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ASTM G87-02

(Practice)

Standard Practice for Conducting Moist SO2 Tests

Standard Practice for Conducting Moist SO<sub>2</sub> Tests

SCOPE
1.1 This practice describes the apparatus and procedure to be used in conducting qualitative assessment tests in accordance with the requirements of material or product specifications by means of specimen exposure to condensed moisture containing sulfur dioxide.
1.2 The exposure conditions may be varied to suit particular requirements and this practice includes provisions for use of different concentrations of sulfur dioxide and for tests either running continuously or in cycles of alternate exposure to the sulfur dioxide containing atmosphere and to the ambient atmosphere.
1.3 The variant of the test to be used, the exposure period required, the type of test specimen, and the criteria of failure are not prescribed by this practice. Such details are provided in appropriate material and product purchase specifications.
1.4 The values stated in SI units are to be regarded as standard. The inch-pound values in parentheses may be approximate.
1.5 This standard does not purport to address all of the safety concerns, if any associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.  For specific hazard statements see 4.3.

General Information

Status
Historical
Publication Date
09-Oct-2002
ICS
77.060 - Corrosion of metals
Technical Committee
G01 - Corrosion of Metals
Drafting Committee
G01.05 - Laboratory Corrosion Tests
Current Stage
Ref Project

Relations

Replaces
ASTM G87-98 - Standard Practice for Conducting Moist SO<sub>2</sub> Tests
Effective Date
10-Oct-2002
Replaced By
ASTM G87-02(2007) - Standard Practice for Conducting Moist SO<sub>2</sub> Tests
Effective Date
01-May-2007
Referred By
ASTM D1654-08(2016)e1 - Standard Test Method for Evaluation of Painted or Coated Specimens Subjected to Corrosive Environments
Effective Date
10-Oct-2002
Referred By
ASTM D3794-22 - Standard Guide for Testing Coil Coatings
Effective Date
10-Oct-2002
Referred By
ASTM D6294/D6294M-13(2019) - Standard Test Method for Corrosion Resistance of Ferrous Metal Fastener Assemblies Used in Roofing and Waterproofing
Effective Date
10-Oct-2002
Referred By
ASTM D7893-13(2018) - Standard Guide for Corrosion Test Panel Preparation, Testing, and Rating of Coil-Coated Building Products
Effective Date
10-Oct-2002

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ASTM G87-02 - Standard Practice for Conducting Moist SO<sub>2</sub> TestsASTM G87-02 - Standard Practice for Conducting Moist SO<sub>2</sub> Tests
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ASTM G87-02 - Standard Practice for Conducting Moist SO<sub>2</sub> Tests
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Standards Content (Sample)

