ASTM B466/B466M-18
(Specification)Standard Specification for Seamless Copper-Nickel Pipe and Tube
Standard Specification for Seamless Copper-Nickel Pipe and Tube
ABSTRACT
This specification covers the requirements for seamless UNS C70400, C70600, C71000, C71500, C71520, and C72200 copper-nickel pipes and tubes in straight lengths suitable for engineering applications. UNS C70620 and C71520 copper alloys are intended for products that are to be welded subsequently. Each product should be manufactured from cast billets by hot extrusion or piercing and then subjected to cold working and annealing. The standard tempers for the products in this specification are soft annealed (O60), light drawn (H55), hard drawn (H80), and hard drawn and end annealed (HE80). Pipe and tube tensile properties, Rockwell hardness, and test performance should conform to the values specified herein. Performance requirements include those from expansion, flattening, and eddy Current tests.
SCOPE
1.1 This specification establishes the requirements for seamless copper-nickel pipe and tube in straight lengths, suitable for general engineering purposes. The alloys involved are copper alloys UNS Nos. C70400, C70600, C70620, C71000, C71500, C71520, and C72200.
1.1.1 Copper alloys UNS Nos. C70620 and C71520 are intended for product that will be subsequently welded.
1.2 Units—Values stated in either SI units or inch-pound units are to be regarded separately as standard. Within the text, SI units are shown in brackets. The values stated in each system may not be exact equivalents; therefore, each system shall be used independently of the other. Combining values from the two systems may result in nonconformance with the specification.
1.3 The following safety hazard caveat pertains only to the test methods described in this specification:
1.3.1 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
General Information
- Status
- Published
- Publication Date
- 28-Feb-2018
- Technical Committee
- B05 - Copper and Copper Alloys
- Drafting Committee
- B05.04 - Pipe and Tube
Relations
- Effective Date
- 01-Mar-2018
- Effective Date
- 01-Jan-2024
- Effective Date
- 01-Aug-2019
- Effective Date
- 01-Jan-2019
- Effective Date
- 01-Jul-2018
- Effective Date
- 01-Jun-2018
- Effective Date
- 01-Jul-2017
- Effective Date
- 15-Jul-2016
- Effective Date
- 01-Feb-2015
- Effective Date
- 01-Dec-2013
- Effective Date
- 01-Jun-2013
- Effective Date
- 01-Dec-2012
- Effective Date
- 01-Dec-2011
- Effective Date
- 01-Nov-2011
- Effective Date
- 01-Jun-2011
Overview
ASTM B466/B466M-18 is the internationally recognized standard specification for seamless copper-nickel pipe and tube. Developed by ASTM International, this specification defines the requirements for supplying seamless pipes and tubes made from several UNS copper-nickel alloys, including C70400, C70600, C70620, C71000, C71500, C71520, and C72200. Products are supplied in straight lengths and are specifically designed for general engineering applications. The standard applies to products intended for further fabrication, including welding, as well as for use in systems requiring high corrosion resistance and mechanical integrity.
This specification details requirements for:
- Materials and manufacturing processes, including hot extrusion, piercing, cold working, and annealing
- Mechanical properties such as tensile strength and Rockwell hardness
- Dimensional tolerances and performance tests, including expansion, flattening, and non-destructive eddy current examinations
ASTM B466/B466M-18 can be applied using either SI units or inch-pound units, with clear guidelines preventing cross-use to maintain compliance.
Key Topics
- Scope and Alloys Covered: Specifies seamless copper-nickel pipe and tube for general engineering purposes, including alloys specifically intended for welding after fabrication.
- Manufacturing Requirements: Pipes and tubes must be produced from cast billets by hot working processes, with necessary subsequent cold working and annealing to ensure a seamless, uniform structure.
- Tempers: Four standard tempers are included:
- Soft annealed (O60)
- Light drawn (H55)
- Hard drawn (H80)
- Hard drawn and end annealed (HE80)
- Mechanical Properties: Products must meet minimum tensile strength and Rockwell hardness values.
- Testing and Performance:
- Expansion test for certain tempers
- Flattening test alternative (for diameters over 4 in.)
- Eddy current testing or optional hydrostatic/pneumatic tests for leak detection and quality
- Chemical Composition: Specifies permitted contents for copper, nickel, iron, other alloying elements, and allowable impurities.
Applications
Seamless copper-nickel pipes and tubes manufactured under ASTM B466/B466M-18 are widely used due to their corrosion resistance, particularly against seawater and various industrial fluids. Common applications include:
- Marine engineering: Shipbuilding, offshore oil and gas, seawater piping, and heat exchanger systems
- Power generation: Condenser tubes and other cooling system components
- Desalination plants: Saltwater handling equipment
- Chemical processing: Where resistance to corrosion and biofouling is critical
The specification supports products for both structural and pressure applications, including those requiring subsequent welding or assembly to ASME Boiler and Pressure Vessel Code standards.
