ASTM D2593-23
(Test Method)Standard Test Method for Butadiene Purity and Hydrocarbon Impurities by Gas Chromatography
Standard Test Method for Butadiene Purity and Hydrocarbon Impurities by Gas Chromatography
SIGNIFICANCE AND USE
4.1 The trace hydrocarbon compounds listed can have an effect in the commercial use of butadiene. This test method is suitable for use in process quality control and in setting specifications.
SCOPE
1.1 This test method covers the determination of butadiene-1,3 purity and impurities such as propane, propylene, isobutane, n-butane, butene-1, isobutylene, propadiene, trans-butene-2, cis-butene-2, butadiene-1,2, pentadiene-1,4, and, methyl, dimethyl, ethyl, and vinyl acetylene in polymerization grade butadiene by gas chromatography. Impurities including butadiene dimer, carbonyls, inhibitor, and residue are measured by appropriate ASTM procedures and the results used to normalize the component distribution obtained by chromatography.
Note 1: Other impurities present in commercial butadiene must be calibrated and analyzed. Other impurities were not tested in the cooperative work on this test method.
Note 2: This test method can be used to check for pentadiene-1,4 and other C5s instead of Test Method D1088.
1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. For specific warning statements, see 6.1 and 9.3.
1.3.1 The user is advised to obtain LPG safety training for the safe operation of this test method procedure and related activities.
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
General Information
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Standards Content (Sample)
This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the
Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
Designation: D2593 − 23
Standard Test Method for
Butadiene Purity and Hydrocarbon Impurities by Gas
1
Chromatography
This standard is issued under the fixed designation D2593; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope* 2. Referenced Documents
2
1.1 This test method covers the determination of butadiene- 2.1 ASTM Standards:
1,3 purity and impurities such as propane, propylene, D1088 Method of Test for Boiling Point Range of
3
isobutane, n-butane, butene-1, isobutylene, propadiene, trans- Polymerization-Grade Butadiene (Withdrawn 1983)
4
butene-2, cis-butene-2, butadiene-1,2, pentadiene-1,4, and,
2.2 Energy Institute Standards:
methyl, dimethyl, ethyl, and vinyl acetylene in polymerization
IP 194 Analysis of Butadiene-1,3 Polymerization Grade
grade butadiene by gas chromatography. Impurities including
3. Summary of Test Method
butadiene dimer, carbonyls, inhibitor, and residue are measured
by appropriate ASTM procedures and the results used to
3.1 A representative sample is introduced into a gas-liquid
normalize the component distribution obtained by chromatog-
partition column. The butadiene and other components are
raphy.
separated as they are transported through the column by an
inert carrier gas. Their presence in the effluent is measured by
NOTE 1—Other impurities present in commercial butadiene must be
a detector and recorded as a chromatogram. The chromatogram
calibrated and analyzed. Other impurities were not tested in the coopera-
tive work on this test method.
of the sample is interpreted by applying component attenuation
NOTE 2—This test method can be used to check for pentadiene-1,4 and
and detector response factors to the peak areas or peak heights
other C s instead of Test Method D1088.
5
and the relative concentration determined by relating indi-
1.2 The values stated in SI units are to be regarded as
vidual peak response to total peak response. Impurities includ-
standard. No other units of measurement are included in this
ing butadiene dimer, carbonyls, inhibitor, and residue are
standard.
measured by appropriate ASTM procedures and the results
used to normalize the distribution obtained by gas chromatog-
1.3 This standard does not purport to address all of the
raphy.
safety concerns, if any, associated with its use. It is the
responsibility of the user of this standard to establish appro-
4. Significance and Use
priate safety, health, and environmental practices and deter-
mine the applicability of regulatory limitations prior to use. 4.1 The trace hydrocarbon compounds listed can have an
For specific warning statements, see 6.1 and 9.3. effect in the commercial use of butadiene. This test method is
1.3.1 The user is advised to obtain LPG safety training for suitable for use in process quality control and in setting
the safe operation of this test method procedure and related specifications.
activities.
5. Apparatus
1.4 This international standard was developed in accor-
5.1 Chromatograph—Any chromatograph having either a
dance with internationally recognized principles on standard-
thermal-conductivity or flame ionization detector can be used
ization established in the Decision on Principles for the
provided the system has sufficient sensitivity and stability to
Development of International Standards, Guides and Recom-
obtain a recorder deflection of at least 2 mm at signal-to-noise
mendations issued by the World Trade Organization Technical
ratio of at least 5:1 for 0.01 % by mass of impurity.
