FprEN 1420

SLOVENSKI STANDARD
01-februar-2025
Vpliv organskih snovi na pitno vodo - Ugotavljanje vonja, okusa, barve in motnosti
vode v vodovodnih in skladniščnih sistemih
Influence of organic materials on water intended for human consumption - Determination
of odour, flavour, colour and turbidity of water in piping and storage systems
Einfluss von organischen Werkstoffen auf Wasser für den menschlichen Gebrauch -
Bestimmung des Geruchs und Geschmacks des Wassers in Rohrleitungssystemen
Influence des matériaux organiques sur l'eau destinée à la consommation humaine -
Détermination de l'odeur, de la flaveur, de la couleur et de la turbidité de l'eau dans les
réseaux de conduites et les systèmes de stockage
Ta slovenski standard je istoveten z: prEN 1420
ICS:
13.060.20 Pitna voda Drinking water
91.140.60 Sistemi za oskrbo z vodo Water supply systems
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.

DRAFT
EUROPEAN STANDARD
prEN 1420
NORME EUROPÉENNE
EUROPÄISCHE NORM
December 2024
ICS 13.060.20 Will supersede EN 1420:2016
English Version
Influence of organic materials on water intended for
human consumption - Determination of odour, flavour,
colour and turbidity of water in piping and storage
systems
Influence des matériaux organiques sur l'eau destinée Einfluss von organischen Werkstoffen auf Wasser für
à la consommation humaine - Détermination de den menschlichen Gebrauch - Bestimmung des Geruchs
l'odeur, de la flaveur, de la couleur et de la turbidité de und Geschmacks des Wassers in Rohrleitungssystemen
l'eau dans les réseaux de conduites et les systèmes de
stockage
This draft European Standard is submitted to CEN members for enquiry. It has been drawn up by the Technical Committee
CEN/TC 164.
If this draft becomes a European Standard, CEN members are bound to comply with the CEN/CENELEC Internal Regulations
which stipulate the conditions for giving this European Standard the status of a national standard without any alteration.

This draft European Standard was established by CEN in three official versions (English, French, German). A version in any other
language made by translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC
Management Centre has the same status as the official versions.

CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,
Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway,
Poland, Portugal, Republic of North Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Türkiye and
United Kingdom.
Recipients of this draft are invited to submit, with their comments, notification of any relevant patent rights of which they are
aware and to provide supporting documentation.

Warning : This document is not a European Standard. It is distributed for review and comments. It is subject to change without
notice and shall not be referred to as a European Standard.

EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION

EUROPÄISCHES KOMITEE FÜR NORMUNG

CEN-CENELEC Management Centre: Rue de la Science 23, B-1040 Brussels
© 2024 CEN All rights of exploitation in any form and by any means reserved Ref. No. prEN 1420:2024 E
worldwide for CEN national Members.

prEN 1420:2024 (E)
Contents Page
European foreword . 4
Introduction . 5
1 Scope . 6
2 Normative references . 6
3 Terms and definitions . 6
4 Principle . 8
5 Reagents . 9
5.1 Waters to be used for testing . 9
5.2 Sodium hypochlorite solution . 9
5.3 Sodium thiosulfate solution . 9
5.4 Ascorbic acid solution . 9
5.5 1-Butanol (analytic reagent grade) . 9
5.6 2-Methoxy-2-methylpropane (Methyl-tert-butyl ether, MtBE) (analytic reagent
grade) . 9
5.7 Cleaning liquids for glassware . 9
6 Apparatus . 10
7 Sampling, transport, storage, and preparation of test pieces . 10
7.1 General. 10
7.2 Site-applied products . 11
7.3 Surface-area-to-volume ratio (S/V) . 11
8 Preparation of reagents and apparatus . 13
8.1 Test water . 13
8.2 Test water with chlorine content . 13
8.3 Cleaning of glassware . 13
9 Pretreatment of test pieces . 13
9.1 General. 13
9.2 Test pieces to be tested at (23 ± 2) °C (Cold water test) . 14
9.3 Test pieces to be tested at elevated temperature (60 °C or 85 °C) . 14
9.4 Prewashing . 14
10 Test procedure . 15
10.1 General. 15
10.2 Cold water test procedure . 15
10.3 Elevated temperature test procedure . 15
11 Determination of TON and TFN . 16
12 Determination of colour and turbidity . 16
13 Expression of results . 16
14 Test report . 16
14.1 General information . 16
14.2 Information on the product/material . 17
14.3 Information for site-applied products . 17
prEN 1420:2024 (E)
14.4 Information on the test procedure . 18
14.5 Test results. 18
Annex A (informative) Schematic presentation of test method. 19
Annex B (normative) Sequence of additional migration periods . 21
Annex C (normative) Panel qualification for odour and flavour testing . 23
C.1 General . 23
C.2 Individual TON determination. 23
C.3 Ranking test . 24
C.4 Long term monitoring . 24
Annex D (informative) Preparation of dilution series for panel qualification . 25
D.1 Series of successive MtBE dilutions . 25
D.2 Series of successive 1-butanol concentrations . 25
Bibliography . 27