Related Standards
Several ASTM and industry standards are referenced within ASTM B466/B466M-18 to ensure comprehensive quality and compatibility, including:
- ASTM B251/B251M: General requirements for wrought seamless copper and copper-alloy tubes
- ASTM B153: Expansion test method for copper and copper-alloy pipe and tubing
- ASTM B968/B968M: Flattening test method for copper and copper-alloy tubes
- ASTM E8/E8M: Tension testing of metallic materials
- ASTM E18: Rockwell hardness testing methods
- ASME Boiler and Pressure Vessel Code: For components intended for high-pressure or boiler service
By adhering to ASTM B466/B466M-18, manufacturers and engineers ensure that seamless copper-nickel pipe and tube products deliver consistent performance, reliability, and compliance in essential industrial and marine environments.
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Frequently Asked Questions
ASTM B466/B466M-18 is a technical specification published by ASTM International. Its full title is "Standard Specification for Seamless Copper-Nickel Pipe and Tube". This standard covers: ABSTRACT This specification covers the requirements for seamless UNS C70400, C70600, C71000, C71500, C71520, and C72200 copper-nickel pipes and tubes in straight lengths suitable for engineering applications. UNS C70620 and C71520 copper alloys are intended for products that are to be welded subsequently. Each product should be manufactured from cast billets by hot extrusion or piercing and then subjected to cold working and annealing. The standard tempers for the products in this specification are soft annealed (O60), light drawn (H55), hard drawn (H80), and hard drawn and end annealed (HE80). Pipe and tube tensile properties, Rockwell hardness, and test performance should conform to the values specified herein. Performance requirements include those from expansion, flattening, and eddy Current tests. SCOPE 1.1 This specification establishes the requirements for seamless copper-nickel pipe and tube in straight lengths, suitable for general engineering purposes. The alloys involved are copper alloys UNS Nos. C70400, C70600, C70620, C71000, C71500, C71520, and C72200. 1.1.1 Copper alloys UNS Nos. C70620 and C71520 are intended for product that will be subsequently welded. 1.2 Units—Values stated in either SI units or inch-pound units are to be regarded separately as standard. Within the text, SI units are shown in brackets. The values stated in each system may not be exact equivalents; therefore, each system shall be used independently of the other. Combining values from the two systems may result in nonconformance with the specification. 1.3 The following safety hazard caveat pertains only to the test methods described in this specification: 1.3.1 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. 1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
ABSTRACT This specification covers the requirements for seamless UNS C70400, C70600, C71000, C71500, C71520, and C72200 copper-nickel pipes and tubes in straight lengths suitable for engineering applications. UNS C70620 and C71520 copper alloys are intended for products that are to be welded subsequently. Each product should be manufactured from cast billets by hot extrusion or piercing and then subjected to cold working and annealing. The standard tempers for the products in this specification are soft annealed (O60), light drawn (H55), hard drawn (H80), and hard drawn and end annealed (HE80). Pipe and tube tensile properties, Rockwell hardness, and test performance should conform to the values specified herein. Performance requirements include those from expansion, flattening, and eddy Current tests. SCOPE 1.1 This specification establishes the requirements for seamless copper-nickel pipe and tube in straight lengths, suitable for general engineering purposes. The alloys involved are copper alloys UNS Nos. C70400, C70600, C70620, C71000, C71500, C71520, and C72200. 1.1.1 Copper alloys UNS Nos. C70620 and C71520 are intended for product that will be subsequently welded. 1.2 Units—Values stated in either SI units or inch-pound units are to be regarded separately as standard. Within the text, SI units are shown in brackets. The values stated in each system may not be exact equivalents; therefore, each system shall be used independently of the other. Combining values from the two systems may result in nonconformance with the specification. 1.3 The following safety hazard caveat pertains only to the test methods described in this specification: 1.3.1 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. 1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
ASTM B466/B466M-18 is classified under the following ICS (International Classification for Standards) categories: 77.150.30 - Copper products. The ICS classification helps identify the subject area and facilitates finding related standards.
ASTM B466/B466M-18 has the following relationships with other standards: It is inter standard links to ASTM B466/B466M-14, ASTM E8/E8M-24, ASTM B846-19a, ASTM B846-19, ASTM E18-18, ASTM E243-18, ASTM E18-17, ASTM E8/E8M-16, ASTM E8/E8M-15, ASTM E243-13, ASTM E8/E8M-13, ASTM E18-12, ASTM E8/E8M-11, ASTM E18-11, ASTM B846-11a. Understanding these relationships helps ensure you are using the most current and applicable version of the standard.
