ASTM D4836-09(2023)
(Specification)Standard Specification for Dipropylene Glycol Monomethyl Ether
Standard Specification for Dipropylene Glycol Monomethyl Ether
ABSTRACT
This specification covers dipropylene glycol monomethyl ether (DPM). Dipropylene glycol monomethyl ether shall conform to the requirements specified for the following: (1) assay content, (2) distillation range defined by the initial boiling point and dry point, (3) apparent specific gravity, (4) platinum-cobalt scale color, (5) water content, and (6) acidity (free acid as acetic acid). The sampling and test methods to determine conformance to the specified properties are given.
SCOPE
1.1 This specification covers dipropylene glycol monomethyl ether (DPM).
Note 1: Dipropylene glycol monomethyl ether (DPM) is a mixture of isomers, the predominant isomer being 1-(2-methoxy-1-methylethoxy)-2-propanol.
1.2 The following applies to all specified limits in this standard; for purposes of determining conformance with this standard, an observed value or a calculated value shall be rounded off “to the nearest unit” in the last right-hand digit used in expressing the specification limit, in accordance with the rounding-off method of Practice E29.
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.4 For specific hazard information and guidance, consult the supplier’s Safety Data Sheet for materials listed in this standard.
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
General Information
- Status
- Published
- Publication Date
- 30-Jun-2023
- Technical Committee
- D01 - Paint and Related Coatings, Materials, and Applications
- Drafting Committee
- D01.35 - Solvents, Plasticizers, and Chemical Intermediates
Relations
- Effective Date
- 01-Jun-2012
- Effective Date
- 15-Nov-2011
- Effective Date
- 01-Jan-2010
- Effective Date
- 01-Apr-2009
- Effective Date
- 01-Oct-2008
- Effective Date
- 01-Jun-2007
- Effective Date
- 01-Jun-2007
- Effective Date
- 01-Jun-2007
- Effective Date
- 15-Nov-2006
- Effective Date
- 15-Sep-2006
- Effective Date
- 01-May-2006
- Effective Date
- 01-Apr-2006
- Effective Date
- 15-Oct-2005
- Effective Date
- 15-May-2005
- Effective Date
- 15-May-2005
Overview
ASTM D4836-09(2023), Standard Specification for Dipropylene Glycol Monomethyl Ether (DPM), establishes detailed requirements for the quality and properties of dipropylene glycol monomethyl ether. Developed by ASTM International, this standard ensures that DPM products meet consistent criteria for use in industrial, chemical, and coating applications. It covers parameters such as assay purity, distillation characteristics, specific gravity, color, water content, and acidity. Compliance with ASTM D4836 is essential for manufacturers, distributors, and end-users requiring reliable DPM quality for their operations.
Key Topics
- Assay Purity: Specifies the minimum content of dipropylene glycol monomethyl ether required, ensuring the chemical meets a high purity standard for industrial use.
- Distillation Range: Defines allowable ranges for initial boiling point and dry point, indicative of composition and purity consistency.
- Specific Gravity: Sets accepted values for apparent specific gravity at specified temperatures, supporting accurate identification of DPM batches.
- Color (Platinum-Cobalt Scale): Limits maximum color value to ensure product transparency and aesthetic quality.
- Water Content: Specifies the maximum allowable water presence to prevent negative impacts on chemical performance.
- Acidity: Sets a stringent limit on free acid content (as acetic acid), important for stability and compatibility in applications.
- Sampling and Test Methods: References standardized ASTM methods for verifying compliance, including D1078 (distillation), D1209 (color), D1364 (water), and D1613 (acidity).
Applications
Dipropylene glycol monomethyl ether (DPM) is widely used in industrial and commercial sectors due to its effective solvent properties and chemical stability. Key application areas include:
- Paints, Coatings, and Inks: Utilized as a high-performance solvent for water-based and solvent-based formulations, improving flow, leveling, and drying characteristics.
- Cleaning Agents: Incorporated in industrial cleaning formulations where excellent solvency and controlled evaporation are required.
- Chemical Processing: Serves as an intermediate in the manufacture of other chemicals and as a carrier or diluent for various formulations.
