the right to be represented on that committee. International
organizations, governmental and non-governmental, in liaison with ISO, also take part in the work.
ISO collaborates closely with the International Electrotechnical Commission (IEC) on all matters of
electrotechnical standardization.
The procedures used to develop this document and those intended for its further maintenance are
described in the ISO/IEC Directives, Part 1. In particular the different approval criteria needed for the
different types of ISO documents should be noted. This document was drafted in accordance with the
editorial rules of the ISO/IEC Directives, Part 2 (see www .iso .org/ directives).
Attention is drawn to the possibility that some of the elements of this document may be the subject of
patent rights. ISO shall not be held responsible for identifying any or all such patent rights. Details of
any patent rights identified during the development of the document will be in the Introduction and/or
on the ISO list of patent declarations received (see www .iso .org/ patents).
Any trade name used in this document is information given for the convenience of users and does not
constitute an endorsement.
For an explanation on the voluntary nature of standards, the meaning of ISO specific terms and
expressions related to conformity assessment, as well as information about ISO's adherence to the
World Trade Organization (WTO) principles in the Technical Barriers to Trade (TBT) see the following
URL: www .iso .org/ iso/ foreword .html.
This document was prepared by Technical Committee ISO/TC 17, Steel, Subcommittee SC 1, Methods of
determination of chemical composition.
This second edition cancels and replaces the first edition (ISO 4829-1:1986), which has been technically
revised.
A list of all the parts in the ISO 4829 series can be found on the ISO website.
iv © ISO 2018 – All rights reserved

INTERNATIONAL STANDARD ISO 4829-1:2018(E)
Steel and cast iron — Determin
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