ASTM B466/B466M-18 is available in PDF format for immediate download after purchase. The document can be added to your cart and obtained through the secure checkout process. Digital delivery ensures instant access to the complete standard document.
Standards Content (Sample)
This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the
Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
Designation:B466/B466M −18
Standard Specification for
Seamless Copper-Nickel Pipe and Tube
This standard is issued under the fixed designation B466/B466M; the number immediately following the designation indicates the year
of original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval.
A superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
This standard has been approved for use by agencies of the U.S. Department of Defense.
1. Scope* B153 Test Method for Expansion (Pin Test) of Copper and
Copper-Alloy Pipe and Tubing
1.1 Thisspecificationestablishestherequirementsforseam-
B251/B251M Specification for General Requirements for
lesscopper-nickelpipeandtubeinstraightlengths,suitablefor
Wrought Seamless Copper and Copper-Alloy Tube
general engineering purposes. The alloys involved are copper
B846 Terminology for Copper and Copper Alloys
alloys UNS Nos. C70400, C70600, C70620, C71000, C71500,
B968/B968M Test Method for Flattening of Copper and
C71520, and C72200.
Copper-Alloy Pipe and Tube
1.1.1 Copper alloys UNS Nos. C70620 and C71520 are
E8/E8M Test Methods for Tension Testing of Metallic Ma-
intended for product that will be subsequently welded.
terials
1.2 Units—Values stated in either SI units or inch-pound
E18 Test Methods for Rockwell Hardness of Metallic Ma-
units are to be regarded separately as standard. Within the text,
terials
SI units are shown in brackets. The values stated in each
E54 Test Methods for ChemicalAnalysis of Special Brasses
system may not be exact equivalents; therefore, each system
and Bronzes (Withdrawn 2002)
shall be used independently of the other. Combining values
E62 Test Methods for Chemical Analysis of Copper and
from the two systems may result in nonconformance with the
CopperAlloys(PhotometricMethods)(Withdrawn2010)
specification.
E75 Test Methods for Chemical Analysis of Copper-Nickel
1.3 The following safety hazard caveat pertains only to the and Copper-Nickel-Zinc Alloys (Withdrawn 2010)
E76 Test Methods for Chemical Analysis of Nickel-Copper
test methods described in this specification:
1.3.1 This standard does not purport to address all of the Alloys (Withdrawn 2003)
E118 Test Methods for Chemical Analysis of Copper-
safety concerns, if any, associated with its use. It is the
responsibility of the user of this standard to establish appro- Chromium Alloys (Withdrawn 2010)
priate safety, health, and environmental practices and deter- E243 Practice for Electromagnetic (Eddy Current) Examina-
tion of Copper and Copper-Alloy Tubes
mine the applicability of regulatory limitations prior to use.
E478 Test Methods for ChemicalAnalysis of CopperAlloys
1.4 This international standard was developed in accor-
2.2 Other Standard:
dance with internationally recognized principles on standard-
ASME Boiler and Pressure Vessel Code
ization established in the Decision on Principles for the
Development of International Standards, Guides and Recom-
3. General Requirements
mendations issued by the World Trade Organization Technical
3.1 The following sections of Specification B251/B251M
Barriers to Trade (TBT) Committee.
constitute a part of this specification:
3.1.1 Terminology,
2. Referenced Documents
3.1.2 Materials and Manufacture,
2.1 ASTM Standards:
3.1.3 Dimensions, Mass, and Permissible Variations,
3.1.4 Workmanship, Finish, and Appearance,
3.1.5 Sampling,
ThisspecificationisunderthejurisdictionofASTMCommitteeB05onCopper
3.1.6 Number of Tests and Retests,
and CopperAlloys and is the direct responsibility of Subcommittee B05.04 on Pipe
3.1.7 Test Specimens,
and Tube.
Current edition approved March 1, 2018. Published April 2018. Originally
approved in 1968. Last previous edition approved in 2014 as B466/B466M – 14.
DOI: 10.1520/B0466_B0466M-18 The last approved version of this historical standard is referenced on
For referenced ASTM standards, visit the ASTM website, www.astm.org, or www.astm.org.
contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM Available from American Society of Mechanical Engineers (ASME), ASME
Standards volume information, refer to the standard’s Document Summary page on International Headquarters, Two Park Ave., New York, NY 10016-5990, http://
the ASTM website. www.asme.org.
