Standard Test Method for Determination of Hydrocarbon Group Types and Select Hydrocarbon and Oxygenate Compounds in Automotive Spark-Ignition Engine Fuel Using Gas Chromatography with Vacuum Ultraviolet Absorption Spectroscopy Detection (GC-VUV)

SIGNIFICANCE AND USE
5.1 The determination of class group composition of automotive spark-ignition fuels as well as quantification of various individual species such as oxygenates and aromatics in automotive fuels is useful for evaluating quality and expected performance, as well as compliance with various governmental regulations.
SCOPE
1.1 This test method is a standard procedure for the determination in percent mass or percent volume of hydrocarbon group types (paraffins, isoparaffins, olefins, naphthenes, aromatics), methanol, ethanol, benzene, toluene, ethylbenzene, xylenes, naphthalene, and methylnaphthalenes in automotive spark-ignition engine fuels using gas chromatography and vacuum ultraviolet detection (GC-VUV).  
1.1.1 The concentration ranges for which precision has been determined are as follows:    
Property  
Units  
Applicable Range  
Paraffins  
% Volume  
3.572 to 23.105  
Isoparaffins  
% Volume  
22.697 to 71.993  
Olefins  
% Volume  
0.011 to 44.002  
Olefins  
% Mass  
0.027 to 41.954  
Naphthenes  
% Volume  
0.606 to 18.416  
Aromatics  
% Volume  
14.743 to 58.124  
Methanol  
% Volume  
0.063 to 3.426  
Ethanol  
% Mass  
0.042 to 15.991  
Benzene  
% Volume  
0.09 to 1.091  
Toluene  
% Volume  
0.698 to 31.377  
Ethylbenzene  
% Volume  
0.5 to 3.175  
Xylenes  
% Volume  
3.037 to 18.955  
Naphthalene  
% Volume  
0.019 to 0.779  
Methylnaphthalenes  
% Volume  
0.21 to 1.484  
1.1.2 This test method may be applicable to other concentration ranges, to other properties, or to other hydrocarbon streams, however precision has not been determined.  
1.2 Individual hydrocarbon components are typically not baseline-separated by the procedure described in this test method, that is, some components will coelute. The coelutions are resolved at the detector using VUV absorbance spectra and deconvolution algorithms.  
1.3 While this test method reports percent mass and percent volume for several specific components that may be present in automotive spark-ignition engine fuel, it does not attempt to speciate all possible components that may occur in automotive spark-ignition engine fuel. In particular, this test method is not intended as a type of detailed hydrocarbon analysis (DHA).  
1.4 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. See specific hazard statements in subsection 8.4 and Section 9.  
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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Published
Publication Date
30-Jun-2021
Current Stage
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ASTM D8071-21 - Standard Test Method for Determination of Hydrocarbon Group Types and Select Hydrocarbon and Oxygenate Compounds in Automotive Spark-Ignition Engine Fuel Using Gas Chromatography with Vacuum Ultraviolet Absorption Spectroscopy Detection (GC-VUV)
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REDLINE ASTM D8071-21 - Standard Test Method for Determination of Hydrocarbon Group Types and Select Hydrocarbon and Oxygenate Compounds in Automotive Spark-Ignition Engine Fuel Using Gas Chromatography with Vacuum Ultraviolet Absorption Spectroscopy Detection (GC-VUV)
English language
18 pages
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Standards Content (Sample)

