Textiles and textile products - Determination of certain residual solvents - Part 2: Determination of benzene, method using headspace gas chromatography

This document specifies a method using headspace gas chromatography and mass selective spectroscopy (HS-GC-MS) for detection and quantification of benzene in components of textile products.

Textilien und textile Erzeugnisse - Bestimmung von bestimmten Lösemittelrückständen - Teil 2: Bestimmung von Benzol, Verfahren mittels Headspace-Gaschromatographie

Dieses Dokument legt ein Verfahren zum Nachweis und zur quantitativen Bestimmung von Benzol in Bestandteilen textiler Erzeugnisse unter Anwendung von Headspace-Gaschromatographie und massenselektiver Spektroskopie (HS-GC-MS) fest.
WARNUNG - Die Anwendung dieses Dokuments umfasst gefährliche Stoffe. Es wird nicht der Anspruch erhoben, dass in diesem Dokument alle mit ihrer Anwendung verbundenen Sicherheits- und Umweltrisiken angemessen behandelt werden. Es liegt in der Verantwortung der Personen, die dieses Dokument anwenden, die geeigneten Maßnahmen zu ergreifen, um den Sicherheits- und Gesundheitsschutz des Personals und der Umwelt vor Anwendung des Dokuments sicherzustellen und die diesem Zweck dienenden gesetzlichen und behördlichen Anforderungen zu erfüllen.

Textiles et produits textiles - Détermination de certains solvants résiduels - Partie 2 : Détermination du benzène, méthode par chromatographie en phase gazeuse à espace de tête

Le présent document spécifie une méthode utilisant la chromatographie en phase gazeuse à espace de tête et la spectroscopie sélective de masse (HS-GC-MS) pour la détection et la quantification du benzène dans les composants de produits textiles.

Tekstilije in tekstilni izdelki - Določevanje nekaterih preostalih topil - 2. del: Določevanje benzena, metoda z uporabo "headspace" plinske kromatografije

General Information

Status
Not Published
Publication Date
25-May-2025
Current Stage
4599 - Dispatch of FV draft to CMC - Finalization for Vote
Start Date
21-Aug-2024
Due Date
25-Nov-2024
Completion Date
21-Aug-2024

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SLOVENSKI STANDARD
01-januar-2024
Tekstilije in tekstilni izdelki - Določevanje nekaterih preostalih topil - 2. del:
Določevanje benzena, metoda z uporabo "headspace" plinske kromatografije
Textiles and textile products - Determination of certain residual solvents - Part 2:
Determination of benzene, method using headspace gas chromatography
Textilien und textile Erzeugnisse - Bestimmung von bestimmten Lösemittelrückständen -
Teil 2: Bestimmung von Benzol, Verfahren mittels Headspace-Gaschromatographie
Textiles et produits textiles - Détermination de certains solvants résiduels - Partie 2 :
Détermination du benzène, méthode par chromatographie en phase gazeuse à espace
de tête
Ta slovenski standard je istoveten z: prEN 17131-2
ICS:
59.080.01 Tekstilije na splošno Textiles in general
71.040.50 Fizikalnokemijske analitske Physicochemical methods of
metode analysis
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.

DRAFT
EUROPEAN STANDARD
NORME EUROPÉENNE
EUROPÄISCHE NORM
November 2023
ICS 59.080.01 Will supersede EN 17131:2019
English Version
Textiles and textile products - Determination of certain
residual solvents - Part 2: Determination of benzene,
method using headspace gas chromatography
Produits textiles - Textiles et produits textiles - Textilien und textile Erzeugnisse - Bestimmung von
Détermination du xxx, méthode par chromatographie Lösemittelrückständen - Teil 2: Bestimmung von
en phase gazeuse Benzol, Verfahren mittels Headspace-
Gaschromatographie
This draft European Standard is submitted to CEN members for enquiry. It has been drawn up by the Technical Committee
CEN/TC 248.
If this draft becomes a European Standard, CEN members are bound to comply with the CEN/CENELEC Internal Regulations
which stipulate the conditions for giving this European Standard the status of a national standard without any alteration.

