Construction products - Assessment of release of dangerous substances - Determination of emissions into indoor air of ammonia from cellulose insulation at 90 % RH

This Technical Report specifies a method for the determination of ammonia from cellulose insulation products at 90% relative humidity (RH).
This document is based on the existing prEN 16516 standard which provides an horizontal reference method for the determination of emissions of regulated dangerous substances from construction products into indoor air.

Bauprodukte - Bewertung der Freisetzung gefährlicher Stoffe - Bestimmung der Ammoniakemissionen von Zellulosedämmstoffen bei einer relativen Luftfeuchtigkeit von 90%

Produits de construction - Évaluation de l'émission de substances dangereuses - Détermination des émissions d'ammoniac dans l'air intérieur provenant des isolants en ouate de cellulose à 90 % HR

Le présent document spécifie une méthode de détermination des émissions d’ammoniac par les isolants en ouate de cellulose dans l’air intérieur à 90 % d’humidité relative (HR). Il repose sur l’utilisation d’une chambre d’essai d’émission et sur l’analyse ultérieure de l’ammoniac dans l’air de la chambre d’essai.

Gradbeni proizvodi - Ocenjevanje sproščanja nevarnih snovi - Določevanje emisij amoniaka iz celuloznih izolacijskih materialov v notranji zrak pri 90 % relativni vlažnosti

To tehnično poročilo določa metodo za določevanje amoniaka iz celuloznih izolacijskih materialov pri 90 % relativni vlažnosti.
Ta evropski standard temelji na obstoječem standardu prEN 1651, ki vsebuje horizontalno referenčno metodo za določevanje emisije reguliranih nevarnih snovi iz gradbenih proizvodov v notranji zrak.

General Information

Status
Published
Publication Date
13-Nov-2018
Current Stage
6060 - Definitive text made available (DAV) - Publishing
Start Date
14-Nov-2018
Due Date
24-Oct-2018
Completion Date
14-Nov-2018

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SLOVENSKI STANDARD
01-marec-2019
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Construction products - Assessment of release of dangerous substances - Determination
of emissions into indoor air of ammonia from cellulose insulation at 90 % RH
Bauprodukte - Bewertung der Freisetzung gefährlicher Stoffe - Bestimmung der
Ammoniakemissionen von Zellulosedämmstoffen bei einer relativen Luftfeuchtigkeit von
90%
Produits de construction - Évaluation de l'émission de substances dangereuses -
Détermination des émissions d'ammoniac dans l'air intérieur provenant des isolants
cellulosiques à 90 % HR
Ta slovenski standard je istoveten z: CEN/TR 17304:2018
ICS:
13.020.99 Drugi standardi v zvezi z Other standards related to
varstvom okolja environmental protection
91.100.60 0DWHULDOL]DWRSORWQRLQ Thermal and sound insulating
]YRþQRL]RODFLMR materials
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.

CEN/TR 17304
TECHNICAL REPORT
RAPPORT TECHNIQUE
November 2018
TECHNISCHER BERICHT
ICS 91.100.60
English Version
Construction products - Assessment of release of
dangerous substances - Determination of emissions into
indoor air of ammonia from cellulose insulation at 90 %
RH
Produits de construction - Évaluation de l'émission de Bauprodukte - Bewertung der Freisetzung gefährlicher
substances dangereuses - Détermination des émissions Stoffe - Bestimmung der Ammoniakemissionen von
d'ammoniac dans l'air intérieur provenant des isolants Zellulosedämmstoffen bei einer relativen
cellulosiques à 90 % HR Luftfeuchtigkeit von 90%

This Technical Report was approved by CEN on 5 November 2018. It has been drawn up by the Technical Committee CEN/TC
351.
CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,
Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania,
Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland,
Turkey and United Kingdom.
EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION

EUROPÄISCHES KOMITEE FÜR NORMUNG

CEN-CENELEC Management Centre: Rue de la Science 23, B-1040 Brussels
© 2018 CEN All rights of exploitation in any form and by any means reserved Ref. No. CEN/TR 17304:2018 E
worldwide for CEN national Members.

Contents Page
European foreword . 4
Introduction . 5
1 Scope . 6
2 Normative references . 6
3 Terms and definitions . 6
3.1 Terms relating to sampling and products . 6
3.2 Terms relating to emissions into indoor air and associated laboratory testing . 7
3.3 Terms relating to determination of emitted substances . 9
4 Intended conditions of use, emission scenarios and European reference room . 9
4.1 Intended conditions of use and emission scenario . 9
4.2 Reference room and emission scenario . 9
4.2.1 General . 9
4.2.2 Dimensions and loading factors in the reference room . 10
4.2.3 Ventilation in the reference room. 11
4.2.4 Climate conditions in the reference room . 11
4.3 Time schedule of emission(s) determination . 11
5 Product sampling and transport to the laboratory . 11
6 Handling of product samples in the laboratory . 12
6.1 Storage of sample in the testing laboratory . 12
6.2 Preparation of the test specimen . 12
7 Test chamber conditions . 12
7.1 Principles . 12
7.2 Dimensions of test specimen . 13
7.3 Loading factor . 13
7.4 Ventilation . 13
7.5 Air velocity . 13
7.6 Cleanliness of test chamber . 13
7.7 Testing climate (temperature, relative humidity of supply air) . 13
7.8 Storage of test specimen . 14
7.9 Large products . 14
7.10 Volume of test chamber . 14
7.11 Placement of test specimen in test chamber . 14
8 Determination of ammonia in test chamber air . 15
9 Calculation of specific emission rates and expression of results at the reference
room . 15
10 Reporting for the reference method . 17
10.1 General . 17
10.2 Sampling . 17
10.3 Handling of samples in the laboratory, preparation of test specimen . 17
10.4 Test chamber conditions . 17
10.5 Determination of ammonia in test chamber air . 17
11 Indirect methods . 18
Annex A (informative) Examples of indirect methods (also called simplified, screening,
secondary, derived or alternative methods) . 19
A.1 General . 19
A.2 Indirect methods‐emissions testing . 19
Bibliography . 20

