EN 71-7:2014

SLOVENSKI STANDARD
01-julij-2014
1DGRPHãþD
SIST EN 71-7:2003
9DUQRVWLJUDþGHO3UVWQHEDUYH=DKWHYHLQSUHVNXVQHPHWRGH
Safety of toys - Part 7: Finger paints - Requirements and test methods
Sicherheit von Spielzeug - Teil 7: Fingermalfarben - Anforderungen und Prüfverfahren
Sécurité des jouets - Partie 7: Peintures au doigt - Exigences et méthodes d'essai
Ta slovenski standard je istoveten z: EN 71-7:2014
ICS:
97.200.50 ,JUDþH Toys
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.

EUROPEAN STANDARD
EN 71-7
NORME EUROPÉENNE
EUROPÄISCHE NORM
April 2014
ICS 97.200.50 Supersedes EN 71-7:2002
English Version
Safety of toys - Part 7: Finger paints - Requirements and test
methods
Sécurité des jouets - Partie 7: Peintures au doigt - Sicherheit von Spielzeug - Fingermalfarben - Teil 7:
Exigences et méthodes d'essai Anforderungen und Prüfverfahren
This European Standard was approved by CEN on 8 February 2014.

CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European
Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national
standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN member.

This European Standard exists in three official versions (English, French, German). A version in any other language made by translation
under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management Centre has the same
status as the official versions.

CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,
Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania,
Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and United
Kingdom.
EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION

EUROPÄISCHES KOMITEE FÜR NORMUNG

CEN-CENELEC Management Centre: Avenue Marnix 17, B-1000 Brussels
© 2014 CEN All rights of exploitation in any form and by any means reserved Ref. No. EN 71-7:2014 E
worldwide for CEN national Members.

Contents Page
Foreword .4
Introduction .6
1 Scope .7
2 Normative references .7
3 Terms and definitions .7
4 Requirements .8
4.1 General .8
4.2 Colourants .8
4.3 Preservatives .9
4.4 Migration of certain elements .9
4.5 Limits for impurities .9
4.5.1 Limits for primary aromatic amines .9
4.5.2 Limits for other impurities . 10
4.6 Taste and smell . 10
4.7 pH-value . 11
4.8 Binding agents, extenders, humectants and surfactants . 11
4.9 N-Nitrosamines . 11
4.10 Containers . 11
5 Product information. 11
5.1 General . 11
5.2 Marking . 11
5.2.1 Primary packaging . 11
5.2.2 Container . 12
D.1 General . 24
D.2 Reagents . 25
D.3 Apparatus . 26
D.4 Instrumentation . 26
D.5 Sampling procedure . 26
D.6 Procedure . 26
D.7 Calculation . 35
D.8 Precision . 36
D.8.1 Linearity . 36
D.8.2 Limits of Detection (LOD) and Quantification (LOQ) . 36
D.8.3 Repeatability and reproducibility data for soluble aromatic amines . 37
D.8.4 Repeatability and reproducibility data for reductively cleaved aromatic amines . 38
D.8.5 Recovery . 39
D.9 Report . 40
D.10 Additional Information . 40
E.1 Principle . 41
E.2 Standards, reagents and solvents . 41
E.3 Apparatus . 43
E.4 Instrumentation . 43
E.5 Sampling. 44
E.6 Procedure . 44
E.6.1 General . 44
E.6.2 Sample preparation . 44
E.6.3 Solvent extraction . 44
E.6.4 Solid phase extraction . 45
E.6.5 Sample concentration for determining HCB and PCB congeners . 45
E.6.6 Sample concentration for determining B[α]P . 45
E.6.7 Gas chromatography conditions . 45
E.6.8 Mass spectrometry . 46
E.6.9 SIM mode . 46
E.7 Calculation . 51
E.8 Precision. 53
E.8.1 Linearity . 53
E.8.2 Limits of detection (LOD) and Quantification (LOQ) . 53
E.8.3 Repeatability and reproducibility data for HCB, PCB congeners and B[α]P . 53
E.8.4 Recovery. 54
E.9 Report . 54
E.10 Additional information . 55
F.1 Finger paints (see 3.1 and 3.2) . 59
F.2 Colourants (see 4.2.1) . 59
F.3 Preservatives (see 4.3) . 59
F.4 Elements (see 4.4) . 59
F.5 Primary aromatic amines (see 4.5.1.2, Tables 1 and 2 and Annex D) . 59
F.6 Limit for Benzo[α]Pyrene (see 4.5.2) . 60
F.7 Embittering agents (see 4.6). 60
F.8 pH value (see 4.7) . 60
F.9 N-Nitrosamines (see 4.9). 60
F.10 Container (see 4.10) . 60
F.11 Labelling phrases (see 5.2.1.2) . 61
F.12 List of polychlorinated biphenyl congeners (see Annex E) . 61
F.13 Reference materials (see Annex D and E) . 61
F.14 PCB Analytical Method (see E.6) . 61
Annex ZA (informative) Relationship between this European Standard and the Essential

Requirements of EU Directive 2009/48/EC . 64
Bibliography . 65

Foreword
This document (EN 71-7:2014) has been prepared by Technical Committee CEN/TC 52 “Safety of toys”, the
secretariat of which is held by DS.
This European Standard shall be given the status of a national standard, either by publication of an identical
text or by endorsement, at th
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