*A Summary of Changes section appears at the end of this standard
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
B466/B466M−18
3.1.8 Test Methods, 5.2.8 WhentheproductinalloysC71000orC72200istobe
3.1.9 Significance of Numerical Limits, subsequently welded (Table 1, Footnote A), and
3.1.10 Inspection, 5.2.9 When product is purchased for an agency of the U.S.
3.1.11 Rejection and Rehearing, Government (Purchases for U.S. Government section).
3.1.12 Certification,
6. Materials and Manufacture
3.1.13 Packing and Package Marking, and
3.1.14 Mill Test Report.
6.1 Materials—The material of manufacture shall be cast
billets of copper alloys UNS Nos. C70400, C70600, C70620,
3.2 In addition, when a section with a title identical to that
C71000, C71500, C71520, and C72200 of such purity and
referenced in 3.1, above, appears in this specification, it
soundness as to be suitable for processing into the products
contains additional requirements which supplement those ap-
prescribed herein.
pearing in Specification B251/B251M.
6.2 Manufacture—The product shall be manufactured by
4. Terminology
such hot extrusion or piercing and subsequent cold working
4.1 Definitions—For definitions of terms related to copper
and annealing as to produce a uniform, seamless wrought
and copper alloys, refer to Terminology B846.
structure in the finished product.
5. Ordering Information
7. Chemical Composition
5.1 Include the following specified choices when placing
7.1 The material shall conform to the chemical composition
orders for product under this specification, as applicable:
requirements in Table 1 for the copper alloy UNS No.
5.1.1 ASTM designation and year of issue,
designation specified in the ordering information.
5.1.2 Copper Alloy UNS No. (Scope section),
7.2 These composition limits do not preclude the presence
5.1.3 Temper (Temper section),
of other elements. By agreements between the manufacturer
5.1.4 Dimensions; diameter or distance between parallel
and purchaser, limits may be established and analysis required
surfaces, wall thickness, or size (see also Table X1.1).
for unnamed elements.
5.1.5 Totallength,totalweight,ornumberofpiecesofeach,
7.2.1 For alloys in which copper is listed as “remainder,”
and
copper is the difference between the sum of results of all
5.1.6 Intended application.
elements determined and 100 %.
5.2 The following options are available but may not be
7.2.2 When all elements in Table 1 are determined, the sum
included unless specified at the time of placing of the order
of results shall be as shown below:
when required.
Copper Plus Named
Copper Alloy UNS No.
5.2.1 Whentensiontestsarerequiredforlargediametertube
Elements, % min
(Mechanical Property Requirements section),
C70400 99.5
5.2.2 Hydrostatic Test (Nondestructive Test Requirements
C70600 & C70620 99.5
section),
C71000 99.5
C71500 & C71520 99.5
5.2.2.1 If the product needs to be subjected to a pressure
C72200 99.8
gage reading over 1000 psi [7 MPa].
5.2.3 Pneumatic Test (Nondestructive Test Requirements
8. Temper
section),
8.1 The standard tempers for products described in this
5.2.4 Heat identification or traceability requirements, or
specification are given in Table 2.
both,
8.1.1 Annealed Temper—O60 (soft anneal).
5.2.5 Certification (Specification B251/B251M),
8.1.2 Drawn Tempers—H55 (light drawn), H80 (hard
5.2.6 Mill test report (Specification B251/B251M),
drawn), or HE80 (hard drawn and end annealed).
5.2.7 When product is ordered for ASME Boiler and Pres-
sure Vessel Code Application, NOTE 1—The H55 (light drawn) temper is used only when product of
TABLE 1 Chemical Requirements
Composition, %
Copper Alloy
Copper Nickel incl Lead, Zinc, Sulfur, Phosphorus, Other Named
UNS Nos. Iron Manganese Chromium
incl Silver Cobalt max max max max Elements
C70400 remainder 4.8 to 6.2 0.05 1.3 to 1.7 1.0 0.30 to 0.8 0.02 0.02 . . . . . .
C70600 remainder 9.0 to 11.0 0.05 1.0 to 1.8 1.0 1.0 max . . . . . . . .
C70620 86.5 min 9.0 to 11.0 0.02 1.0 to 1.8 0.50 1.0 max 0.02 0.02 . . . Carbon 0.05
max
A A A
C71000 remainder 19.0 to 23.0 0.05 0.5to1.0 1.0 1.0 max 0.02 0.02 . . .
C71500 remainder 29.0 to 33.0 0.05 0.40 to 1.0 1.0 1.0 max . . . . . . . .
C71520 65.0 min 29.0 to 33.0 0.02 0.40 to 1.0 0.50 1.0 max 0.02 0.02 . . . Carbon 0.05
max
A A A,B
C72200 remainder 15.0 to 18.0 0.05 0.50 to 1.0 1.0 1.0 max 0.02 0.02 0.30 to 0.7
A
When the product is for subsequent welding applications, and so specified by the purchaser, zinc shall be 0.50 % max, lead 0.02 % max, and carbon 0.05 % max.