This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the
Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
Designation: D8071 − 21
Standard Test Method for
Determination of Hydrocarbon Group Types and Select
Hydrocarbon and Oxygenate Compounds in Automotive
Spark-Ignition Engine Fuel Using Gas Chromatography with
Vacuum Ultraviolet Absorption Spectroscopy Detection (GC-
1
VUV)
This standard is issued under the fixed designation D8071; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope* automotive spark-ignition engine fuel, it does not attempt to
speciate all possible components that may occur in automotive
1.1 This test method is a standard procedure for the deter-
spark-ignition engine fuel. In particular, this test method is not
mination in percent mass or percent volume of hydrocarbon
intended as a type of detailed hydrocarbon analysis (DHA).
group types (paraffins, isoparaffins, olefins, naphthenes,
aromatics), methanol, ethanol, benzene, toluene, ethylbenzene, 1.4 The values stated in SI units are to be regarded as
xylenes, naphthalene, and methylnaphthalenes in automotive standard. No other units of measurement are included in this
spark-ignition engine fuels using gas chromatography and standard.
vacuum ultraviolet detection (GC-VUV).
1.5 This standard does not purport to address all of the
1.1.1 Theconcentrationrangesforwhichprecisionhasbeen
safety concerns, if any, associated with its use. It is the
determined are as follows:
responsibility of the user of this standard to establish appro-
Property Units Applicable Range
priate safety, health, and environmental practices and deter-
Paraffins % Volume 3.572 to 23.105
mine the applicability of regulatory limitations prior to use.
Isoparaffins % Volume 22.697 to 71.993
See specific hazard statements in subsection 8.4 and Section 9.
Olefins % Volume 0.011 to 44.002
Olefins % Mass 0.027 to 41.954
1.6 This international standard was developed in accor-
Naphthenes % Volume 0.606 to 18.416
dance with internationally recognized principles on standard-
Aromatics % Volume 14.743 to 58.124
ization established in the Decision on Principles for the
Methanol % Volume 0.063 to 3.426
Ethanol % Mass 0.042 to 15.991
Development of International Standards, Guides and Recom-
Benzene % Volume 0.09 to 1.091
mendations issued by the World Trade Organization Technical
Toluene % Volume 0.698 to 31.377
Barriers to Trade (TBT) Committee.
Ethylbenzene % Volume 0.5 to 3.175
Xylenes % Volume 3.037 to 18.955
Naphthalene % Volume 0.019 to 0.779
2. Referenced Documents
Methylnaphthalenes % Volume 0.21 to 1.484
2
2.1 ASTM Standards:
1.1.2 This test method may be applicable to other concen-
D1319 Test Method for Hydrocarbon Types in Liquid Petro-
tration ranges, to other properties, or to other hydrocarbon
leum Products by Fluorescent Indicator Adsorption
streams, however precision has not been determined.
D3606 Test Method for Determination of Benzene and
1.2 Individual hydrocarbon components are typically not
Toluene in Spark Ignition Fuels by Gas Chromatography
baseline-separated by the procedure described in this test
D4057 Practice for Manual Sampling of Petroleum and
method, that is, some components will coelute. The coelutions
Petroleum Products
are resolved at the detector using VUV absorbance spectra and
D4307 Practice for Preparation of Liquid Blends for Use as
deconvolution algorithms.
Analytical Standards
D5599 Test Method for Determination of Oxygenates in
1.3 While this test method reports percent mass and percent
Gasoline by Gas Chromatography and Oxygen Selective
volume for several specific components that may be present in
Flame Ionization Detection
1
This test method is under the jurisdiction of ASTM Committee D02 on
Petroleum Products, Liquid Fuels, and Lubricants and is the direct responsibility of
2
Subcommittee D02.04.0L on Gas Chromatography Methods. For referenced ASTM standards, visit the ASTM website, www.astm.org, or
Current edition approved July 1, 2021. Published August 2021. Originally contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM
approved in 2017. Last previous edition approved in 2020 as D8071 – 20. DOI: Standards volume information, refer to the standard’s Document Summary page on
10.1520/D8071-21. the ASTM website.
*A Summary of Changes section appears at the end of this standard
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
1

---------------------- Page: 1 ----------------------
D8071 − 21
...