NOTICE: This standard has either been superseded and replaced by a new version or withdrawn.
Contact ASTM International (www.astm.org) for the latest information
Designation:G87–02
Standard Practice for
1
Conducting Moist SO Tests
2
ThisstandardisissuedunderthefixeddesignationG 87;thenumberimmediatelyfollowingthedesignationindicatestheyearoforiginal
adoption or, in the case of revision, the year of last revision.Anumber in parentheses indicates the year of last reapproval.Asuperscript
epsilon (e) indicates an editorial change since the last revision or reapproval.
1. Scope G 1 Practice for Preparing, Cleaning, and Evaluating Cor-
4
rosion Test Specimens
1.1 This practice describes the apparatus and procedure to
G 46 Guide for Examination and Evaluation of Pitting
be used in conducting qualitative assessment tests in accor-
4
Corrosion
dance with the requirements of material or product specifica-
tions by means of specimen exposure to condensed moisture
3. Significance and Use
containing sulfur dioxide.
3.1 Moist air containing sulfur dioxide quickly produces
1.2 The exposure conditions may be varied to suit particular
easily visible corrosion on many metals in a form resembling
requirements and this practice includes provisions for use of
that occurring in industrial environments. It is therefore a test
different concentrations of sulfur dioxide and for tests either
medium well suited to detect pores or other sources of
running continuously or in cycles of alternate exposure to the
weakness in protective coatings and deficiencies in corrosion
sulfur dioxide containing atmosphere and to the ambient
resistance associated with unsuitable alloy composition or
atmosphere.
treatments.
1.3 The variant of the test to be used, the exposure period
3.2 Theresultsobtainedinthetestshouldnotberegardedas
required, the type of test specimen, and the criteria of failure
a general guide to the corrosion resistance of the tested
are not prescribed by this practice. Such details are provided in
materials in all environments where these materials may be
appropriate material and product purchase specifications.
used. Performance of different materials in the test should only
1.4 The values stated in SI units are to be regarded as
be taken as a general guide to the relative corrosion resistance
standard. The inch-pound values in parentheses may be ap-
of these materials in moist SO service.
2
proximate.
1.5 This standard does not purport to address all of the
4. Apparatus
safety concerns, if any associated with its use. It is the
4.1 The apparatus required for moist SO testing consists of
2
responsibility of the user of this standard to establish appro-
3
a test chamber having an internal capacity of 300 L (10.6 ft ),
priate safety and health practices and determine the applica-
a supply of sulfur dioxide with metering device, specimen
bility of regulatory limitations prior to use. For specific hazard
supports, provisions for heating the chamber, and necessary
statements see 4.3.
means of control. The size and detailed construction of the
apparatus are optional, provided the conditions obtained meet
2. Referenced Documents
the requirements of this method. Suitable apparatus which may
2.1 ASTM Standards:
beusedtoobtaintheseconditionsisdescribedinAppendixX1.
D 714 Test Method for Evaluating Degree of Blistering of
2 4.2 Drops of condensing moisture which accumulate on the
Paints
3 ceiling of the chamber shall not be permitted to fall on the
D 1193 Specification for Reagent Water
specimens being tested.
D 1654 Test Method for Evaluation of Painted or Coated
2 4.3 Warning—Suck-back into cylinder may cause explo-
Specimens Subjected to Corrosive Environments
sion. Always use a check valve, vacuum break, or other
protective apparatus in any line or piping from cylinder to test
1
This practice is under the jurisdiction of ASTM Committee G01 on Corrosion chamber to prevent suck-back. Installation of the chamber
of Metals and is the direct responsibility of Subcommittee G01.05 on Laboratory
under a fume hood is recommended.
Corrosion Tests.
Current edition approved Oct. 10, 2002. Published February 2003. Originally
approved in 1997. Last previous edition approved in 1998 as G 87-98.
2
Annual Book of ASTM Standards, Vol 06.01.
3 4
Annual Book of ASTM Standards, Vol 11.01. Annual Book of ASTM Standards, Vol 03.02.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959, United States.
1

---------------------- Page: 1 ----------------------
G87–02
5. Reagents materials or protective film formers. Care in handling is
necessary so as not to recontaminate the test specimens.
5.1 Purity of Reagents—Reagent grade chemicals shall be
7.4.2 If test specimens are cut from a larger coated article,
used in all tests. Unless otherwise indicated, it is intended that
carry out the cutting in such a way that coating damage is
all reagents shall conform to the specifications of the Commit-
minimized in the area adjac
...

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Standard Practice for Conducting Moist SO2 Tests