This draft European Standard was established by CEN in three official versions (English, French, German). A version in any other
language made by translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC
Management Centre has the same status as the official versions.

CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,
Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway,
Poland, Portugal, Republic of North Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Türkiye and
United Kingdom.
Recipients of this draft are invited to submit, with their comments, notification of any relevant patent rights of which they are
aware and to provide supporting documentation.

Warning : This document is not a European Standard. It is distributed for review and comments. It is subject to change without
notice and shall not be referred to as a European Standard.

EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION

EUROPÄISCHES KOMITEE FÜR NORMUNG

CEN-CENELEC Management Centre: Rue de la Science 23, B-1040 Brussels
© 2023 CEN All rights of exploitation in any form and by any means reserved Ref. No. prEN 17131-2:2023 E
worldwide for CEN national Members.

Contents Page
European foreword . 3
Introduction . 4
1 Scope . 5
2 Normative references . 5
3 Terms and definitions . 5
4 Principle . 5
5 Reagents . 5
6 Equipment . 6
7 Preparation of test samples . 6
8 Procedure. 7
9 Expression of results . 8
10 Test report . 8
Annex A (informative) Example of instrumental conditions. 9
A.1 Measuring technique . 9
A.2 Chromatographic conditions . 9
A.3 MS conditions . 9
Annex B (informative) Reliability of the method. 10
Bibliography . 11

European foreword
This document (prEN 17131-2:2023) has been prepared by Technical Committee CEN/TC 248 “Textiles
and textile products”, the secretariat of which is held by BSI.
This document is currently submitted to the CEN Enquiry.
Introduction
In Europe, according to Regulation (EU) 2018/1513 [1] amending Annex XVII to Regulation (EC) No
1907/2006 (REACH) by Entry 72, (a) clothing or related accessories; (b) textiles other than clothing
which, under normal or reasonably foreseeable conditions of use, come into contact with human skin to
an extent similar to clothing; (c) footwear are not to be placed on the market after 1 November 2020, if
they contain more than 5 mg/kg of benzene.
This restriction does not apply to: (a) clothing, related accessories or footwear, or parts of clothing,
related accessories or footwear, made exclusively of natural leather, fur or hide; (b) non-textile fasteners
and non-textile decorative attachments; (c) second-hand clothing, related accessories, textiles other than
clothing or footwear; (d) wall-to-wall carpets and textile floor coverings for indoor use, rugs and runners.
It also does not apply to clothing, related accessories, textiles other than clothing, or footwear within the
scope of Regulation (EU) 2016/425 or Regulation (EU) 2017/745. The restriction on textiles other than
clothing does not apply to disposable textiles. “Disposable textiles” means textiles that are designed to be
used only once or for a limited time and are not intended for subsequent use for the same or a similar
purpose.
Although the regulation excludes non-textile fastenings and decorative items, this method is also suitable
for such materials.
WARNING — The use of this document involves hazardous materials. It does not purport to address all
of the safety or environmental problems associated with its use. It is the responsibility of users of this
document to take appropriate measures to ensure the safety and health of personnel and the
environment prior to application of the document and fulfil statutory and regulatory requirements for
this purpose.
1 Scope
This document specifies a method using headspace gas chromatography and mass selective spectroscopy
(HS-GC-MS) for detection and quantification of benzene in components of textile products.
2 Normative references
The following documents are referred to in the text in such a way that some or all of their content
constitutes requirements of this document. For dated references, only the edition cited applies. For
undated references, the latest edition of the referenced document (including any amendments) applies.
EN ISO 4787, Laboratory glass and plastic ware - Volumetric instruments - Methods for testing of capacity
and for use (ISO 4787)
3 Terms and definitions
No terms and definitions are listed in this document.
ISO and IEC maintain terminological databases for use in standardization at the following addresses:
• IEC Electropedia: available at https://www.electropedia.org/
• ISO Online browsing platform: available at https://
...

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