ASTM B418-16a(2021)
(Specification)Standard Specification for Cast and Wrought Galvanic Zinc Anodes
Standard Specification for Cast and Wrought Galvanic Zinc Anodes
ABSTRACT
This specification covers cast and wrought galvanic zin anodes used for the cathodic protection of more noble metals and alloys in sea water, brackish water, other saline electrolytes, or other corrosive environments. The anodes shall undergo chemical analysis and spectrochemical analysis and shall conform to the required chemical compositions of aluminum, cadmium, iron, lead, copper, and zinc.
SCOPE
1.1 This specification covers cast and wrought galvanic zinc anodes used for the cathodic protection of more noble metals and alloys in sea water, brackish water, other saline electrolytes, or other corrosive environments.
1.2 Type I anodes are most commonly used for such applications. The Type I anode composition in this specification meets the chemical composition requirements of MIL-A-18001K.
1.3 Zinc anodes conforming to this specification may be used in other waters, electrolytes, backfills, and soils where experience has shown that the specified composition is efficient and reliable. Type II anodes are most commonly used for such applications.
1.4 The values stated in inch-pound units are to be regarded as standard. The values given in parentheses are mathematical conversions to SI units that are provided for information only and are not considered standard.
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to become familiar with all hazards including those identified in the appropriate Safety Data Sheet (SDS) for this product/material as provided by the manufacturer, to establish appropriate safety, health, and environmental practices, and determine the applicability of regulatory limitations prior to use.
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
General Information
- Status
- Published
- Publication Date
- 31-Mar-2021
- Technical Committee
- B02 - Nonferrous Metals and Alloys
- Drafting Committee
- B02.04 - Zinc and Cadmium
Relations
- Effective Date
- 01-Oct-2016
- Effective Date
- 01-Oct-2015
- Effective Date
- 01-Jun-2015
- Effective Date
- 01-Oct-2014
- Refers
ASTM B949-13 - Standard Specification for General Requirements for Zinc and Zinc Alloy Products - Effective Date
- 01-Aug-2013
- Effective Date
- 01-Feb-2013
- Effective Date
- 01-Feb-2013
- Effective Date
- 01-May-2012
- Effective Date
- 01-Oct-2009
- Effective Date
- 01-Oct-2009
- Effective Date
- 01-Oct-2009
- Effective Date
- 01-Nov-2008
- Effective Date
- 01-Oct-2008
- Refers
ASTM B949-08 - Standard Specification for General Requirements for Zinc and Zinc Alloy Products - Effective Date
- 15-May-2008
- Effective Date
- 01-Mar-2008
Overview
ASTM B418-16a(2021) - Standard Specification for Cast and Wrought Galvanic Zinc Anodes defines the requirements for zinc anodes used in cathodic protection systems. These anodes are designed to protect more noble metals and alloys from corrosion in sea water, brackish water, saline electrolytes, and other corrosive environments. The standard covers both cast and wrought forms of zinc anodes and establishes chemical composition, analysis methods, sampling procedures, and product identification requirements.
Compliance with ASTM B418 ensures superior protection and longevity of metallic structures by specifying zinc anodes that deliver reliable performance in harsh, corrosive environments.
Key Topics
Scope of Application:
The standard applies to zinc anodes intended for the cathodic protection of metals in various water and soil environments where corrosion is a concern.Types of Zinc Anodes:
- Type I: Most used for marine applications. Its chemical composition aligns with military specification MIL-A-18001K.
- Type II: Recommended for environments where experience confirms efficiency, particularly for elevated temperatures or specialized soils and backfills.
Chemical Composition Requirements:
- Zinc anodes must consist of special high-grade zinc with controlled limits on aluminum, cadmium, iron, lead, copper, and other elements.
- Type II anodes feature stricter iron content to minimize intergranular corrosion above 120°F (50°C).
Testing and Analysis:
- Chemical analysis methods must be in accordance with referenced ASTM and ISO standards.
- Sampling procedures ensure representative quality across production lots.
- Spectrochemical and chemical testing methods are specified for accuracy and conformity.
Product Workmanship:
- Anodes must be free of defects like cracks, flash, burrs, and slag.
- Guidelines for anode design, including bolt holes and rod inserts for mounting, are provided.
Marking and Packaging:
- Slabs, blocks, and ingots require clear identification according to ASTM B949.
Applications
Cast and wrought galvanic zinc anodes play a critical role in the following areas:
Marine Structures:
Used extensively for ship hulls, offshore platforms, piers, and pipelines in saltwater and brackish water environments to prevent corrosion.Underground and Submerged Metallic Installations:
Ideal for protecting buried pipelines, storage tanks, and steel pilings in aggressive soils and saline backfills.Industrial Equipment:
Suitable for use in reactors, process vessels, and cooling systems exposed to corrosive electrolytes.Infrastructure Protection:
Deployed in water treatment plants, reservoirs, and bridge supports where saline or corrosive environments threaten metallic integrity.