B
Silicon 0.03 max, titanium 0.03 max.
B466/B466M−18
TABLE 2 Mechanical Requirements
B
Rockwell
A
Tensile Strength, Yield Strength,
Copper Alloy Hardness
min
Temper Code Temper Name min
30 T
UNS Nos.
ksi MPa ksi MPa
C
O60 Soft anneal C70400 37 255 12 85 45 max
C70600 & C70620 38 260 13 90 45 max
C71000 45 310 16 110 48 max
C71500 & C71520 52 360 18 125 51 max
C72200 40 275 14 95 45 max
H55 Light drawn C70400 40 275 30 205 41 to 65
C70600 & C70620 45 310 35 240 45 to 70
C72200 48 330 42 290 55 to 70
H80 Hard drawn C70400 45 310 35 240 60 min
C70600 & C70620 50 345 40 275 63 min
C71000 55 380 43 295 67 min
C71500 & C71520 70 485 45 310 70 min
C72200 55 380 44 305 67 min
A
At 0.5 % extension under load.
B
Rockwell hardness values shall apply only to tube or pipe having a wall thickness of 0.020 in. [0.5 mm] or over and an outside diameter of ⁄16 in. [8 mm] or over. For
all other tube no Rockwell hardness values shall apply. Rockwell hardness tests shall be made on the inside surface of the tube. When suitable equipment is not available
for determining the specified Rockwell hardness, other Rockwell scales and values may be specified subject to agreement between the manufacturer and the purchaser.
C
Although no minimum grain size is specified, the product must nevertheless have fully recrystallized grain structure.
some stiffness yet capable of being bent is needed. The H80 (hard drawn)
10.1.1 Tube furnished in the O60 (soft anneal) temper and
temper is used only when there is a need for material as strong as
the HE80 (hard drawn and end annealed) shall withstand an
commercially feasible.
expansion to 30 % of the outside diameter when tested in
accordance with Test Method B153.
9. Mechanical Property Requirements
10.1.1.1 The expanded sample shall show no cracking or
9.1 Tensile Strength Requirements—Product furnished un-
other defect visible to the unaided eye.
der this specification shall conform to the tensile and yield
10.1.1.2 The expansion test is not required for tube fur-
strength requirements prescribed in Table 2 when tested in
nished in tempers other than O60 and HE80.
accordance with Test Methods E8/E8M.
10.2 Flattening Test Alternative:
9.2 Rockwell Hardness Requirements—Product furnished
10.2.1 As an alternate to the expansion test for product over
underthisspecificationshallconformtotheRockwellhardness
4 in. [100 mm] in diameter, the flattening test described inTest
requirements prescribed in Table 2 when tested in accordance
Method B968/B968M may be performed.
with Test Methods E18.
10.2.2 During inspection, the flattened areas of the test
9.3 The mechanical property requirements for tubes of all
specimenshallbefreeofdefects,butblemishesofanaturethat
alloys in the H80 temper are only applicable to the following
do not interfere with the intended application are acceptable.
sizes:
Outside Diameter, in. [mm] Wall Thickness, in. [mm]
11. Other Requirements
Up to 1 [25] incl 0.020-0.120 [0.5-3.0] incl
11.1 Purchases for U.S. Government Agencies—If the prod-
Over 1-2 [25-50] incl 0.035-0.180 [0.9-4.5] incl
Over 2-4 [50-100] incl 0.060-0.250 [1.5-6.5] incl
uct ordered is for an agency of the U.S. Government, when
specified in the contract or purchase order, the product fur-
9.3.1 For other sizes in the H80 (hard drawn) temper, the
nished shall conform to the conditions specified in the Supple-
mechanical property requirements shall be established by
mentary Requirements section of Specification B251/B251M.
agreement between the manufacturer and the purchaser.
9.4 The mechanical property requirements for tubes of the 11.2 Nondestructive Test Requirements:
HE80 (hard drawn and end annealed) temper shall be estab-
11.2.1 Electromagnetic (Eddy Current) Test: Each tube up
lished by agreement between the manufacturer or supplier and
to and including 3.125-in. [80-mm] nominal outside diameter
the purchaser.
shall be subjected to an eddy current test. Testing shall follow
the procedures of Practice E243 and the Test Methods section
9.5 Tension tests are required to be performed for products
of this specification.
having a wall thickness under 0.020 in. [0.5 mm] and an inside
11.2.1.1 The provisions for the determination of “end-
diameter of 0.312 [0.8 mm] or smaller.
effect” in Practice E243 sh
...