- Adhesives and Sealants: Used to adjust viscosity and improve the application properties of numerous adhesive and sealant systems.
- Personal Care and Household Products: Selected for its low odor and favorable environmental profile in select consumer products, always with careful review of compatibility and safety.
Adhering to ASTM D4836 ensures that DPM supplied for these applications consistently meets stringent industrial and regulatory requirements, enabling high product performance and safety.
Related Standards
Several other ASTM and international standards provide supporting guidance for quality control, testing, and safe handling of DPM and similar organic solvents:
- ASTM D1078 - Test Method for Distillation Range of Volatile Organic Liquids
- ASTM D1209 - Test Method for Color of Clear Liquids (Platinum-Cobalt Scale)
- ASTM D1364 - Test Method for Water in Volatile Solvents (Karl Fischer Reagent Titration)
- ASTM D1613 - Test Method for Acidity in Volatile Solvents and Chemical Intermediates
- ASTM D4052 - Test Method for Density, Relative Density, and API Gravity of Liquids by Digital Density Meter
- ASTM E300 - Practice for Sampling Industrial Chemicals
- PPP-C-2020 - U.S. Federal Specification for Chemicals Packaging
For comprehensive quality assurance and consistent manufacturing outcomes, it is recommended that DPM stakeholders reference these related documents alongside ASTM D4836-09(2023). This approach supports compliance with international trade and safety standards, contributing to a reliable supply chain for dipropylene glycol monomethyl ether.
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Frequently Asked Questions
ASTM D4836-09(2023) is a technical specification published by ASTM International. Its full title is "Standard Specification for Dipropylene Glycol Monomethyl Ether". This standard covers: ABSTRACT This specification covers dipropylene glycol monomethyl ether (DPM). Dipropylene glycol monomethyl ether shall conform to the requirements specified for the following: (1) assay content, (2) distillation range defined by the initial boiling point and dry point, (3) apparent specific gravity, (4) platinum-cobalt scale color, (5) water content, and (6) acidity (free acid as acetic acid). The sampling and test methods to determine conformance to the specified properties are given. SCOPE 1.1 This specification covers dipropylene glycol monomethyl ether (DPM). Note 1: Dipropylene glycol monomethyl ether (DPM) is a mixture of isomers, the predominant isomer being 1-(2-methoxy-1-methylethoxy)-2-propanol. 1.2 The following applies to all specified limits in this standard; for purposes of determining conformance with this standard, an observed value or a calculated value shall be rounded off “to the nearest unit” in the last right-hand digit used in expressing the specification limit, in accordance with the rounding-off method of Practice E29. 1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard. 1.4 For specific hazard information and guidance, consult the supplier’s Safety Data Sheet for materials listed in this standard. 1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
ABSTRACT This specification covers dipropylene glycol monomethyl ether (DPM). Dipropylene glycol monomethyl ether shall conform to the requirements specified for the following: (1) assay content, (2) distillation range defined by the initial boiling point and dry point, (3) apparent specific gravity, (4) platinum-cobalt scale color, (5) water content, and (6) acidity (free acid as acetic acid). The sampling and test methods to determine conformance to the specified properties are given. SCOPE 1.1 This specification covers dipropylene glycol monomethyl ether (DPM). Note 1: Dipropylene glycol monomethyl ether (DPM) is a mixture of isomers, the predominant isomer being 1-(2-methoxy-1-methylethoxy)-2-propanol. 1.2 The following applies to all specified limits in this standard; for purposes of determining conformance with this standard, an observed value or a calculated value shall be rounded off “to the nearest unit” in the last right-hand digit used in expressing the specification limit, in accordance with the rounding-off method of Practice E29. 1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard. 1.4 For specific hazard information and guidance, consult the supplier’s Safety Data Sheet for materials listed in this standard. 1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
ASTM D4836-09(2023) is classified under the following ICS (International Classification for Standards) categories: 71.080.60 - Alcohols. Ethers. The ICS classification helps identify the subject area and facilitates finding related standards.