Adhering to ASTM B418 improves asset longevity, reduces maintenance costs, and supports regulatory compliance in cathodic protection applications.
Related Standards
For comprehensive guidance and interrelated specifications, consider these key standards frequently referenced alongside ASTM B418:
- ASTM B6: Specification for Zinc, covering purity requirements of raw zinc materials.
- ASTM B949: General requirements for zinc and zinc alloy products, including marking and packaging.
- ASTM E29: Practice for significant digits in test data.
- ASTM E527: Practice for numbering metals and alloys in the Unified Numbering System (UNS).
- ASTM E536: Test methods for chemical analysis of zinc and zinc alloys.
- ISO 3815-1 / ISO 3815-2: Analytical procedures for zinc and zinc alloys.
- MIL-A-18001K: Military specification for sacrificial zinc alloy anodes.
By adhering to ASTM B418-16a(2021) and associated references, manufacturers, engineers, and operators ensure optimal performance and regulatory alignment for cathodic protection zinc anodes.
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ASTM B418-16a(2021) - Standard Specification for Cast and Wrought Galvanic Zinc Anodes
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Frequently Asked Questions
ASTM B418-16a(2021) is a technical specification published by ASTM International. Its full title is "Standard Specification for Cast and Wrought Galvanic Zinc Anodes". This standard covers: ABSTRACT This specification covers cast and wrought galvanic zin anodes used for the cathodic protection of more noble metals and alloys in sea water, brackish water, other saline electrolytes, or other corrosive environments. The anodes shall undergo chemical analysis and spectrochemical analysis and shall conform to the required chemical compositions of aluminum, cadmium, iron, lead, copper, and zinc. SCOPE 1.1 This specification covers cast and wrought galvanic zinc anodes used for the cathodic protection of more noble metals and alloys in sea water, brackish water, other saline electrolytes, or other corrosive environments. 1.2 Type I anodes are most commonly used for such applications. The Type I anode composition in this specification meets the chemical composition requirements of MIL-A-18001K. 1.3 Zinc anodes conforming to this specification may be used in other waters, electrolytes, backfills, and soils where experience has shown that the specified composition is efficient and reliable. Type II anodes are most commonly used for such applications. 1.4 The values stated in inch-pound units are to be regarded as standard. The values given in parentheses are mathematical conversions to SI units that are provided for information only and are not considered standard. 1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to become familiar with all hazards including those identified in the appropriate Safety Data Sheet (SDS) for this product/material as provided by the manufacturer, to establish appropriate safety, health, and environmental practices, and determine the applicability of regulatory limitations prior to use. 1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
ABSTRACT This specification covers cast and wrought galvanic zin anodes used for the cathodic protection of more noble metals and alloys in sea water, brackish water, other saline electrolytes, or other corrosive environments. The anodes shall undergo chemical analysis and spectrochemical analysis and shall conform to the required chemical compositions of aluminum, cadmium, iron, lead, copper, and zinc. SCOPE 1.1 This specification covers cast and wrought galvanic zinc anodes used for the cathodic protection of more noble metals and alloys in sea water, brackish water, other saline electrolytes, or other corrosive environments. 1.2 Type I anodes are most commonly used for such applications. The Type I anode composition in this specification meets the chemical composition requirements of MIL-A-18001K. 1.3 Zinc anodes conforming to this specification may be used in other waters, electrolytes, backfills, and soils where experience has shown that the specified composition is efficient and reliable. Type II anodes are most commonly used for such applications. 1.4 The values stated in inch-pound units are to be regarded as standard. The values given in parentheses are mathematical conversions to SI units that are provided for information only and are not considered standard. 1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to become familiar with all hazards including those identified in the appropriate Safety Data Sheet (SDS) for this product/material as provided by the manufacturer, to establish appropriate safety, health, and environmental practices, and determine the applicability of regulatory limitations prior to use. 1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
ASTM B418-16a(2021) is classified under the following ICS (International Classification for Standards) categories: 25.220.01 - Surface treatment and coating in general. The ICS classification helps identify the subject area and facilitates finding related standards.
ASTM B418-16a(2021) has the following relationships with other standards: It is inter standard links to ASTM B899-16, ASTM B899-15, ASTM E536-15, ASTM B899-14, ASTM B949-13, ASTM B6-13, ASTM B899-13, ASTM B6-12, ASTM B899-09, ASTM B6-09, ASTM B899-09e1, ASTM B6-08, ASTM E29-08, ASTM B949-08, ASTM E536-08. Understanding these relationships helps ensure you are using the most current and applicable version of the standard.
ASTM B418-16a(2021) is available in PDF format for immediate download after purchase. The document can be added to your cart and obtained through the secure checkout process. Digital delivery ensures instant access to the complete standard document.