prEN 1420:2024 (E)
European foreword
This document (prEN 1420:2024) has been prepared by Technical Committee CEN/TC 164 “Water
supply”, the secretariat of which is held by AFNOR.
This document will supersede EN 1420-1:2016.
This document includes the following standards:
— EN 13052-1:2001, Influence of materials on water intended for human consumption – Organic
materials – Determination of colour and turbidity of water in piping systems – Part 1: Test method
— EN 14395-1:2004, Influence of organic materials on water intended for human consumption —
Organoleptic assessment of water in storage systems — Part 1: Test method
This document has been prepared under a mandate given to CEN by the European Commission and the
European Free Trade Association.
prEN 1420:2024 includes the following significant technical changes with respect to EN 1420-1:2016:
— the test methods for turbidity and colour have been included,
— the scope of the standard has been extended: all organic products (included storage systems) can
be tested according to this standard.
prEN 1420:2024 (E)
Introduction
In respect of potential adverse effects on the quality of the water intended for human consumption,
arising from contact with materials used for conveying and distribution, it is recalled to mind that,
national regulations remain in force.
prEN 1420:2024 (E)
1 Scope
This document specifies a procedure for obtaining a migration water to determine odour, flavour,
colour and turbidity for products made from organic materials intended to come in contact with water
for human consumption (drinking water) and used in piping and storage systems. Such products
include pipes, tanks, reservoirs, fittings, ancillaries and their coatings both for site applied and factory-
made products.
This document is applicable to products to be used under various conditions for the transport, storage
and distribution of water intended for human consumption and raw water used for the manufacture of
water intended for human consumption.
This document specifies a test method comprising a set of procedures. The use might be dependent on
the relevant national regulations and/or the system or product standards.
2 Normative references
The following documents are referred to in the text in such a way that some or all of their content
constitutes requirements of this document. For dated references, only the edition cited applies. For
undated references, the latest edition of the referenced document (including any amendments) applies.
EN 1622, Water quality — Determination of the threshold odour number (TON) and threshold flavour
number (TFN)
EN 12873-1, Influence of materials on water intended for human consumption — Influence due to
migration — Part 1: Test method for factory-made products made from or incorporating organic or glassy
(porcelain/vitreous enamel) materials
EN 12873-2, Influence of materials on water intended for human consumption — Influence due to
migration — Part 2: Test method for non-metallic and noncementitious site-applied materials
EN ISO 7393-2, Water quality — Determination of free chlorine and total chlorine — Part 2: Colorimetric
method using N,N-dialkyl-1,4-phenylenediamine, for routine control purposes (ISO 7393-2)
EN ISO 7027-1, Water quality — Determination of turbidity — Part 1: Quantitative methods (ISO 7027-1)
EN ISO 7887, Water quality — Examination and determination of colour (ISO 7887)
3 Terms and definitions
For the purposes of this document, the following terms and definitions apply.
ISO and IEC maintain terminology databases for use in standardization at the following addresses:

— ISO Online browsing platform: available at https://www.iso.org/obp/
— IEC Electropedia: available at https://www.electropedia.org/
3.1
blank water
test water which has been kept at the same specified conditions as migration water but without contact
with the test piece
prEN 1420:2024 (E)
3.2
colour
optical property that causes the changing of the spectral composition of transmitted visible light
measured at three wavelengths
[SOURCE: EN ISO 7887, 3]
3.3
fitting, ancillary
complete functional unit made up of one or more components and materials, parts of which are in
contact with drinking water, e.g. taps, valves
3.4
flavour
complex combination of the olfactory, gustatory and trigeminal sensations perceived during tasting
which may be influenced by tactile, thermal, painful and/or kinaesthesic effects
[SOURCE: EN ISO 5492]
3.5
membranes
elastomer as used in pressure relief devices
3.6
migration water
test water which has been in contact with a test piece under specified conditions
3.7
odour
organoleptic attribute perceptible by the olfactory organ on sniffing certain volatile substances
[SOURCE: EN ISO 5492]
3.8
panel coordinator
person responsible for the qualification of the members of the odour/flavour panel (panellists) and the
check of the reliability of the determined TON-/TFN-results
3.9
prewashing water
tapwater without any odour and flavour and a chlorine content less than 0,05 mg/l as Cl
3.10
product
manufactured item, in its finished form
3.11
sample
one or more units, or a specified quantity, drawn from a batch or lot, selected at random for inspection
3.12
site-applied product
product where the final surface in contact with drinking water is prepared on site
prEN 1420:2024 (E)
3.13
storage vessels
tanks, reservoirs, cisterns and their coatings
3.14
test piece
sample or portion of sample that is conditioned, treated or otherwise prepared to be tested to obtain a
single test result
3.15
test water
water used for testing purposes prepared as described in 5.1.1 and 5.1.2
3.16
testing panel
group of people meeting the relevant requirements of EN 1622
3.17
threshold flavour number – TFN
dilution ratio beyond which the diluted sample does not have any perceptible flavour
[SOURCE: EN 1622:2006, 3.4]
3.18
threshold odour number –TON
dilution ratio beyond which the diluted sample does not have any perceptible odour
[SOURCE: EN 1622:2006, 3.3]
3.19
turbidity
reduction of transparency of a liquid caused by the presence of undissolved matter
[SOURCE: EN ISO 7027-1, 3]
4 Principle
Following a defined pretreatment procedure of flushing, stagnation with test water and then
prewashing, the surface of the test pieces, exposed in practice to drinking water, is brought into contact
with test waters.
The migration procedure is carried out under specified conditions as follows: test pieces are put in
contact with chlorinated and where required unchlorinated test waters for 72 h at (23 ± 2) °C (cold
water test), or put in contact with unchlorinated test water for 24 h at temperature of (60 ± 2) °C (warm
water test) or (85 ± 2) °C (hot water test). If warm or hot water test is required, additionally a cold
water test shall be performed.
NOTE The choice of the type of test water (chlorinated and/or chlorine-free), the temperature of the test
water, the number of additional migration periods will be specified in product standards or national regulations.
After this contact, the migration water is assessed for colour and turbidity (see Clause 12) and by a test
panel to determine the TON and TFN (see Clause 11).
prEN 1420:2024 (E)
Additional information concerning the temperature to be used in the test and the sequence of extraction
periods is given in Clause 10.
5 Reagents
5.1 Waters to be used for testing
5.1.1 Test water shall be without any perceptible odour and flavour, and with a spectral absorption
-1
coefficient less than 0,1 m , with an NTU < 0,1. The test water shall be conformed to the reference
water in EN 1622.
NOTE Reference water is the term used in EN 1622, which has the same characteristics as the water used for
the testing in the present standard, referred as test water.
5.1.2 Chlorinated test water shall consist of test water (5.1.1) with a free chlorine content of (1 ± 0,2)
mg/l as Cl after addition of sodium hypochlorite solution (5.2). When chlorinated test water is
dechlorinated after 72 h (see Clause 11) with sodium thiosulfate (5.3) or ascorbic acid (5.4), it shall
have no perceptible odour and flavour.
5.2 Sodium hypochlorite solution
Sodium hypochlorite solution, prepared from a technical or general purpose reagent grade of sodium
hypochlorite (NaOCl), using test water (5.1.1) and having a known concentration of about 0,1 % by
mass of free chlorine determined in accordance with EN ISO 7393-2.
