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ASTM D1836-02

(Specification)

Standard Specification for Commercial Hexanes

Standard Specification for Commercial Hexanes

SCOPE
1.1 This specification covers the range of products commonly referred to as hexanes, which find uses in the preparation of adhesives, coatings, and printing inks, as raw materials in chemical synthesis operations, and as solvents in various kinds of extraction operations.
1.2 The following applies to all specified limits in this standard; for purposes of determining conformance with this standard, an observed value or a calculated value shall be rounded off "to the nearest unit" in the last right-hand digit used in expressing the specification limit, in accordance with the rounding-off method of Practice E 29.
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.
1.4 For specific hazard information and guidance consult supplier's Material Safety Data Sheet.

General Information

Status
Historical
Publication Date
09-Dec-2002
ICS
71.080.10 - Aliphatic hydrocarbons
Technical Committee
D01 - Paint and Related Coatings, Materials, and Applications
Drafting Committee
D01.35 - Solvents, Plasticizers, and Chemical Intermediates
Current Stage
Ref Project

Relations

Replaces
ASTM D1836-99 - Standard Specification for Commercial Hexanes
Effective Date
10-Dec-2002
Replaced By
ASTM D1836-07 - Standard Specification for Commercial Hexanes
Effective Date
01-Jun-2007
Referred By
ASTM F302-09(2021) - Standard Practice for Field Sampling of Aerospace Fluids in Containers
Effective Date
10-Dec-2002
Referred By
ASTM D4898-16 - Standard Test Method for Insoluble Contamination of Hydraulic Fluids by Gravimetric Analysis
Effective Date
10-Dec-2002
Referred By
ASTM F303-08(2023)e1 - Standard Practices for Sampling for Particles in Aerospace Fluids and Components
Effective Date
10-Dec-2002
Referred By
ASTM D7670-10(2021) - Standard Practice for Processing In-service Fluid Samples for Particulate Contamination Analysis Using Membrane Filters
Effective Date
10-Dec-2002
Referred By
ASTM F311-08(2020) - Standard Practice for Processing Aerospace Liquid Samples for Particulate Contamination Analysis Using Membrane Filters
Effective Date
10-Dec-2002
Referred By
ASTM D1094-07(2019) - Standard Test Method for Water Reaction of Aviation Fuels
Effective Date
10-Dec-2002