Standards Content (Sample)
This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the
Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
Designation:B418 −16a (Reapproved 2021)
Standard Specification for
Cast and Wrought Galvanic Zinc Anodes
This standard is issued under the fixed designation B418; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope 2. Referenced Documents
2.1 ASTM Standards:
1.1 This specification covers cast and wrought galvanic zinc
B6 Specification for Zinc
anodes used for the cathodic protection of more noble metals
B899 Terminology Relating to Non-ferrous Metals and Al-
and alloys in sea water, brackish water, other saline
loys
electrolytes, or other corrosive environments.
B949 Specification for General Requirements for Zinc and
1.2 Type I anodes are most commonly used for such
Zinc Alloy Products
applications. The Type I anode composition in this specifica-
E29 Practice for Using Significant Digits in Test Data to
tion meets the chemical composition requirements of MIL-A-
Determine Conformance with Specifications
18001K.
E527 Practice for Numbering Metals and Alloys in the
Unified Numbering System (UNS)
1.3 Zinc anodes conforming to this specification may be
E536 Test Methods for Chemical Analysis of Zinc and Zinc
used in other waters, electrolytes, backfills, and soils where
Alloys
experiencehasshownthatthespecifiedcompositionisefficient
2.2 Military Standard:
and reliable. Type II anodes are most commonly used for such
MIL-A-18001K w/INT. AMENDMENT 3, 24 October
applications.
2007 Military SpecificationAnodes Sacrificial ZincAlloy
1.4 The values stated in inch-pound units are to be regarded 4
2.3 ISO Standards:
as standard. The values given in parentheses are mathematical
ISO 3815-1 Zinc and zinc alloys — Part 1:Analysis of solid
conversions to SI units that are provided for information only
samples by optical emission spectrometry
and are not considered standard.
ISO 3815-2 Zinc and zinc alloys — Part 2: Analysis by
inductively coupled plasma optical emission spectrometry
1.5 This standard does not purport to address all of the
safety concerns, if any, associated with its use. It is the
3. Terminology
responsibility of the user of this standard to become familiar
with all hazards including those identified in the appropriate 3.1 Terms shall be defined in accordance with Terminology
Safety Data Sheet (SDS) for this product/material as provided B899.
by the manufacturer, to establish appropriate safety, health,
3.2 Definitions of Terms Specific to This Standard:
and environmental practices, and determine the applicability
3.2.1 cathodic protection, n—reduction of corrosion by
of regulatory limitations prior to use.
making the protected metal the cathode in a conducting
1.6 This international standard was developed in accor-
medium by applying direct current.
dance with internationally recognized principles on standard-
3.2.2 galvanic anode, n—a metal electrode that sacrificially
ization established in the Decision on Principles for the
corrodes when coupled to a more noble metal in a conducting
Development of International Standards, Guides and Recom-
medium, and thereby supplies a protective electric current to
mendations issued by the World Trade Organization Technical
the noble electrode.
Barriers to Trade (TBT) Committee.
For referenced ASTM standards, visit the ASTM website, www.astm.org, or
contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM
This specification is under the jurisdiction of ASTM Committee B02 on Standards volume information, refer to the standard’s Document Summary page on
Nonferrous Metals and Alloys and is the direct responsibility of Subcommittee the ASTM website.
B02.04 on Zinc and Cadmium. Available from DLA Document Services, Building 4/D, 700 Robbins Ave.,
Current edition approved April 1, 2021. Published April 2021. Originally Philadelphia, PA 19111-5094, http://quicksearch.dla.mil.
approved in 1964. Last previous edition approved in 2016 as B418 – 16a. DOI: Available fromAmerican National Standards Institute (ANSI), 25 W. 43rd St.,
10.1520/B0418-16AR21. 4th Floor, New York, NY 10036, http://www.ansi.org.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
B418−16a (2021)
TABLE 2 Minimum Number of Anodes in Sample
3.2.3 saline electrolyte, n—a solution consisting of mainly
the chlorides of the alkali metals. Minimum Number of
Number of Anodes in Lot
Anodes in Sample
4. Ordering Information 1to500 2
500 to 1000 3
4.1 Orders for zinc anodes under this specification shall
Each additional 1000 or part thereof 1
include information as specified in Specification B949.
4.2 Additional ordering information specific to this standard
in a lot shall be thoroughly mixed to form a uniform sample of
is as follows:
not less than 50 g total.
4.2.1 Type of anode material (see Table 1),
6.1.3 Other sampling procedures shall be in compliance
4.2.2 Number of anodes,
with the provisions of Specification B949.
4.2.3 Size of anode and whether contains rod insert and if
so, type of insert and whether contains bolt hole and if so,
7. Methods of Chemical Analysis
whether threaded.
7.1 The chemical compositions enumerated in this specifi-
cation shall, in case of disagreement, preferably be determined
5. Chemical Requirements
by methods mutually agreed upon or the methods listed in
5.1 The anode shall be made from Special High Grade zinc
Table 3 (note: spectrochemical methods may include
conforming to Specification B6, with
...




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