ASTM D4836-09(2023) has the following relationships with other standards: It is inter standard links to ASTM D1613-06(2012), ASTM D1078-11, ASTM D5386-10, ASTM D891-09, ASTM E29-08, ASTM D1364-02(2007), ASTM D268-01(2007), ASTM D4773-02(2007), ASTM E29-06b, ASTM E29-06a, ASTM E29-06, ASTM D1613-06, ASTM D5386-05, ASTM D1078-05, ASTM D1209-05. Understanding these relationships helps ensure you are using the most current and applicable version of the standard.
ASTM D4836-09(2023) is available in PDF format for immediate download after purchase. The document can be added to your cart and obtained through the secure checkout process. Digital delivery ensures instant access to the complete standard document.
Standards Content (Sample)
This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the
Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
Designation: D4836 − 09 (Reapproved 2023)
Standard Specification for
Dipropylene Glycol Monomethyl Ether
This standard is issued under the fixed designation D4836; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope D1078 Test Method for Distillation Range of Volatile Or-
ganic Liquids
1.1 This specification covers dipropylene glycol monom-
D1209 Test Method for Color of Clear Liquids (Platinum-
ethyl ether (DPM).
Cobalt Scale)
NOTE 1—Dipropylene glycol monomethyl ether (DPM) is a mixture of
D1364 Test Method for Water in Volatile Solvents (Karl
isomers, the predominant isomer being 1-(2-methoxy-1-methylethoxy)-2-
Fischer Reagent Titration Method)
propanol.
D1613 Test Method for Acidity in Volatile Solvents and
1.2 The following applies to all specified limits in this
Chemical Intermediates Used in Paint, Varnish, Lacquer,
standard; for purposes of determining conformance with this
and Related Products
standard, an observed value or a calculated value shall be
D4052 Test Method for Density, Relative Density, and API
rounded off “to the nearest unit” in the last right-hand digit
Gravity of Liquids by Digital Density Meter
used in expressing the specification limit, in accordance with
D4773 Test Method for Purity of Propylene Glycol Monom-
the rounding-off method of Practice E29.
ethyl Ether, Dipropylene Glycol Monomethyl Ether, and
Propylene Glycol Monomethyl Ether Acetate (Withdrawn
1.3 The values stated in SI units are to be regarded as
standard. No other units of measurement are included in this 2021)
D5386 Test Method for Color of Liquids Using Tristimulus
standard.
Colorimetry
1.4 For specific hazard information and guidance, consult
E29 Practice for Using Significant Digits in Test Data to
the supplier’s Safety Data Sheet for materials listed in this
Determine Conformance with Specifications
standard.
E300 Practice for Sampling Industrial Chemicals
1.5 This international standard was developed in accor-
2.2 U.S. Federal Specification:
dance with internationally recognized principles on standard-
PPP-C-2020 Chemicals, Liquid, Dry, and Paste: Packaging
ization established in the Decision on Principles for the
of
Development of International Standards, Guides and Recom-
mendations issued by the World Trade Organization Technical
3. Properties
Barriers to Trade (TBT) Committee.
3.1 Dipropylene glycol monomethyl ether (DPM) shall
conform to the following requirements:
2. Referenced Documents
Assay, weight %, min 98.0
2.1 ASTM Standards:
Initial boiling point, min 184
D268 Guide for Sampling and Testing Volatile Solvents and Dry point, max 195
Apparent specific gravity:
Chemical Intermediates for Use in Paint and Related
20/20 °C 0.953 to 0.956
Coatings and Material
or
D891 Test Methods for Specific Gravity, Apparent, of Liquid 25/25 °C 0.949 to 0.952
Color, platinum-cobalt scale, max (Note 2) 15
Industrial Chemicals
Water, weight %, max 0.15
A
Acidity (free acid as acetic acid), weight %, max 0.01
A
Equivalent to 0.1 mg of potassium hydroxide (KOH) per 1 g of specimen.
This specification is under the jurisdiction of ASTM Committee D01 on Paint
and Related Coatings, Materials, and Applications and is the direct responsibility of
NOTE 2—Instrumental Pt-Co color determine
...
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