This document is not an ASTM standard and is intended only to provide the user of an ASTM standard an indication of what changes have been made to the previous version. Because
it may not be technically possible to adequately depict all changes accurately, ASTM recommends that users consult prior editions as appropriate. In all cases only the current version
of the standard as published by ASTM is to be considered the official document.
Designation: B466/B466M − 14 B466/B466M − 18
Standard Specification for
Seamless Copper-Nickel Pipe and Tube
This standard is issued under the fixed designation B466/B466M; the number immediately following the designation indicates the year
of original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval.
A superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
This standard has been approved for use by agencies of the U.S. Department of Defense.
1. Scope*
1.1 This specification establishes the requirements for seamless copper-nickel pipe and tube in straight lengths, suitable for
general engineering purposes. The alloys involved are copper alloys UNS Nos. C70400, C70600, C70620, C71000, C71500,
C71520, and C72200.
1.1.1 Copper alloys UNS Nos. C70620 and C71520 are intended for product that will be subsequently welded.
1.2 Units—Values stated in either SI units or inch-pound units are to be regarded separately as standard. Within the text, SI units
are shown in brackets. The values stated in each system may not be exact equivalents; therefore, each system shall be used
independently of the other. Combining values from the two systems may result in nonconformance with the specification.
1.3 The following safety hazard caveat pertains only to the test methods described in this specification:
1.3.1 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility
of the user of this standard to establish appropriate safety safety, health, and healthenvironmental practices and determine the
applicability of regulatory limitations prior to use.
1.4 This international standard was developed in accordance with internationally recognized principles on standardization
established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued
by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
2. Referenced Documents
2.1 ASTM Standards:
B153 Test Method for Expansion (Pin Test) of Copper and Copper-Alloy Pipe and Tubing
B251B251/B251M Specification for General Requirements for Wrought Seamless Copper and Copper-Alloy Tube (Metric)
B0251_B0251M
B251M Specification for General Requirements for Wrought Seamless Copper and Copper-Alloy Tube (Metric) (Withdrawn
2017)
B846 Terminology for Copper and Copper Alloys
B950 Guide for Editorial Procedures and Form of Product Specifications for Copper and Copper Alloys
B968/B968M Test Method for Flattening of Copper and Copper-Alloy Pipe and Tube
E8/E8M Test Methods for Tension Testing of Metallic Materials
E18 Test Methods for Rockwell Hardness of Metallic Materials
E54 Test Methods for Chemical Analysis of Special Brasses and Bronzes (Withdrawn 2002)
E62 Test Methods for Chemical Analysis of Copper and Copper Alloys (Photometric Methods) (Withdrawn 2010)
E75 Test Methods for Chemical Analysis of Copper-Nickel and Copper-Nickel-Zinc Alloys (Withdrawn 2010)
E76 Test Methods for Chemical Analysis of Nickel-Copper Alloys (Withdrawn 2003)
E118 Test Methods for Chemical Analysis of Copper-Chromium Alloys (Withdrawn 2010)
E243 Practice for Electromagnetic (Eddy Current) Examination of Copper and Copper-Alloy Tubes
E478 Test Methods for Chemical Analysis of Copper Alloys
This specification is under the jurisdiction of ASTM Committee B05 on Copper and Copper Alloys and is the direct responsibility of Subcommittee B05.04 on Pipe and
Tube.
Current edition approved April 1, 2014March 1, 2018. Published May 2014April 2018. Originally approved in 1968. Last previous edition approved in 20092014 as
B466/B466M – 09.B466/B466M – 14. DOI: 10.1520/B0466_B0466M-1410.1520/B0466_B0466M-18
For referenced ASTM standards, visit the ASTM website, www.astm.org, or contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM Standards
volume information, refer to the standard’s Document Summary page on the ASTM website.
The last approved version of this historical standard is referenced on www.astm.org.
*A Summary of Changes section appears at the end of this standard
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B466/B466M − 18
2.2 Other Standard:
ASME Boiler and Pressure Vessel Code
3. General Requirements
3.1 The following sections of Specification B251B251/B251M or B251Mconstitute a part of this specification:
3.1.1 Terminology,
3.1.2 Materials and Manufacture,
3.1.3 Dimensions, Mass, and Permissible Variations,
3.1.4 Workmanship, Finish, and Appearance,
3.1.5 Sampling,
3.1.6 Number of Tests and Retests,
3.1.7 Test Specimens,
3.1.8 Test Methods,
3.1.9 Significance of Numerical Limits,
3.1.10 Inspection,
3.1.11 Rejection and Rehearing,
3.1.12 Certification,
3.1.13 Packing and Package Marking, and
3.1.14 Mill Test Report.
3.2 In addition, when a section with a title identical to that referenced in 3.1, above, appears in this specification, it contains
additional requirements which supplement those appearing in Specification B251B251/B251M or B251M.