Barriers to Trade (TBT) Committee.
2
For referenced ASTM standards, visit the ASTM website, www.astm.org, or
1
This test method is under the jurisdiction of ASTM Committee D02 on contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM
Petroleum Products, Liquid Fuels, and Lubricants and is the direct responsibility of Standards volume information, refer to the standard’s Document Summary page on
Subcommittee D02.D0.04 on C4 and C5 Hydrocarbons. the ASTM website.
3
This test method was adopted as a joint ASTM-IP Standard, IP 194, in 1972. The last approved version of this historical standard is referenced on
Current edition approved March 1, 2023. Published June 2023. Originally www.astm.org.
4
approved in 1967. Last previous edition approved in 2019 as D2593 – 19. DOI: Obsolete. Contact Energy Institute, 61 New Cavendish St., London, WIG 7AR,
10.1520/D2593-23. U.K., http://www.energyinst.org.uk.
*A Summary of
...
This document is not an ASTM standard and is intended only to provide the user of an ASTM standard an indication of what changes have been made to the previous version. Because
it may not be technically possible to adequately depict all changes accurately, ASTM recommends that users consult prior editions as appropriate. In all cases only the current version
of the standard as published by ASTM is to be considered the official document.
Designation: D2593 − 19 D2593 − 23
Standard Test Method for
Butadiene Purity and Hydrocarbon Impurities by Gas
1
Chromatography
This standard is issued under the fixed designation D2593; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope*
1.1 This test method covers the determination of butadiene-1,3 purity and impurities such as propane, propylene, isobutane,
n-butane, butene-1, isobutylene, propadiene, trans-butene-2, cis-butene-2, butadiene-1,2, pentadiene-1,4, and, methyl, dimethyl,
ethyl, and vinyl acetylene in polymerization grade butadiene by gas chromatography. Impurities including butadiene dimer,
carbonyls, inhibitor, and residue are measured by appropriate ASTM procedures and the results used to normalize the component
distribution obtained by chromatography.
NOTE 1—Other impurities present in commercial butadiene must be calibrated and analyzed. Other impurities were not tested in the cooperative work
on this test method.
NOTE 2—This test method can be used to check for pentadiene-1,4 and other C s instead of Test Method D1088.
5
1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility
of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of
regulatory limitations prior to use. For specific warning statements, see 6.1 and 9.3.
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of
the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of
regulatory limitations prior to use. For specific warning statements, see 6.1 and 9.3.
1.3.1 The user is advised to obtain LPG safety training for the safe operation of this test method procedure and related activities.
1.4 This international standard was developed in accordance with internationally recognized principles on standardization
established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued
by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
2. Referenced Documents
2
2.1 ASTM Standards:
1
This test method is under the jurisdiction of ASTM Committee D02 on Petroleum Products, Liquid Fuels, and Lubricants and is the direct responsibility of Subcommittee
D02.D0.04 on C4 and C5 Hydrocarbons.
This test method was adopted as a joint ASTM-IP Standard, IP 194, in 1972.
Current edition approved Dec. 1, 2019March 1, 2023. Published January 2020June 2023. Originally approved in 1967. Last previous edition approved in 20142019 as
D2593 – 93 (2014).D2593 – 19. DOI: 10.1520/D2593-19.10.1520/D2593-23.
2
For referenced ASTM standards, visit the ASTM website, www.astm.org, or contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM Standards
volume information, refer to the standard’s Document Summary page on the ASTM website.
*A Summary of Changes section appears at the end of this standard
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
1
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D2593 − 23
3
D1088 Method of Test for Boiling Point Range of Polymerization-Grade Butadiene (Withdrawn 1983)
4
2.2 Energy Institute Standards:
IP 194 Analysis of Butadiene-1,3 Polymerization Grade
3. Summary of Test Method
3.1 A representative sample is introduced into a gas-liquid partition column. The butadiene and other components are separated
as they are transported through the column by an inert carrier gas. Their presence in the effluent is measured by a detector and
recorded as a chromatogram. The chromatogram of the sample is interpreted by applying component attenuation and detector
response factors to the peak areas or peak heights and the relative concentration determined by relating individual peak response
to total peak response. Impurities including butadiene dimer, carbonyls, inhibitor, and residue are measured by appropriate ASTM
procedures and the results used to normalize the dis
...
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