SIGNIFICANCE AND USE
3.1 Moist air containing sulfur dioxide quickly produces easily visible corrosion on many metals in a form resembling that occurring in industrial environments. It is therefore a test medium well suited to detect pores or other sources of weakness in protective coatings and deficiencies in corrosion resistance associated with unsuitable alloy composition or treatments.  
3.2 The results obtained in the test should not be regarded as a general guide to the corrosion resistance of the tested materials in all environments where these materials may be used. Performance of different materials in the test should only be taken as a general guide to the relative corrosion resistance of these materials in moist SO2 service.
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1.1 This practice covers the apparatus and procedure to be used in conducting qualitative assessment tests in accordance with the requirements of material or product specifications by means of specimen exposure to condensed moisture containing sulfur dioxide.  
1.2 The exposure conditions may be varied to suit particular requirements and this practice includes provisions for use of different concentrations of sulfur dioxide and for tests either running continuously or in cycles of alternate exposure to the sulfur dioxide containing atmosphere and to the ambient atmosphere.  
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1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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Standard Practice for Determining the Susceptibility of Stainless Steels and Related Nickel-Chromium-Iron Alloys to Stress-Corrosion Cracking in Polythionic Acids

SIGNIFICANCE AND USE
4.1 Polythionic acids are chemically described as H2SxO6, where x is usually 3, 4, or 5 (1)3 though can be more than 50 (2). These acid environments provide a way of evaluating the resistance of stainless steels and related alloys to intergranular stress corrosion cracking. Failure is accelerated by the presence of increasing amounts of intergranular precipitate. Results for the polythionic acid test have not been correlated exactly with those of intergranular corrosion tests (Test Methods G28). Also, this test may not be relevant to stress corrosion cracking in chlorides or caustic environments.  
4.2 The polythionic acid environment may produce areas of shallow intergranular attack in addition to the more localized and deeper cracking mode of attack. Examination of failed specimens is necessary to confirm that failure occurred by cracking rather than mechanical failure of reduced sections.
SCOPE
1.1 This practice covers procedures for preparing and conducting the polythionic acid test at room temperature, 22 °C to 25 °C (72 °F to 77 °F), to determine the relative susceptibility of stainless steels or other related materials (nickel-chromium-iron alloys) to intergranular stress corrosion cracking.  
1.2 This practice can be used to evaluate stainless steels or other materials in the “as received” condition or after being subjected to high-temperature service, 482 °C to 815 °C (900 °F to 1500 °F), for prolonged periods of time.  
1.3 This practice can be applied to wrought products, castings, and weld metal of stainless steels or other related materials to be used in environments containing sulfur or sulfides. Other materials capable of being sensitized can also be tested in accordance with this test.  
1.4 This practice may be used with a variety of stress corrosion test specimens, surface finishes, and methods of applying stress.  
1.5 The values stated in SI units are to be regarded as standard. The values given in parentheses after SI units are provided for information only and are not considered standard.  
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5.1 This test method is designed to compare alloys and may be used as one method of screening materials prior to service. In general, this test method is more useful for stainless steels than the boiling magnesium chloride test of Practice G36. The boiling magnesium chloride test cracks materials with the nickel levels found in relatively resistant austenitic and duplex stainless steels, thus making comparisons and evaluations for many service environments difficult.  
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5.1 The U-bend specimen may be used for any metal alloy sufficiently ductile to be formed into the U-shape without mechanically cracking. The specimen is most easily made from strip or sheet but can be machined from plate, bar, castings, or weldments; wire specimens may be used also.  
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FIG. 1 Typical Stressed U-bends  
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5.1 Autoclave tests are commonly used to evaluate the corrosion performance of metallic and non-metallic materials under simulated HP and HTHP service conditions. Examples of service environments in which HP and HTHP corrosion tests have been used include chemical processing, petroleum production and refining, food processing, pressurized cooling water, electric power systems, and aerospace propulsion.  
5.2 For the applications of corrosion testing listed in 5.1, the service environment involves handling corrosive and potentially hazardous media under conditions of high pressure or high temperature, or both. The temperature and pressure, among other parameters, usually drive the composition and properties of the aqueous phase and, hence, the severity of the corrosion process. Consequently, the laboratory evaluation of corrosion severity cannot be performed in conventional low pressure glassware without making potentially invalid assumptions as to the potential effects of high temperature and pressure on corrosion severity.  
5.3 Therefore, there is a substantial need to provide standardized methods by which corrosion testing can be performed under HP and HTHP. In many cases, however, the standards used for exposure of specimens in conventional low-pressure glassware experiments cannot be followed due to the limitations of access, volume, and visibility arising from the construction of high-pressure test cells. This guide refers to existing corrosion standards and practices, as applicable, and then goes further in areas in which specific guidelines for performing HP and HTHP corrosion testing are needed.
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1.1 This guide covers procedures, specimens, and equipment for conducting laboratory corrosion tests on metallic materials under conditions of high pressure (HP) or the combination of high temperature and high pressure (HTHP). See 3.2 for definitions of high pressure and temperature.  
1.2 The procedures and methods in this guide are applicable for conducting mass loss corrosion, localized corrosion, and electrochemical tests as well as for use in environmentally induced cracking tests that need to be conducted under HP or HTHP conditions.  
1.3 The primary purpose for this guide is to promote consistency of corrosion test results. Furthermore, this guide will aid in the comparison of corrosion data between laboratories or testing organizations that utilize different equipment.  
1.4 The values stated in SI units are to be regarded as standard. The values given in parentheses after SI units are provided for information only and are not considered standard.  
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
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Standard Guide for Examination and Evaluation of Pitting Corrosion