4. Terminology
4.1 Definitions—For definitions of terms related to copper and copper alloys, refer to Terminology B846.
5. Ordering Information
5.1 Include the following specified choices when placing orders for product under this specification, as applicable:
5.1.1 ASTM designation and year of issue,
5.1.2 Copper Alloy UNS No. (Scope section),
5.1.3 Temper (Temper section),
5.1.4 Dimensions; diameter or distance between parallel surfaces, wall thickness, or size (see also Table X1.1).
5.1.5 Total length, total weight, or number of pieces of each, and
5.1.6 Intended application.
5.2 The following options are available but may not be included unless specified at the time of placing of the order when
required.
5.2.1 When tension tests are required for large diameter tube (Mechanical Property Requirements section),
5.2.2 Hydrostatic Test (Nondestructive Test Requirements section),
5.2.2.1 If the product needs to be subjected to a pressure gage reading over 1000 psi [7 MPa].
5.2.3 Pneumatic Test (Nondestructive Test Requirements section),
5.2.4 Heat identification or traceability requirements, or both,
5.2.5 Certification (Specification B251B251/B251M or B251M),
5.2.6 Mill test report (Specification B251B251/B251M or B251M),
5.2.7 When product is ordered for ASME Boiler &and Pressure Vessel Code Application,
5.2.8 When the product in alloys C71000 or C72200 is to be subsequently welded (Table 1, Footnote A), and
5.2.9 When product is purchased for an agency of the U.S. Government (Purchases for U.S. Government section).
6. Materials and Manufacture
6.1 Materials—The material of manufacture shall be cast billets of copper alloys UNS Nos. C70400, C70600, C70620, C71000,
C71500, C71520, and C72200 of such purity and soundness as to be suitable for processing into the products prescribed herein.
6.2 Manufacture—The product shall be manufactured by such hot extrusion or piercing and subsequent cold working and
annealing as to produce a uniform, seamless wrought structure in the finished product.
7. Chemical Composition
7.1 The material shall conform to the chemical composition requirements in Table 1 for the copper alloy UNS No. designation
specified in the ordering information.
Available from American Society of Mechanical Engineers (ASME), ASME International Headquarters, Two Park Ave., New York, NY 10016-5990, http://
www.asme.org.
B466/B466M − 18
TABLE 1 Chemical Requirements
Composition, %
Copper Alloy
Copper Nickel incl Lead, Zinc, Sulfur, Phosphorus, Other Named
UNS Nos. Iron Manganese Chromium
incl Silver Cobalt max max max max Elements
C70400 remainder 4.8 to 6.2 0.05 1.3 to 1.7 1.0 0.30 to 0.8 0.02 0.02 . . . . . .
C70400 remainder 4.8 to 6.2 0.05 1.3 to 1.7 1.0 0.30 to 0.8 0.02 0.02 . . . . . .
C70600 remainder 9.0 to 11.0 0.05 1.0 to 1.8 1.0 1.0 max . . . . . . . .
C70600 remainder 9.0 to 11.0 0.05 1.0 to 1.8 1.0 1.0 max . . . . . . . .
C70620 86.5 min 9.0 to 11.0 0.02 1.0 to 1.8 0.50 1.0 max 0.02 0.02 . . . Carbon 0.05
max
A A A
C71000 remainder 19.0 to 23.0 0.05 0.5 to 1.0 1.0 1.0 max 0.02 0.02 . . .
A A A
C71000 remainder 19.0 to 23.0 0.05 0.5 to 1.0 1.0 1.0 max 0.02 0.02 . . .
C71500 remainder 29.0 to 33.0 0.05 0.40 to 1.0 1.0 1.0 max . . . . . . . .
C71520 65.0 min 29.0 to 33.0 0.02 0.40 to 1.0 0.50 1.0 max 0.02 0.02 . . . Carbon 0.05
max
A A A,B
C72200 remainder 15.0 to 18.0 0.05 0.50 to 1.0 1.0 1.0 max 0.02 0.02 0.30 to 0.7
A
When the product is for subsequent welding applications, and so specified by the purchaser, zinc shall be 0.50 % max, lead 0.02 % max, and carbon 0.05 % max.
B
Silicon 0.03 max, titanium 0.03 max.
7.2 These composition limits do not preclude the presence of other elements. By agreements between the manufacturer and
purchaser, limits may be established and analysis required for unnamed elements.
7.2.1 For alloys in which copper is listed as “remainder,” copper is the difference between the sum of results of all elements
determined and 100 %.