European foreword
This document (CEN/TR 17304:2018) has been prepared by Technical Committee CEN/TC 351
“Construction products: Assessment of release of dangerous substances”, the secretariat of which is held
by NEN.
Attention is drawn to the possibility that some of the elements of this document may be the subject of
patent rights. CEN shall not be held responsible for identifying any or all such patent rights.
This document has been prepared under a standardization request given to CEN by the European
Commission and the European Free Trade Association.
Introduction
This document was developed under the remit of Commission Regulation (EU) 2016/1017 of
23 June 2016 amending Annex XVII to Regulation (EC) No 1907/2006 of the European Parliament and of
the Council concerning the Registration, Evaluation, Authorization and Restriction of Chemicals (REACH)
as regards inorganic ammonium salts [1].
This document is derived from the horizontal standard EN 16516 [2] which specifies the horizontal
reference method for testing the emission (release) of dangerous substances from construction products
into indoor air.
This method uses a test chamber in which emissions are generated under conditions which are kept
constant during the test.
1 Scope
This document specifies a method for the determination of emissions of ammonia from cellulose
insulation products into indoor air at 90 % relative humidity (RH). It is based on the use of an emission
test chamber and subsequent analysis of ammonia in test chamber air.
2 Normative references
The following documents are referred to in the text in such a way that some or all of their content
constitutes requirements of this document. For dated references, only the edition cited applies. For
undated references, the latest edition of the referenced document (including any amendments) applies.
EN 16687, Construction products - Assessment of release of dangerous substances - Terminology
3 Terms and definitions
For the purposes of this document, the terms and definitions given in EN 16687 and the following apply.
ISO and IEC maintain terminological databases for use in standardization at the following addresses:
• IEC Electropedia: available at http://www.electropedia.org/
• ISO Online browsing platform: available at https://www.iso.org/obp
3.1 Terms relating to sampling and products
3.1.1
laboratory sample
sample or sub-sample(s) sent to or received by the laboratory
Note 1 to entry: The laboratory sample is the final sample from the point of view of sample collection but it is the
initial sample from the point of view of the laboratory.
[SOURCE: IUPAC, 2.5.5 [3]]
3.1.2
population
totality of products under consideration
[SOURCE: adapted from ISO 11074:2005, 4.1.11 as in CEN/TR 16220:2011, 2.4.3 [4]]
3.1.3
sample
representative portion of product or material selected from a larger quantity of product or material
[SOURCE: IUPAC, 2.1.1 [3]]
3.1.4
sampling plan
predetermined procedure for the selection, withdrawal, preservation and transportation of product
samples
[SOURCE: CEN/TR 16220:2011, 2.3 [4]]
3.1.5
scale
minimum quantity (mass, volume or units) of the product for which representative test results can be
obtained
[SOURCE: CEN/TR 16220:2011, 2.4.4 [4]]
3.2 Terms relating to emissions into indoor air and associated laboratory testing
3.2.1
air change rate
ratio of the volume of air brought into the test chamber per hour and the volume of the empty test
chamber
−1
Note 1 to entry: Air change rate is expressed as h .
[SOURCE: adapted from EN ISO 16000-9:2006+AC:2007, 3.1 [5]]
3.2.2
air flow rate ventilation rate
air volume entering into the emission test chamber per unit of time
[SOURCE: adapted from EN ISO 16000-9:2006+AC:2007, 3.2 [5]]
3.2.3
chamber blank value
test result obtained by carrying out the test procedure in the absence of a test portion/specimen
3.2.4
emission
liberation of chemical substances (ammonia) from a construction product (cellulose insulation product)
into air
3.2.5
emission test chamber
enclosure with controlled operational parameters for the determination of vapour phase organic
compounds emitted from construction products
[SOURCE: adapted from EN ISO 16000-9:2006+AC:2007, 3.6 [5]]
3.2.6
emission test chamber concentration
mass concentration of ammonia in test chamber air measured at the emission test chamber outlet
[SOURCE: EN ISO 16000-9:2006+AC:2007, 3.7 [5]]
3.2.7
intended conditions of use
con
...

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