SIGNIFICANCE AND USE
4.1 It is important to be able to determine the extent of pitting, either in a service application in which it is necessary to predict the remaining life in a metal structure, or in laboratory test programs that are used to select the most pitting-resistant materials for service. The purpose of the study is crucial in determining the appropriate examination and evaluation steps.  
4.2 Some typical purposes of laboratory tests include, but are not limited to, evaluating performance of alloys, determining whether an alloy is resistant to the environment, evaluating how environmental conditions including corrosion inhibitor affect or prevent pitting, and evaluating whether a lot of metal is sufficiently resistant for its use in a particular application or environment.  
4.3 Some typical purposes of field studies include, but are not limited to, determining if pits are likely to grow and cause leak or release of process fluid, and assisting a determination of whether to replace or repair damage from pits (remaining life assessment).
SCOPE
1.1 This guide covers the selection of procedures that can be used in the examination and evaluation of pitted metals. These procedures include both nondestructive and destructive approaches.  
1.2 The procedures covered in this guide include those that may be used in laboratory evaluations of corroded metal specimens and field examinations and inspections.  
1.3 The values stated in SI units are to be regarded as standard. The values given in parentheses after SI units are provided for information only and are not considered standard.  
1.3.1 Exception—In X1.2.1, mils per year (MPY) are regarded as standard for the target corrosion rate.  
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Standard Practice for Use of Mattsson's Solution of pH 7.2 to Evaluate the Stress-Corrosion Cracking Susceptibility of Copper-Zinc Alloys