7.2.2 When all elements in Table 1 are determined, the sum of results shall be as shown below:
Copper Plus Named
Copper Alloy UNS No.
Elements, % min
C70400 99.5
C70600 & C70620 99.5
C71000 99.5
C71500 & C71520 99.5
C72200 99.8
8. Temper
8.1 The standard tempers for products described in this specification are given in Table 2.
8.1.1 Annealed Temper—O60 (soft anneal).
8.1.2 Drawn Tempers—H55 (light drawn), H80 (hard drawn), or HE80 (hard drawn and end annealed).
NOTE 1—The H55 (light drawn) temper is used only when product of some stiffness yet capable of being bent is needed. The H80 (hard drawn) temper
is used only when there is a need for material as strong as commercially feasible.
TABLE 2 Mechanical Requirements
B
Rockwell
A
Tensile Strength,
Yield Strength,
Copper Alloy Hardness
Temper Code Temper Name min min
30 T
UNS Nos.
ksi MPa ksi MPa
C
O60 Soft anneal C70400 37 255 12 85 45 max
C70600 & C70620 38 260 13 90 45 max
C71000 45 310 16 110 48 max
C71500 & C71520 52 360 18 125 51 max
C72200 40 275 14 95 45 max
H55 Light drawn C70400 40 275 30 205 41 to 65
C70600 & C70620 45 310 35 240 45 to 70
C72200 48 330 42 290 55 to 70
H80 Hard drawn C70400 45 310 35 240 60 min
C70600 & C70620 50 345 40 275 63 min
C71000 55 380 43 295 67 min
C71500 & C71520 70 485 45 310 70 min
C72200 55 380 44 305 67 min
A
At 0.5 % extension under load.
B 5
Rockwell hardness values shall apply only to tube or pipe having a wall thickness of 0.020 in. [0.5 mm] or over and an outside diameter of ⁄16 in. [8 mm] or over. For
all other tube no Rockwell hardness values shall apply. Rockwell hardness tests shall be made on the inside surface of the tube. When suitable equipment is not available
for determining the specified Rockwell hardness, other Rockwell scales and values may be specified subject to agreement between the manufacturer and the purchaser.
C
Although no minimum grain size is specified, the product must nevertheless have fully recrystallized grain structure.
B466/B466M − 18
9. Mechanical Property Requirements
9.1 Tensile Strength Requirements—Product furnished under this specification shall conform to the tensile and yield strength
requirements prescribed in Table 2 when tested in accordance with Test Methods E8/E8M.
9.2 Rockwell Hardness Requirements—Product furnished under this specification shall conform to the Rockwell hardness
requirements prescribed in Table 2 when tested in accordance with Test Methods E18.
9.3 The mechanical property requirements for tubes of all alloys in the H80 temper are only applicable to the following sizes:
Outside Diameter, in. [mm] Wall Thickness, in. [mm]
Up to 1 [25] incl 0.020-0.120 [0.5-3.0] incl
Over 1-2 [25-50] incl 0.035-0.180 [0.9-4.5] incl
Over 2-4 [50-100] incl 0.060-0.250 [1.5-6.5] incl
9.3.1 For other sizes in the H80 (hard drawn) temper, the mechanical property requirements shall be established by agreement
between the manufacturer and the purchaser.
9.4 The mechanical property requirements for tubes of the HE80 (hard drawn and end annealed) temper shall be established by
agreement between the manufacturer or supplier and the purchaser.
9.5 Tension tests are required to be performed for products having a wall thickness under 0.020 in. [0.5 mm] and an inside
diameter of 0.312 [0.8 mm] or smaller.
9.5.1 Tension tests for other sizes need not be performed except when specified in the contract or purchase order at the time
of placing the order.
10. Performance Requirements
10.1 Expansion Test Requirements:
10.1.1 Tube furnished in the O60 (soft anneal) temper and the HE80 (hard drawn and end annealed) shall withstand an
expansion to 30 % of the outside diameter when tested in accordance with Test Method B153.
10.1.1.1 The expanded sample shall show no cracking or other defect visible to the unaided eye.
10.1.1.2 The expansion test is not required for tube furnished in tempers other than O60 and HE80.
10.2 Flattening Test Alternative:
10.2.1 As an alternate to the expansion test for product over 4 in. [100 mm] in diameter, the flattening test described in Test
Method B968/B968M may be performed.
10.2.2 During inspection, the flattened areas of the test specimen shall be free of defects, but blemishes of a nature that do not
interfere with the intended application are acceptable.
11. Other Requirements
11.1 Purchases for U.S. Government Agencies—If the product ordered is for an agency of the U.S. Government, when specified
in the contract or purchase order, the product furnished shall conf
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