EN 71-7:2014+A3:2020

SLOVENSKI STANDARD
01-junij-2020
Nadomešča:
SIST EN 71-7:2014+A2:2018
Varnost igrač - 7. del: Prstne barve - Zahteve in preskusne metode (vključno z
dopolnilom A3)
Safety of toys - Part 7: Finger paints - Requirements and test methods
Sicherheit von Spielzeug - Teil 7: Fingermalfarben - Anforderungen und Prüfverfahren
Sécurité des jouets - Partie 7: Peintures au doigt - Exigences et méthodes d'essai
Ta slovenski standard je istoveten z: EN 71-7:2014+A3:2020
ICS:
97.200.50 Igrače Toys
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.

EN 71-7:2014+A3
EUROPEAN STANDARD
NORME EUROPÉENNE
April 2020
EUROPÄISCHE NORM
ICS 97.200.50
English Version
Safety of toys - Part 7: Finger paints - Requirements and
test methods
Sécurité des jouets - Partie 7: Peintures au doigt - Sicherheit von Spielzeug - Teil 7: Fingermalfarben -
Exigences et méthodes d'essai Anforderungen und Prüfverfahren
This European Standard was approved by CEN on 9 January 2018 and includes Amendment 3 approved by CEN on 13 February
2020.
CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this
European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references
concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN
member.
This European Standard exists in three official versions (English, French, German). A version in any other language made by
translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management
Centre has the same status as the official versions.

CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,
Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway,
Poland, Portugal, Republic of North Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and
United Kingdom.
EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION

EUROPÄISCHES KOMITEE FÜR NORMUNG

CEN-CENELEC Management Centre: Rue de la Science 23, B-1040 Brussels
© 2020 CEN All rights of exploitation in any form and by any means reserved Ref. No. EN 71-7:2014+A3:2020 E
worldwide for CEN national Members.

Contents Page
European foreword . 5
Introduction . 7
1 Scope . 8
2 Normative references . 8
3 Terms and definitions . 8
4 Requirements . 9
4.1 General . 9
4.2 Colourants . 9
4.3 Preservatives . 10
4.4 Migration of certain elements . 10
4.5 Limits for impurities . 10
4.5.1 Limits for primary aromatic amines . 10
4.5.2 Limits for other impurities . 11
4.6 Taste and smell . 12
4.7 pH-value . 12
4.8 Binding agents, extenders, humectants and surfactants . 12
4.9 N-Nitrosamines . 12
4.10 Containers . 13
5 Product information . 13
5.1 General . 13
5.2 Marking . 13
5.2.1 Primary packaging . 13
5.2.2 Container . 14
Annex A (informative) Non-exhaustive list of colourants which are commonly used in finger
paints, and need to be in compliance with both the general and specified purity
requirements . 15
Annex B (normative) List of preservatives allowed for use in finger paints . 21
Annex C (informative) Ingredients used in the manufacture of finger paints . 26
Annex D (normative) Method for the detection of certain azo colourants and determination
of free primary aromatic amines . 28
D.1 General . 28
D.2 Reagents . 29
D.3 Apparatus . 30
D.4 Instrumentation . 30
D.5 Sampling procedure . 30
D.6 Procedure. 31
D.7 Calculation . 40
D.8 Precision . 41
D.8.1 Linearity . 41
D.8.2 Limits of Detection (LOD) and Quantification (LOQ) . 41
D.8.3 Repeatability and reproducibility data for soluble aromatic amines . 42
D.8.4 Repeatability and reproducibility data for reductively cleaved aromatic amines . 43
D.8.5 Recovery . 44
D.9 Report . 46
D.10 Additional Information . 46
Annex E (normative) Method for the determination of hexachlorobenzene, polychlorinated
biphenyls and %benzo[a]pyrene& . 47
E.1 Principle . 47
E.2 Standards, reagents and solvents . 47
E.3 Apparatus . 49
E.4 Instrumentation . 50
E.5 Sampling . 50
E.6 Procedure . 50
E.6.1 General . 50
E.6.2 Sample preparation . 50
E.6.3 Solvent extraction . 50
E.6.4 Solid phase extraction . 51
E.6.5 Sample concentration for determining HCB and PCB congeners . 51
E.6.6 Sample concentration for determining B[α]P . 51
E.6.7 Gas chromatography conditions . 51
E.6.8 Mass spectrometry . 52
E.6.9 SIM mode . 52
E.7 Calculation. 57
E.8 Precision . 60
E.8.1 Linearity . 60
E.8.2 Limits of detection (LOD) and Quantification (LOQ) . 60
E.8.3 Repeatability and reproducibility data for HCB, PCB congeners and B[α]P . 60
E.8.4 Recovery . 61
E.9 Report . 62
E.10 Additional information . 62
Annex F (informative) Rationale . 66
F.1 Finger paints (see 3.1 and 3.2) . 66
F.2 Colourants (see 4.2.1) . 66
F.3 Preservatives (see 4.3) . 66
F.4 Elements (see 4.4) . 66
F.5 Primary aromatic amines (see 4.5.1.2, Tables 1 and 2 and Annex D) . 66
F.6 Limit for %Benzo[a]Pyrene& (see 4.5.2) .
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