SIGNIFICANCE AND USE
4.1 This test environment is believed to give an accelerated ranking of the relative or absolute degree of stress-corrosion cracking susceptibility for different brasses. It has been found to correlate well with the corresponding service ranking in environments that cause stress-corrosion cracking which is thought to be due to the combined presence of traces of moisture and ammonia vapor. The extent to which the accelerated ranking correlates with the ranking obtained after long-term exposure to environments containing corrodents other than ammonia is not at present known. Examples of such environments may be severe marine atmospheres (Cl−), severe industrial atmospheres (predominantly SO2), and super-heated ammonia-free steam.  
4.2 It is not possible at present to specify any particular time to failure (defined on the basis of any particular failure criteria) in pH 7.2 Mattsson’s solution that corresponds to a distinction between acceptable and unacceptable stress-corrosion behavior in brass alloys. Such particular correlations must be determined individually.  
4.3 Mattsson's solution of pH 7.2 may also cause stress independent general and intergranular corrosion of brasses to some extent. This leads to the possibility of confusing stress-corrosion failures with mechanical failures induced by corrosion-reduced net cross sections. This danger is particularly great with small cross section specimens, high applied stress levels, long exposure periods and stress-corrosion resistant alloys. Careful metallographic examination is recommended for correct diagnosis of the cause of failure. Alternatively, unstressed control specimens may be exposed to evaluate the extent to which stress independent corrosion degrades mechanical properties.
SCOPE
1.1 This practice covers the preparation and use of Mattsson’s solution of pH 7.2 as an accelerated stress-corrosion cracking test environment for brasses (copper-zinc base alloys). The variables (to the extent that these are known at present) that require control are described together with possible means for controlling and standardizing these variables.  
1.2 This practice is recommended only for brasses (copper-zinc base alloys). The use of this test environment is not recommended for other copper alloys since the results may be erroneous, providing completely misleading rankings. This is particularly true of alloys containing aluminum or nickel as deliberate alloying additions.  
1.3 This practice is intended primarily where the test objective is to determine the relative stress-corrosion cracking susceptibility of different brasses under the same or different stress conditions or to determine the absolute degree of stress corrosion cracking susceptibility, if any, of a particular brass or brass component under one or more specific stress conditions. Other legitimate test objectives for which this test solution may be used do, of course, exist. The tensile stresses present may be known or unknown, applied or residual. The practice may be applied to wrought brass products or components, brass castings, brass weldments, and so forth, and to all brasses. Strict environmental test conditions are stipulated for maximum assurance that apparent variations in stress-corrosion susceptibility are attributable to real variations in the material being tested or in the tensile stress level and not to environmental variations.  
1.4 This practice relates solely to the preparation and control of the test environment. No attempt is made to recommend surface preparation or finish, or both, as this may vary with the test objectives. Similarly, no attempt is made to recommend particular stress-corrosion test specimen configurations or methods of applying the stress. Test specimen configurations that may be used are referenced in Practice G30 and STP 425.2  
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Standard Test Method for Determining Whether Gas-Leak-Detector Fluid Solutions Can Cause Stress Corrosion Cracking of Brass Alloys

SIGNIFICANCE AND USE
5.1 Brass components are routinely used in compressed gas service for valves, pressure regulators, connectors and many other components. Although soft brass is not susceptible to ammonia SCC, work-hardened brass is susceptible if its hardness exceeds about 54 HR 30T (55HRB) (Rockwell scale). Normal assembly of brass components should not induce sufficient work hardening to cause susceptibility to ammonia SCC. However, it is has been observed that over-tightening of the components will render them susceptible to SCC, and the problem becomes more severe in older components that have been tightened many times. In this test, the specimens are obtained in the hardened condition and are strained beyond the elastic limit to accelerate the tendency towards SCC.  
5.2 It is normal practice to use LDFs to check pressurized systems to assure that leaking is not occurring. LDFs are usually aqueous solutions containing surfactants that will form bubbles at the site of a leak. If the LDF contains ammonia or other agent that can cause SCC in brass, serious damage can occur to the system that will compromise its safety and integrity.  
5.3 It is important to test LDFs to assure that they do not cause SCC of brass and to assure that the use of these products does not compromise the integrity of the pressure containing system.  
5.4 It has been found that corrosion of brass is necessary before SCC can occur. The reason for this is that the corrosion process results in cupric and cuprous ions accumulating in the electrolyte. Therefore, adding copper metal and cuprous oxide (Cu2O) to the aqueous solution accelerates the SCC process if agents that cause SCC are present. However, adding these components to a solution that does not cause SCC will not make stressed brass crack.  
5.5 Repeated application of the solution to the specimen followed by a drying period causes the components in the solution to concentrate thereby further increasing the rate of cracking. This also simulates se...
SCOPE
1.1 This test method covers an accelerated test method for evaluating the tendency of gas leak detection fluids (LDFs) to cause stress corrosion cracking (SCC) of brass components in compressed gas service.  
1.2 The values stated in inch-pound units are to be regarded as standard. The values given in parentheses are mathematical conversions to SI units that are provided for information only and are not considered standard.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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