This document is not an ASTM standard and is intended only to provide the user of an ASTM standard an indication of what changes have been made to the previous version. Because
it may not be technically possible to adequately depict all changes accurately, ASTM recommends that users consult prior editions as appropriate. In all cases only the current version
of the standard as published by ASTM is to be considered the official document.
Designation: D8071 − 20 D8071 − 21
Standard Test Method for
Determination of Hydrocarbon Group Types and Select
Hydrocarbon and Oxygenate Compounds in Automotive
Spark-Ignition Engine Fuel Using Gas Chromatography with
Vacuum Ultraviolet Absorption Spectroscopy Detection (GC-
1
VUV)
This standard is issued under the fixed designation D8071; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope*
1.1 This test method is a standard procedure for the determination in percent mass or percent volume of hydrocarbon group types
(paraffins, isoparaffins, olefins, naphthenes, aromatics), methanol, ethanol, benzene, toluene, ethylbenzene, xylenes, naphthalene,
and methylnaphthalenes in automotive spark-ignition engine fuels using gas chromatography and vacuum ultraviolet detection
(GC-VUV).
1.1.1 The concentration ranges for which precision has been determined are as follows:
Property Units Applicable Range
Paraffins % Volume 3.572 to 23.105
Isoparaffins % Volume 22.697 to 71.993
Olefins % Volume 0.011 to 44.002
Olefin % Mass 0.027 to 41.954
Olefins % Mass 0.027 to 41.954
Naphthenes % Volume 0.606 to 18.416
Aromatics % Volume 14.743 to 58.124
Methanol % Volume 0.063 to 3.426
Ethanol % Mass 0.042 to 15.991
Benzene % Volume 0.09 to 1.091
Toluene % Volume 0.698 to 31.377
Ethylbenzene % Volume 0.5 to 3.175
Xylenes % Volume 3.037 to 18.955
Naphthalene % Volume 0.019 to 0.779
Methylnaphthalenes % Volume 0.21 to 1.484
1.1.2 This test method may be applicable to other concentration ranges, to other properties, or to other hydrocarbon streams,
however precision has not been determined.
1.2 Individual hydrocarbon components are typically not baseline-separated by the procedure described in this test method, that
is, some components will coelute. The coelutions are resolved at the detector using VUV absorbance spectra and deconvolution
algorithms.
1
This test method is under the jurisdiction of ASTM Committee D02 on Petroleum Products, Liquid Fuels, and Lubricants and is the direct responsibility of Subcommittee
D02.04.0L on Gas Chromatography Methods.
Current edition approved Sept. 1, 2020July 1, 2021. Published October 2020August 2021. Originally approved in 2017. Last previous edition approved in 20192020 as
D8071 – 19.D8071 – 20. DOI: 10.1520/D8071-20.10.1520/D8071-21.
*A Summary of Changes section appears at the end of this standard
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
1

---------------------- Page: 1 ----------------------
D8071 − 21
1.3 While this test method reports percent mass and percent volume for several specific components that may be present in
automotive spark-ignition engine fuel, it does not attempt to speciate all possible components that may occur in automotive
spark-ignition engine fuel. In particular, this test method is not intended as a type of detailed hydrocarbon analysis (DHA).
1.4 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility
of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of
regulatory limitations prior to use. See specific hazard statements in subsection 8.4 and Section 9.
1.6 This international standard was developed in accordance with internationally recognized principles on standardization
established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued
by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
2. Referenced Documents
2
2.1 ASTM Standards:
D1319 Test Method for Hydrocarbon Types in Liquid Petroleum Products by Fluorescent Indicator Adsorption
D3606 Test Method for Determination of Benzene and Toluene in Spark Ignition Fuels by Gas Chromatography
D4057 Practice for Manual Sampling of Petroleum and Petroleum Products
D4307 Practice for Preparation of Liquid Blends for Use as Analytical Standards
D5599 Test Method for Determination of Oxygenates in Gasoline by Gas Chromatography and Oxygen Selective Flame
Ionization Detection
D5769 Test Method for Determination
...

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