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ASTM D1836-02 - Standard Specification for Commercial HexanesASTM D1836-02 - Standard Specification for Commercial Hexanes
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ASTM D1836-02 - Standard Specification for Commercial Hexanes
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NOTICE: This standard has either been superseded and replaced by a new version or withdrawn.
Contact ASTM International (www.astm.org) for the latest information
Designation: D 1836 – 02
Standard Specification for
1
Commercial Hexanes
This standard is issued under the fixed designation D 1836; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (e) indicates an editorial change since the last revision or reapproval.
1. Scope * D 1296 Test Method for Odor of Volatile Solvents and
3
Diluents
1.1 This specification covers the range of products com-
D 1353 Test Method for Nonvolatile Matter in Volatile
monly referred to as hexanes, which find uses in the prepara-
Solvents for Use in Paint, Varnish, Lacquer, and Related
tion of adhesives, coatings, and printing inks, as raw materials
3
Products
in chemical synthesis operations, and as solvents in various
D 2710 Test Method for Bromine Index of Petroleum Hy-
kinds of extraction operations.
4
drocarbons by Electrometric Titration
1.2 The following applies to all specified limits in this
D 3120 Test Method for Trace Quantities of Sulfur in Light
standard; for purposes of determining conformance with this
Liquid Petroleum Hydrocarbons by Oxidative Microcou-
standard, an observed value or a calculated value shall be
4
lometry
rounded off “to the nearest unit” in the last right-hand digit
D 4367 Test Method for Benzene in Hydrocarbon Solvents
used in expressing the specification limit, in accordance with
3
By Gas Chromatography
the rounding-off method of Practice E 29.
5
E 1 Specification for ASTM Thermometers
1.3 This standard does not purport to address all of the
E 29 Practice for Using Significant Digits in Test Data To
safety concerns, if any, associated with its use. It is the
6
Determine Conformance with Specifications
responsibility of the user of this standard to establish appro-
7
E 300 Practice for Sampling Industrial Chemicals
priate safety and health practices and determine the applica-
2.2 U.S. Federal Specification:
bility of regulatory limitations prior to use.
PPP-C-2020 Chemicals, Liquid, Dry, and Paste: Packaging
1.4 For specific hazard information and guidance consult
8
of
supplier’s Material Safety Data Sheet.
3. Properties
2. Referenced Documents
3.1 Commercial hexanes shall conform to the following
2.1 ASTM Standards:
requirements:
D 156 Test Method for Saybolt Color of Petroleum Prod-
2
Aniline point, min 57°C
ucts (Saybolt Chromometer Method)
Apparent specific gravity
D 268 Guide for Sampling and Testing Volatile Solvents
15.6/15.6°C 0.660–0.686
and Chemical Intermediates for Use in Paint and Related
Bromine index, max 100
3
Color not darker than + 28 on the Saybolt
Coatings and Materials
Scale or 10 on the Pt-Co Scale
D 611 Test Methods for Aniline Point and Mixed Aniline
Distillation range:
2
Point of Petroleum Products and Hydrocarbon Solvents Initial boiling point, min 63°C
Dry point, max 71°C
D 1078 Test Method for Distillation Range of Volatile
Kauri-butanol value, max 33
3
Organic Liquids
Nonvolatile matter, mg/100 mL, max 1
D 1133 Test Method for Kauri-Butanol Value of Hydrocar-
Odor nonresidual
3
Sulfur, ppm, max 5
bon Solvents
Benzene content, weight %, max 0.1
D 1209 Test Method for Color of Clear Liquids (Platinum-
3
Cobalt Scale)
1
This specification is under the jurisdiction of ASTM Committee D01 on Paint
4
and Related Coatings, Materials, andApplications and is the direct responsibility of Annual Book of ASTM Standards, Vol 05.01.
5
Subcommittee D01.35 on Solvents, Plasticizers, and Chemical Intermediates. Annual Book of ASTM Standards, Vol 14.03.
6
Current edition approved Dec. 10, 2002. Published February 2003. Originally Annual Book of ASTM Standards, Vol 14.02.
7
Annual Book of ASTM Standards, Vol 15.05.
approved in 1961. Last previous edition approved in 1999 as D 1836 – 99.
8
2
Available from Standardization Documents Order Desk, DODSSP, Bldg. 4,
Annual Book of ASTM Standards, Vol 05.01.
3
Annual Book of ASTM Standards, Vol 06.04. Section D, 700 Robbins Ave., Philadelphia, PA 19111-5098
*ASummary of Changes section appears at the end of this standard.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959, United States.
1

---------------------- Page: 1 ----------------------
D1836–02
4. Sampling 5.1.6 Distillation—Test Method D 1078, using an ASTM
SolventsDistillationThermometer39Chavingarangefrom48
4.1 The material shall be sampled in accordance with
to 102°C and conforming to the requirements in Specification
Practice E 300.
E1.
5.1.7 Kauri-Butanol Value—Test Method D 1133.
5. Test Methods
5.1.8 Nonvolatile Matter—Test Method D 1353.
5.1 The properties enumerated in this specification shall be
5.1.9 Odor—Test Method D 1296. Samples of particular
determined in accordance with the following ASTM test
types of pr
...

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This specification covers commercial hexanes used in the preparation of adhesives, coatings, and printing inks, as raw materials in chemical synthesis, and as solvents in various kinds of extraction operations. The commercial hexanes should conform to the specified requirements for aniline point, apparent specific gravity, bromine index, color Pt-Co, distillation range, kauri-butanol value, nonvolatile matter content, odor, sulfur content, and benzene content.
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5.1 This test method is suitable for setting specifications on the materials referenced in Table 1 and for use as an internal quality control tool where cyclohexane is produced or is used in a manufacturing process. It may also be used in development or research work involving cyclohexane.  
5.2 This test method is useful in determining the purity of cyclohexane with normal impurities present. If extremely high boiling or unusual impurities are present in the cyclohexane, this test method would not necessarily detect them and the purity calculation would be erroneous.
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1.1 This test method covers the determination of the purity of cyclohexane by gas chromatography.  
1.2 This test method is applicable to the measurement of impurities in Table 1. This test method is applicable to samples with concentrations to 400 mg/kg, but may be applicable to a wider range. The limit of detection (LOD) is 1 mg/kg and the limit of quantitation (LOQ) is 3 mg/kg for benzene.
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This specification covers a grade of cyclohexane identified as "cyclohexane 999." The material shall conform to the required purity, benzene content, n-hexane content, methylcyclohexane content, methylcyclopentane content, sulfur content, appearance, color, and distillation range.
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1.1 This specification covers a grade of cyclohexane identified as “cyclohexane 999.”  
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