NOTE This sodium hypochlorite solution is unstable, and it is important to prepare it on the day of use.
5.3 Sodium thiosulfate solution
Sodium thiosulfate solution, comprising a solution of 3,5 g per litre of sodium thiosulfate pentahydrate
(Na S O⋅5H O) analytical grade, stored in the absence of light at a temperature below 10 °C, for a
2 2 3 2
maximum of 1 week. Two ml of this solution will neutralize 1 mg/l of residual chlorine in 1 l of water.
Occasionally this solution causes odours/flavours that interfere with analyses. An alternative (5.4) is
available.
5.4 Ascorbic acid solution
Ascorbic acid solution, comprising a solution of 4,0 g per litre of L (+)-ascorbic acid analytical grade,
stored in the absence of light at a temperature below 10 °C, for a maximum of one month. Two ml of this
solution will neutralize 1 mg/l of residual chlorine in 1 l of water.
5.5 1-Butanol (analytic reagent grade)
5.6 2-Methoxy-2-methylpropane (Methyl-tert-butyl ether, MtBE) (analytic reagent
grade)
5.7 Cleaning liquids for glassware
5.7.1 Hydrochloric acid, concentrated (30 % mass per volume) analytical reagent grade.
5.7.2 Hydrochloric acid solution, prepared by slowly adding (0,5 ± 0,01) l of concentrated
hydrochloric acid (5.7.1) to (0,5 ± 0,01) l of test water (5.1.1).
prEN 1420:2024 (E)
NOTE Care is needed because preparing the solution might generate heat.
5.7.3 Nitric acid, concentrated ((65 ± 3) % mass per volume) analytical reagent grade.
5.7.4 Nitric acid solution, (2 % mass per volume) is prepared by slowly adding (0,15 ± 0,01) l of
concentrated nitric acid (5.7.3) to (5,0 ± 0,1) l of test water (5.1.1).
NOTE Care is needed because preparing the solution might generate heat.
5.7.5 Hydrogen peroxide, 3 % vol/vol (analytical reagent grade).
6 Apparatus
6.1 Vessels, containers, stoppers and connectors, shall consist of a material, such as glass or stainless
steel, that is inert under the specified test conditions.
6.2 Plates stainless steel, mild steel, sand-blasted glass or concrete/cement-mortar plates, for testing
certain site-applied products. The plates shall be covered completely by the test material.
6.3 Equipment, capable of maintaining the appropriate migration temperature, e.g (23 ± 2) °C,
(60 ± 2) °C or (85 ± 2) °C.
6.4 500 ml Erlenmeyer flasks with ground stoppers shall be used for the presentation of the dilution
series to panellists.
6.5 Apparatus for colour analysis complying with the requirements of EN ISO 7887, Clause 5.5
6.6 Apparatus for turbidity analysis complying with the requirements of EN ISO 7027-1, Clause 5.3.1
7 Sampling, transport, storage, and preparation of test pieces
7.1 General
Sampling of products (i.e. collection of (a) sample(s) from a batch of lot) shall be performed in
accordance with the relevant product standard, system standard or the national regulations when
applicable.
During transport and storage samples shall be protected from contamination. If the manufacturer
provides written transport and storage instructions they shall be followed and documented. All samples
shall be transported and stored in their original form as delivered. Transport storage and test
containers shall be clean.
The room used for sample and test piece preparation shall be free from odour and flavour. The general
environment shall not adversely affect the preparation (see Section 6 in EN 1622).
The test pieces shall be prepared such that only the surface intended to come into contact with drinking
water is exposed to the test waters (5.1.1 and 5.1.2). When the product has the same material
composition for the outside and inside surfaces, the test pieces may be immersed in test water.
NOTE Composite products, for example kitchen taps, can consist of different substances and materials. It is
important to assess the components in terms of each material. If there are components of organic material, these
come under the scope of application of this document.
prEN 1420:2024 (E)
7.2 Site-applied products
Test samples for site-applied products shall be prepared, stored and transported in accordance to
EN 12873-2 and 7.1.
If the preparation procedure for a test piece for a particular type of product has not been covered in this
document, deviation from this procedure is allowable under the following conditions:
a) the finished product and the test piece shall be produced in the same manner;
b) the preparation of test pieces before testing shall include the procedures which are performed in
practice before the system is put into operation, e.g. curing and cleaning procedures.
The surface of the test pieces intended to come into contact with test water shall be free from adhesive
tape, labels, ink or pencil marks.
The minimum age of the test pieces shall conform to the relevant product standard or system standard
or, if not given in such a standard, to that recommended by the manufacturer for the produ
...